Jump to content

Antimony(III) acetate: Difference between revisions

From Wikipedia, the free encyclopedia
Browse history interactively
← Previous edit
Content deleted Content added
VisualWikitext
m superscripting
 
(One intermediate revision by one other user not shown)
Line 23: Line 23:
| CASNo_Ref = {{cascite|correct|??}}
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 6923-52-0
| CASNo = 6923-52-0
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = F6Z6EKG4QY
| PubChem = 16685080
| PubChem = 16685080
| RTECS = AF4200000
| RTECS = AF4200000
Line 57: Line 59:


==Preparation==
==Preparation==
It can be prepared by the reaction of [[antimony(III) oxide]] with [[acetic acid]]:
It can be prepared by the reaction of [[antimony(III) oxide]] with [[acetic anhydride]]:


:Sb<sub>2</sub>O<sub>3</sub> + 6 CH<sub>3</sub>CO<sub>2</sub>H → 2 Sb(CH<sub>3</sub>CO<sub>2</sub>)<sub>3</sub> + 3 H<sub>2</sub>O
:Sb<sub>2</sub>O<sub>3</sub> + 3 C<sub>4</sub>H<sub>6</sub>O<sub>3</sub> → 2 Sb(CH<sub>3</sub>CO<sub>2</sub>)<sub>3</sub>


==Structure==
==Structure==

Latest revision as of 07:22, 29 August 2022

Antimony(III) acetate
Antimony(III) acetate
Names
IUPAC name
Antimony(III) acetate
Other names
Antimony triacetate
Acetic acid, antimony(3+) salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.027.312 Edit this at Wikidata
RTECS number
  • AF4200000
UNII
  • InChI=1S/3C2H4O2.Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3 checkY
    Key: JVLRYPRBKSMEBF-UHFFFAOYSA-K checkY
  • InChI=1/3C2H4O2.Sb.3H/c3*1-2(3)4;;;;/h3*1H3,(H,3,4);;;;/q;;;+3;;;/p-3/r3C2H4O2.H3Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);1H3/q;;;+3/p-3
    Key: NSMVVPJZMRQLMR-ZHOQVWKLAW
  • InChI=1/3C2H4O2.Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
    Key: JVLRYPRBKSMEBF-DFZHHIFOAU
  • O=C(C)O[Sb](OC(C)=O)OC(C)=O
Properties
Sb(CH3COO)3
Appearance White powder
Density 1.22 g/cm3 (20 °C)
Melting point 128.5 °C (263.3 °F; 401.6 K) (decomposes to Sb2O3)
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Lethal dose or concentration (LD, LC):
4480 mg/kg (rat)
NIOSH (US health exposure limits):
PEL (Permissible)
 TWA 0.5 mg/m3 (as Sb)[1]
REL (Recommended)
 TWA 0.5 mg/m3 (as Sb)[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Antimony(III) acetate is the compound of antimony with the chemical formula of Sb(CH3CO2)3. It is a white powder, is moderately water-soluble, and is used as a catalyst in the production of polyesters.

Preparation

[edit]

It can be prepared by the reaction of antimony(III) oxide with acetic anhydride:

Sb2O3 + 3 C4H6O3 → 2 Sb(CH3CO2)3

Structure

[edit]

The crystal structure of antimony(III) acetate has been determined by X-ray crystallography. It consists of discrete Sb(OAc)3 monomers with monodentate acetate ligands. The monomers are linked together into chains by weaker C=O···Sb intermolecular interactions.[2]

References

[edit]
  1. ^ a b NIOSH Pocket Guide to Chemical Hazards. "#0036". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ Hall, M.; Sowerby, D. B. (1980). "Antimony(III) acetate and thioacetate: spectra and crystal structures". J. Chem. Soc., Dalton Trans. (8): 1292–1296. doi:10.1039/DT9800001292.
Stub icon

This inorganic compound–related article is a stub. You can help Wikipedia by expanding it.

Retrieved from "https://en.wikipedia.org/enwiki/w/index.php?title=Antimony(III)_acetate&oldid=1107297413"