Antimony(III) acetate: Difference between revisions

Antimony(III) acetate
Names
	IUPAC name Antimony(III) acetate
	Other names Antimony triacetate; Acetic acid, antimony(3+) salt
Identifiers
CAS Number	6923-52-0 ;
3D model (JSmol)	Interactive image;
ChemSpider	21839 ;
ECHA InfoCard	100.027.312
PubChem CID	16685080;
RTECS number	AF4200000;
UNII	F6Z6EKG4QY ;
CompTox Dashboard (EPA)	DTXSID3029283 ;
	InChI InChI=1S/3C2H4O2.Sb/c31-2(3)4;/h31H3,(H,3,4);/q;;;+3/p-3 Key: JVLRYPRBKSMEBF-UHFFFAOYSA-K ; InChI=1/3C2H4O2.Sb.3H/c31-2(3)4;;;;/h31H3,(H,3,4);;;;/q;;;+3;;;/p-3/r3C2H4O2.H3Sb/c31-2(3)4;/h31H3,(H,3,4);1H3/q;;;+3/p-3 Key: NSMVVPJZMRQLMR-ZHOQVWKLAW; InChI=1/3C2H4O2.Sb/c31-2(3)4;/h31H3,(H,3,4);/q;;;+3/p-3 Key: JVLRYPRBKSMEBF-DFZHHIFOAU;
	SMILES O=C(C)O[Sb](OC(C)=O)OC(C)=O;
Properties
Chemical formula	Sb(CH3COO)3
Appearance	White powder
Density	1.22 g/cm3 (20 °C)
Melting point	128.5 °C (263.3 °F; 401.6 K) (decomposes to Sb2O3)
Hazards
NFPA 704 (fire diamond)	1 0 0
	Lethal dose or concentration (LD, LC):
LD50 (median dose)	4480 mg/kg (rat)
	NIOSH (US health exposure limits):
PEL (Permissible)	TWA 0.5 mg/m3 (as Sb)
REL (Recommended)	TWA 0.5 mg/m3 (as Sb)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

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Antimony(III) acetate is the compound of antimony with the chemical formula of Sb(CH₃CO₂)₃. It is a white powder, is moderately water-soluble, and is used as a catalyst in the production of polyesters.

Preparation

It can be prepared by the reaction of antimony(III) oxide with acetic anhydride:

Sb₂O₃ + 3 C₄H₆O₃ → 2 Sb(CH₃CO₂)₃

Structure

The crystal structure of antimony(III) acetate has been determined by X-ray crystallography. It consists of discrete Sb(OAc)₃ monomers with monodentate acetate ligands. The monomers are linked together into chains by weaker C=O···Sb intermolecular interactions.^[2]

References

^ ^a ^b NIOSH Pocket Guide to Chemical Hazards. "#0036". National Institute for Occupational Safety and Health (NIOSH).
^ Hall, M.; Sowerby, D. B. (1980). "Antimony(III) acetate and thioacetate: spectra and crystal structures". J. Chem. Soc., Dalton Trans. (8): 1292–1296. doi:10.1039/DT9800001292.

This inorganic compound–related article is a stub. You can help Wikipedia by expanding it.

[PGCH-1] NIOSH Pocket Guide to Chemical Hazards. "#0036". National Institute for Occupational Safety and Health (NIOSH).

[2] Hall, M.; Sowerby, D. B. (1980). "Antimony(III) acetate and thioacetate: spectra and crystal structures". J. Chem. Soc., Dalton Trans. (8): 1292–1296. doi:10.1039/DT9800001292.

[1]

[2]

@@ Line 1: / Line 1: @@
 {{chembox
+| Verifiedfields = changed
-| verifiedrevid = 399528978
+| Watchedfields = changed
-|   Name = Antimony(III) acetate
+| verifiedrevid = 429853293
-|   ImageFile = Antimony acetate.png
+| Name = Antimony(III) acetate
-|   ImageSize = 150px
-|   ImageName = Antimony(III) acetate
+| ImageFile = Antimony(III)-acetate-xtal-1980-CM-3D-balls.png
+| ImageSize = 250px
-|   IUPACName = Antimony(III) acetate
+| ImageName = Antimony(III) acetate
-|   OtherNames = Antimony triacetate<br />Acetic acid, antimony(3+) salt<br />Octan antimonity<
+| IUPACName = Antimony(III) acetate
-| Section1 = {{Chembox Identifiers
+| OtherNames = Antimony triacetate<br />Acetic acid, antimony(3+) salt
-|   SMILES = CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[SbH3+3]
+|Section1={{Chembox Identifiers
-|   ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
+| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
 | ChemSpiderID = 21839
 | InChI = 1/3C2H4O2.Sb.3H/c3*1-2(3)4;;;;/h3*1H3,(H,3,4);;;;/q;;;+3;;;/p-3/r3C2H4O2.H3Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);1H3/q;;;+3/p-3
@@ Line 15: / Line 16: @@
 | InChI1 = 1/3C2H4O2.Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
 | InChIKey1 = JVLRYPRBKSMEBF-DFZHHIFOAU
-| SMILES1 = CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Sb+3]
+| SMILES = O=C(C)O[Sb](OC(C)=O)OC(C)=O
 | StdInChI_Ref = {{stdinchicite|correct|chemspider}}
 | StdInChI = 1S/3C2H4O2.Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
 | StdInChIKey = JVLRYPRBKSMEBF-UHFFFAOYSA-K
+| CASNo_Ref = {{cascite|correct|??}}
 | CASNo = 6923-52-0
+| UNII_Ref = {{fdacite|correct|FDA}}
+| UNII = F6Z6EKG4QY
+| PubChem = 16685080
+| RTECS = AF4200000
   }}
-| Section2 = {{Chembox Properties
+|Section2={{Chembox Properties
-|   Formula = Sb(CH<sub>3</sub>COO)<sub>3</sub>
+| Formula = Sb(CH<sub>3</sub>COO)<sub>3</sub>
-|   MolarMass = 298.89 g/mol
+| Appearance = White powder
+| Density = 1.22 g/cm<sup>3</sup> (20 °C)
-|   Appearance = White powder
+| Solubility =
-|   Density = 1.22 g/cm³ (20 °C)
-|   Solubility =
+| MeltingPtC = 128.5
+| MeltingPt_notes = (decomposes to [[antimony(III) oxide|Sb<sub>2</sub>O<sub>3</sub>]])
-|   MeltingPtC = 127
-|   BoilingPt =
+| BoilingPt =
-|   pKa =
+| pKa =
-|   pKb =
+| pKb =
-|   Viscosity =
+| Viscosity =
   }}
-| Section3 = {{Chembox Structure
+|Section3={{Chembox Structure
-|   Coordination =
+| Coordination =
-|   CrystalStruct =
+| CrystalStruct =
-|   Dipole =
+| Dipole =
   }}
-| Section7 = {{Chembox Hazards
+|Section7={{Chembox Hazards
-|   MainHazards =
+| MainHazards =
-|   NFPA-H = 1
+| NFPA-H = 1
-|   NFPA-F = 0
+| NFPA-F = 0
-|   NFPA-R = 0
+| NFPA-R = 0
-|   LD50 = 4480 mg/kg (rat)
+| LD50 = 4480 mg/kg (rat)
+| REL = TWA 0.5 mg/m<sup>3</sup> (as Sb)<ref name=PGCH>{{PGCH|0036}}</ref>
+| PEL = TWA 0.5 mg/m<sup>3</sup> (as Sb)<ref name=PGCH/>
   }}
 }}
-'''Antimony(III) acetate''' is the [[antimony]] [[Salt (chemistry)|salt]] of [[acetic acid]] with the [[chemical formula]] of Sb(CH<sub>3</sub>COO)<sub>3</sub>. It has the appearance of a white powder and is used as a [[catalyst]] in the production of [[synthetic fiber]]s. It can be prepared by the reaction of antimony(III) oxide with acetic acid:
+'''Antimony(III) acetate''' is the compound of [[antimony]] with the [[chemical formula]] of Sb(CH<sub>3</sub>CO<sub>2</sub>)<sub>3</sub>. It is a white powder, is moderately water-soluble, and is used as a [[catalyst]] in the production of [[polyester]]s.
-: Sb<sub>2</sub>O<sub>3</sub> + 6 HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> → 2 Sb(C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)<sub>3</sub> + 3 H<sub>2</sub>O
+==Preparation==
-{{Antimony compounds}}
+It can be prepared by the reaction of [[antimony(III) oxide]] with [[acetic anhydride]]:
+:Sb<sub>2</sub>O<sub>3</sub>  +  3 C<sub>4</sub>H<sub>6</sub>O<sub>3</sub>  →   2 Sb(CH<sub>3</sub>CO<sub>2</sub>)<sub>3</sub>
-[[Category:Antimony compounds]]
-[[Category:Acetates]]
+==Structure==
+The crystal structure of antimony(III) acetate has been determined by [[X-ray crystallography]]. It consists of discrete Sb(OAc)<sub>3</sub> monomers with monodentate [[acetate]] ligands. The monomers are linked together into chains by weaker C=O···Sb [[intermolecular interaction]]s.<ref>{{ cite journal | journal = [[Dalton Transactions|J. Chem. Soc., Dalton Trans.]] | year = 1980 | pages = 1292–1296 | first1 = M. | last1 = Hall | first2 = D. B. | last2 = Sowerby | title = Antimony(III) acetate and thioacetate: spectra and crystal structures | doi = 10.1039/DT9800001292 | issue = 8 }}</ref>
+==References==
-{{inorganic-compound-stub}}
+{{reflist}}
+{{Inorganic-compound-stub}}
-[[ar:خلات أنتيموان ثلاثي]]
-[[nl:Antimoon(III)acetaat]]
+{{Antimony compounds}}
-[[zh:乙酸锑]]
+{{clear}}
+{{Acetates}}
+[[Category:Antimony(III) compounds]]
+[[Category:Acetates]]