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| ImageSize1 = 200
| ImageSize1 = 200
| ImageAlt1 = Tetrahydroxy-1,4-benzoquinone bisoxalate molecule
| ImageAlt1 = Tetrahydroxy-1,4-benzoquinone bisoxalate molecule
| PIN = Benzo[1,2-''b'':4,5-''b''′]bis([1,4]dioxine)hexone
| IUPACName =
| OtherNames =
| OtherNames = Benzo[1,2-b:4,5-b']bis-p-dioxin-2,3,5,7,8,10-hexone (8CI)
|Section1={{Chembox Identifiers
|Section1={{Chembox Identifiers
| CASNo =
| CASNo = 20068-66-0
| PubChem =
| PubChem = 85762080
| SMILES = O=C1C(OC2=O)=C(OC2=O)C(C3=C1OC(C(O3)=O)=O)=O }}
| SMILES = O=C1C(OC2=O)=C(OC2=O)C(C3=C1OC(C(O3)=O)=O)=O }}
|Section2={{Chembox Properties
|Section2={{Chembox Properties
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The compound was first described by [[H. S. Verter]], [[H. Porter]], and [[R. Dominic]] in 1968. It was obtained by reacting tetrahydroxy-1,4-benzoquinone with [[oxalyl chloride]] in [[tetrahydrofuran]]. It is a yellow solid that can be crystallized as a tetrahydrofuran [[solvate]], but could not be prepared in pure form.<ref name=verter>
The compound was first described by [[H. S. Verter]], [[H. Porter]], and [[R. Dominic]] in 1968. It was obtained by reacting tetrahydroxy-1,4-benzoquinone with [[oxalyl chloride]] in [[tetrahydrofuran]]. It is a yellow solid that can be crystallized as a tetrahydrofuran [[solvate]], but could not be prepared in pure form.<ref name=verter>
H. S. Verter, H. Porter, and R. Dominic (Verter, Porter and Dominic, 1968), ''A new carbon oxide: synthesis of tetrahydroxybenzoquinone bisoxalate''. Chemical Communications (London), p. 973b–974. {{doi|10.1039/C1968000973b}}
H. S. Verter, H. Porter, and R. Dominic (Verter, Porter and Dominic, 1968), ''A new carbon oxide: synthesis of tetrahydroxybenzoquinone bisoxalate''. Chemical Communications, p. 973b–974. {{doi|10.1039/C1968000973b}}
</ref>
</ref>


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{{Oxides of carbon}}
{{Oxides of carbon}}

{{chem-stub}}


[[Category:Oxocarbons]]
[[Category:Oxocarbons]]
[[Category:1,4-Benzoquinones]]
[[Category:1,4-Benzoquinones]]
[[Category:Oxalates]]
[[Category:Oxalate esters]]
[[Category:Oxygen heterocycles]]
[[Category:Oxygen heterocycles]]
[[Category:Heterocyclic compounds (3 rings)]]
[[Category:Heterocyclic compounds with 3 rings]]

Latest revision as of 19:13, 7 May 2023

Tetrahydroxy-1,4-benzoquinone bisoxalate
Tetrahydroxy-1,4-benzoquinone bisoxalate molecule
Names
Preferred IUPAC name
Benzo[1,2-b:4,5-b′]bis([1,4]dioxine)hexone
Other names
Benzo[1,2-b:4,5-b']bis-p-dioxin-2,3,5,7,8,10-hexone (8CI)
Identifiers
3D model (JSmol)
  • O=C1C(OC2=O)=C(OC2=O)C(C3=C1OC(C(O3)=O)=O)=O
Properties
C10O10
Molar mass 280.00 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tetrahydroxy-1,4-benzoquinone bisoxalate is a chemical compound, an oxide of carbon with formula C
10O
10. Its molecule consists of a 1,4-benzoquinone core with the four hydrogen atoms replaced by two oxalate groups. It can be seen as a fourfold ester of tetrahydroxy-1,4-benzoquinone and oxalic acid.

The compound was first described by H. S. Verter, H. Porter, and R. Dominic in 1968. It was obtained by reacting tetrahydroxy-1,4-benzoquinone with oxalyl chloride in tetrahydrofuran. It is a yellow solid that can be crystallized as a tetrahydrofuran solvate, but could not be prepared in pure form.[1]

See also

[edit]

References

[edit]
  1. ^ H. S. Verter, H. Porter, and R. Dominic (Verter, Porter and Dominic, 1968), A new carbon oxide: synthesis of tetrahydroxybenzoquinone bisoxalate. Chemical Communications, p. 973b–974. doi:10.1039/C1968000973b
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