Xenon nitrate: Difference between revisions
Content deleted Content added
xenon nitrate |
Alfa-ketosav (talk | contribs) m →top |
||
| (45 intermediate revisions by 17 users not shown) | |||
| Line 1: | Line 1: | ||
{{Short description|Chemical compound}} |
|||
'''Xenon nitrate''' is a hypothetical compound made by reacting [[xenon difluoride]] with ... It has not been detected yet. |
|||
{{Chembox |
|||
|Section1={{Chembox Identifiers |
|||
|SMILES = [O-][N+](=O)O[Xe]O[N+](=O)[O-] |
|||
|StdInChI=1S/N2O6Xe/c3-1(4)7-9-8-2(5)6 |
|||
|StdInChIKey=DDUBBJJTDIIEIU-UHFFFAOYSA-N |
|||
}} |
|||
|Section2={{Chembox Properties |
|||
|Xe=1|N=2|O=6 |
|||
}} |
|||
|Section3={{Chembox Related |
|||
|OtherCompounds = [[xenon fluoride nitrate|FXeNO<sub>3</sub>]] |
|||
}} |
|||
}} |
|||
'''Xenon nitrate''', also called '''xenon dinitrate''', is an [[inorganic compound]] consisting of one [[xenon]] atom bonded to two [[nitrate]] groups. It can be made by reacting [[xenon difluoride]] with [[anhydrous]] [[nitric acid]], but it only exists transiently before decomposing, and therefore it has not been isolated and fully characterized. A related compound, [[xenon fluoride nitrate]], has been made and is stable enough to be studied in more detail. |
|||
==Production== |
|||
Attempted production has used the following reaction:<ref name="MoranM2007">{{cite thesis|type=PhD|last=Moran|first=Matthew D.|title=Synthesis and Structural Characterization of new Xenon(II) Compounds and the Use of a Xenon(II) Cation as an Oxidant for the Preparation of Halogenated Hydrocarbons|url=https://macsphere.mcmaster.ca/bitstream/11375/14167/1/fulltext.pdf|access-date=4 Oct 2014|year=2007|publisher=McMaster University|pages=42, 99–145}}</ref><ref name="Eisenberg1970">{{cite journal|last=Eisenberg|first=Max|author2=Darryl D. DesMarteau|year=1970|title=The reaction of xenon difluoride with some strong oxy-acids|journal=Inorganic and Nuclear Chemistry Letters|volume=6|issue=1|pages=29–34|issn=0020-1650|doi=10.1016/0020-1650(70)80279-3}}</ref> |
|||
:XeF<sub>2</sub> + 2 HNO<sub>3</sub> → Xe(NO<sub>3</sub>)<sub>2</sub> + 2 HF |
|||
This reaction makes a red-brown solid. However, it decomposes spontaneously at 23 °C, turning blue temporarily while doing so:<ref name="Eisenberg1970"/> |
|||
:Xe(NO<sub>3</sub>)<sub>2</sub> → Xe + O<sub>2</sub>NOONO<sub>2</sub> (an unstable nitrogen [[main group peroxides|peroxide]]) |
|||
==References== |
|||
{{reflist}} |
|||
{{Xenon compounds}} |
|||
{{nitrates}} |
|||
{{noble gas compounds}} |
|||
[[Category:Xenon(II) compounds]] |
|||
[[Category:Nitrates]] |
|||
Latest revision as of 18:34, 16 March 2024
| Identifiers | |
|---|---|
3D model (JSmol)
|
|
| |
| |
| Properties | |
| N2O6Xe | |
| Molar mass | 255.301 g·mol−1 |
| Related compounds | |
Related compounds
|
FXeNO3 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Xenon nitrate, also called xenon dinitrate, is an inorganic compound consisting of one xenon atom bonded to two nitrate groups. It can be made by reacting xenon difluoride with anhydrous nitric acid, but it only exists transiently before decomposing, and therefore it has not been isolated and fully characterized. A related compound, xenon fluoride nitrate, has been made and is stable enough to be studied in more detail.
Production
[edit]Attempted production has used the following reaction:[1][2]
- XeF2 + 2 HNO3 → Xe(NO3)2 + 2 HF
This reaction makes a red-brown solid. However, it decomposes spontaneously at 23 °C, turning blue temporarily while doing so:[2]
- Xe(NO3)2 → Xe + O2NOONO2 (an unstable nitrogen peroxide)
References
[edit]- ^ Moran, Matthew D. (2007). Synthesis and Structural Characterization of new Xenon(II) Compounds and the Use of a Xenon(II) Cation as an Oxidant for the Preparation of Halogenated Hydrocarbons (PDF) (PhD). McMaster University. pp. 42, 99–145. Retrieved 4 Oct 2014.
- ^ a b Eisenberg, Max; Darryl D. DesMarteau (1970). "The reaction of xenon difluoride with some strong oxy-acids". Inorganic and Nuclear Chemistry Letters. 6 (1): 29–34. doi:10.1016/0020-1650(70)80279-3. ISSN 0020-1650.