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An '''oxalate chloride''' or '''oxalato chloride''' is a [[mixed anion compound]] contains both [[oxalate]] and [[chloride]] [[anion]]s.
An '''oxalate chloride''' or '''oxalato chloride''' is a [[mixed anion compound]] contains both [[oxalate]] and [[chloride]] [[anion]]s.


Related compounds include oxalate fluorides<ref name=":5" /> and oxalate bromides.<ref>{{Cite journal |last1=Lugwisha |first1=E. H. J. |last2=Mulokozi |first2=A. M. |last3=Masabo |first3=M. K. J. |date=November 1991 |title=Activation energy of thermal decomposition of LaC2O4Br |url=http://link.springer.com/10.1007/BF01912801 |journal=Journal of Thermal Analysis |language=en |volume=37 |issue=11–12 |pages=2567–2572 |doi=10.1007/BF01912801 |s2cid=95356620 |issn=0368-4466}}</ref>
Related compounds include [[Oxalate fluoride|oxalate fluorides]]<ref name=":5" /> and [[Oxalate bromide|oxalate bromides]].<ref>{{Cite journal |last1=Lugwisha |first1=E. H. J. |last2=Mulokozi |first2=A. M. |last3=Masabo |first3=M. K. J. |date=November 1991 |title=Activation energy of thermal decomposition of LaC2O4Br |url=http://link.springer.com/10.1007/BF01912801 |journal=Journal of Thermal Analysis |language=en |volume=37 |issue=11–12 |pages=2567–2572 |doi=10.1007/BF01912801 |s2cid=95356620 |issn=0368-4466}}</ref>


== Production ==
== Production ==
Oxalate chlorides may be produced by treating an oxalate salt with concentrated hydrochloric acid, or with a metal oxide dissolved in oxalic acid and hydrochloric acid solutions that are evaporated.<ref>{{Cite journal |last=Mulokozi |first=A.M. |date=June 1972 |title=The nature of products obtained from the reaction of hydrogen halides with some rare-earth metal oxalate hydrates |url=https://linkinghub.elsevier.com/retrieve/pii/0022508872900756 |journal=Journal of the Less Common Metals |language=en |volume=27 |issue=3 |pages=419–422 |doi=10.1016/0022-5088(72)90075-6}}</ref>
Oxalate chlorides may be produced by treating an oxalate salt with concentrated hydrochloric acid, or with a metal oxide dissolved in [[oxalic acid]] and [[hydrochloric acid]] solutions that are evaporated.<ref>{{Cite journal |last=Mulokozi |first=A.M. |date=June 1972 |title=The nature of products obtained from the reaction of hydrogen halides with some rare-earth metal oxalate hydrates |url=https://linkinghub.elsevier.com/retrieve/pii/0022508872900756 |journal=Journal of the Less Common Metals |language=en |volume=27 |issue=3 |pages=419–422 |doi=10.1016/0022-5088(72)90075-6}}</ref>


==List==
==List==
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|monoclinic
|monoclinic
|''I''2/''m''
|''I''2/''m''
|a= 6.936 b= 7.382 c= 7.443 β= 94.3°
|a=6.936 b=7.382 c=7.443 β=94.3°
|
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|
|
|looses water at 25°C to 2H<sub>2</sub>O; refract: α=1.571 β=1.648 γ=1.718 2V=87° (−)
|looses water at 25°C to 2H<sub>2</sub>O; refract: α=1.571 β=1.648 γ=1.718 2V=87° (−)
|<ref name=":1" /><ref>{{Cite journal |last1=Piro |first1=Oscar E. |last2=Echeverría |first2=Gustavo A. |last3=González-Baró |first3=Ana C. |last4=Baran |first4=Enrique J. |date=February 2018 |title=Crystal structure and spectroscopic behavior of synthetic novgorodovaite Ca2(C2O4)Cl2·2H2O and its twinned triclinic heptahydrate analog |url=http://link.springer.com/10.1007/s00269-017-0907-0 |journal=Physics and Chemistry of Minerals |language=en |volume=45 |issue=2 |pages=185–195 |doi=10.1007/s00269-017-0907-0 |s2cid=103745968 |issn=0342-1791}}</ref>
|<ref name=":1" /><ref>{{Cite journal |last1=Piro |first1=Oscar E. |last2=Echeverría |first2=Gustavo A. |last3=González-Baró |first3=Ana C. |last4=Baran |first4=Enrique J. |date=February 2018 |title=Crystal structure and spectroscopic behavior of synthetic novgorodovaite Ca2(C2O4)Cl2·2H2O and its twinned triclinic heptahydrate analog |url=http://link.springer.com/10.1007/s00269-017-0907-0 |journal=Physics and Chemistry of Minerals |language=en |volume=45 |issue=2 |pages=185–195 |doi=10.1007/s00269-017-0907-0 |s2cid=103745968 |issn=0342-1791|hdl=11336/87551 |hdl-access=free }}</ref>
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|<ref name=":3" />
|<ref name=":3" />
|-
|DABCO=1,4-diazabicyclo[2.2.2]octane;
|(DABCO-H<sup>+</sup>)<sub>2</sub>(DABCO-2H<sup>2+</sup>)[Mn<sup>II</sup>(CH<sub>3</sub>OH)(Cl<sup>−</sup>)Cr<sup>III</sup>(oxalate)<sub>3</sub>]<sup>2−</sup><sub>2</sub>(CH<sub>3</sub>OH)
|triclinic
|''P''{{overbar|1}}
|''a''=8.093 ''b''=9.070 ''c''=19.574 ''α''=83.471° ''β''=89.875° ''γ''=86.765°
|
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|<ref>{{Cite journal |last1=Yoshitake |first1=Masashi |last2=Kubo |first2=Kazuya |last3=Endo |first3=Toru |last4=Noro |first4=Shin-ichiro |last5=Akutagawa |first5=Tomoyuki |last6=Nakamura |first6=Takayoshi |date=2016-03-15 |title=Structural Design of Coordination Polymers Based on Manganese and Chromium Ions Bridged by Oxalate Ligands |url=https://academic.oup.com/bcsj/article/89/3/354/7344617 |journal=Bulletin of the Chemical Society of Japan |language=en |volume=89 |issue=3 |pages=354–360 |doi=10.1246/bcsj.20150373 |issn=0009-2673}}</ref>
|-
|-
|tetrakis(methylammonium) tetrakis(μ-oxalato)-octachloro-tetra-iron(iii) pentahydrate
|tetrakis(methylammonium) tetrakis(μ-oxalato)-octachloro-tetra-iron(iii) pentahydrate
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|
|
|<ref name=":2" />
|<ref name=":2" />
|-
|DMF = dimethylformamide
|Fe<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)Cl<sub>4</sub>(DMF)<sub>4</sub>
|triclinic
|''P''{{overbar|1}}
|''a''=8.3919 ''b''=8.7834 ''c''=11.2881 ''α''=70.248° ''β''=71.993° ''γ''=64.423°
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|<ref>{{Cite journal |last1=Zhang |first1=Bin |last2=Zhang |first2=Yan |last3=Kurmoo |first3=Mohamedally |date=May 2007 |title=Preparation, crystal structure and magnetic property of a binuclear oxalate-bridged iron(III) compound: Fe2(C2O4)Cl4(DMF)4 (DMF=dimethylformamide) |url=https://linkinghub.elsevier.com/retrieve/pii/S0020169306006815 |journal=Inorganica Chimica Acta |language=en |volume=360 |issue=7 |pages=2513–2517 |doi=10.1016/j.ica.2006.10.028}}</ref>
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|<ref>{{Cite journal |last1=Cot |first1=Sergi |last2=Leu |first2=Meike K. |last3=Kalamiotis |first3=Alexis |last4=Dimitrakis |first4=Georgios |last5=Sans |first5=Victor |last6=de Pedro |first6=Imanol |last7=Cano |first7=Israel |date=July 2019 |title=An Oxalate-Bridged Binuclear Iron(III) Ionic Liquid for the Highly Efficient Glycolysis of Polyethylene Terephthalate under Microwave Irradiation |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cplu.201900075 |journal=ChemPlusChem |language=en |volume=84 |issue=7 |pages=786–793 |doi=10.1002/cplu.201900075 |pmid=31943995 |s2cid=196896383 |issn=2192-6506}}</ref>
|<ref>{{Cite journal |last1=Cot |first1=Sergi |last2=Leu |first2=Meike K. |last3=Kalamiotis |first3=Alexis |last4=Dimitrakis |first4=Georgios |last5=Sans |first5=Victor |last6=de Pedro |first6=Imanol |last7=Cano |first7=Israel |date=July 2019 |title=An Oxalate-Bridged Binuclear Iron(III) Ionic Liquid for the Highly Efficient Glycolysis of Polyethylene Terephthalate under Microwave Irradiation |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cplu.201900075 |journal=ChemPlusChem |language=en |volume=84 |issue=7 |pages=786–793 |doi=10.1002/cplu.201900075 |pmid=31943995 |hdl=10234/185443 |s2cid=196896383 |issn=2192-6506|hdl-access=free }}</ref>
|-
|-
|L<small><sub>2</sub></small>=1,4-bis(imidazol-1-ylmethyl)benzene
|L<sub>2</sub>=1,4-bis(imidazol-1-ylmethyl)benzene
bis(1,1'-(1,4-Phenylenebis(methylene))bis-1H-imidazol-3-ium) (μ<sub>2</sub>-oxalato)-tetrachloro-bis(oxalato)-di-iron(iii)
bis(1,1'-(1,4-Phenylenebis(methylene))bis-1H-imidazol-3-ium) (μ<sub>2</sub>-oxalato)-tetrachloro-bis(oxalato)-di-iron(iii)
|(H<small><sub>2</sub></small>-L<small><sub>2</sub></small>)<small><sub>2</sub></small>{Fe<small><sub>2</sub></small>(C<small><sub>2</sub></small>O<small><sub>4</sub></small>)<small><sub>3</sub></small>Cl<small><sub>4</sub></small>}
|(H<sub>2</sub>-L<sub>2</sub>)<sub>2</sub>{Fe<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>Cl<sub>4</sub>}
|triclinic
|triclinic
|''P''{{overbar|1}}
|''P''{{overbar|1}}
|''a'' 10.6758 ''b'' 10.7457 ''c'' 10.8774 ''α'' 113.219° ''β'' 109.138° ''γ'' 99.294° Z=1
|''a''=10.6758 ''b''=10.7457 ''c''=10.8774 ''α''=113.219° ''β''=109.138° ''γ''=99.294° Z=1
|1020.8
|1020.8
|1.624
|1.624
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|-
|-
|tetramelaminium trioxalatoferrate(III) chloride dihydrate
|tetramelaminium trioxalatoferrate(III) chloride dihydrate
|(C<sub>3</sub>H<sub>7</sub>N<sub>6</sub>)<small><sub>4</sub></small>{Fe(C<small><sub>2</sub></small>O<small><sub>4</sub></small>)<small><sub>3</sub></small>}Cl·2H<small><sub>2</sub></small>O
|(C<sub>3</sub>H<sub>7</sub>N<sub>6</sub>)<sub>4</sub>{Fe(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>}Cl·2H<sub>2</sub>O
|monoclinic
|monoclinic
|''P''2<sub>1</sub>/''c''
|''P''2<sub>1</sub>/''c''
Line 141: Line 161:
|diethylmethylammonium
|diethylmethylammonium
|[NH(CH<sub>3</sub>)(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub>][FeCl<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)]
|[NH(CH<sub>3</sub>)(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub>][FeCl<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)]
|monoclinic
|
|''P''2<sub>1</sub>/c
|''P''2<sub>1</sub>/c
|a=8.5125 b=10.775 c=14.9703 ''β''=104.798° Z=4
|a=8.5125 b=10.775 c=14.9703 ''β''=104.798° Z=4
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|yellow; proton conductor
|yellow; proton conductor
|<ref>{{Cite journal |last1=Burazer |first1=Sanja |last2=Molčanov |first2=Krešimir |last3=Šantić |first3=Ana |last4=Klaser |first4=Teodoro |last5=Wenger |first5=Emmanuel |last6=Pajić |first6=Damir |last7=Jagličić |first7=Zvonko |last8=Popović |first8=Jasminka |last9=Jurić |first9=Marijana |date=2021-09-24 |title=Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility |journal=Materials |language=en |volume=14 |issue=19 |pages=5543 |doi=10.3390/ma14195543 |doi-access=free |pmid=34639934 |pmc=8509436 |bibcode=2021Mate...14.5543B |issn=1996-1944}}</ref>
|<ref>{{Cite journal |last1=Burazer |first1=Sanja |last2=Molčanov |first2=Krešimir |last3=Šantić |first3=Ana |last4=Klaser |first4=Teodoro |last5=Wenger |first5=Emmanuel |last6=Pajić |first6=Damir |last7=Jagličić |first7=Zvonko |last8=Popović |first8=Jasminka |last9=Jurić |first9=Marijana |date=2021-09-24 |title=Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility |journal=Materials |language=en |volume=14 |issue=19 |pages=5543 |doi=10.3390/ma14195543 |doi-access=free |pmid=34639934 |pmc=8509436 |bibcode=2021Mate...14.5543B |issn=1996-1944}}</ref>
|-
|bis(Tetramethylammonium) bis(μ<sub>2</sub>-oxalato)-tetrachloro-di-iron(iii)
|Me<sub>4</sub>N[Fe<sup>III</sup>(ox)Cl<sub>2</sub>]
|monoclinic
|''P''2<sub>1</sub>/c
|''a''=7.9441 ''b''=8.6093 ''c''=17.8251 ''β''=91.869
|
|
|
|<ref name=":9">{{Cite journal |last1=Xu |first1=Hong-Bin |last2=Wang |first2=Zhe-Ming |last3=Liu |first3=Tao |last4=Gao |first4=Song |date=2007-04-01 |title=Synthesis, Structure, and Magnetic Properties of (A)[Fe III (oxalate)Cl 2 ] (A = Alkyl Ammonium Cations) with Anionic 1D [Fe III (oxalate)Cl 2 ] - Chains |url=https://pubs.acs.org/doi/10.1021/ic0618854 |journal=Inorganic Chemistry |language=en |volume=46 |issue=8 |pages=3089–3096 |doi=10.1021/ic0618854 |pmid=17352466 |issn=0020-1669}}</ref>
|-
|hexakis(Triethylammonium) hexakis(μ<sub>2</sub>-oxalato)-dodecachloro-hexa-iron(iii)
|Et<sub>3</sub>NH[Fe<sup>III</sup>(ox)Cl<sub>2</sub>]
|triclinic
|''P''{{overbar|1}}
|''a''=10.9609 ''b''=14.4602 ''c''=14.5780 ''α''=85.006° ''β''=78.845° ''γ''=83.0191
|
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|
|<ref name=":9" />
|-
|Triethylammonium (μ<sub>2</sub>-oxalato)-dichloro-iron(iii)
|Et<sub>3</sub>NH[Fe<sup>III</sup>(ox)Cl<sub>2</sub>]
|orthorhombic
|''Fdd''2
|''a''=13.5878 ''b''=37.972 ''c''=10.8210
|
|
|
|<ref name=":9" />
|-
|bis(Tetra-n-butylammonium) bis(μ<sub>2</sub>-oxalato)-tetrachloro-di-iron(iii)
|''n''-Bu<sub>4</sub>N[Fe<sup>III</sup>(ox)Cl<sub>2</sub>]
|monoclinic
|''P''2<sub>1</sub>/c
|''a''=8.8836 ''b''=15.1939 ''c''=17.968 ''β''=91.556°
|
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|<ref name=":9" />
|-
|
|[Fe(oxalato)Cl<sub>2</sub>]<sub>3</sub>(3,5-dimethylpyrazole)<sub>2</sub>(3,5- dimethylpyrazolium)<sub>2</sub>
|monoclinic
|''C''2/''c''
|a=19.527 b=11.867 c=19.429 ''β''=115.66° Z=4
|4058.20
|1.684
|green
|<ref>{{Cite journal |title=Oxalate-Bridged Binuclear Iron (III) Complexes of 3, 5-Dimethylpyrazole Ligands: Synthesis, Structure, Spectral and Electrochemical Properties |journal=International Journal of Chemical Engineering |volume=31 |issue=2 |pages=1179}}</ref>
|-
|-
|BETS = Bis(ethylenedithio)tetraselenafulvalene
|BETS = Bis(ethylenedithio)tetraselenafulvalene
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|black; metallic;
|black; metallic;
|<ref>{{Cite journal |last1=Zhang |first1=Bin |last2=Wang |first2=Zheming |last3=Zhang |first3=Yan |last4=Takahashi |first4=Kazuyuki |last5=Okano |first5=Yoshinori |last6=Cui |first6=Hengbo |last7=Kobayashi |first7=Hayao |last8=Inoue |first8=Katsuya |last9=Kurmoo |first9=Mohamedally |last10=Pratt |first10=Francis L. |last11=Zhu |first11=Daoben |date=2006-04-17 |title=Hybrid Organic−Inorganic Conductor with a Magnetic Chain Anion: κ-BETS 2 [Fe III (C 2 O 4 )Cl 2 ] [BETS = Bis(ethylenedithio)tetraselenafulvalene] |url=https://pubs.acs.org/doi/10.1021/ic051870q |journal=Inorganic Chemistry |language=en |volume=45 |issue=8 |pages=3275–3280 |doi=10.1021/ic051870q |pmid=16602784 |issn=0020-1669}}</ref>
|<ref>{{Cite journal |last1=Zhang |first1=Bin |last2=Wang |first2=Zheming |last3=Zhang |first3=Yan |last4=Takahashi |first4=Kazuyuki |last5=Okano |first5=Yoshinori |last6=Cui |first6=Hengbo |last7=Kobayashi |first7=Hayao |last8=Inoue |first8=Katsuya |last9=Kurmoo |first9=Mohamedally |last10=Pratt |first10=Francis L. |last11=Zhu |first11=Daoben |date=2006-04-17 |title=Hybrid Organic−Inorganic Conductor with a Magnetic Chain Anion: κ-BETS 2 [Fe III (C 2 O 4 )Cl 2 ] [BETS = Bis(ethylenedithio)tetraselenafulvalene] |url=https://pubs.acs.org/doi/10.1021/ic051870q |journal=Inorganic Chemistry |language=en |volume=45 |issue=8 |pages=3275–3280 |doi=10.1021/ic051870q |pmid=16602784 |issn=0020-1669}}</ref>
|-
|bis(2-(5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-1-ium) bis(μ-oxalato)-tetrachloro-di-iron(iii)
|[BEDT-TTF][Fe(C<sub>2</sub>O<sub>4</sub>)Cl<sub>2</sub>]
|triclinic
|''P''{{overbar|1}}
|''a''=8.896 ''b''=11.401 ''c''=11.427 ''α''=112.062° ''β''=103.775° ''γ''=100.328°
|
|
|
|<ref>{{Cite journal |last1=Zhang |first1=B. |last2=Zhang |first2=Y. |last3=Wang |first3=Z. |last4=Yang |first4=D. |last5=Gao |first5=Z. |last6=Wang |first6=D. |last7=Guo |first7=Y. |last8=Zhu |first8=D. |last9=Mori |first9=T. |date=2016 |title=[BEDT-TTF][Fe(C 2 O 4 )Cl 2 ]: an organic–inorganic hybrid semiconductive antiferromagnet |url=http://xlink.rsc.org/?DOI=C6DT01845A |journal=Dalton Transactions |language=en |volume=45 |issue=42 |pages=16561–16565 |doi=10.1039/C6DT01845A |pmid=27344978 |issn=1477-9226}}</ref>
|-
|BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene
|(BEDT-TTF)[Fe(C<sub>2</sub>O<sub>4</sub>)Cl<sub>2</sub>](CH<sub>2</sub>Cl<sub>2</sub>)
|monoclinic
|''P''2<sub>1</sub>/''c''
|''a''=8.858 ''b''=11.012 ''c''=14.932 ''β''=103.39°
|
|
|
|<ref>{{Cite journal |last1=Zhang |first1=Bin |last2=Zhang |first2=Yan |last3=Gao |first3=Zengqiang |last4=Chang |first4=Guangcai |last5=Su |first5=Shaokui |last6=Wang |first6=Dongwei |last7=Guo |first7=Yanjun |last8=Zhu |first8=Daoben |date=August 2014 |title=Synthesis, Crystal Structure, and Characterization of the Charge-Transfer Salt (BEDT-TTF)[Fe(C 2 O 4 )Cl 2 ](CH 2 Cl 2 ), {BEDT‐TTF = Bis(ethylenedithio)tetrathiafulvalene} |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201402112 |journal=European Journal of Inorganic Chemistry |language=en |volume=2014 |issue=24 |pages=4028–4032 |doi=10.1002/ejic.201402112 |issn=1434-1948}}</ref>
|-
|tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate
|[Co(en)<sub>3</sub>]Cl(C<sub>2</sub>O<sub>4</sub>)·3H<sub>2</sub>O
|monoclinic
|''C''2/''c''
|''a'' = 19.932 ''b'' = 9.3344 ''c'' = 19.088 ''β'' = 96.846° ''Z'' = 8
|
|
|
|<ref>{{Cite journal |last1=Jone Kirubavathy |first1=S. |last2=Velmurugan |first2=R. |last3=Parameswari |first3=K. |last4=Chitra |first4=S. |date=November 2019 |title=Synthesis, characterization, single crystal XRD, in vitro antimicrobial and cytotoxicity study of tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate |journal=Arabian Journal of Chemistry |language=en |volume=12 |issue=7 |pages=1581–1586 |doi=10.1016/j.arabjc.2014.10.013|doi-access=free }}</ref>
|-
|dpyam=di-2-pyridylamine; (μ<sub>2</sub>-Oxalato)-bis(di-2-pyridylamine)-dichloro-di-copper(ii)
|Cu<sub>2</sub>(dpyam)<sub>2</sub>(μ-C<sub>2</sub>O<sub>4</sub>)(Cl)<sub>2</sub>
|triclinic
|''P''{{overbar|1}}
|''a''=7.4122 ''b''=8.6586 ''c''=9.8002 ''α''=87.900° ''β''=72.022° ''γ''=71.845°
|
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|
|<ref>{{Cite journal |last1=Youngme |first1=Sujittra |last2=Cheansirisomboon |first2=Achareeya |last3=Danvirutai |first3=Chanaiporn |last4=Chaichit |first4=Narongsak |last5=Pakawatchai |first5=Chaveng |last6=van Albada |first6=Gerard A. |last7=Reedijk |first7=Jan |date=September 2006 |title=Two new oxalato-bridged dinuclear copper(II) complexes with di-2-pyridylamine: crystal structures, spectroscopic and magnetic properties |url=https://linkinghub.elsevier.com/retrieve/pii/S1387700306001924 |journal=Inorganic Chemistry Communications |language=en |volume=9 |issue=9 |pages=973–977 |doi=10.1016/j.inoche.2006.05.022}}</ref>
|-
|L = 3,5-dimethyl-1''H''-pyrazole
|Cu<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)(L)<sub>2</sub>Cl<sub>2</sub>(MeOH)<sub>2</sub>
|triclinic
|''P''{{overbar|1}}
|''a''=7.244 ''b''=8.039 ''c''=8.848 ''α''=92.16° ''β''=92.73° ''γ''=96.21°
|
|
|
|<ref>{{Cite journal |last1=Bahemmat |first1=Samira |last2=Neumüller |first2=Bernhard |last3=Ghassemzadeh |first3=Mitra |date=August 2015 |title=One-Pot Synthesis of an Oxalato-Bridged Cu II Coordination Polymer Containing an In Situ Produced Pyrazole Moiety: A Precursor for the Preparation of CuO Nanostructures |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201500255 |journal=European Journal of Inorganic Chemistry |language=en |volume=2015 |issue=24 |pages=4116–4124 |doi=10.1002/ejic.201500255 |issn=1434-1948}}</ref>
|-
|bpy=bipyridine
|[Fe(bpy)<sub>3</sub>]<sub>2</sub>[NbO(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]Cl·11H<sub>2</sub>O
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|<ref name=":11">{{Cite journal |last1=Jurić |first1=Marijana |last2=Perić |first2=Berislav |last3=Brničević |first3=Nevenka |last4=Planinić |first4=Pavica |last5=Pajić |first5=Damir |last6=Zadro |first6=Krešo |last7=Giester |first7=Gerald |last8=Kaitner |first8=Branko |date=2008 |title=Supramolecular motifs and solvatomorphism within the compounds [M(bpy) 3 ] 2 [NbO(C 2 O 4 ) 3 ]Cl·nH 2 O (M = Fe 2+ , Co 2+ , Ni 2+ , Cu 2+ and Zn 2+ ; n = 11, 12). Syntheses, structures and magnetic properties |url=http://xlink.rsc.org/?DOI=B707937K |journal=Dalton Trans. |language=en |issue=6 |pages=742–754 |doi=10.1039/B707937K |pmid=18239829 |issn=1477-9226}}</ref>
|-
|
|[Fe(bpy)<sub>3</sub>]<sub>2</sub>[NbO(<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]Cl·12H<sub>2</sub>O
|orthorhombic
|''P''2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>
|a=14.975 b=21.708 c=22.351 Z=4
|7266
|1.530
|dark red
|<ref name=":11" />
|-
|
|[Co(bpy)<sub>3</sub>]<sub>2</sub>[NbO(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]Cl·11H<sub>2</sub>O
|monoclinic
|''P''2<sub>1</sub>/''c''
|a=23.548 b=13.631 c=22.812 ''β''=101.04
|7187
|1.536
|orange red
|<ref name=":11" />
|-
|
|[Co(bpy)<sub>3</sub>]<sub>2</sub>[NbO(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]Cl·12H<sub>2</sub>O
|orthorhombic
|''P''2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>
|a=15.103 b=22.075 c=22.386 Z=4
|7463
|1.495
|brown
|<ref name=":11" />
|-
|
|[Ni(bpy)<sub>3</sub>]<sub>2</sub>[NbO(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]Cl·11H<sub>2</sub>O
|monoclinic
|''P''2<sub>1</sub>/''c''
|a=23.875 b=13.265 c=23.115 ''β''=101.69 Z=4
|7169
|1.539
|pink
|<ref name=":11" />
|-
|
|[Ni(bpy)<sub>3</sub>]<sub>2</sub>[NbO(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]Cl·12H<sub>2</sub>O
|orthorhombic
|''P''2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>
|15.058 b=22.039 c=22.398 Z=4
|7433
|1.500
|dark pink
|<ref name=":11" />
|-
|
|[Cu(bpy)<sub>3</sub>]<sub>2</sub>[NbO(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]Cl·12H<sub>2</sub>O
|orthorhombic
|''P''2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>
|a=15.035 b=22.267 c=22.538 Z=4
|7545
|1.487
|blue
|<ref name=":11" />
|-
|
|[Zn(bpy)<sub>3</sub>]<sub>2</sub>[NbO(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]Cl·11H<sub>2</sub>O
|monoclinic
|''P''2<sub>1</sub>/''c''
|24.070 b=13.332 c=23.168 β=102.19 Z=4
|7267
|1.530
|pink
|<ref name=":11" />
|-
|
|[Zn(bpy)<sub>3</sub>]<sub>2</sub>[NbO(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]Cl·12H<sub>2</sub>O
|
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|<ref name=":11" />
|-
|tris(Tetraethylammonium) tetrakis(μ<sub>3</sub>-sulfido)-(oxalato-O,O')-trichloro-cyano-tri-iron-molybdenum
|(Et<sub>4</sub>N)<sub>5</sub>{[C<sub>2</sub>O<sub>4</sub>)MoFe<sub>3</sub>S<sub>4</sub>Cl<sub>2</sub>]<sub>2</sub>(μ-CN)(μ-S)}
|monoclinic
|''P''2<sub>1</sub>/''n''
|''a''=10.331 ''b''=22.580 ''c''=19.083 ''β''=91.97°
|
|
|double cubane structure
|<ref>{{Cite journal |last1=Demadis |first1=Konstantinos D. |last2=Chen |first2=Sue-Jane |last3=Coucouvanis |first3=Dimitri |date=November 1994 |title=The synthesis, and properties of Fe/Mo/S clusters with MoFe3S4 cubane subunits, Mo bound bidentate oxalate ligands and terminal or bridging cyanide ligands. Structural characterization of (Et4N)3[(C2O4)(CN)MoFe3S4Cl3] and (Et4N)5{[C2O4)MoFe3S4Cl2]2(μ-CN)(μ-S)} |url=https://linkinghub.elsevier.com/retrieve/pii/S0277538700836840 |journal=Polyhedron |language=en |volume=13 |issue=22 |pages=3147–3151 |doi=10.1016/S0277-5387(00)83684-0|hdl=2027.42/31244 |hdl-access=free }}</ref>
|-
|(μ<sub>2</sub>-Oxalato)-dichloro-bis(η<sup>6</sup>-p-cymene)-di-ruthenium
|[Ru<sub>2</sub>(μ-η<sup>4</sup>-C<sub>2</sub>O<sub>4</sub>)Cl<sub>2</sub>(η<sup>6</sup>-p-Pr<sup>i</sup>C<sub>6</sub>H<sub>4</sub>Me)<sub>2</sub>]
|monoclinic
|''P''2<sub>1</sub>/''n''
|''a''=7.571 ''b''=8.998 ''c''=16.528 ''β''=95.52° Z=2
|1120.73
|
|yellow
|<ref>{{Cite journal |last1=Yan |first1=Hong |last2=Süss-Fink |first2=Georg |last3=Neels |first3=Antonia |last4=Stoeckli-Evans |first4=Helen |date=1997 |title=Mono-, di- and tetra-nuclear p-cymeneruthenium complexes containing oxalato ligands |url=http://xlink.rsc.org/?DOI=a704658h |journal=Journal of the Chemical Society, Dalton Transactions |issue=22 |pages=4345–4350 |doi=10.1039/a704658h}}</ref>
|-
|chloro-(oxalato)-tris(pyridine)-rhodium
|''mer''-[Rh(C<sub>2</sub>O<sub>4</sub>)Cl(py)<sub>3</sub>]
|orthorhombic
|''P''2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>
|''a''=9.9999 ''b''=12.0930 ''c''=14.9368 Z=4
|1806.2
|1.705
|yellow
|<ref>{{Cite journal |last1=Vasilchenko |first1=Danila |last2=Tkachev |first2=Sergey |last3=Baidina |first3=Iraida |last4=Korolkov |first4=Ilya |last5=Berdyugin |first5=Semen |last6=Kozlova |first6=Ekaterina |last7=Kozlov |first7=Denis |date=2018 |title=Preparation of a rhodium( iii ) cis -diaquacomplex by protic acid induced oxalate-release from mer -[Rh(C 2 O 4 )Cl(py) 3 ] |url=http://xlink.rsc.org/?DOI=C8NJ04264K |journal=New Journal of Chemistry |language=en |volume=42 |issue=24 |pages=19637–19643 |doi=10.1039/C8NJ04264K |issn=1144-0546}}</ref>
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|CHLOROPENTAAMMINECHROMIUM(III) BIS(OXALATO)PALLADATE
|[Cr(NH<sub>3</sub>)<sub>5</sub>Cl][Pd(C<sub>2</sub>O<sub>4</sub>)<sub>2</sub>]
|triclinic
|
|''a'' = 3.225 ''b'' = 10.290 ''c'' = 11.390 α = 116.5° β = 97.9° γ = 91.2°
|334.5
|
|
|<ref>{{Cite journal |last1=Lagunova |first1=V. I. |last2=Filatov |first2=E. Yu. |last3=Plyusnin |first3=P. E. |last4=Komarov |first4=V. Yu. |last5=Martynova |first5=S. A. |last6=Korenev |first6=S. V. |date=April 2021 |title=Synthesis and Thermal Properties of Double Complex Salt: Chloropentaamminechromium(III) Bis(Oxalato)Palladate |url=https://link.springer.com/10.1134/S0022476621040065 |journal=Journal of Structural Chemistry |language=en |volume=62 |issue=4 |pages=555–562 |doi=10.1134/S0022476621040065 |s2cid=235374161 |issn=0022-4766}}</ref>
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Line 163: Line 413:
|triclinic
|triclinic
|''P''{{overbar|1}}
|''P''{{overbar|1}}
|''a'' =6.8136 ''b'' =7.4890 ''c'' =10.0515 ''α'' =84.082° ''β'' =77.806° ''γ'' =88.813°
|''a''=6.8136 ''b''=7.4890 ''c''=10.0515 ''α''=84.082° ''β''=77.806° ''γ''=88.813°
|
|
|
|
|band gap 3.76 eV
|band gap 3.76 eV
|<ref name=":0">{{Cite journal |last1=Xu |first1=Wei |last2=Ma |first2=Liang |last3=Lv |first3=Yi-Lei |last4=Ma |first4=Si-Yu |last5=Liu |first5=Wenlong |last6=Guo |first6=Sheng-Ping |last7=Tang |first7=Ru-Ling |date=2023-12-19 |title=C(NH 2 ) 3 Cd(C 2 O 4 )Cl(H 2 O)·H 2 O and BaCd(C 2 O 4 ) 1.5 Cl(H 2 O) 2 : Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c04154 |journal=Inorganic Chemistry |volume=63 |issue=1 |pages=67–72 |language=en |doi=10.1021/acs.inorgchem.3c04154 |pmid=38112437 |s2cid=266373131 |issn=0020-1669}}</ref>
|<ref name=":0">{{Cite journal |last1=Xu |first1=Wei |last2=Ma |first2=Liang |last3=Lv |first3=Yi-Lei |last4=Ma |first4=Si-Yu |last5=Liu |first5=Wenlong |last6=Guo |first6=Sheng-Ping |last7=Tang |first7=Ru-Ling |date=2023-12-19 |title=C(NH 2 ) 3 Cd(C 2 O 4 )Cl(H 2 O)·H 2 O and BaCd(C 2 O 4 ) 1.5 Cl(H 2 O) 2 : Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c04154 |journal=Inorganic Chemistry |volume=63 |issue=1 |pages=67–72 |language=en |doi=10.1021/acs.inorgchem.3c04154 |pmid=38112437 |s2cid=266373131 |issn=0020-1669}}</ref>
|-
|
|SnC<sub>2</sub>O<sub>4</sub>Cl<sub>2</sub>
|
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|
|<ref name=":12">{{Cite journal |last1=Allouch |first1=Hassan |last2=Diop |first2=Libasse |date=2012 |title=SYNTHESIS AND INFRARED STUDY OF SOME NEW SnC^sub 2^O^sub 4^Cl^sub 2^ ADDUCTS AND COMPLEXES |url=https://www.proquest.com/docview/1499908259 |journal=Scientific Study & Research. Chemistry & Chemical Engineering, Biotechnology, Food Industry |language=English |volume=13 |issue=3 |pages=317–323|id={{ProQuest|1499908259}} }}</ref>
|-
|
|SnC<sub>2</sub>O<sub>4</sub>Cl<sub>2</sub> . CuBr<sub>2</sub> 1/4EtOH
|
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|
|green
|<ref name=":12" />
|-
|
|SnC<sub>2</sub>O<sub>4</sub>Cl<sub>2</sub> . CuCl<sub>2</sub> . H<sub>2</sub>O
|
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|green
|<ref name=":12" />
|-
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|SnC<sub>2</sub>O<sub>4</sub>Cl<sub>2</sub> . CoBr2 1/8EtOH
|
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|
|rose colour
|<ref name=":12" />
|-
|
|(Et<sub>4</sub>N)<sub>2</sub>C<sub>2</sub>O<sub>4</sub> . SnCl<sub>2</sub>F<sub>2</sub> . 2H<sub>2</sub>O:
|
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|white
|<ref name=":12" />
|-
|
|(Me<sub>4</sub>N)<sub>2</sub>Sn(C<sub>2</sub>O<sub>4</sub>)Cl<sub>2</sub>
|
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|
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|
|white
|<ref name=":12" />
|-
|
|(Et<sub>4</sub>N)<sub>2</sub>Sn(C<sub>2</sub>O<sub>4</sub>)Cl<sub>2</sub> .(Et<sub>4</sub>N)<sub>2</sub>C<sub>2</sub>O<sub>4</sub>(SnCl<sub>4</sub>)<sub>2</sub> . EtOH
|
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|white
|<ref name=":12" />
|-
|
|Sn(C<sub>2</sub>O<sub>4</sub>)<sub>2</sub> . 2[SnCl<sub>4</sub> . (Pyridine)<sub>2</sub>]
|
|
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|
|
|white
|<ref name=":12" />
|-
|
|(Et<sub>4</sub>N)<sub>2</sub>SnCl<sub>6</sub> . (Et<sub>4</sub>N)<sub>2</sub>C<sub>2</sub>O<sub>4</sub> . 2SnC<sub>2</sub>O<sub>4</sub>(OH)<sub>2</sub>
|
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|
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|white
|<ref name=":12" />
|-
|
|(NH<sub>4</sub>)<sub>2</sub>Sb(C<sub>2</sub>O<sub>4</sub>)Cl<sub>3</sub>
|orthorhombic
|''P''2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>
|a=8.6961 b=8.7844 c=13.5956 Z=4
|1038.57
|2.253
|
|<ref name=":7">{{Cite journal |last1=Zhang |first1=Die |last2=Wang |first2=Qiang |last3=Luo |first3=Han |last4=Cao |first4=Liling |last5=Dong |first5=Xuehua |last6=Huang |first6=Ling |last7=Gao |first7=Daojiang |last8=Zou |first8=Guohong |date=March 2023 |title=Deep Eutectic Solvents Synthesis of A 2 Sb(C 2 O 4 )Cl 3 (A = NH 4 , K, Rb) with Superior Optical Performance |url=https://onlinelibrary.wiley.com/doi/10.1002/adom.202202874 |journal=Advanced Optical Materials |language=en |volume=11 |issue=6 |doi=10.1002/adom.202202874 |s2cid=256156085 |issn=2195-1071}}</ref>
|-
|
|K<sub>2</sub>Sb(C<sub>2</sub>O<sub>4</sub>)Cl<sub>3</sub>
|orthorhombic
|''P''2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>
|a=8.3966 b=8.6023 c=13,6342 Z=4
|984.80
|2.660
|
|<ref name=":7" />
|-
|
|Rb<sub>2</sub>Sb(C<sub>2</sub>O<sub>4</sub>)Cl<sub>3</sub>
|orthorhombic
|''P''2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>
|a=8.6769 b=8.8485 c=13.8014 Z=4
|1059.64
|3.053
|birefringence 0.22@546 nm;NLO 2.1 × KH<sub>2</sub>PO<sub>4</sub>
|<ref name=":7" />
|-
|
|Ba<sub>2</sub>Mn<sub>2</sub>Cl<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>·4H<sub>2</sub>O
|monoclinic
|''C''2/''c''
|''a''=22.916 ''b''=8.248 ''c''=9.904 ''β''=99.53°
|
|
|
|<ref name=":10">{{Cite journal |last1=Price |first1=Daniel J. |last2=Powell |first2=Annie K. |last3=Wood |first3=Paul T. |date=2003 |title=A new series of layered transition metal oxalates: hydrothermal synthesis, structural and magnetic studies |url=http://xlink.rsc.org/?DOI=b301658g |journal=Dalton Transactions |language=en |issue=12 |pages=2478–2482 |doi=10.1039/b301658g |issn=1477-9226}}</ref>
|-
|
|Ba<sub>2</sub>Fe<sub>2</sub>Cl<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>·4H<sub>2</sub>O
|monoclinic
|''C''2/''c''
|''a''=22.798 ''b''=8.297 ''c''=9.849 ''β''=99.90°
|
|
|
|<ref name=":10" />
|-
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|Ba<sub>2</sub>Co<sub>2</sub>Cl<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>·4H<sub>2</sub>O
|monoclinic
|''C''2/''c''
|''a''=22.675 ''b''=8.230 ''c''=9.757 ''β''=100.00°
|
|
|purple
|<ref>{{Cite journal |last1=Song |first1=Yujie |last2=Niu |first2=Haoyu |last3=Zeng |first3=Zhuo |last4=Jiang |first4=Dequan |last5=Liang |first5=Youyuan |last6=Huang |first6=Hao |last7=Xiao |first7=Lixia |last8=Xia |first8=Zhengcai |date=September 2022 |title=The tuning of oxalato-bridge on magnetic interaction and field-induced phase transition in Ba2Co2Cl2(C2O4)3·4H2O |url=https://linkinghub.elsevier.com/retrieve/pii/S0304885322004048 |journal=Journal of Magnetism and Magnetic Materials |language=en |volume=557 |pages=169475 |doi=10.1016/j.jmmm.2022.169475|s2cid=248877927 }}</ref><ref name=":10" />
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Line 181: Line 581:
|
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|La(C<sub>2</sub>O<sub>4</sub>)Cl
|La(C<sub>2</sub>O<sub>4</sub>)Cl
|monoclinic
|''P''2<sub>1</sub>/''n''
|''a''=8.489 ''b''=16.19 ''c''=5.880 ''β''=104.14°
|
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|<ref>{{Cite journal |last1=Hölsä |first1=Jorma |last2=Koriseva |first2=Eija |date=August 1991 |title=Thermal decomposition of LaC2O4Cl·3H2O : Eu3+: a high-resolution luminescence spectroscopy study |url=https://linkinghub.elsevier.com/retrieve/pii/004060319180114X |journal=Thermochimica Acta |language=en |volume=185 |issue=1 |pages=25–33 |doi=10.1016/0040-6031(91)80114-X}}</ref><ref>{{Cite journal |last1=Baker |first1=P. |last2=Smith |first2=A. J. |date=1990-06-15 |title=Structure of lanthanum chloride oxalate trihydrate |url=https://scripts.iucr.org/cgi-bin/paper?S0108270189009248 |journal=Acta Crystallographica Section C Crystal Structure Communications |volume=46 |issue=6 |pages=984–985 |doi=10.1107/S0108270189009248|bibcode=1990AcCrC..46..984B |s2cid=98752634 }}</ref>
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|<ref>{{Cite journal |last1=Hölsä |first1=Jorma |last2=Koriseva |first2=Eija |date=August 1991 |title=Thermal decomposition of LaC2O4Cl·3H2O : Eu3+: a high-resolution luminescence spectroscopy study |url=https://linkinghub.elsevier.com/retrieve/pii/004060319180114X |journal=Thermochimica Acta |language=en |volume=185 |issue=1 |pages=25–33 |doi=10.1016/0040-6031(91)80114-X}}</ref>
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Line 268: Line 668:
|
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|<ref name=":4" /><ref>{{Cite journal |last1=Mulokozi |first1=A. M. |last2=Weigel |first2=F. |date=April 1975 |title=Characeriztion of Rare-Earth Metal Oxalato Halide-Hydrates by thermal analytical methods |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19754140108 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=414 |issue=1 |pages=62–68 |doi=10.1002/zaac.19754140108 |issn=0044-2313}}</ref>
|<ref name=":4" /><ref>{{Cite journal |last1=Mulokozi |first1=A. M. |last2=Weigel |first2=F. |date=April 1975 |title=Characeriztion of Rare-Earth Metal Oxalato Halide-Hydrates by thermal analytical methods |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19754140108 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=414 |issue=1 |pages=62–68 |doi=10.1002/zaac.19754140108 |issn=0044-2313}}</ref>
|-
|
|(Et<sub>4</sub>N)<sub>2</sub>Sn(C<sub>2</sub>O<sub>4</sub>)Cl<sub>2</sub> . (Et<sub>4</sub>N)<sub>2</sub>C<sub>2</sub>O<sub>4</sub>(SnCl<sub>4</sub>)<sub>2</sub> . EtOH
|
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|
|<ref name=":12" />
|-
|
|[(Me<sub>4</sub>N)<sub>2</sub>C<sub>2</sub>O<sub>4</sub>SnCl<sub>4</sub>]<sub>2</sub> . [(Me<sub>4</sub>N)<sub>2</sub>Sn(C<sub>2</sub>O<sub>4</sub>)<sub>2</sub>Cl<sub>2</sub>]<sub>2</sub> . Sn(WO<sub>4</sub>)<sub>2</sub>
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|<ref name=":12" />
|-
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|[Pt(HC<sub>2</sub>O<sub>4</sub>)Cl<sub>3</sub>]<sup>2−</sup>
|
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|
|<ref name=":6">{{Cite journal |last1=Dunham |first1=S. O. |last2=Larsen |first2=R. D. |last3=Abbott |first3=E. H. |date=November 1991 |title=Nuclear magnetic resonance investigation of the formation of oxalato, malonato, and 2-methylmalonato complexes of platinum(II). Crystal and molecular structures of potassium anti-bis(2-methylmalonato)platinate(II) dihydrate and potassium dichloro(oxalato)platinate(II) hydrate |url=https://pubs.acs.org/doi/abs/10.1021/ic00023a009 |journal=Inorganic Chemistry |language=en |volume=30 |issue=23 |pages=4328–4335 |doi=10.1021/ic00023a009 |issn=0020-1669}}</ref>
|-
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|[Pt(HC<sub>2</sub>O<sub>4</sub>)(C<sub>2</sub>O<sub>4</sub>)Cl]<sup>2−</sup>
|
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|<ref name=":6" />
|-
|
|K<sub>2</sub>[Pt(C<sub>2</sub>O<sub>4</sub>)Cl<sub>2</sub>]·H<sub>2</sub>O
|triclinic
|''P''{{overbar|1}}
|a=7.136 b=7.308 c=10.130 α=86.75° β=74.58° γ=54.28° Z=2
|457.7
|3.27
|
|<ref>{{Cite web |title=K2[Pt(C2O4)Cl2]·H2O (K2Pt[C2O4]Cl2[H2O]) Crystal Structure - SpringerMaterials |url=https://materials.springer.com/isp/crystallographic/docs/sd_1904131 |access-date=2024-02-08 |website=materials.springer.com}}</ref><ref name=":6" />
|-
|
|[Pt(NH<sub>3</sub>)<sub>5</sub>Cl][Cr(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>] · 4H<sub>2</sub>O
|orthorhombic
|''Pccn''
|''a''=38.901 ''b''=13.7267 ''c''=14.9141
|
|
|
|<ref name=":8">{{Cite journal |last1=Yusenko |first1=K. V. |last2=Vasil’chenko |first2=D. B. |last3=Zadesenets |first3=A. V. |last4=Baidina |first4=I. A. |last5=Shubin |first5=Yu. V. |last6=Korenev |first6=S. V. |date=October 2007 |title=Double complex salts [Pt(NH3)5Cl][M(C2O4)3] · nH2O (M = Fe, Co, Cr): Synthesis and study |url=http://link.springer.com/10.1134/S0036023607100014 |journal=Russian Journal of Inorganic Chemistry |language=en |volume=52 |issue=10 |pages=1487–1491 |doi=10.1134/S0036023607100014 |s2cid=96549903 |issn=0036-0236}}</ref>
|-
|
|[Pt(NH<sub>3</sub>)<sub>5</sub>Cl][Fe(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>] · 4H<sub>2</sub>O
|orthorhombic
|''Pccn''
|''a''=39.0123 ''b''=13.7232 ''c''=14.8990
|
|
|
|<ref name=":8" />
|-
|
|[Pt(NH<sub>3</sub>)<sub>5</sub>Cl][Co(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>] · 2H<sub>2</sub>O
|monoclinic
|''P''2<sub>1</sub>
|''a''=8.5158 ''b''=12.6409 ''c''=8.5726 ''β''=105.000°
|
|
|
|<ref name=":8" />
|-
|lead chloride oxalate
|Pb<sub>2</sub>Cl<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)
|monoclinic
|''C''2/''m''
|a=5.9411 b=5.8714 c=9.4212 β=95.232° Z=2
|327.26
|5.82
|dec 350°C to Pb, Pb<sub>5</sub>O<sub>2</sub>Cl<sub>6</sub> and Pb<sub>3</sub>O<sub>2</sub>Cl<sub>2</sub>
|<ref>{{Cite journal |last1=Boudaren |first1=Chaouki |last2=Auffrédic |first2=Jean-Paul |last3=Louër |first3=Michèle |last4=Louër |first4=Daniel |date=September 2003 |title=A powder X-ray diffraction study of lead chloride oxalate Pb 2 Cl 2 (C 2 O 4 ): ab initio structure determination and thermal behavior |url=https://www.cambridge.org/core/product/identifier/S0885715600006898/type/journal_article |journal=Powder Diffraction |language=en |volume=18 |issue=3 |pages=205–213 |doi=10.1154/1.1590352 |s2cid=98700786 |issn=0885-7156}}</ref>
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|-
|Plutonium(III) oxalato chloride
|Plutonium(III) oxalato chloride
|?Pu(C<sub>2</sub>O<sub>4</sub>)Cl·3H<sub>2</sub>O
|
|
|
|
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Line 288: Line 778:
|blue; biaxial (−)
|blue; biaxial (−)
|<ref>{{Cite book |last=Staritzky |first=Eugene |url=http://www.sciencemadness.org/lanl2_a/lib-www/la-pubs/00349867.pdf |title=Optical and Morphological Crystallography of Plutonium Compounds |date=28 August 1949 |publisher=US Atomic Energy Commission |pages=34}}</ref>
|<ref>{{Cite book |last=Staritzky |first=Eugene |url=http://www.sciencemadness.org/lanl2_a/lib-www/la-pubs/00349867.pdf |title=Optical and Morphological Crystallography of Plutonium Compounds |date=28 August 1949 |publisher=US Atomic Energy Commission |pages=34}}</ref>
|-
|
|Am(C<sub>2</sub>O<sub>4</sub>)Cl·3H<sub>2</sub>O
|monoclinic
|''P''2<sub>1</sub>/''n''
|''a''=5.852 ''b''=15.823 ''c''=8.351 ''β''=104.243°
|
|
|
|<ref>{{Cite journal |last1=Arteaga |first1=Ana |last2=Nicholas |first2=Aaron D. |last3=Ducati |first3=Lucas C. |last4=Autschbach |first4=Jochen |last5=Surbella |first5=Robert G. |date=2023-03-27 |title=Americium Oxalate: An Experimental and Computational Investigation of Metal–Ligand Bonding |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c03976 |journal=Inorganic Chemistry |language=en |volume=62 |issue=12 |pages=4814–4822 |doi=10.1021/acs.inorgchem.2c03976 |pmid=36920249 |osti=1968457 |s2cid=257534787 |issn=0020-1669}}</ref>
|}
|}


==References==
==References==
{{Reflist}}
{{Reflist}}

{{Chlorides}}
{{Oxalates}}

[[Category:Oxalates]]
[[Category:Chlorides]]
[[Category:Mixed anion compounds]]

Latest revision as of 04:58, 1 June 2024

An oxalate chloride or oxalato chloride is a mixed anion compound contains both oxalate and chloride anions.

Related compounds include oxalate fluorides[1] and oxalate bromides.[2]

Production

[edit]

Oxalate chlorides may be produced by treating an oxalate salt with concentrated hydrochloric acid, or with a metal oxide dissolved in oxalic acid and hydrochloric acid solutions that are evaporated.[3]

List

[edit]
name formula crystal space group cell volume density comment ref
Novgorodovaite Ca2(C2O4)Cl2•2H2O monoclinic I2/m a=6.936 b=7.382 c=7.443 β=94.3° loses water over 205°C; refract: α=1.500 β=1.545 γ=1.568 2V=71° (−) [4][5][6]
Ca2(C2O4)Cl2•7H2O triclinic P1 a = 7.3928 b = 8.9925 c = 10.484 α = 84.070 β = 70.95 γ = 88.545° 655.3 looses water at 25°C to 2H2O; refract: α=1.571 β=1.648 γ=1.718 2V=87° (−) [4][7]
Ca4(C2O4)3Cl2•8H2O dubious [4]
octakis(ethyl(dimethyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese [NH(CH3)2(C2H5)]8[Mn4Cl4Cr4(C2O4)12] monoclinic P21 a=13.8321 b=17.1042 c=20.4209 β=91.874° [8]
octakis(diethyl(methyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese [NH(CH3)(C2H5)2]8[Mn4Cl4Cr4(C2O4)12] monoclinic P21 a=14.1863 b=17.3479 c=20.4140 β=91.937° [8]
DABCO=1,4-diazabicyclo[2.2.2]octane; (DABCO-H+)2(DABCO-2H2+)[MnII(CH3OH)(Cl−)CrIII(oxalate)3]2−2(CH3OH) triclinic P1 a=8.093 b=9.070 c=19.574 α=83.471° β=89.875° γ=86.765° [9]
tetrakis(methylammonium) tetrakis(μ-oxalato)-octachloro-tetra-iron(iii) pentahydrate (MeNH3)2[Fe2(ox)2Cl4]·2.5H2O monoclinic P21/c a 10.7832 b 13.913 c 13.0578 β 104.060° [10]
methylammonium (μ-hydroxo)-bis(μ-oxalato)-dichloro-di-iron(iii) trihydrate MeNH3[Fe2(OH)(ox)2Cl2]·2H2O monoclinic Cc a=8.945 b=14.936 c=12.408 β=108.531° [10]
methylammonium oxonium bis(μ-oxalato)-(μ-oxo)-dichloro-di-iron(iii) dihydrate (H3O)(MeNH3)[Fe2O(ox)2Cl2]·3H2O orthorhombic Fdd2 a=14.914 b=23.507 c=9.261 [10]
DMF = dimethylformamide Fe2(C2O4)Cl4(DMF)4 triclinic P1 a=8.3919 b=8.7834 c=11.2881 α=70.248° β=71.993° γ=64.423° [11]
(dimim)2[Fe2Cl4(μ-ox)] ionic liquid [12]
L2=1,4-bis(imidazol-1-ylmethyl)benzene

bis(1,1'-(1,4-Phenylenebis(methylene))bis-1H-imidazol-3-ium) (μ2-oxalato)-tetrachloro-bis(oxalato)-di-iron(iii)

(H2-L2)2{Fe2(C2O4)3Cl4} triclinic P1 a=10.6758 b=10.7457 c=10.8774 α=113.219° β=109.138° γ=99.294° Z=1 1020.8 1.624 emerald [13]
tetramelaminium trioxalatoferrate(III) chloride dihydrate (C3H7N6)4{Fe(C2O4)3}Cl·2H2O monoclinic P21/c a=11.597 b=22.299 c=13.655 β=94.344° Z=4 3521 1.698 green [14]
methylammonium (μ-aqua)-tris(μ-chloro)-(μ-oxalato)-iron(iii)-potassium K(MeNH3)[Fe(ox)Cl3(H2O) monoclinic P21/m a=8.725 b=7.508 c=9.026 β=112.421° [10]
diethylmethylammonium [NH(CH3)(C2H5)2][FeCl2(C2O4)] monoclinic P21/c a=8.5125 b=10.775 c=14.9703 β=104.798° Z=4 1327.6 1.516 yellow; proton conductor [15]
bis(Tetramethylammonium) bis(μ2-oxalato)-tetrachloro-di-iron(iii) Me4N[FeIII(ox)Cl2] monoclinic P21/c a=7.9441 b=8.6093 c=17.8251 β=91.869 [16]
hexakis(Triethylammonium) hexakis(μ2-oxalato)-dodecachloro-hexa-iron(iii) Et3NH[FeIII(ox)Cl2] triclinic P1 a=10.9609 b=14.4602 c=14.5780 α=85.006° β=78.845° γ=83.0191 [16]
Triethylammonium (μ2-oxalato)-dichloro-iron(iii) Et3NH[FeIII(ox)Cl2] orthorhombic Fdd2 a=13.5878 b=37.972 c=10.8210 [16]
bis(Tetra-n-butylammonium) bis(μ2-oxalato)-tetrachloro-di-iron(iii) n-Bu4N[FeIII(ox)Cl2] monoclinic P21/c a=8.8836 b=15.1939 c=17.968 β=91.556° [16]
[Fe(oxalato)Cl2]3(3,5-dimethylpyrazole)2(3,5- dimethylpyrazolium)2 monoclinic C2/c a=19.527 b=11.867 c=19.429 β=115.66° Z=4 4058.20 1.684 green [17]
BETS = Bis(ethylenedithio)tetraselenafulvalene κ-BETS2[FeIII(C2O4)Cl2] black; metallic; [18]
bis(2-(5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-1-ium) bis(μ-oxalato)-tetrachloro-di-iron(iii) [BEDT-TTF][Fe(C2O4)Cl2] triclinic P1 a=8.896 b=11.401 c=11.427 α=112.062° β=103.775° γ=100.328° [19]
BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)[Fe(C2O4)Cl2](CH2Cl2) monoclinic P21/c a=8.858 b=11.012 c=14.932 β=103.39° [20]
tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate [Co(en)3]Cl(C2O4)·3H2O monoclinic C2/c a = 19.932 b = 9.3344 c = 19.088 β = 96.846° Z = 8 [21]
dpyam=di-2-pyridylamine; (μ2-Oxalato)-bis(di-2-pyridylamine)-dichloro-di-copper(ii) Cu2(dpyam)2(μ-C2O4)(Cl)2 triclinic P1 a=7.4122 b=8.6586 c=9.8002 α=87.900° β=72.022° γ=71.845° [22]
L = 3,5-dimethyl-1H-pyrazole Cu2(C2O4)(L)2Cl2(MeOH)2 triclinic P1 a=7.244 b=8.039 c=8.848 α=92.16° β=92.73° γ=96.21° [23]
bpy=bipyridine [Fe(bpy)3]2[NbO(C2O4)3]Cl·11H2O [24]
[Fe(bpy)3]2[NbO(2O4)3]Cl·12H2O orthorhombic P212121 a=14.975 b=21.708 c=22.351 Z=4 7266 1.530 dark red [24]
[Co(bpy)3]2[NbO(C2O4)3]Cl·11H2O monoclinic P21/c a=23.548 b=13.631 c=22.812 β=101.04 7187 1.536 orange red [24]
[Co(bpy)3]2[NbO(C2O4)3]Cl·12H2O orthorhombic P212121 a=15.103 b=22.075 c=22.386 Z=4 7463 1.495 brown [24]
[Ni(bpy)3]2[NbO(C2O4)3]Cl·11H2O monoclinic P21/c a=23.875 b=13.265 c=23.115 β=101.69 Z=4 7169 1.539 pink [24]
[Ni(bpy)3]2[NbO(C2O4)3]Cl·12H2O orthorhombic P212121 15.058 b=22.039 c=22.398 Z=4 7433 1.500 dark pink [24]
[Cu(bpy)3]2[NbO(C2O4)3]Cl·12H2O orthorhombic P212121 a=15.035 b=22.267 c=22.538 Z=4 7545 1.487 blue [24]
[Zn(bpy)3]2[NbO(C2O4)3]Cl·11H2O monoclinic P21/c 24.070 b=13.332 c=23.168 β=102.19 Z=4 7267 1.530 pink [24]
[Zn(bpy)3]2[NbO(C2O4)3]Cl·12H2O [24]
tris(Tetraethylammonium) tetrakis(μ3-sulfido)-(oxalato-O,O')-trichloro-cyano-tri-iron-molybdenum (Et4N)5{[C2O4)MoFe3S4Cl2]2(μ-CN)(μ-S)} monoclinic P21/n a=10.331 b=22.580 c=19.083 β=91.97° double cubane structure [25]
(μ2-Oxalato)-dichloro-bis(η6-p-cymene)-di-ruthenium [Ru2(μ-η4-C2O4)Cl2(η6-p-PriC6H4Me)2] monoclinic P21/n a=7.571 b=8.998 c=16.528 β=95.52° Z=2 1120.73 yellow [26]
chloro-(oxalato)-tris(pyridine)-rhodium mer-[Rh(C2O4)Cl(py)3] orthorhombic P212121 a=9.9999 b=12.0930 c=14.9368 Z=4 1806.2 1.705 yellow [27]
CHLOROPENTAAMMINECHROMIUM(III) BIS(OXALATO)PALLADATE [Cr(NH3)5Cl][Pd(C2O4)2] triclinic a = 3.225 b = 10.290 c = 11.390 α = 116.5° β = 97.9° γ = 91.2° 334.5 [28]
C(NH2)3Cd(C2O4)Cl(H2O)·H2O triclinic P1 a=6.8136 b=7.4890 c=10.0515 α=84.082° β=77.806° γ=88.813° band gap 3.76 eV [29]
SnC2O4Cl2 [30]
SnC2O4Cl2 . CuBr2 1/4EtOH green [30]
SnC2O4Cl2 . CuCl2 . H2O green [30]
SnC2O4Cl2 . CoBr2 1/8EtOH rose colour [30]
(Et4N)2C2O4 . SnCl2F2 . 2H2O: white [30]
(Me4N)2Sn(C2O4)Cl2 white [30]
(Et4N)2Sn(C2O4)Cl2 .(Et4N)2C2O4(SnCl4)2 . EtOH white [30]
Sn(C2O4)2 . 2[SnCl4 . (Pyridine)2] white [30]
(Et4N)2SnCl6 . (Et4N)2C2O4 . 2SnC2O4(OH)2 white [30]
(NH4)2Sb(C2O4)Cl3 orthorhombic P212121 a=8.6961 b=8.7844 c=13.5956 Z=4 1038.57 2.253 [31]
K2Sb(C2O4)Cl3 orthorhombic P212121 a=8.3966 b=8.6023 c=13,6342 Z=4 984.80 2.660 [31]
Rb2Sb(C2O4)Cl3 orthorhombic P212121 a=8.6769 b=8.8485 c=13.8014 Z=4 1059.64 3.053 birefringence 0.22@546 nm;NLO 2.1 × KH2PO4 [31]
Ba2Mn2Cl2(C2O4)3·4H2O monoclinic C2/c a=22.916 b=8.248 c=9.904 β=99.53° [32]
Ba2Fe2Cl2(C2O4)3·4H2O monoclinic C2/c a=22.798 b=8.297 c=9.849 β=99.90° [32]
Ba2Co2Cl2(C2O4)3·4H2O monoclinic C2/c a=22.675 b=8.230 c=9.757 β=100.00° purple [33][32]
BaCd(C2O4)1.5Cl(H2O)2 monoclinic C2/c a=23.101 b=8.253 c=10.040 β 99.14° band gap 4.53 eV [29]
La(C2O4)Cl monoclinic P21/n a=8.489 b=16.19 c=5.880 β=104.14° [34][35]
La(C2O4)Cl·3H2O [36]
Ce(C2O4)Cl [1]
Ce(C2O4)Cl·3H2O [36]
Pr(C2O4)Cl·3H2O stable to 163°C [36][1]
Nd(C2O4)Cl·3H2O stable to 167°C; dec 510° to NdOCl [36][1][37]
Sm(C2O4)Cl·3H2O stable to 174°C; dec at 347° to EuC2O4 [36][1]
Eu(C2O4)Cl·3H2O stable to 178°C [36][1]
Gd(C2O4)Cl·3H2O [36][38]
(Et4N)2Sn(C2O4)Cl2 . (Et4N)2C2O4(SnCl4)2 . EtOH [30]
[(Me4N)2C2O4SnCl4]2 . [(Me4N)2Sn(C2O4)2Cl2]2 . Sn(WO4)2 [30]
[Pt(HC2O4)Cl3]2− [39]
[Pt(HC2O4)(C2O4)Cl]2− [39]
K2[Pt(C2O4)Cl2]·H2O triclinic P1 a=7.136 b=7.308 c=10.130 α=86.75° β=74.58° γ=54.28° Z=2 457.7 3.27 [40][39]
[Pt(NH3)5Cl][Cr(C2O4)3] · 4H2O orthorhombic Pccn a=38.901 b=13.7267 c=14.9141 [41]
[Pt(NH3)5Cl][Fe(C2O4)3] · 4H2O orthorhombic Pccn a=39.0123 b=13.7232 c=14.8990 [41]
[Pt(NH3)5Cl][Co(C2O4)3] · 2H2O monoclinic P21 a=8.5158 b=12.6409 c=8.5726 β=105.000° [41]
lead chloride oxalate Pb2Cl2(C2O4) monoclinic C2/m a=5.9411 b=5.8714 c=9.4212 β=95.232° Z=2 327.26 5.82 dec 350°C to Pb, Pb5O2Cl6 and Pb3O2Cl2 [42]
Th4Cl4(C2O4)6•20H2O
Plutonium(III) oxalato chloride ?Pu(C2O4)Cl·3H2O blue; biaxial (−) [43]
Am(C2O4)Cl·3H2O monoclinic P21/n a=5.852 b=15.823 c=8.351 β=104.243° [44]

References

[edit]
  1. ^ a b c d e f Mulokozi, A.M.; Weigel, F. (May 1973). "Differential thermal analysis studies of some rare earth metal oxalato halide-hydrates". Journal of Inorganic and Nuclear Chemistry. 35 (5): 1487–1492. doi:10.1016/0022-1902(73)80236-2.
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  10. ^ a b c d Mastropietro, Teresa F.; Marino, Nadia; Munno, Giovanni De; Lloret, Francesc; Julve, Miguel; Pardo, Emilio; Armentano, Donatella (2016-11-07). "Selective Guest Inclusion in Oxalate-Based Iron(III) Magnetic Coordination Polymers". Inorganic Chemistry. 55 (21): 11160–11169. doi:10.1021/acs.inorgchem.6b01769. ISSN 0020-1669. PMID 27749048.
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  12. ^ Cot, Sergi; Leu, Meike K.; Kalamiotis, Alexis; Dimitrakis, Georgios; Sans, Victor; de Pedro, Imanol; Cano, Israel (July 2019). "An Oxalate-Bridged Binuclear Iron(III) Ionic Liquid for the Highly Efficient Glycolysis of Polyethylene Terephthalate under Microwave Irradiation". ChemPlusChem. 84 (7): 786–793. doi:10.1002/cplu.201900075. hdl:10234/185443. ISSN 2192-6506. PMID 31943995. S2CID 196896383.
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