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{{Short description|none}}
{{infobox copernicium isotopes}}
{{Infobox copernicium isotopes}}
[[Copernicium]] (<sub>112</sub>Cn) is a [[synthetic element]], and thus a [[standard atomic weight]] cannot be given. Like all synthetic elements, it has no [[stable isotope]]s. The first [[isotope]] to be synthesized was <sup>277</sup>Cn in 1996. There are 6 known [[radioisotope]]s (with one more unconfirmed); the longest-lived isotope is <sup>285</sup>Cn with a [[half-life]] of 29 seconds.
[[Copernicium]] (<sub>112</sub>Cn) is a [[synthetic element]], and thus a [[standard atomic weight]] cannot be given. Like all synthetic elements, it has no [[stable isotope]]s. The first [[isotope]] to be synthesized was <sup>277</sup>Cn in 1996. There are seven known [[radioisotope]]s (with one more unconfirmed); the longest-lived isotope is <sup>285</sup>Cn with a [[half-life]] of 30 seconds.


== List of isotopes ==
== List of isotopes ==
{{Anchor|Copernicium-276|Copernicium-278|Copernicium-279|Copernicium-285m|Copernicium-287|Copernicium-288}}

<!--Please delete anchor(s) from the list above or table below if adding a dedicated isotope section(s).-->

{{Isotopes table
{{Isotopes table
|symbol=Cn
|symbol=Cn
|refs=NUBASE2020
|refs=<!-- not NUBASE2016 yet -->
|notes=unc(), mass#, spin#, EC, SF
|notes=unc(), mass#, spin#, EC, SF
}}
}}
|-id=Copernicium-277
<!-- |-
| <sup>276</sup>Cn
| 112
| 164
| 276.16141(64)#
|
| -->
|-
| <sup>277</sup>Cn
| <sup>277</sup>Cn
| 112
| 112
| 165
| 165
| 277.16364(15)#
| 277.16354(17)#
| {{val|790|(330)|u=us}}<br/>
| 1.1(7)&nbsp;ms<br>[0.69(+69−24)&nbsp;ms]
| [[alpha decay|α]]
| [[alpha decay|α]]
| <sup>273</sup>Ds
| <sup>273</sup>Ds
| 3/2+#
| 3/2+#
|-id=Copernicium-280
<!--|-
| <sup>280</sup>Cn<ref name=jinr2024>{{Cite web |url=https://indico.jinr.ru/event/4343/contributions/28663/attachments/20748/36083/U%20+%20Cr%20AYSS%202024.pptx |title=Synthesis and study of the decay properties of isotopes of superheavy element Lv in Reactions <sup>238</sup>U + <sup>54</sup>Cr and <sup>242</sup>Pu + <sup>50</sup>Ti |last=Ibadullayev |first=Dastan |date=2024 |website=jinr.ru |publisher=[[Joint Institute for Nuclear Research]] |access-date=2 November 2024 |quote=}}</ref><ref group=n>Not directly synthesized, created as [[decay product]] of <sup>288</sup>Lv</ref>
| <sup>278</sup>Cn
| 112
| 112
| 166
| 168
| 278.16416(47)#
| 280.16710(63)#
| {{val|100|p=<|u=us}}
| 10#&nbsp;ms
| SF
| (various)
| 0+
| 0+
|-id=Copernicium-281
|-
| <sup>279</sup>Cn
| 112
| 167
| 279.16654(50)#
| 0.1#&nbsp;s
|
|-
| <sup>280</sup>Cn
| 112
| 168
| 280.16715(63)#
| 1#&nbsp;s
| 0+ -->
|-
| <sup>281</sup>Cn<ref group=n>Not directly synthesized, created as [[decay product]] of <sup>285</sup>Fl</ref>
| <sup>281</sup>Cn<ref group=n>Not directly synthesized, created as [[decay product]] of <sup>285</sup>Fl</ref>
| 112
| 112
| 169
| 169
| 281.16975(42)#
| 281.16956(43)#
| 180&nbsp;ms<ref name=PuCa2017>{{cite journal |last1=Utyonkov |first1=V. K. |last2=Brewer |first2=N. T. |first3=Yu. Ts. |last3=Oganessian |first4=K. P. |last4=Rykaczewski |first5=F. Sh. |last5=Abdullin |first6=S. N. |last6=Dimitriev |first7=R. K. |last7=Grzywacz |first8=M. G. |last8=Itkis |first9=K. |last9=Miernik |first10=A. N. |last10=Polyakov |first11=J. B. |last11=Roberto |first12=R. N. |last12=Sagaidak |first13=I. V. |last13=Shirokovsky |first14=M. V. |last14=Shumeiko |first15=Yu. S. |last15=Tsyganov |first16=A. A. |last16=Voinov |first17=V. G. |last17=Subbotin |first18=A. M. |last18=Sukhov |first19=A. V. |last19=Karpov |first20=A. G. |last20=Popeko |first21=A. V. |last21=Sabel'nikov |first22=A. I. |last22=Svirikhin |first23=G. K. |last23=Vostokin |first24=J. H. |last24=Hamilton |first25=N. D. |last25=Kovrizhnykh |first26=L. |last26=Schlattauer |first27=M. A. |last27=Stoyer |first28=Z. |last28=Gan |first29=W. X. |last29=Huang |first30=L. |last30=Ma |date=30 January 2018 |display-authors=3 |title=Neutron-deficient superheavy nuclei obtained in the <sup>240</sup>Pu+<sup>48</sup>Ca reaction |journal=Physical Review C |volume=97 |issue=14320 |pages=014320 |doi=10.1103/PhysRevC.97.014320|bibcode=2018PhRvC..97a4320U |doi-access=free }}</ref>
| {{val|180|100|40|u=ms}}<ref name="PuCa2017">{{cite journal |last1=Utyonkov |first1=V. K. |last2=Brewer |first2=N. T. |first3=Yu. Ts. |last3=Oganessian |first4=K. P. |last4=Rykaczewski |first5=F. Sh. |last5=Abdullin |first6=S. N. |last6=Dimitriev |first7=R. K. |last7=Grzywacz |first8=M. G. |last8=Itkis |first9=K. |last9=Miernik |first10=A. N. |last10=Polyakov |first11=J. B. |last11=Roberto |first12=R. N. |last12=Sagaidak |first13=I. V. |last13=Shirokovsky |first14=M. V. |last14=Shumeiko |first15=Yu. S. |last15=Tsyganov |first16=A. A. |last16=Voinov |first17=V. G. |last17=Subbotin |first18=A. M. |last18=Sukhov |first19=A. V. |last19=Karpov |first20=A. G. |last20=Popeko |first21=A. V. |last21=Sabel'nikov |first22=A. I. |last22=Svirikhin |first23=G. K. |last23=Vostokin |first24=J. H. |last24=Hamilton |first25=N. D. |last25=Kovrizhnykh |first26=L. |last26=Schlattauer |first27=M. A. |last27=Stoyer |first28=Z. |last28=Gan |first29=W. X. |last29=Huang |first30=L. |last30=Ma |date=30 January 2018 |display-authors=3 |title=Neutron-deficient superheavy nuclei obtained in the <sup>240</sup>Pu+<sup>48</sup>Ca reaction |journal=Physical Review C |volume=97 |issue=14320 |pages=014320 |doi=10.1103/PhysRevC.97.014320|bibcode=2018PhRvC..97a4320U |doi-access=free }}</ref>
| α
| α
| <sup>277</sup>Ds
| <sup>277</sup>Ds
| 3/2+#
| 3/2+#
|-id=Copernicium-282
|-
| <sup>282</sup>Cn
| <sup>282</sup>Cn
| 112
| 112
| 170
| 170
| 282.1705(7)#
| 282.17051(59)#
| {{val|0.83|0.18|0.13|u=ms}}<ref name=PuCa2022/>
| 0.8&nbsp;ms
| [[Spontaneous fission|SF]]
| [[Spontaneous fission|SF]]
| (various)
| (various)
| 0+
| 0+
|-id=Copernicium-283
|-
| rowspan=3|<sup>283</sup>Cn
| rowspan=3|<sup>283</sup>Cn
| rowspan=3|112
| rowspan=3|112
| rowspan=3|171
| rowspan=3|171
| rowspan=3|283.17327(65)#
| rowspan=3|283.17320(66)#
| rowspan=3|4&nbsp;s
| rowspan=3|{{val|3.81|0.45|0.36|u=s}}<ref name="PuCa2022" />
| α (90%)
| α (96%)<ref name="PuCa2022" />
| <sup>279</sup>Ds
| <sup>279</sup>Ds
| rowspan=3|
| rowspan=3|
|-
|-
| SF (10%)
| SF (4%)
| (various)
| (various)
|-
|-
| [[electron capture|EC]]?
| [[electron capture|EC]]?
| <sup>283</sup>Rg
| <sup>283</sup>Rg
|-id=Copernicium-284
|-
| rowspan=2|<sup>284</sup>Cn<ref group=n>Not directly synthesized, created as decay product of <sup>288</sup>Fl</ref>
| rowspan=2|<sup>284</sup>Cn<ref group=n>Not directly synthesized, created as decay product of <sup>288</sup>Fl</ref>
| rowspan=2|112
| rowspan=2|112
| rowspan=2|172
| rowspan=2|172
| rowspan=2|284.17416(91)#
| rowspan=2|284.17436(82)#
| rowspan=2|97&nbsp;ms
| rowspan=2|{{val|121|20|15|u=ms}}<ref name="280Ds2021"/>
| SF (98%)
| SF (98%)
| (various)
| (various)
| rowspan=2|0+
| rowspan=2|0+
|-
|-
| α (2%)<ref name="280Ds2021">{{Cite journal |doi = 10.1103/PhysRevLett.126.032503|title = Spectroscopy along Flerovium Decay Chains: Discovery of <sup>280</sup>Ds and an Excited State in <sup>282</sup>Cn|journal = Physical Review Letters|volume = 126|pages = 032503|year = 2021|last1 = Såmark-Roth|first1 = A.|last2 = Cox|first2 = D. M.|last3 = Rudolph|first3 = D.|last4 = Sarmento|first4 = L. G.|last5 = Carlsson|first5 = B. G.|last6 = Egido|first6 = J. L.|last7 = Golubev|first7 = P|last8 = Heery|first8 = J.|last9 = Yakushev|first9 = A.|last10 = Åberg|first10 = S.|last11 = Albers|first11 = H. M.|last12 = Albertsson|first12 = M.|last13 = Block|first13 = M.|last14 = Brand|first14 = H.|last15 = Calverley|first15 = T.|last16 = Cantemir|first16 = R.|last17 = Clark|first17 = R. M.|last18 = Düllmann|first18 = Ch. E.|last19 = Eberth|first19 = J.|last20 = Fahlander|first20 = C.|last21 = Forsberg|first21 = U.|last22 = Gates|first22 = J. M.|last23 = Giacoppo|first23 = F.|last24 = Götz|first24 = M.|last25 = Hertzberg|first25 = R.-D.|last26 = Hrabar|first26 = Y.|last27 = Jäger|first27 = E.|last28 = Judson|first28 = D.|last29 = Khuyagbaatar|first29 = J.|last30 = Kindler|first30 = B.| issue=3 | pmid=33543956 | bibcode=2021PhRvL.126c2503S |display-authors = 3|doi-access = free|hdl = 10486/705608|hdl-access = free}}</ref>
| α (2%)
| <sup>280</sup>Ds
| <sup>280</sup>Ds<ref name=Kaji>{{cite journal |last1=Kaji |first1=Daiya |last2=Morita |first2=Kosuke |first3=Kouji |last3=Morimoto |first4=Hiromitsu |last4=Haba |first5=Masato |last5=Asai |first6=Kunihiro |last6=Fujita |first7=Zaiguo |last7=Gan |first8=Hans |last8=Geissel |first9=Hiroo |last9=Hasebe |first10=Sigurd |last10=Hofmann |first11=MingHui |last11=Huang |first12=Yukiko |last12=Komori |first13=Long |last13=Ma |first14=Joachim |last14=Maurer |first15=Masashi |last15=Murakami |first16=Mirei |last16=Takeyama |first17=Fuyuki |last17=Tokanai |first18=Taiki |last18=Tanaka |first19=Yasuo |last19=Wakabayashi |first20=Takayuki |last20=Yamaguchi |first21=Sayaka |last21=Yamaki |first22=Atsushi |last22=Yoshida |display-authors=3 |date=2017 |title=Study of the Reaction <sup>48</sup>Ca + <sup>248</sup>Cm → <sup>296</sup>Lv* at RIKEN-GARIS |journal=Journal of the Physical Society of Japan |volume=86 |issue=3 |pages=034201–1–7 |doi=10.7566/JPSJ.86.034201 |bibcode=2017JPSJ...86c4201K }}</ref><ref name=280Ds2021>{{Cite journal |url = https://journals.aps.org/prl/pdf/10.1103/PhysRevLett.126.032503|doi = 10.1103/PhysRevLett.126.032503|title = Spectroscopy along Flerovium Decay Chains: Discovery of <sup>280</sup>Ds and an Excited State in <sup>282</sup>Cn|journal = Physical Review Letters|volume = 126|pages = 032503|year = 2021|last1 = Såmark-Roth|first1 = A.|last2 = Cox|first2 = D. M.|last3 = Rudolph|first3 = D.|last4 = Sarmento|first4 = L. G.|last5 = Carlsson|first5 = B. G.|last6 = Egido|first6 = J. L.|last7 = Golubev|first7 = P|last8 = Heery|first8 = J.|last9 = Yakushev|first9 = A.|last10 = Åberg|first10 = S.|last11 = Albers|first11 = H. M.|last12 = Albertsson|first12 = M.|last13 = Block|first13 = M.|last14 = Brand|first14 = H.|last15 = Calverley|first15 = T.|last16 = Cantemir|first16 = R.|last17 = Clark|first17 = R. M.|last18 = Düllmann|first18 = Ch. E.|last19 = Eberth|first19 = J.|last20 = Fahlander|first20 = C.|last21 = Forsberg|first21 = U.|last22 = Gates|first22 = J. M.|last23 = Giacoppo|first23 = F.|last24 = Götz|first24 = M.|last25 = Hertzberg|first25 = R.-D.|last26 = Hrabar|first26 = Y.|last27 = Jäger|first27 = E.|last28 = Judson|first28 = D.|last29 = Khuyagbaatar|first29 = J.|last30 = Kindler|first30 = B.|display-authors = 3|doi-access = free}}</ref><ref>{{Cite journal |arxiv = 1502.03030|doi = 10.1016/j.nuclphysa.2016.04.025|title = Recoil-α-fission and recoil-α–α-fission events observed in the reaction 48Ca + 243Am|journal = Nuclear Physics A|volume = 953|pages = 117–138|year = 2016|last1 = Forsberg|first1 = U.|last2 = Rudolph|first2 = D.|last3 = Andersson|first3 = L.-L.|last4 = Di Nitto|first4 = A.|last5 = Düllmann|first5 = Ch.E.|last6 = Fahlander|first6 = C.|last7 = Gates|first7 = J.M.|last8 = Golubev|first8 = P.|last9 = Gregorich|first9 = K.E.|last10 = Gross|first10 = C.J.|last11 = Herzberg|first11 = R.-D.|last12 = Heßberger|first12 = F.P.|last13 = Khuyagbaatar|first13 = J.|last14 = Kratz|first14 = J.V.|last15 = Rykaczewski|first15 = K.|last16 = Sarmiento|first16 = L.G.|last17 = Schädel|first17 = M.|last18 = Yakushev|first18 = A.|last19 = Åberg|first19 = S.|last20 = Ackermann|first20 = D.|last21 = Block|first21 = M.|last22 = Brand|first22 = H.|last23 = Carlsson|first23 = B.G.|last24 = Cox|first24 = D.|last25 = Derkx|first25 = X.|last26 = Dobaczewski|first26 = J.|last27 = Eberhardt|first27 = K.|last28 = Even|first28 = J.|last29 = Gerl|first29 = J.|last30 = Jäger|first30 = E.|display-authors = 3|bibcode = 2016NuPhA.953..117F}}</ref>
|-id=Copernicium-285
|-
| <sup>285</sup>Cn<ref group=n>Not directly synthesized, created as decay product of <sup>289</sup>Fl</ref>
| <sup>285</sup>Cn<ref group=n>Not directly synthesized, created as decay product of <sup>289</sup>Fl</ref>
| 112
| 112
| 173
| 173
| 285.17712(60)#
| 285.17723(54)#
| {{val|30|(8)|u=s}}
| 29&nbsp;s
| α
| α
| <sup>281</sup>Ds
| <sup>281</sup>Ds
Line 106: Line 92:
| <sup>281m</sup>Ds
| <sup>281m</sup>Ds
| -->
| -->
|-id=Copernicium-286
|-
| <sup>286</sup>Cn<ref name="Kaji">{{cite journal |last1=Kaji |first1=Daiya |last2=Morita |first2=Kosuke |first3=Kouji |last3=Morimoto |first4=Hiromitsu |last4=Haba |first5=Masato |last5=Asai |first6=Kunihiro |last6=Fujita |first7=Zaiguo |last7=Gan |first8=Hans |last8=Geissel |first9=Hiroo |last9=Hasebe |first10=Sigurd |last10=Hofmann |first11=MingHui |last11=Huang |first12=Yukiko |last12=Komori |first13=Long |last13=Ma |first14=Joachim |last14=Maurer |first15=Masashi |last15=Murakami |first16=Mirei |last16=Takeyama |first17=Fuyuki |last17=Tokanai |first18=Taiki |last18=Tanaka |first19=Yasuo |last19=Wakabayashi |first20=Takayuki |last20=Yamaguchi |first21=Sayaka |last21=Yamaki |first22=Atsushi |last22=Yoshida |display-authors=3 |date=2017 |title=Study of the Reaction <sup>48</sup>Ca + <sup>248</sup>Cm → <sup>296</sup>Lv* at RIKEN-GARIS |journal=Journal of the Physical Society of Japan |volume=86 |issue=3 |pages=034201–1–7 |doi=10.7566/JPSJ.86.034201 |bibcode=2017JPSJ...86c4201K }}</ref><ref group=n>Not directly synthesized, created as decay product of <sup>294</sup>Lv</ref><ref group=n>This isotope is unconfirmed</ref>
| <sup>286</sup>Cn<ref name=Kaji/><ref group=n>Not directly synthesized, created as decay product of <sup>294</sup>Lv</ref><ref group=n>This isotope is unconfirmed</ref>
| 112
| 112
| 174
| 174
| 286.17869(75)#
|
| {{val|8.4|40.5|3.9|u=s}}
| 8.45&nbsp;s
| SF
| (various)
| 0+
|-
| <sup>287</sup>Cn<ref name=Kaji/><ref group=n>Not directly synthesized, created as decay product of <sup>287</sup>Nh</ref><ref group=n>This isotope is unconfirmed</ref>
| 112
| 175
|
| 40 m
| SF
| SF
| (various)
| (various)
Line 129: Line 106:


===Nucleosynthesis===
===Nucleosynthesis===
[[Superheavy element]]s such as copernicium are produced by bombarding lighter elements in [[particle accelerator]]s that induces [[fusion reaction]]s. Whereas most of the isotopes of copernicium can be synthesized directly this way, some heavier ones have only been observed as decay products of elements with higher [[atomic number]]s.<ref name=fusion>
[[Superheavy element]]s such as copernicium are produced by bombarding lighter elements in [[particle accelerator]]s that induces [[fusion reaction]]s. Whereas most of the isotopes of copernicium can be synthesized directly this way, some heavier ones have only been observed as decay products of elements with higher [[atomic number]]s.<ref name="fusion">
{{cite journal
{{cite journal
|last1=Barber |first1=R. C.
|last1=Barber |first1=R. C.
Line 137: Line 114:
|volume=81 |issue=7 |page=1331
|volume=81 |issue=7 |page=1331
|doi=10.1351/PAC-REP-08-03-05
|doi=10.1351/PAC-REP-08-03-05
|s2cid=95703833
|url=http://pac.iupac.org/publications/pac/pdf/2009/pdf/8107x1331.pdf
|url=http://pac.iupac.org/publications/pac/pdf/2009/pdf/8107x1331.pdf
|display-authors=etal}}</ref>
|display-authors=etal}}</ref>


Depending on the energies involved, the former are separated into "hot" and "cold". In hot fusion reactions, very light, high-energy projectiles are accelerated toward very heavy targets such as [[actinide]]s, giving rise to compound nuclei at high excitation energy (~40–50&nbsp;[[electronvolt|MeV]]) that may either fission or evaporate several (3 to 5) neutrons.<ref name=fusion/> In cold fusion reactions, the produced fused nuclei have a relatively low excitation energy (~10–20&nbsp;MeV), which decreases the probability that these products will undergo fission reactions. As the fused nuclei cool to the [[ground state]], they require emission of only one or two neutrons, and thus, allows for the generation of more neutron-rich products.<ref name=AM89>
Depending on the energies involved, the former are separated into "hot" and "cold". In hot fusion reactions, very light, high-energy projectiles are accelerated toward very heavy targets such as [[actinide]]s, giving rise to compound nuclei at high excitation energy (~40–50&nbsp;[[electronvolt|MeV]]) that may either fission or evaporate several (3 to 5) neutrons.<ref name="fusion"/> In cold fusion reactions, the produced fused nuclei have a relatively low excitation energy (~10–20&nbsp;MeV), which decreases the probability that these products will undergo fission reactions. As the fused nuclei cool to the [[ground state]], they require emission of only one or two neutrons, and thus, allows for the generation of more neutron-rich products.<ref name="AM89">
{{Cite journal
{{Cite journal
|last1=Armbruster |first1=P.
|last1=Armbruster |first1=P.
Line 149: Line 127:
|volume=34 |pages=1331–1339
|volume=34 |pages=1331–1339
|osti=6481060
|osti=6481060
}}</ref> The latter is a distinct concept from that of where nuclear fusion claimed to be achieved at room temperature conditions (see [[cold fusion]]).<ref>
}}</ref> The latter is a distinct concept from that of where nuclear fusion claimed to be achieved at room temperature conditions (see [[cold fusion]]).<ref name="Cn-Fleischmann">
{{cite journal
{{cite journal
|last1=Fleischmann |first1=M.
|last1=Fleischmann |first1=M.
Line 203: Line 181:


====Cold fusion====
====Cold fusion====
The first cold fusion reaction to produce copernicium was performed by GSI in 1996, who reported the detection of two decay chains of copernicium-277.<ref name=96Ho01>{{Cite journal|title=The new element 112|journal=[[Zeitschrift für Physik A]] |author=S. Hofmann|volume=354|issue=1|year=1996|pages=229–230|doi=10.1007/BF02769517|display-authors=etal|bibcode=1996ZPhyA.354..229H}}</ref>
The first cold fusion reaction to produce copernicium was performed by GSI in 1996, who reported the detection of two decay chains of copernicium-277.<ref name="96Ho01">{{Cite journal|title=The new element 112|journal=[[Zeitschrift für Physik A]] |author=S. Hofmann|volume=354|issue=1|year=1996|pages=229–230|doi=10.1007/BF02769517|display-authors=etal|bibcode=1996ZPhyA.354..229H|s2cid=119975957 }}</ref>


:{{nuclide|link=yes|lead|208}} + {{nuclide|link=yes|zinc|70}} → {{nuclide|copernicium|277}} + {{SubatomicParticle|link=yes|Neutron}}
:{{nuclide|link=yes|lead|208}} + {{nuclide|link=yes|zinc|70}} → {{nuclide|copernicium|277}} + {{SubatomicParticle|link=yes|Neutron}}
Line 219: Line 197:
|publisher=[[World Scientific]]
|publisher=[[World Scientific]]
|doi=10.1142/9789812701749_0027
|doi=10.1142/9789812701749_0027
}}</ref> This reaction had also previously been tried in 1971 at the [[Joint Institute for Nuclear Research]] in [[Dubna]], [[Russia]] in an effort to produce <sup>276</sup>Cn in the 2n channel, but without success.<ref>{{cite web |url=http://newuc.jinr.ru/img_sections/file/Practice2016/EU/2016-07%20AGP_SHE.pdf |title=Synthesis of superheavy elements |last=Popeko |first=Andrey G. |date=2016 |website=jinr.ru |publisher=[[Joint Institute for Nuclear Research]] |access-date=4 February 2018 |archive-url=https://web.archive.org/web/20180204124109/http://newuc.jinr.ru/img_sections/file/Practice2016/EU/2016-07%20AGP_SHE.pdf |archive-date=4 February 2018 |url-status=dead }}</ref>
}}</ref> This reaction had also previously been tried in 1971 at the [[Joint Institute for Nuclear Research]] in [[Dubna]], [[Russia]] in an effort to produce <sup>276</sup>Cn in the 2n channel, but without success.<ref name="Cn-Popeko">{{cite web |url=http://newuc.jinr.ru/img_sections/file/Practice2016/EU/2016-07%20AGP_SHE.pdf |title=Synthesis of superheavy elements |last=Popeko |first=Andrey G. |date=2016 |website=jinr.ru |publisher=[[Joint Institute for Nuclear Research]] |access-date=4 February 2018 |archive-url=https://web.archive.org/web/20180204124109/http://newuc.jinr.ru/img_sections/file/Practice2016/EU/2016-07%20AGP_SHE.pdf |archive-date=4 February 2018 |url-status=dead }}</ref>


After the successful synthesis of copernicium-277, the GSI team performed a reaction using a <sup>68</sup>Zn projectile in 1997 in an effort to study the effect of [[isospin]] (neutron richness) on the chemical yield.
After the successful synthesis of copernicium-277, the GSI team performed a reaction using a <sup>68</sup>Zn projectile in 1997 in an effort to study the effect of [[isospin]] (neutron richness) on the chemical yield.
Line 227: Line 205:
In 1990, after some early indications for the formation of isotopes of copernicium in the irradiation of a tungsten target with multi-GeV protons, a collaboration between GSI and the [[Hebrew University]] studied the foregoing reaction.
In 1990, after some early indications for the formation of isotopes of copernicium in the irradiation of a tungsten target with multi-GeV protons, a collaboration between GSI and the [[Hebrew University]] studied the foregoing reaction.
:{{nuclide|link=yes|tungsten|184}} + {{nuclide|link=yes|strontium|88}} → {{nuclide|copernicium|272−x}} + x {{SubatomicParticle|link=yes|Neutron}}
:{{nuclide|link=yes|tungsten|184}} + {{nuclide|link=yes|strontium|88}} → {{nuclide|copernicium|272−x}} + x {{SubatomicParticle|link=yes|Neutron}}
They were able to detect some [[spontaneous fission]] (SF) activity and a 12.5&nbsp;MeV [[alpha decay]], both of which they tentatively assigned to the radiative capture product copernicium-272 or the 1n evaporation residue copernicium-271. Both the TWG and JWP have concluded that a lot more research is required to confirm these conclusions.<ref name=fusion/>
They were able to detect some [[spontaneous fission]] (SF) activity and a 12.5&nbsp;MeV [[alpha decay]], both of which they tentatively assigned to the radiative capture product copernicium-272 or the 1n evaporation residue copernicium-271. Both the TWG and JWP have concluded that a lot more research is required to confirm these conclusions.<ref name="fusion"/>


====Hot fusion====
====Hot fusion====
In 1998, the team at the Flerov Laboratory of Nuclear Research (FLNR) in Dubna, Russia began a research program using calcium-48 nuclei in "warm" fusion reactions leading to [[super-heavy element]]s. In March 1998, they claimed to have synthesized two atoms of the element in the following reaction.
In 1998, the team at the Flerov Laboratory of Nuclear Research (FLNR) in Dubna, Russia began a research program using calcium-48 nuclei in "warm" fusion reactions leading to [[super-heavy element]]s. In March 1998, they claimed to have synthesized two atoms of the element in the following reaction.
:{{nuclide|link=yes|uranium|238}} + {{nuclide|link=yes|calcium|48}} → {{nuclide|copernicium|286−x}} + x {{SubatomicParticle|link=yes|Neutron}} (x=3,4)
:{{nuclide|link=yes|uranium|238}} + {{nuclide|link=yes|calcium|48}} → {{nuclide|copernicium|286−x}} + x {{SubatomicParticle|link=yes|Neutron}} (x=3,4)
The product, copernicium-283, had a claimed half-life of 5&nbsp;minutes, decaying by spontaneous fission.<ref>
The product, copernicium-283, had a claimed half-life of 5&nbsp;minutes, decaying by spontaneous fission.<ref name="283Cn-Oganessian">
{{Cite journal
{{Cite journal
|last1=Oganessian |first1=Yu. Ts.
|last1=Oganessian |first1=Yu. Ts.
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|bibcode=1999EPJA....5...63O
|bibcode=1999EPJA....5...63O
|doi=10.1007/s100500050257
|doi=10.1007/s100500050257
|s2cid=59326674
|display-authors=etal}}</ref>
|display-authors=etal}}</ref>


The long half-life of the product initiated first chemical experiments on the gas phase atomic chemistry of copernicium. In 2000, Yuri Yukashev in Dubna repeated the experiment but was unable to observe any [[spontaneous fission]] events with half-life of 5&nbsp;minutes. The experiment was repeated in 2001 and an accumulation of eight fragments resulting from spontaneous fission were found in the low-temperature section, indicating that copernicium had radon-like properties. However, there is now some serious doubt about the origin of these results. To confirm the synthesis, the reaction was successfully repeated by the same team in January 2003, confirming the decay mode and half-life. They were also able to calculate an estimate of the mass of the spontaneous fission activity to ~285, lending support to the assignment.<ref>
The long half-life of the product initiated first chemical experiments on the gas phase atomic chemistry of copernicium. In 2000, Yuri Yukashev in Dubna repeated the experiment but was unable to observe any [[spontaneous fission]] events with half-life of 5&nbsp;minutes. The experiment was repeated in 2001 and an accumulation of eight fragments resulting from spontaneous fission were found in the low-temperature section, indicating that copernicium had radon-like properties. However, there is now some serious doubt about the origin of these results. To confirm the synthesis, the reaction was successfully repeated by the same team in January 2003, confirming the decay mode and half-life. They were also able to calculate an estimate of the mass of the spontaneous fission activity to ~285, lending support to the assignment.<ref name="285Cn-Oganessian">
{{Cite journal
{{Cite journal
|last1=Oganessian |first1=Yu. Ts.
|last1=Oganessian |first1=Yu. Ts.
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|bibcode=2004EPJA...19....3O
|bibcode=2004EPJA...19....3O
|doi=10.1140/epja/i2003-10113-4
|doi=10.1140/epja/i2003-10113-4
|s2cid=122175380
|display-authors=etal}}</ref>
|display-authors=etal}}</ref>


The team at [[Lawrence Berkeley National Laboratory]] (LBNL) in Berkeley, United States entered the debate and performed the reaction in 2002. They were unable to detect any spontaneous fission and calculated a cross section limit of 1.6&nbsp;pb for the detection of a single event.<ref>
The team at [[Lawrence Berkeley National Laboratory]] (LBNL) in Berkeley, United States entered the debate and performed the reaction in 2002. They were unable to detect any spontaneous fission and calculated a cross section limit of 1.6&nbsp;pb for the detection of a single event.<ref name="Cn-Loveland">
{{Cite journal
{{Cite journal
|last1=Loveland |first1=W.
|last1=Loveland |first1=W.
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|bibcode=2002PhRvC..66d4617L
|bibcode=2002PhRvC..66d4617L
|doi=10.1103/PhysRevC.66.044617
|doi=10.1103/PhysRevC.66.044617
|s2cid=36216985
|display-authors=etal}}</ref>
|display-authors=etal}}</ref>


The reaction was repeated in 2003–2004 by the team at Dubna using a slightly different set-up, the Dubna Gas-Filled Recoil Separator (DGFRS). This time, copernicium-283 was found to decay by emission of a 9.53&nbsp;MeV alpha-particle with a half-life of 4&nbsp;seconds. Copernicium-282 was also observed in the 4n channel (emitting 4&nbsp;neutrons).<ref name=04Og01>
The reaction was repeated in 2003–2004 by the team at Dubna using a slightly different set-up, the Dubna Gas-Filled Recoil Separator (DGFRS). This time, copernicium-283 was found to decay by emission of a 9.53&nbsp;MeV alpha-particle with a half-life of 4&nbsp;seconds. Copernicium-282 was also observed in the 4n channel (emitting 4&nbsp;neutrons).<ref name="04Og01">
{{cite journal|title=Measurements of cross sections and decay properties of the isotopes of elements 112, 114, and 116 produced in the fusion reactions <sup>233,238</sup>U, <sup>242</sup>Pu, and <sup>248</sup>Cm+<sup>48</sup>Ca|doi=10.1103/PhysRevC.70.064609|year=2004|journal=Physical Review C|volume=70|page=064609|last1=Oganessian|first1=Yu. Ts.|last2=Utyonkov|first2=V.|last3=Lobanov|first3=Yu.|last4=Abdullin|first4=F.|last5=Polyakov|first5=A.|last6=Shirokovsky|first6=I.|last7=Tsyganov|first7=Yu.|last8=Gulbekian|first8=G.|last9=Bogomolov|first9=S.|first10=B. N. |last10=Gikal|first11=A. N. |last11=Mezentsev|first12=S. |last12=Iliev|first13=V. G. |last13=Subbotin|first14=A. M. |last14=Sukhov|first15=A. A. |last15=Voinov|first16=G. V. |last16=Buklanov|first17=K. |last17=Subotic|first18=V. I. |last18=Zagrebaev|first19=M. G. |last19=Itkis|first20=J. B. |last20=Patin|first21=K. J. |last21=Moody|first22=J. F. |last22=Wild|first23=M. A. |last23=Stoyer|first24=N. J. |last24=Stoyer|first25=D. A. |last25=Shaughnessy|first26=J. M. |last26=Kenneally|first27=P. A. |last27=Wilk|first28=R. W. |last28=Lougheed|first29=R. I. |last29=Il’kaev|first30=S. P. |last30=Vesnovskii|display-authors=10|bibcode = 2004PhRvC..70f4609O|issue=6|url=http://www1.jinr.ru/Preprints/2004/160(E7-2004-160).pdf}}</ref>
{{cite journal|title=Measurements of cross sections and decay properties of the isotopes of elements 112, 114, and 116 produced in the fusion reactions <sup>233,238</sup>U, <sup>242</sup>Pu, and <sup>248</sup>Cm+<sup>48</sup>Ca|doi=10.1103/PhysRevC.70.064609|year=2004|journal=Physical Review C|volume=70|page=064609|last1=Oganessian|first1=Yu. Ts.|last2=Utyonkov|first2=V.|last3=Lobanov|first3=Yu.|last4=Abdullin|first4=F.|last5=Polyakov|first5=A.|last6=Shirokovsky|first6=I.|last7=Tsyganov|first7=Yu.|last8=Gulbekian|first8=G.|last9=Bogomolov|first9=S.|first10=B. N. |last10=Gikal|first11=A. N. |last11=Mezentsev|first12=S. |last12=Iliev|first13=V. G. |last13=Subbotin|first14=A. M. |last14=Sukhov|first15=A. A. |last15=Voinov|first16=G. V. |last16=Buklanov|first17=K. |last17=Subotic|first18=V. I. |last18=Zagrebaev|first19=M. G. |last19=Itkis|first20=J. B. |last20=Patin|first21=K. J. |last21=Moody|first22=J. F. |last22=Wild|first23=M. A. |last23=Stoyer|first24=N. J. |last24=Stoyer|first25=D. A. |last25=Shaughnessy|first26=J. M. |last26=Kenneally|first27=P. A. |last27=Wilk|first28=R. W. |last28=Lougheed|first29=R. I. |last29=Il’kaev|first30=S. P. |last30=Vesnovskii|display-authors=10|bibcode = 2004PhRvC..70f4609O|issue=6|url=http://www1.jinr.ru/Preprints/2004/160(E7-2004-160).pdf}}</ref>


In 2003, the team at GSI entered the debate and performed a search for the five-minute SF activity in chemical experiments. Like the Dubna team, they were able to detect seven SF fragments in the low temperature section. However, these SF events were uncorrelated, suggesting they were not from actual direct SF of copernicium nuclei and raised doubts about the original indications for radon-like properties.<ref>
In 2003, the team at GSI entered the debate and performed a search for the five-minute SF activity in chemical experiments. Like the Dubna team, they were able to detect seven SF fragments in the low temperature section. However, these SF events were uncorrelated, suggesting they were not from actual direct SF of copernicium nuclei and raised doubts about the original indications for radon-like properties.<ref name="Cn-Soverna">
{{Cite journal
{{Cite report
|last1 = Soverna
|last1 = Soverna
|first1 = S.
|first1 = S.
Line 282: Line 263:
}}</ref> After the announcement from Dubna of different decay properties for copernicium-283, the GSI team repeated the experiment in September 2004. They were unable to detect any SF events and calculated a cross section limit of ~1.6&nbsp;pb for the detection of one event, not in contradiction with the reported 2.5&nbsp;pb yield by Dubna team.
}}</ref> After the announcement from Dubna of different decay properties for copernicium-283, the GSI team repeated the experiment in September 2004. They were unable to detect any SF events and calculated a cross section limit of ~1.6&nbsp;pb for the detection of one event, not in contradiction with the reported 2.5&nbsp;pb yield by Dubna team.


In May 2005, the GSI performed a physical experiment and identified a single atom of <sup>283</sup>Cn decaying by SF with a short half-time suggesting a previously unknown SF branch.<ref>
In May 2005, the GSI performed a physical experiment and identified a single atom of <sup>283</sup>Cn decaying by SF with a short half-time suggesting a previously unknown SF branch.<ref name="283Cn-Hofmann-2005">
{{Cite journal
{{Cite report
|last1 = Hofmann
|last1 = Hofmann
|first1 = S.
|first1 = S.
Line 298: Line 279:
However, initial work by Dubna team had detected several direct SF events but had assumed that the parent alpha decay had been missed. These results indicated that this was not the case.
However, initial work by Dubna team had detected several direct SF events but had assumed that the parent alpha decay had been missed. These results indicated that this was not the case.


The new decay data on copernicium-283 were confirmed in 2006 by a joint PSI–FLNR experiment aimed at probing the chemical properties of copernicium. Two atoms of copernicium-283 were observed in the decay of the parent [[flerovium]]-287 nuclei. The experiment indicated that contrary to previous experiments, copernicium behaves as a typical member of group 12, demonstrating properties of a volatile metal.<ref name=07Ei01>{{Cite journal |title=Chemical Characterization of Element 112 |journal=[[Nature (journal)|Nature]] |year=2007 |volume=447 |pages=72–75 |doi=10.1038/nature05761 |pmid=17476264 |last1=Eichler |first1=R | last2=Aksenov |first2=NV |last3=Belozerov |first3=AV |last4=Bozhikov |first4=GA |last5=Chepigin |first5=VI |last6=Dmitriev |first6=SN |last7=Dressler |first7=R |last8=Gäggeler |first8=HW |last9=Gorshkov |first9=VA |issue=7140 |bibcode = 2007Natur.447...72E}}</ref>
The new decay data on copernicium-283 were confirmed in 2006 by a joint PSI–FLNR experiment aimed at probing the chemical properties of copernicium. Two atoms of copernicium-283 were observed in the decay of the parent [[flerovium]]-287 nuclei. The experiment indicated that contrary to previous experiments, copernicium behaves as a typical member of group 12, demonstrating properties of a volatile metal.<ref name="07Ei01">{{Cite journal |title=Chemical Characterization of Element 112 |journal=[[Nature (journal)|Nature]] |year=2007 |volume=447 |pages=72–75 |doi=10.1038/nature05761 |pmid=17476264 |last1=Eichler |first1=R | last2=Aksenov |first2=NV |last3=Belozerov |first3=AV |last4=Bozhikov |first4=GA |last5=Chepigin |first5=VI |last6=Dmitriev |first6=SN |last7=Dressler |first7=R |last8=Gäggeler |first8=HW |last9=Gorshkov |first9=VA |issue=7140 |bibcode = 2007Natur.447...72E|s2cid=4347419 }}</ref>


Finally, the team at GSI successfully repeated their physical experiment in January 2007, and detected three atoms of copernicium-283, confirming both the alpha and SF decay modes.<ref>
Finally, the team at GSI successfully repeated their physical experiment in January 2007, and detected three atoms of copernicium-283, confirming both the alpha and SF decay modes.<ref name="283Cn-Hofmann-2007">
{{Cite journal
{{Cite journal
|last1=Hofmann |first1=S.
|last1=Hofmann |first1=S.
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|bibcode=2007EPJA...32..251H
|bibcode=2007EPJA...32..251H
|doi=10.1007/BF01415134
|doi=10.1007/BF01415134
|s2cid=100784990
|display-authors=etal}}</ref>
|display-authors=etal}}</ref>


As such, the 5-minute SF activity is still unconfirmed and unidentified. It is possible that it refers to an isomer, namely copernicium-283b, whose yield is dependent upon the exact production methods. It is also possible that it is the result of an electron capture branch in <sup>283</sup>Cn leading to <sup>283</sup>Rg, which would necessitate a reassignment of its parent to <sup>287</sup>Nh (the electron-capture daughter of <sup>287</sup>Fl).<ref name=EXON/>
As such, the 5-minute SF activity is still unconfirmed and unidentified. It is possible that it refers to an isomer, namely copernicium-283b, whose yield is dependent upon the exact production methods. It is also possible that it is the result of an electron capture branch in <sup>283</sup>Cn leading to <sup>283</sup>Rg, which would necessitate a reassignment of its parent to <sup>287</sup>Nh (the electron-capture daughter of <sup>287</sup>Fl).<ref name="EXON"/>


:{{nuclide|link=yes|uranium|233}} + {{nuclide|link=yes|calcium|48}} → {{nuclide|copernicium|281−x}} + x {{SubatomicParticle|link=yes|Neutron}}
:{{nuclide|link=yes|uranium|233}} + {{nuclide|link=yes|calcium|48}} → {{nuclide|copernicium|281−x}} + x {{SubatomicParticle|link=yes|Neutron}}
The team at FLNR studied this reaction in 2004. They were unable to detect any atoms of copernicium and calculated a cross section limit of 0.6&nbsp;pb. The team concluded that this indicated that the neutron mass number for the compound nucleus has an effect on the yield of evaporation residues.<ref name=04Og01/>
The team at FLNR studied this reaction in 2004. They were unable to detect any atoms of copernicium and calculated a cross section limit of 0.6&nbsp;pb. The team concluded that this indicated that the neutron mass number for the compound nucleus has an effect on the yield of evaporation residues.<ref name="04Og01"/>


====Decay products====
====Decay products====
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! Evaporation residue !! Observed copernicium isotope
! Evaporation residue !! Observed copernicium isotope
|-
|-
|<sup>285</sup>Fl ||<sup>281</sup>Cn<ref name="281Cn">
|<sup>288</sup>Lv, <sup>284</sup>Fl ||<sup>280</sup>Cn<ref name=jinr2024/>
|-
|<sup>289</sup>Lv, <sup>285</sup>Fl ||<sup>281</sup>Cn<ref name=jinr2024/><ref name="281Cn">
{{Cite news
{{Cite news
|author=Public Affairs Department
|author=Public Affairs Department
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|-
|-
|<sup>291</sup>Lv, <sup>287</sup>Fl||<sup>283</sup>Cn<ref name="283Cn">
|<sup>291</sup>Lv, <sup>287</sup>Fl||<sup>283</sup>Cn<ref name="283Cn">
{{cite journal|doi=10.1038/22281|title=Synthesis of nuclei of the superheavy element 114 in reactions induced by <sup>48</sup>Ca|year=1999|journal=Nature|volume=400|pages=242–245|last1=Oganessian|first1=Yu. Ts.|last2=Yeremin|first2=A. V.|last3=Popeko|first3=A. G.|last4=Bogomolov|first4=S. L.|last5=Buklanov|first5=G. V.|last6=Chelnokov|first6=M. L.|last7=Chepigin|first7=V. I.|last8=Gikal|first8=B. N.|last9=Gorshkov|first9=V. A.|first10=G. G.|last10=Gulbekian|first11=M. G.|last11=Itkis|first12=A. P.|last12=Kabachenko|first13=A. Yu.|last13=Lavrentev|first14=O. N.|last14=Malyshev|first15=J.|last15=Rohac|first16=R. N.|last16=Sagaidak|first17=S.|last17=Hofmann|first18=S.|last18=Saro|first19=G.|last19=Giardina|first20=K.|last20=Morita|display-authors=10|bibcode = 1999Natur.400..242O|issue=6741}}</ref>
{{cite journal|doi=10.1038/22281|title=Synthesis of nuclei of the superheavy element 114 in reactions induced by <sup>48</sup>Ca|year=1999|journal=Nature|volume=400|pages=242–245|last1=Oganessian|first1=Yu. Ts.|last2=Yeremin|first2=A. V.|last3=Popeko|first3=A. G.|last4=Bogomolov|first4=S. L.|last5=Buklanov|first5=G. V.|last6=Chelnokov|first6=M. L.|last7=Chepigin|first7=V. I.|last8=Gikal|first8=B. N.|last9=Gorshkov|first9=V. A.|first10=G. G.|last10=Gulbekian|first11=M. G.|last11=Itkis|first12=A. P.|last12=Kabachenko|first13=A. Yu.|last13=Lavrentev|first14=O. N.|last14=Malyshev|first15=J.|last15=Rohac|first16=R. N.|last16=Sagaidak|first17=S.|last17=Hofmann|first18=S.|last18=Saro|first19=G.|last19=Giardina|first20=K.|last20=Morita|display-authors=10|bibcode = 1999Natur.400..242O|issue=6741|s2cid=4399615 }}</ref>
|-
|-
|<sup>292</sup>Lv, <sup>288</sup>Fl||<sup>284</sup>Cn<ref name="284Cn">
|<sup>292</sup>Lv, <sup>288</sup>Fl||<sup>284</sup>Cn<ref name="284Cn">
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|bibcode=2004PhRvC..69e4607O
|bibcode=2004PhRvC..69e4607O
|doi=10.1103/PhysRevC.69.054607
|doi=10.1103/PhysRevC.69.054607
|url=http://link.aps.org/abstract/PRC/V69/E054607/
|display-authors=etal}}</ref>
|display-authors=etal|doi-access=free
}}</ref>
|-
|-
|<sup>294</sup>Lv, <sup>290</sup>Fl ?||<sup>286</sup>Cn ?<ref name=Kaji/>
|<sup>294</sup>Lv, <sup>290</sup>Fl ?||<sup>286</sup>Cn ?<ref name="Kaji"/>
|}</div>
|}</div>
Copernicium has been observed as decay products of [[flerovium]]. Flerovium currently has seven known isotopes, all but one (the lightest, <sup>284</sup>Fl) of which have been shown to undergo alpha decays to become copernicium nuclei, with [[mass number]]s between 281 and 286. Copernicium isotopes with mass numbers 281, 284, 285, and 286 to date have only been produced by flerovium nuclei decay.
Copernicium has been observed as decay products of [[flerovium]]. Flerovium currently has seven known isotopes, all of which have been shown to undergo alpha decays to become copernicium nuclei, with [[mass number]]s between 280 and 286. Copernicium isotopes with mass numbers 280, 281, 284, 285, and 286 to date have only been produced by flerovium nuclei decay. Parent flerovium nuclei can be themselves decay products of [[livermorium]] or [[oganesson]].<ref name="nuclidetable">{{CRC85|chapter=11}}</ref>
Parent flerovium nuclei can be themselves decay products of [[livermorium]] or [[oganesson]]. To date, no other elements have been known to decay to copernicium.<ref name=nuclidetable>{{CRC85|chapter=11}}</ref>


For example, in May 2006, the Dubna team ([[Joint Institute for Nuclear Research|JINR]]) identified copernicium-282 as a final product in the decay of oganesson via the alpha decay sequence. It was found that the final nucleus undergoes [[spontaneous fission]].<ref name="282Cn">{{cite journal |first1=Yu. Ts. |last1=Oganessian |first2=V. K. |last2=Utyonkov |first3=Yu. V. |last3=Lobanov |first4=F. Sh. |last4=Abdullin |first5=A. N. |last5=Polyakov |first6=R. N. |last6=Sagaidak |first7=I. V. |last7=Shirokovsky |first8=Yu. S. |last8=Tsyganov |first9=A. A. |last9=Voinov |first10=G. G. |last10=Gulbekian |first11=S. L. |last11=Bogomolov |first12=B. N. |last12=Gikal |first13=A. N. |last13=Mezentsev |first14=S. |last14=Iliev |first15=V. G. |last15=Subbotin |first16=A. M. |last16=Sukhov |first17=K. |last17=Subotic |first18=V. I. |last18=Zagrebaev |first19=G. K. |last19=Vostokin |first20=M. G. |last20=Itkis |first21=K. J. |last21=Moody |first22=J. B. |last22=Patin |first23=D. A. |last23=Shaughnessy |first24=M. A. |last24=Stoyer |first25=N. J. |last25=Stoyer |first26=P. A. |last26=Wilk |first27=J. M. |last27=Kenneally |first28=J. H. |last28=Landrum |first29=J. F. |last29=Wild |first30=R. W. |last30=Lougheed
For example, in May 2006, the Dubna team ([[Joint Institute for Nuclear Research|JINR]]) identified copernicium-282 as a final product in the decay of oganesson via the alpha decay sequence. It was found that the final nucleus undergoes [[spontaneous fission]].<ref name="282Cn">{{cite journal |first1=Yu. Ts. |last1=Oganessian |first2=V. K. |last2=Utyonkov |first3=Yu. V. |last3=Lobanov |first4=F. Sh. |last4=Abdullin |first5=A. N. |last5=Polyakov |first6=R. N. |last6=Sagaidak |first7=I. V. |last7=Shirokovsky |first8=Yu. S. |last8=Tsyganov |first9=A. A. |last9=Voinov |first10=G. G. |last10=Gulbekian |first11=S. L. |last11=Bogomolov |first12=B. N. |last12=Gikal |first13=A. N. |last13=Mezentsev |first14=S. |last14=Iliev |first15=V. G. |last15=Subbotin |first16=A. M. |last16=Sukhov |first17=K. |last17=Subotic |first18=V. I. |last18=Zagrebaev |first19=G. K. |last19=Vostokin |first20=M. G. |last20=Itkis |first21=K. J. |last21=Moody |first22=J. B. |last22=Patin |first23=D. A. |last23=Shaughnessy |first24=M. A. |last24=Stoyer |first25=N. J. |last25=Stoyer |first26=P. A. |last26=Wilk |first27=J. M. |last27=Kenneally |first28=J. H. |last28=Landrum |first29=J. F. |last29=Wild |first30=R. W. |last30=Lougheed
Line 372: Line 357:
:{{nuclide|Flerovium|286}} → {{nuclide|copernicium|282}} + {{nuclide|helium|4}}
:{{nuclide|Flerovium|286}} → {{nuclide|copernicium|282}} + {{nuclide|helium|4}}


In the claimed synthesis of oganesson-293 in 1999, copernicium-281 was identified as decaying by emission of a 10.68&nbsp;MeV [[alpha particle]] with half-life 0.90&nbsp;ms.<ref name=Ninov1999>
In the claimed synthesis of oganesson-293 in 1999, copernicium-281 was identified as decaying by emission of a 10.68&nbsp;MeV [[alpha particle]] with half-life 0.90&nbsp;ms.<ref name="Ninov1999">
{{cite journal
{{cite journal
|last1=Ninov |first1=V.
|last1=Ninov |first1=V.
|year=1999
|year=1999
|title=Observation of Superheavy Nuclei Produced in the Reaction of {{SimpleNuclide2|Krypton|86}} with {{SimpleNuclide2|Lead|208}}
|title=Observation of Superheavy Nuclei Produced in the Reaction of {{SimpleNuclide|Krypton|86}} with {{SimpleNuclide|Lead|208}}
|journal=[[Physical Review Letters]]
|journal=[[Physical Review Letters]]
|volume=83 |issue=6 |pages=1104–1107
|volume=83 |issue=6 |pages=1104–1107
|doi=10.1103/PhysRevLett.83.1104
|doi=10.1103/PhysRevLett.83.1104
|bibcode=1999PhRvL..83.1104N
|bibcode=1999PhRvL..83.1104N
|display-authors=etal|url=https://zenodo.org/record/1233919/files/article.pdf
|display-authors=etal|url=https://zenodo.org/record/1233919
}}</ref> The claim was retracted in 2001. This isotope was finally created in 2010 and its decay properties contradicted the previous data.<ref name="281Cn"/>
}}</ref> The claim was retracted in 2001. This isotope was finally created in 2010 and its decay properties contradicted the previous data.<ref name="281Cn"/>


===Nuclear isomerism===
===Nuclear isomerism===
First experiments on the synthesis of <sup>283</sup>Cn produced a SF activity with half-life ~5&nbsp;min.<ref name=nuclidetable/> This activity was also observed from the alpha decay of flerovium-287. The decay mode and half-life were also confirmed in a repetition of the first experiment. Later, copernicium-283 was observed to undergo 9.52&nbsp;MeV alpha decay and SF with a half-life of 3.9&nbsp;s. It has also been found that alpha decay of copernicium-283 leads to different excited states of darmstadtium-279.<ref name=04Og01/> These results suggest the assignment of the two activities to two different isomeric levels in copernicium-283, creating copernicium-283a and copernicium-283b. This result may also be due to an electron-capture branching of the parent <sup>287</sup>Fl to <sup>287</sup>Nh, so that the longer-lived activity would be assigned to <sup>283</sup>Rg.<ref name="EXON">{{cite conference |title=Remarks on the Fission Barriers of SHN and Search for Element 120 |first1=S. |last1=Hofmann |first2=S. |last2=Heinz |first3=R. |last3=Mann |first4=J. |last4=Maurer |first5=G. |last5=Münzenberg |first6=S. |last6=Antalic |first7=W. |last7=Barth |first8=H. G. |last8=Burkhard |first9=L. |last9=Dahl |first10=K. |last10=Eberhardt |first11=R. |last11=Grzywacz |first12=J. H. |last12=Hamilton |first13=R. A. |last13=Henderson |first14=J. M. |last14=Kenneally |first15=B. |last15=Kindler |first16=I. |last16=Kojouharov |first17=R. |last17=Lang |first18=B. |last18=Lommel |first19=K. |last19=Miernik |first20=D. |last20=Miller |first21=K. J. |last21=Moody |first22=K. |last22=Morita |first23=K. |last23=Nishio |first24=A. G. |last24=Popeko |first25=J. B. |last25=Roberto |first26=J. |last26=Runke |first27=K. P. |last27=Rykaczewski |first28=S. |last28=Saro |first29=C. |last29=Schneidenberger |first30=H. J. |last30=Schött |first31=D. A. |last31=Shaughnessy |first32=M. A. |last32=Stoyer |first33=P. |last33=Thörle-Pospiech |first34=K. |last34=Tinschert |first35=N. |last35=Trautmann |first36=J. |last36=Uusitalo |first37=A. V. |last37=Yeremin |year=2016 |conference=Exotic Nuclei |editor-first1=Yu. E. |editor-last1=Peninozhkevich |editor-first2=Yu. G. |editor-last2=Sobolev |book-title=Exotic Nuclei: EXON-2016 Proceedings of the International Symposium on Exotic Nuclei |pages=155–164 |isbn=9789813226555}}</ref>
First experiments on the synthesis of <sup>283</sup>Cn produced a SF activity with half-life ~5&nbsp;min.<ref name="nuclidetable"/> This activity was also observed from the alpha decay of flerovium-287. The decay mode and half-life were also confirmed in a repetition of the first experiment. Later, copernicium-283 was observed to undergo 9.52&nbsp;MeV alpha decay and SF with a half-life of 3.9&nbsp;s. It has also been found that alpha decay of copernicium-283 leads to different excited states of darmstadtium-279.<ref name="04Og01"/> These results suggest the assignment of the two activities to two different isomeric levels in copernicium-283, creating copernicium-283a and copernicium-283b. This result may also be due to an electron-capture branching of the parent <sup>287</sup>Fl to <sup>287</sup>Nh, so that the longer-lived activity would be assigned to <sup>283</sup>Rg.<ref name="EXON">{{cite conference |title=Remarks on the Fission Barriers of SHN and Search for Element 120 |first1=S. |last1=Hofmann |first2=S. |last2=Heinz |first3=R. |last3=Mann |first4=J. |last4=Maurer |first5=G. |last5=Münzenberg |first6=S. |last6=Antalic |first7=W. |last7=Barth |first8=H. G. |last8=Burkhard |first9=L. |last9=Dahl |first10=K. |last10=Eberhardt |first11=R. |last11=Grzywacz |first12=J. H. |last12=Hamilton |first13=R. A. |last13=Henderson |first14=J. M. |last14=Kenneally |first15=B. |last15=Kindler |first16=I. |last16=Kojouharov |first17=R. |last17=Lang |first18=B. |last18=Lommel |first19=K. |last19=Miernik |first20=D. |last20=Miller |first21=K. J. |last21=Moody |first22=K. |last22=Morita |first23=K. |last23=Nishio |first24=A. G. |last24=Popeko |first25=J. B. |last25=Roberto |first26=J. |last26=Runke |first27=K. P. |last27=Rykaczewski |first28=S. |last28=Saro |first29=C. |last29=Schneidenberger |first30=H. J. |last30=Schött |first31=D. A. |last31=Shaughnessy |first32=M. A. |last32=Stoyer |first33=P. |last33=Thörle-Pospiech |first34=K. |last34=Tinschert |first35=N. |last35=Trautmann |first36=J. |last36=Uusitalo |first37=A. V. |last37=Yeremin |year=2016 |conference=Exotic Nuclei |editor-first1=Yu. E. |editor-last1=Peninozhkevich |editor-first2=Yu. G. |editor-last2=Sobolev |book-title=Exotic Nuclei: EXON-2016 Proceedings of the International Symposium on Exotic Nuclei |pages=155–164 |isbn=9789813226555}}</ref>


Copernicium-285 has only been observed as a decay product of flerovium-289 and livermorium-293; during the first recorded synthesis of flerovium, one flerovium-289 was created, which alpha decayed to copernicium-285, which itself emitted an alpha particle in 29&nbsp;seconds, releasing 9.15&nbsp;or&nbsp;9.03&nbsp;MeV.<ref name="04Og01"/> However, in the first experiment to successfully synthesize livermorium, when livermorium-293 was created, it was shown that the created nuclide alpha decayed to flerovium-289, decay data for which differed from the known values significantly. Although unconfirmed, it is highly possible that this is associated with an isomer. The resulting nuclide decayed to copernicium-285, which emitted an alpha particle with a half-life of around 10&nbsp;minutes, releasing 8.586&nbsp;MeV. Similar to its parent, it is believed to be a nuclear isomer, copernicium-285b.<ref name=03Pa01>{{cite report
Copernicium-285 has only been observed as a decay product of flerovium-289 and livermorium-293; during the first recorded synthesis of flerovium, one flerovium-289 was created, which alpha decayed to copernicium-285, which itself emitted an alpha particle in 29&nbsp;seconds, releasing 9.15&nbsp;or&nbsp;9.03&nbsp;MeV.<ref name="04Og01"/> However, in the first experiment to successfully synthesize livermorium, when livermorium-293 was created, it was shown that the created nuclide alpha decayed to flerovium-289, decay data for which differed from the known values significantly. Although unconfirmed, it is highly possible that this is associated with an isomer. The resulting nuclide decayed to copernicium-285, which emitted an alpha particle with a half-life of around 10&nbsp;minutes, releasing 8.586&nbsp;MeV. Similar to its parent, it is believed to be a nuclear isomer, copernicium-285b.<ref name="03Pa01">{{cite report
|last1=Patin
|last1=Patin
|first1=J. B.
|first1=J. B.
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|archive-date=2016-01-30
|archive-date=2016-01-30
|url-status=dead
|url-status=dead
}}</ref><!--this ref says on page 7 in the "SF Event 2, file: tsy1094,energy: 174.43 (161.92+12.51)&nbsp;MeV". It is unclear if the 612 or the 545 sec even refers to Cn-285 though---> Due to the low beam energies associated with the initial <sup>244</sup>Pu+<sup>48</sup>Ca experiment, it is possible that the 2n channel may have been reached, producing <sup>290</sup>Fl instead of <sup>289</sup>Fl; this would then undergo undetected electron capture to <sup>290</sup>Nh, thus resulting in a reassignment of this activity to its alpha daughter <sup>286</sup>Rg.<ref name=Hofmann2016>{{cite journal |last=Hofmann |first=S. |last2=Heinz |first2=S. |first3=R. |last3=Mann |first4=J. |last4=Maurer |first5=G. |last5=Münzenberg |first6=S. |last6=Antalic |first7=W. |last7=Barth |first8=H. G. |last8=Burkhard |first9=L. |last9=Dahl |first10=K. |last10=Eberhardt |first11=R. |last11=Grzywacz |first12=J. H. |last12=Hamilton |first13=R. A. |last13=Henderson |first14=J. M. |last14=Kenneally |first15=B. |last15=Kindler |first16=I. |last16=Kojouharov |first17=R. |last17=Lang |first18=B. |last18=Lommel |first19=K. |last19=Miernik |first20=D. |last20=Miller |first21=K. J. |last21=Moody |first22=K. |last22=Morita |first23=K. |last23=Nishio |first24=A. G. |last24=Popeko |first25=J. B. |last25=Roberto |first26=J. |last26=Runke |first27=K. P. |last27=Rykaczewski |first28=S. |last28=Saro |first29=C. |last29=Scheidenberger |first30=H. J. |last30=Schött |first31=D. A. |last31=Shaughnessy |first32=M. A. |last32=Stoyer |first33=P. |last33=Thörle-Popiesch |first34=K. |last34=Tinschert |first35=N. |last35=Trautmann |first36=J. |last36=Uusitalo |first37=A. V. |last37=Yeremin |date=2016 |title=Review of even element super-heavy nuclei and search for element 120 |journal=The European Physical Journal A |volume=2016 |issue=52 |pages=180 |doi=10.1140/epja/i2016-16180-4|bibcode=2016EPJA...52..180H |url=https://zenodo.org/record/897926 }}</ref>
}}</ref><!--this ref says on page 7 in the "SF Event 2, file: tsy1094,energy: 174.43 (161.92+12.51)&nbsp;MeV". It is unclear if the 612 or the 545 sec even refers to Cn-285 though---> Due to the low beam energies associated with the initial <sup>244</sup>Pu+<sup>48</sup>Ca experiment, it is possible that the 2n channel may have been reached, producing <sup>290</sup>Fl instead of <sup>289</sup>Fl; this would then undergo undetected electron capture to <sup>290</sup>Nh, thus resulting in a reassignment of this activity to its alpha daughter <sup>286</sup>Rg.<ref name="Hofmann2016">{{cite journal |last1=Hofmann |first1=S. |last2=Heinz |first2=S. |first3=R. |last3=Mann |first4=J. |last4=Maurer |first5=G. |last5=Münzenberg |first6=S. |last6=Antalic |first7=W. |last7=Barth |first8=H. G. |last8=Burkhard |first9=L. |last9=Dahl |first10=K. |last10=Eberhardt |first11=R. |last11=Grzywacz |first12=J. H. |last12=Hamilton |first13=R. A. |last13=Henderson |first14=J. M. |last14=Kenneally |first15=B. |last15=Kindler |first16=I. |last16=Kojouharov |first17=R. |last17=Lang |first18=B. |last18=Lommel |first19=K. |last19=Miernik |first20=D. |last20=Miller |first21=K. J. |last21=Moody |first22=K. |last22=Morita |first23=K. |last23=Nishio |first24=A. G. |last24=Popeko |first25=J. B. |last25=Roberto |first26=J. |last26=Runke |first27=K. P. |last27=Rykaczewski |first28=S. |last28=Saro |first29=C. |last29=Scheidenberger |first30=H. J. |last30=Schött |first31=D. A. |last31=Shaughnessy |first32=M. A. |last32=Stoyer |first33=P. |last33=Thörle-Popiesch |first34=K. |last34=Tinschert |first35=N. |last35=Trautmann |first36=J. |last36=Uusitalo |first37=A. V. |last37=Yeremin |date=2016 |title=Review of even element super-heavy nuclei and search for element 120 |journal=The European Physical Journal A |volume=2016 |issue=52 |pages=180 |doi=10.1140/epja/i2016-16180-4|bibcode=2016EPJA...52..180H |s2cid=124362890 |url=https://zenodo.org/record/897926 }}</ref>


[[File:Even Z alpha decay chains.svg|thumb|center|738px|Summary of observed alpha decay chains from superheavy elements with ''Z'' = 114, 116, 118, or 120 as of 2016. Assignments for dotted nuclides (including the early Dubna chains 5 and 8 containing <sup>287</sup>Nh and <sup>290</sup>Nh as alternative explanations instead of isomerism in <sup>287m</sup>Fl and <sup>289m</sup>Fl) are tentative.<ref name=EXON/>]]
[[File:Even Z alpha decay chains.svg|thumb|center|738px|Summary of observed alpha decay chains from superheavy elements with ''Z'' = 114, 116, 118, or 120 as of 2016. Assignments for dotted nuclides (including the early Dubna chains 5 and 8 containing <sup>287</sup>Nh and <sup>290</sup>Nh as alternative explanations instead of isomerism in <sup>287m</sup>Fl and <sup>289m</sup>Fl) are tentative.<ref name="EXON"/> According to another analysis, chain 3 (starting at element 120) is not a real decay chain, but is rather a random sequence of events.<ref>{{cite journal |last1=Heßberger |first1=F. P. |last2=Ackermann |first2=D. |date=2017 |title=Some critical remarks on a sequence of events interpreted to possibly originate from a decay chain of an element 120 isotope |journal=The European Physical Journal A |volume=53 |issue=123 |page=123 |doi=10.1140/epja/i2017-12307-5|bibcode=2017EPJA...53..123H |s2cid=125886824 }}</ref>]]


===Chemical yields of isotopes===
===Chemical yields of isotopes===
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|}
|}


===Fission of compound nuclei with Z=112===
===Fission of compound nuclei with atomic number 112===
Several experiments have been performed between 2001 and 2004 at the Flerov Laboratory of Nuclear Reactions in Dubna studying the fission characteristics of the compound nucleus <sup>286</sup>Cn. The nuclear reaction used is <sup>238</sup>U+<sup>48</sup>Ca. The results have revealed how nuclei such as this fission predominantly by expelling closed shell nuclei such as <sup>132</sup>Sn (Z=50, N=82). It was also found that the yield for the fusion-fission pathway was similar between <sup>48</sup>Ca and <sup>58</sup>Fe projectiles, indicating a possible future use of <sup>58</sup>Fe projectiles in superheavy element formation.<ref>see [http://www1.jinr.ru/Reports/Reports_eng_arh.html Flerov lab annual reports 2001–2004]</ref>
Several experiments have been performed between 2001 and 2004 at the Flerov Laboratory of Nuclear Reactions in Dubna studying the fission characteristics of the compound nucleus <sup>286</sup>Cn. The nuclear reaction used is <sup>238</sup>U+<sup>48</sup>Ca. The results have revealed how nuclei such as this fission predominantly by expelling closed shell nuclei such as <sup>132</sup>Sn (''Z''&nbsp;=&nbsp;50, ''N''&nbsp;=&nbsp;82). It was also found that the yield for the fusion-fission pathway was similar between <sup>48</sup>Ca and <sup>58</sup>Fe projectiles, indicating a possible future use of <sup>58</sup>Fe projectiles in superheavy element formation.<ref name="Cn-jinr">see [http://www1.jinr.ru/Reports/Reports_eng_arh.html Flerov lab annual reports 2001–2004]</ref>


===Theoretical calculations===
===Theoretical calculations===
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|-
|-
!<sup>208</sup>Pb
!<sup>208</sup>Pb
|<sup>70</sup>Zn||<sup>278</sup>Cn||1n (<sup>277</sup>Cn)||1.5&nbsp;pb||DNS||<ref name=FengColdFusion>{{Cite journal|doi = 10.1103/PhysRevC.76.044606 | title = Formation of superheavy nuclei in cold fusion reactions|year = 2007|last = Feng |first=Zhao-Qing|journal = Physical Review C|volume = 76| issue = 4|page = 044606|bibcode=2007PhRvC..76d4606F|arxiv = 0707.2588 }}</ref>
|<sup>70</sup>Zn||<sup>278</sup>Cn||1n (<sup>277</sup>Cn)||1.5&nbsp;pb||DNS||<ref name="FengColdFusion">{{Cite journal|doi = 10.1103/PhysRevC.76.044606 | title = Formation of superheavy nuclei in cold fusion reactions|year = 2007|last = Feng |first=Zhao-Qing|journal = Physical Review C|volume = 76| issue = 4|page = 044606|bibcode=2007PhRvC..76d4606F|arxiv = 0707.2588 | s2cid = 711489}}</ref>
|-
|-
!<sup>208</sup>Pb
!<sup>208</sup>Pb
|<sup>67</sup>Zn||<sup>275</sup>Cn||1n (<sup>274</sup>Cn)||2&nbsp;pb||DNS||<ref name=FengColdFusion />
|<sup>67</sup>Zn||<sup>275</sup>Cn||1n (<sup>274</sup>Cn)||2&nbsp;pb||DNS||<ref name="FengColdFusion "/>
|-
|-
!<sup>238</sup>U
!<sup>238</sup>U
|<sup>48</sup>Ca||<sup>286</sup>Cn||4n (<sup>282</sup>Cn)||0.2&nbsp;pb||DNS||<ref name=FengEntranceChannel >{{Cite journal|doi =10.1016/j.nuclphysa.2010.01.244|arxiv = 0904.2994|title = Influence of entrance channels on formation of superheavy nuclei in massive fusion reactions|journal = Nuclear Physics A|volume = 836|issue = 1–2|pages = 82–90|bibcode =2010NuPhA.836...82F|year = 2010|last1 = Feng|first1 = Zhao-Qing|last2 = Jin|first2 = Gen-Ming|last3 = Li|first3 = Jun-Qing|last4 = Peterson|first4 = D.|last5 = Rouki|first5 = C.|last6 = Zielinski|first6 = P. M.|last7 = Aleklett|first7 = K.}}</ref>
|<sup>48</sup>Ca||<sup>286</sup>Cn||4n (<sup>282</sup>Cn)||0.2&nbsp;pb||DNS||<ref name="FengEntranceChannel ">{{Cite journal|doi =10.1016/j.nuclphysa.2010.01.244|arxiv = 0904.2994|title = Influence of entrance channels on formation of superheavy nuclei in massive fusion reactions|journal = Nuclear Physics A|volume = 836|issue = 1–2|pages = 82–90|bibcode =2010NuPhA.836...82F|year = 2010|last1 = Feng|first1 = Zhao-Qing|last2 = Jin|first2 = Gen-Ming|last3 = Li|first3 = Jun-Qing|last4 = Peterson|first4 = D.|last5 = Rouki|first5 = C.|last6 = Zielinski|first6 = P. M.|last7 = Aleklett|first7 = K.| s2cid=10170328 }}</ref>
|-
|-
!<sup>235</sup>U
!<sup>235</sup>U
|<sup>48</sup>Ca||<sup>283</sup>Cn||3n (<sup>280</sup>Cn)||50&nbsp;fb||DNS||<ref name=neutronnumbers>{{cite journal|last=Zhu|first=L.|last2=Su|first2=J.|last3=Zhang|first3=F.|title=Influence of the neutron numbers of projectile and target on the evaporation residue cross sections in hot fusion reactions|journal=[[Physical Review C]]|date=2016|url=https://www.researchgate.net/publication/304366659|volume=93|issue=6| doi=10.1103/PhysRevC.93.064610}}</ref>
|<sup>48</sup>Ca||<sup>283</sup>Cn||3n (<sup>280</sup>Cn)||50&nbsp;fb||DNS||<ref name="neutronnumbers">{{cite journal|last1=Zhu|first1=L.|last2=Su|first2=J.|last3=Zhang|first3=F.|title=Influence of the neutron numbers of projectile and target on the evaporation residue cross sections in hot fusion reactions|journal=[[Physical Review C]]|date=2016|url=https://www.researchgate.net/publication/304366659|volume=93|issue=6|page=064610 | doi=10.1103/PhysRevC.93.064610|bibcode=2016PhRvC..93f4610Z }}</ref>
|-
|-
!<sup>238</sup>U
!<sup>238</sup>U
|<sup>44</sup>Ca||<sup>282</sup>Cn||4-5n (<sup>278,277</sup>Cn)||23&nbsp;fb||DNS||<ref name=neutronnumbers />
|<sup>44</sup>Ca||<sup>282</sup>Cn||4–5n (<sup>278,277</sup>Cn)||23&nbsp;fb||DNS||<ref name="neutronnumbers "/>
|-
|-
!<sup>244</sup>Pu
!<sup>244</sup>Pu
|<sup>40</sup>Ar||<sup>284</sup>Cn||4n (<sup>280</sup>Cn)||0.1&nbsp;pb; 9.84&nbsp;fb||DNS||<ref name=FengEntranceChannel /><ref name=Feng108114>{{cite journal|last=Feng|first=Z.|last2=Jin|first2=G.|last3=Li|first3=J.|title=Production of new superheavy Z=108-114 nuclei with <sup>238</sup>U, <sup>244</sup>Pu and <sup>248,250</sup>Cm targets|date=2009|arxiv=0912.4069|journal=[[Physical Review C]]|volume=80|pages=057601|doi=10.1103/PhysRevC.80.057601}}</ref>
|<sup>40</sup>Ar||<sup>284</sup>Cn||4n (<sup>280</sup>Cn)||0.1&nbsp;pb; 9.84&nbsp;fb||DNS||<ref name="FengEntranceChannel "/><ref name="Feng108114">{{cite journal|last1=Feng|first1=Z.|last2=Jin|first2=G.|last3=Li|first3=J.|title=Production of new superheavy Z=108-114 nuclei with <sup>238</sup>U, <sup>244</sup>Pu and <sup>248,250</sup>Cm targets|date=2009|arxiv=0912.4069|journal=[[Physical Review C]]|volume=80|pages=057601|doi=10.1103/PhysRevC.80.057601|s2cid=118733755 }}</ref>
|-
|-
!<sup>250</sup>Cm
!<sup>250</sup>Cm
|<sup>36</sup>S||<sup>286</sup>Cn||4n (<sup>282</sup>Cn)||5&nbsp;pb; 0.24&nbsp;pb||DNS||<ref name=FengEntranceChannel /><ref name=Feng108114 />
|<sup>36</sup>S||<sup>286</sup>Cn||4n (<sup>282</sup>Cn)||5&nbsp;pb; 0.24&nbsp;pb||DNS||<ref name="FengEntranceChannel "/><ref name="Feng108114 "/>
|-
|-
!<sup>248</sup>Cm
!<sup>248</sup>Cm
|<sup>36</sup>S||<sup>284</sup>Cn||4n (<sup>280</sup>Cn)||35&nbsp;fb||DNS||<ref name=Feng108114 />
|<sup>36</sup>S||<sup>284</sup>Cn||4n (<sup>280</sup>Cn)||35&nbsp;fb||DNS||<ref name="Feng108114 "/>
|-
|-
!<sup>252</sup>Cf
!<sup>252</sup>Cf
|<sup>30</sup>Si||<sup>282</sup>Cn||3n (<sup>279</sup>Cn)||10&nbsp;pb||DNS||<ref name=FengEntranceChannel />
|<sup>30</sup>Si||<sup>282</sup>Cn||3n (<sup>279</sup>Cn)||10&nbsp;pb||DNS||<ref name="FengEntranceChannel "/>
|}
|}


== References ==
== References ==
{{Reflist}}
<references />
* Isotope masses from:
* Isotope masses from:
**{{cite journal |author=M. Wang |author2=G. Audi |author3=A. H. Wapstra |author4=F. G. Kondev |author5=M. MacCormick |author6=X. Xu|year=2012 |title=The AME2012 atomic mass evaluation (II). Tables, graphs and references. |url=http://amdc.in2p3.fr/masstables/Ame2012/Ame2012b-v2.pdf |journal=Chinese Physics C |volume=36 |issue= 12 |pages=1603–2014 |doi=10.1088/1674-1137/36/12/003|bibcode = 2012ChPhC..36....3M |display-authors=etal}}
**{{cite journal |author=M. Wang |author2=G. Audi |author3=A. H. Wapstra |author4=F. G. Kondev |author5=M. MacCormick |author6=X. Xu|year=2012 |title=The AME2012 atomic mass evaluation (II). Tables, graphs and references. |url=http://amdc.in2p3.fr/masstables/Ame2012/Ame2012b-v2.pdf |journal=Chinese Physics C |volume=36 |issue= 12 |pages=1603–2014 |doi=10.1088/1674-1137/36/12/003|bibcode = 2012ChPhC..36....3M |hdl=11858/00-001M-0000-0010-23E8-5 |s2cid=250839471 |display-authors=etal}}
**{{NUBASE 2003}}
**{{NUBASE 2003}}
* Isotopic compositions and standard atomic masses from:
**{{CAWIA 2003}}
**{{CIAAW 2005}}
* Half-life, spin, and isomer data selected from the following sources.
* Half-life, spin, and isomer data selected from the following sources.
**{{NUBASE 2003}}
**{{NUBASE 2003}}
**{{NNDC}}
**{{NNDC}}
**{{CRC85|chapter=11}}
**{{CRC85|chapter=11}}
**{{cite web |author=GSI |year=2011 |title=Superheavy Element Research at GSI |url=http://tan11.jinr.ru/pdf/08_Sep/S_1/01_Duellmann.pdf |publisher=GSI |access-date=July 2012}}
**{{cite web |author=GSI |year=2011 |title=Superheavy Element Research at GSI |url=http://tan11.jinr.ru/pdf/08_Sep/S_1/01_Duellmann.pdf |publisher=GSI |access-date=13 July 2012}}


{{Navbox element isotopes}}
{{Navbox element isotopes}}

Latest revision as of 15:08, 3 November 2024

Isotopes of copernicium (112Cn)
Main isotopes[1] Decay
abun­dance half-life (t1/2) mode pro­duct
283Cn synth 3.81 s[2] α96% 279Ds
SF4%
ε? 283Rg
285Cn synth 30 s α 281Ds
286Cn synth 8.4 s? SF

Copernicium (112Cn) is a synthetic element, and thus a standard atomic weight cannot be given. Like all synthetic elements, it has no stable isotopes. The first isotope to be synthesized was 277Cn in 1996. There are seven known radioisotopes (with one more unconfirmed); the longest-lived isotope is 285Cn with a half-life of 30 seconds.

List of isotopes

[edit]


Nuclide
Z N Isotopic mass (Da)
[n 1][n 2]
Half-life[1]
Decay
mode
[1]
[n 3]
Daughter
isotope

Spin and
parity[1]
[n 4]
277Cn 112 165 277.16354(17)# 790(330) μs
α 273Ds 3/2+#
280Cn[3][n 5] 112 168 280.16710(63)# <100 μs SF (various) 0+
281Cn[n 6] 112 169 281.16956(43)# 180+100
−40
 ms
[4]
α 277Ds 3/2+#
282Cn 112 170 282.17051(59)# 0.83+0.18
−0.13
 ms
[2]
SF (various) 0+
283Cn 112 171 283.17320(66)# 3.81+0.45
−0.36
 s
[2]
α (96%)[2] 279Ds
SF (4%) (various)
EC? 283Rg
284Cn[n 7] 112 172 284.17436(82)# 121+20
−15
 ms
[5]
SF (98%) (various) 0+
α (2%)[5] 280Ds
285Cn[n 8] 112 173 285.17723(54)# 30(8) s α 281Ds 5/2+#
286Cn[6][n 9][n 10] 112 174 286.17869(75)# 8.4+40.5
−3.9
 s
SF (various) 0+
This table header & footer:
  1. ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  2. ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  3. ^ Modes of decay:
    EC: Electron capture
    SF: Spontaneous fission
  4. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. ^ Not directly synthesized, created as decay product of 288Lv
  6. ^ Not directly synthesized, created as decay product of 285Fl
  7. ^ Not directly synthesized, created as decay product of 288Fl
  8. ^ Not directly synthesized, created as decay product of 289Fl
  9. ^ Not directly synthesized, created as decay product of 294Lv
  10. ^ This isotope is unconfirmed

Isotopes and nuclear properties

[edit]

Nucleosynthesis

[edit]

Superheavy elements such as copernicium are produced by bombarding lighter elements in particle accelerators that induces fusion reactions. Whereas most of the isotopes of copernicium can be synthesized directly this way, some heavier ones have only been observed as decay products of elements with higher atomic numbers.[7]

Depending on the energies involved, the former are separated into "hot" and "cold". In hot fusion reactions, very light, high-energy projectiles are accelerated toward very heavy targets such as actinides, giving rise to compound nuclei at high excitation energy (~40–50 MeV) that may either fission or evaporate several (3 to 5) neutrons.[7] In cold fusion reactions, the produced fused nuclei have a relatively low excitation energy (~10–20 MeV), which decreases the probability that these products will undergo fission reactions. As the fused nuclei cool to the ground state, they require emission of only one or two neutrons, and thus, allows for the generation of more neutron-rich products.[8] The latter is a distinct concept from that of where nuclear fusion claimed to be achieved at room temperature conditions (see cold fusion).[9]

The table below contains various combinations of targets and projectiles which could be used to form compound nuclei with Z = 112.

Target Projectile CN Attempt result
184W 88Sr 272Cn Failure to date
208Pb 68Zn 276Cn Failure to date
208Pb 70Zn 278Cn Successful reaction
233U 48Ca 281Cn Failure to date
234U 48Ca 282Cn Reaction yet to be attempted
235U 48Ca 283Cn Reaction yet to be attempted
236U 48Ca 284Cn Reaction yet to be attempted
238U 48Ca 286Cn Successful reaction
244Pu 40Ar 284Cn Reaction yet to be attempted
250Cm 36S 286Cn Reaction yet to be attempted
248Cm 36S 284Cn Reaction yet to be attempted
252Cf 30Si 282Cn Reaction yet to be attempted

Cold fusion

[edit]

The first cold fusion reaction to produce copernicium was performed by GSI in 1996, who reported the detection of two decay chains of copernicium-277.[10]

208
82
Pb
+ 70
30
Zn
277
112
Cn
+
n

In a review of the data in 2000, the first decay chain was retracted. In a repeat of the reaction in 2000 they were able to synthesize a further atom. They attempted to measure the 1n excitation function in 2002 but suffered from a failure of the zinc-70 beam. The unofficial discovery of copernicium-277 was confirmed in 2004 at RIKEN, where researchers detected a further two atoms of the isotope and were able to confirm the decay data for the entire chain.[11] This reaction had also previously been tried in 1971 at the Joint Institute for Nuclear Research in Dubna, Russia in an effort to produce 276Cn in the 2n channel, but without success.[12]

After the successful synthesis of copernicium-277, the GSI team performed a reaction using a 68Zn projectile in 1997 in an effort to study the effect of isospin (neutron richness) on the chemical yield.

208
82
Pb
+ 68
30
Zn
276−x
112
Cn
+ x
n

The experiment was initiated after the discovery of a yield enhancement during the synthesis of darmstadtium isotopes using nickel-62 and nickel-64 ions. No decay chains of copernicium-275 were detected leading to a cross section limit of 1.2 picobarns (pb). However, the revision of the yield for the zinc-70 reaction to 0.5 pb does not rule out a similar yield for this reaction.

In 1990, after some early indications for the formation of isotopes of copernicium in the irradiation of a tungsten target with multi-GeV protons, a collaboration between GSI and the Hebrew University studied the foregoing reaction.

184
74
W
+ 88
38
Sr
272−x
112
Cn
+ x
n

They were able to detect some spontaneous fission (SF) activity and a 12.5 MeV alpha decay, both of which they tentatively assigned to the radiative capture product copernicium-272 or the 1n evaporation residue copernicium-271. Both the TWG and JWP have concluded that a lot more research is required to confirm these conclusions.[7]

Hot fusion

[edit]

In 1998, the team at the Flerov Laboratory of Nuclear Research (FLNR) in Dubna, Russia began a research program using calcium-48 nuclei in "warm" fusion reactions leading to super-heavy elements. In March 1998, they claimed to have synthesized two atoms of the element in the following reaction.

238
92
U
+ 48
20
Ca
286−x
112
Cn
+ x
n
(x=3,4)

The product, copernicium-283, had a claimed half-life of 5 minutes, decaying by spontaneous fission.[13]

The long half-life of the product initiated first chemical experiments on the gas phase atomic chemistry of copernicium. In 2000, Yuri Yukashev in Dubna repeated the experiment but was unable to observe any spontaneous fission events with half-life of 5 minutes. The experiment was repeated in 2001 and an accumulation of eight fragments resulting from spontaneous fission were found in the low-temperature section, indicating that copernicium had radon-like properties. However, there is now some serious doubt about the origin of these results. To confirm the synthesis, the reaction was successfully repeated by the same team in January 2003, confirming the decay mode and half-life. They were also able to calculate an estimate of the mass of the spontaneous fission activity to ~285, lending support to the assignment.[14]

The team at Lawrence Berkeley National Laboratory (LBNL) in Berkeley, United States entered the debate and performed the reaction in 2002. They were unable to detect any spontaneous fission and calculated a cross section limit of 1.6 pb for the detection of a single event.[15]

The reaction was repeated in 2003–2004 by the team at Dubna using a slightly different set-up, the Dubna Gas-Filled Recoil Separator (DGFRS). This time, copernicium-283 was found to decay by emission of a 9.53 MeV alpha-particle with a half-life of 4 seconds. Copernicium-282 was also observed in the 4n channel (emitting 4 neutrons).[16]

In 2003, the team at GSI entered the debate and performed a search for the five-minute SF activity in chemical experiments. Like the Dubna team, they were able to detect seven SF fragments in the low temperature section. However, these SF events were uncorrelated, suggesting they were not from actual direct SF of copernicium nuclei and raised doubts about the original indications for radon-like properties.[17] After the announcement from Dubna of different decay properties for copernicium-283, the GSI team repeated the experiment in September 2004. They were unable to detect any SF events and calculated a cross section limit of ~1.6 pb for the detection of one event, not in contradiction with the reported 2.5 pb yield by Dubna team.

In May 2005, the GSI performed a physical experiment and identified a single atom of 283Cn decaying by SF with a short half-time suggesting a previously unknown SF branch.[18] However, initial work by Dubna team had detected several direct SF events but had assumed that the parent alpha decay had been missed. These results indicated that this was not the case.

The new decay data on copernicium-283 were confirmed in 2006 by a joint PSI–FLNR experiment aimed at probing the chemical properties of copernicium. Two atoms of copernicium-283 were observed in the decay of the parent flerovium-287 nuclei. The experiment indicated that contrary to previous experiments, copernicium behaves as a typical member of group 12, demonstrating properties of a volatile metal.[19]

Finally, the team at GSI successfully repeated their physical experiment in January 2007, and detected three atoms of copernicium-283, confirming both the alpha and SF decay modes.[20]

As such, the 5-minute SF activity is still unconfirmed and unidentified. It is possible that it refers to an isomer, namely copernicium-283b, whose yield is dependent upon the exact production methods. It is also possible that it is the result of an electron capture branch in 283Cn leading to 283Rg, which would necessitate a reassignment of its parent to 287Nh (the electron-capture daughter of 287Fl).[21]

233
92
U
+ 48
20
Ca
281−x
112
Cn
+ x
n

The team at FLNR studied this reaction in 2004. They were unable to detect any atoms of copernicium and calculated a cross section limit of 0.6 pb. The team concluded that this indicated that the neutron mass number for the compound nucleus has an effect on the yield of evaporation residues.[16]

Decay products

[edit]
List of copernicium isotopes observed by decay
Evaporation residue Observed copernicium isotope
288Lv, 284Fl 280Cn[3]
289Lv, 285Fl 281Cn[3][22]
294Og, 290Lv, 286Fl 282Cn[23]
291Lv, 287Fl 283Cn[24]
292Lv, 288Fl 284Cn[25]
293Lv, 289Fl 285Cn[26]
294Lv, 290Fl ? 286Cn ?[6]

Copernicium has been observed as decay products of flerovium. Flerovium currently has seven known isotopes, all of which have been shown to undergo alpha decays to become copernicium nuclei, with mass numbers between 280 and 286. Copernicium isotopes with mass numbers 280, 281, 284, 285, and 286 to date have only been produced by flerovium nuclei decay. Parent flerovium nuclei can be themselves decay products of livermorium or oganesson.[27]

For example, in May 2006, the Dubna team (JINR) identified copernicium-282 as a final product in the decay of oganesson via the alpha decay sequence. It was found that the final nucleus undergoes spontaneous fission.[23]

294
118
Og
290
116
Lv
+ 4
2
He
290
116
Lv
286
114
Fl
+ 4
2
He
286
114
Fl
282
112
Cn
+ 4
2
He

In the claimed synthesis of oganesson-293 in 1999, copernicium-281 was identified as decaying by emission of a 10.68 MeV alpha particle with half-life 0.90 ms.[28] The claim was retracted in 2001. This isotope was finally created in 2010 and its decay properties contradicted the previous data.[22]

Nuclear isomerism

[edit]

First experiments on the synthesis of 283Cn produced a SF activity with half-life ~5 min.[27] This activity was also observed from the alpha decay of flerovium-287. The decay mode and half-life were also confirmed in a repetition of the first experiment. Later, copernicium-283 was observed to undergo 9.52 MeV alpha decay and SF with a half-life of 3.9 s. It has also been found that alpha decay of copernicium-283 leads to different excited states of darmstadtium-279.[16] These results suggest the assignment of the two activities to two different isomeric levels in copernicium-283, creating copernicium-283a and copernicium-283b. This result may also be due to an electron-capture branching of the parent 287Fl to 287Nh, so that the longer-lived activity would be assigned to 283Rg.[21]

Copernicium-285 has only been observed as a decay product of flerovium-289 and livermorium-293; during the first recorded synthesis of flerovium, one flerovium-289 was created, which alpha decayed to copernicium-285, which itself emitted an alpha particle in 29 seconds, releasing 9.15 or 9.03 MeV.[16] However, in the first experiment to successfully synthesize livermorium, when livermorium-293 was created, it was shown that the created nuclide alpha decayed to flerovium-289, decay data for which differed from the known values significantly. Although unconfirmed, it is highly possible that this is associated with an isomer. The resulting nuclide decayed to copernicium-285, which emitted an alpha particle with a half-life of around 10 minutes, releasing 8.586 MeV. Similar to its parent, it is believed to be a nuclear isomer, copernicium-285b.[29] Due to the low beam energies associated with the initial 244Pu+48Ca experiment, it is possible that the 2n channel may have been reached, producing 290Fl instead of 289Fl; this would then undergo undetected electron capture to 290Nh, thus resulting in a reassignment of this activity to its alpha daughter 286Rg.[30]

Summary of observed alpha decay chains from superheavy elements with Z = 114, 116, 118, or 120 as of 2016. Assignments for dotted nuclides (including the early Dubna chains 5 and 8 containing 287Nh and 290Nh as alternative explanations instead of isomerism in 287mFl and 289mFl) are tentative.[21] According to another analysis, chain 3 (starting at element 120) is not a real decay chain, but is rather a random sequence of events.[31]

Chemical yields of isotopes

[edit]

Cold fusion

[edit]

The table below provides cross-sections and excitation energies for cold fusion reactions producing copernicium isotopes directly. Data in bold represent maxima derived from excitation function measurements. + represents an observed exit channel.

Projectile Target CN 1n 2n 3n
70Zn 208Pb 278Cn 0.5 pb, 10.0, 12.0 MeV +
68Zn 208Pb 276Cn <1.2 pb, 11.3, 12.8 MeV

Hot fusion

[edit]

The table below provides cross-sections and excitation energies for hot fusion reactions producing copernicium isotopes directly. Data in bold represents maxima derived from excitation function measurements. + represents an observed exit channel.

Projectile Target CN 3n 4n 5n
48Ca 238U 286Cn 2.5 pb, 35.0 MeV + 0.6 pb
48Ca 233U 281Cn <0.6 pb, 34.9 MeV

Fission of compound nuclei with atomic number 112

[edit]

Several experiments have been performed between 2001 and 2004 at the Flerov Laboratory of Nuclear Reactions in Dubna studying the fission characteristics of the compound nucleus 286Cn. The nuclear reaction used is 238U+48Ca. The results have revealed how nuclei such as this fission predominantly by expelling closed shell nuclei such as 132Sn (Z = 50, N = 82). It was also found that the yield for the fusion-fission pathway was similar between 48Ca and 58Fe projectiles, indicating a possible future use of 58Fe projectiles in superheavy element formation.[32]

Theoretical calculations

[edit]

Evaporation residue cross sections

[edit]

The below table contains various targets-projectile combinations for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.

DNS = Di-nuclear system; σ = cross section

Target Projectile Cn Channel (product) σmax Model Ref
208Pb 70Zn 278Cn 1n (277Cn) 1.5 pb DNS [33]
208Pb 67Zn 275Cn 1n (274Cn) 2 pb DNS [33]
238U 48Ca 286Cn 4n (282Cn) 0.2 pb DNS [34]
235U 48Ca 283Cn 3n (280Cn) 50 fb DNS [35]
238U 44Ca 282Cn 4–5n (278,277Cn) 23 fb DNS [35]
244Pu 40Ar 284Cn 4n (280Cn) 0.1 pb; 9.84 fb DNS [34][36]
250Cm 36S 286Cn 4n (282Cn) 5 pb; 0.24 pb DNS [34][36]
248Cm 36S 284Cn 4n (280Cn) 35 fb DNS [36]
252Cf 30Si 282Cn 3n (279Cn) 10 pb DNS [34]

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[edit]
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