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{{Distinguish|Nikolai Shilov}}
{{short description|Russian chemist}}
{{Infobox scientist
{{Infobox scientist
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| caption = A. E. Shilov}}
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'''Alexander E. Shilov''' ({{langx|ru|Шилов, Александр Евгеньевич}}) (January 1, 1930 – June 6, 2014) was a Russian chemist, one of the leading figures in Physical Organic Chemistry and Catalysis.


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Shilov was born in [[Ivanovo]], [[Russia]], studied chemistry in [[Kiev]] and received his diploma degree in 1952 from Kiev State University. In 1952-1955 he began working with Nobel Laureate [[Nikolay Semyonov]] toward his Ph.D. at the Academy of Sciences in Moscow. After postdoctoral studies with [[Cyril Norman Hinshelwood|Sir Cyril Norman Hinshelwood]] at Oxford University in London, he returned to the Institute of Biochemical Physics (Moscow), where he became Director and Professor at Moscow State University. In 1952 he moved to [[Institute of Problems of Chemical Physics]], [[Russian Academy of Sciences]] in [[Chernogolovka]] (Moscow district), where he became the Head of Laboratory.<ref>A. E. Shilov, G. B. Shul'pin, "Activation of C−H Bonds by Metal Complexes", Chemical Reviews, 1997, 97 (8), pp 2879–2932 https://dx.doi.org/10.1021/cr9411886</ref> In 1990 he was elected to the [[Academy of Scienсes of the USSR]], which was in someway equivalent to getting a [[financial endowment]] for his research.
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'''Alexander E. Shilov''' ({{lang-ru|Шилов, Александр Евгеньевич}}) (January 1, 1930 – June 6, 2014) was a Russian chemist.


[[Image:shilov_cycle.png|thumb|323px|'''Shilov cycle''' Catalytic cycle for the oxidation of methane to methanol (where R=H) by a Pt(II) complex in the presence of stoichiometric Pt(IV) species as oxidant.]]
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Shilov was born in [[Ivanovo]], [[Russia]], studied Chemistry in [[Kiev]] and received his diploma degee in 1952 from Kiev State University. In 1952-1955 he was working with Nobel Laureate [[Nikolay Semyonov]] toward his Ph.D. at the Academy of Sciences in Moscow. After postdoctoral studies with [[Cyril Norman Hinshelwood|Sir Cyril Norman Hinshelwood]] at Oxford University in London, he returned to the Institute of Biochemical Physics (Moscow), where he is now Director and currently Professor at Moscow State University. In the late 60, he first discovered Pt-catalyzed [[CH activation]] of [[alkane]]s and first provided mechanism supported by kinetic analysis. Since 1952 he is in [[Institute of Problems of Chemical Physics]], [[Russian Academy of Sciences]] in [[Chernogolovka]] (Moscow district), where he is now the Head of Laboratory. In 1969 he discovered the [[Shilov system]]. In 1990 he received the Academian of Scienсes. Academian Shilov is the author of the famous book ''Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes'' together with [[Georgiy B. Shul'pin]].<ref>A. E. Shilov, G. B. Shul’pin, “Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes”, Kluwer Academic Publishers, Dordrecht/Boston/London, 2000 (552 p) (Springer, ISBN 978-0-7923-6101-5).</ref> In addition to his achievements, he first proposed dinitrogen reduction to ammonia in aqueous media by using organometallic complexes.


In the late 1960s and early 1970s, he discovered what are considered to be the first reported examples of alkane reactions catalyzed by a homogeneous (solution-phase) system, the Pt-catalyzed [[CH activation]] of [[alkane]]s,<ref>Gol'dshleger, N. F.; Tyabin, M. B.; Shilov, A. E.; Shteinman, A. A. "Activation of saturated hydrocarbons. Deuterium-hydrogen exchange in solutions of transition metal complexes" Zhurnal Fizicheskoi Khimii 1969, 43, 2174-2175</ref><ref>Gol'dshleger, N. F.; Es'kova, V. V.; Shilov, A. E.; Shteinman, A. A. "Reactions of alkanes in solutions of platinum chloride complexes" Zh. Fiz. Khim. 1972, 46, 1353-13544</ref><ref>Gol'dshleger, N. F.; Khidekel, M. L.; Shilov, A. E.; Shteinman, A. A. "Oxidative dehydrogenation of saturated hydrocarbons in palladium(II) complex solutions" Kinet. Katal. 1974, 15, 261</ref> now known as the [[Shilov system]].<ref>Shilov, A. E.; Shteinman, A. A. "Activation of saturated hydrocarbons by metal complexes in solution" Coord. Chem. Rev. 1977, 24, 97-143 https://doi.org/10.1016/S0010-8545(00)80336-7</ref> Shilov and co-workers conducted extensive mechanistic investigations of this chemistry based on kinetic analysis.<ref>Tyabin, M. B.; Shilov, A. E.; Shteinman, A. A. "Mechanism of platinum-complex catalyzed deuterium-hydrogen exchange involving saturated hydrocarbons and solvent protons" Doklady Akademii Nauk SSSR 1971, 198, 380-383</ref><ref>Gol'dshleger, N. F.; Es'kova, V. V.; Shilov, A. E.; Shteinman, A. A. "Reactions of alkanes in solutions of platinum chloride complexes" Zh. Fiz. Khim. 1972, 46, 1353-13544</ref><ref>Muradov, N. Z.; Shilov, A. E.; Shteinman, A. A. "Partial oxidation of simple alkanes" Kinetika i Kataliz 1972, 13, 1357-1358</ref><ref>Gol'dshleger, N. F.; Khidekel, M. L.; Shilov, A. E.; Shteinman, A. A. "Oxidative dehydrogenation of saturated hydrocarbons in palladium(II) complex solutions" Kinet. Katal. 1974, 15, 261</ref>
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His scientific interests have been published in more than 300 papers and cover research in chemical kinetics and catalysis, mechanisms of chemical reactions, chemical modeling of enzyme systems.
In addition to his pioneering work in the activation and functionalization of hydrocarbons, his interests encompassed dinitrogen reduction to ammonia in aqueous media with the use of organometallic complexes.<ref>Shilov, A. E. Metal Complexes in Biomimetic Chemical Reactions: N2 Fixation in Solution, Activation and Oxidation of Alkanes, Chemical Models of Photosynthesis, 1997</ref>

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His work has been published in more than 300 papers which cover research in chemical kinetics and catalysis, mechanisms of chemical reactions, and chemical modeling of enzyme systems.


== References==
== References==
{{reflist}}
{{reflist}}


{{Authority control}}
{{Persondata
| NAME = Shilov, Alexander E.
| ALTERNATIVE NAMES =
| SHORT DESCRIPTION = Russian chemist
| DATE OF BIRTH = January 1, 1930
| PLACE OF BIRTH =[[Ivanovo]], [[Russia]]
| DATE OF DEATH =June 6, 2014
| PLACE OF DEATH =
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}}


{{DEFAULTSORT:Shilov, Alexander E.}}
{{DEFAULTSORT:Shilov, Alexander E.}}
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[[Category:1930 births]]
[[Category:1930 births]]
[[Category:2014 deaths]]
[[Category:2014 deaths]]
[[Category:Soviet chemists]]

Latest revision as of 13:56, 6 November 2024

Not to be confused with Nikolai Shilov.
Alexander Shilov

Alexander E. Shilov (Russian: Шилов, Александр Евгеньевич) (January 1, 1930 – June 6, 2014) was a Russian chemist, one of the leading figures in Physical Organic Chemistry and Catalysis.

Shilov was born in Ivanovo, Russia, studied chemistry in Kiev and received his diploma degree in 1952 from Kiev State University. In 1952-1955 he began working with Nobel Laureate Nikolay Semyonov toward his Ph.D. at the Academy of Sciences in Moscow. After postdoctoral studies with Sir Cyril Norman Hinshelwood at Oxford University in London, he returned to the Institute of Biochemical Physics (Moscow), where he became Director and Professor at Moscow State University. In 1952 he moved to Institute of Problems of Chemical Physics, Russian Academy of Sciences in Chernogolovka (Moscow district), where he became the Head of Laboratory.[1] In 1990 he was elected to the Academy of Scienсes of the USSR, which was in someway equivalent to getting a financial endowment for his research.

Shilov cycle Catalytic cycle for the oxidation of methane to methanol (where R=H) by a Pt(II) complex in the presence of stoichiometric Pt(IV) species as oxidant.

In the late 1960s and early 1970s, he discovered what are considered to be the first reported examples of alkane reactions catalyzed by a homogeneous (solution-phase) system, the Pt-catalyzed CH activation of alkanes,[2][3][4] now known as the Shilov system.[5] Shilov and co-workers conducted extensive mechanistic investigations of this chemistry based on kinetic analysis.[6][7][8][9] In addition to his pioneering work in the activation and functionalization of hydrocarbons, his interests encompassed dinitrogen reduction to ammonia in aqueous media with the use of organometallic complexes.[10]

His work has been published in more than 300 papers which cover research in chemical kinetics and catalysis, mechanisms of chemical reactions, and chemical modeling of enzyme systems.

References

[edit]
  1. ^ A. E. Shilov, G. B. Shul'pin, "Activation of C−H Bonds by Metal Complexes", Chemical Reviews, 1997, 97 (8), pp 2879–2932 https://dx.doi.org/10.1021/cr9411886
  2. ^ Gol'dshleger, N. F.; Tyabin, M. B.; Shilov, A. E.; Shteinman, A. A. "Activation of saturated hydrocarbons. Deuterium-hydrogen exchange in solutions of transition metal complexes" Zhurnal Fizicheskoi Khimii 1969, 43, 2174-2175
  3. ^ Gol'dshleger, N. F.; Es'kova, V. V.; Shilov, A. E.; Shteinman, A. A. "Reactions of alkanes in solutions of platinum chloride complexes" Zh. Fiz. Khim. 1972, 46, 1353-13544
  4. ^ Gol'dshleger, N. F.; Khidekel, M. L.; Shilov, A. E.; Shteinman, A. A. "Oxidative dehydrogenation of saturated hydrocarbons in palladium(II) complex solutions" Kinet. Katal. 1974, 15, 261
  5. ^ Shilov, A. E.; Shteinman, A. A. "Activation of saturated hydrocarbons by metal complexes in solution" Coord. Chem. Rev. 1977, 24, 97-143 https://doi.org/10.1016/S0010-8545(00)80336-7
  6. ^ Tyabin, M. B.; Shilov, A. E.; Shteinman, A. A. "Mechanism of platinum-complex catalyzed deuterium-hydrogen exchange involving saturated hydrocarbons and solvent protons" Doklady Akademii Nauk SSSR 1971, 198, 380-383
  7. ^ Gol'dshleger, N. F.; Es'kova, V. V.; Shilov, A. E.; Shteinman, A. A. "Reactions of alkanes in solutions of platinum chloride complexes" Zh. Fiz. Khim. 1972, 46, 1353-13544
  8. ^ Muradov, N. Z.; Shilov, A. E.; Shteinman, A. A. "Partial oxidation of simple alkanes" Kinetika i Kataliz 1972, 13, 1357-1358
  9. ^ Gol'dshleger, N. F.; Khidekel, M. L.; Shilov, A. E.; Shteinman, A. A. "Oxidative dehydrogenation of saturated hydrocarbons in palladium(II) complex solutions" Kinet. Katal. 1974, 15, 261
  10. ^ Shilov, A. E. Metal Complexes in Biomimetic Chemical Reactions: N2 Fixation in Solution, Activation and Oxidation of Alkanes, Chemical Models of Photosynthesis, 1997
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