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{{Short description|Artificial nuclides with atomic number of 94 but with different mass numbers}}
{{Short description|none}}
{{Infobox plutonium isotopes}}696996696969699669
{{Infobox plutonium isotopes}}
[[Plutonium]] (<sub>94</sub>Pu) is an [[artificial element]], except for trace quantities resulting from [[neutron capture]] by uranium, and thus a [[standard atomic weight]] cannot be given. Like all artificial elements, it has no [[stable isotope]]s. It was synthesized long before being found in nature, the first [[isotope]] synthesized being <sup>238</sup>Pu in 1940. Twenty plutonium [[radioisotope]]s have been characterized. The most stable are [[plutonium-244]] with a [[half-life]] of 80.8 million years, [[plutonium-242]] with a half-life of 373,300 years, and [[plutonium-239]] with a half-life of 24,110 years. All of the remaining [[radioactive]] isotopes have half-lives that are less than 7,000 years. This element also has eight [[meta state]]s; all have half-lives of less than one second.
[[Plutonium]] ({{sub|94}}Pu) is an [[artificial element]], except for trace quantities resulting from [[neutron capture]] by [[uranium]], and thus a [[standard atomic weight]] cannot be given. Like all artificial elements, it has no [[stable isotope]]s. It was synthesized long before being found in nature, the first [[isotope]] synthesized being {{sup|238}}Pu in 1940. Twenty-two plutonium [[radioisotope]]s have been characterized. The most stable are {{sup|244}}Pu with a [[half-life]] of 80.8 million years; {{sup|242}}Pu with a half-life of 373,300 years; and {{sup|239}}Pu with a half-life of 24,110 years; and {{sup|240}}Pu with a half-life of 6,560 years. This element also has eight [[meta state]]s; all have half-lives of less than one second.


The '''isotopes of plutonium''' range in [[atomic weight]] from 228.0387&nbsp;[[atomic mass unit|u]] (<sup>228</sup>Pu) to 247.074&nbsp;u (<sup>247</sup>Pu). The primary [[decay mode]]s before the most stable isotope, <sup>244</sup>Pu, are [[spontaneous fission]] and [[alpha emission]]; the primary mode after is [[beta emission]]. The primary [[decay product]]s before <sup>244</sup>Pu are [[isotopes of uranium]] and [[isotopes of neptunium|neptunium]] (not considering [[fission product]]s), and the primary decay products after are [[isotopes of americium]].
The known isotopes of plutonium range from {{sup|226}}Pu to {{sup|247}}Pu. The primary [[decay mode]]s before the most stable isotope, {{sup|244}}Pu, are [[spontaneous fission]] and [[alpha decay]]; the primary mode after is [[beta emission]]. The primary [[decay product]]s before {{sup|244}}Pu are [[isotopes of uranium]] and [[isotopes of neptunium|neptunium]] (not considering [[fission product]]s), and the primary decay products after are [[isotopes of americium]].


== List of isotopes ==
== List of isotopes ==
{{Anchor|Plutonium-221|Plutonium-222|Plutonium-223|Plutonium-224|Plutonium-225|Plutonium-226}}

<!--Please delete anchor(s) from the list above or table below if adding a dedicated isotope section(s).-->

{{Isotopes table
{{Isotopes table
|symbol=Pu
|symbol=Pu
|refs=NUBASE2020, AME2020 II
|refs=<!-- not NUBASE2016 yet (2019-07-14) -->
|notes=m, unc(), mass#, spin(), spin#, daughter-st, daughter-nst, EC, SF, CD, IT
|notes=m, unc(), mass#, spin(), spin#, daughter-st, daughter-nst, EC, SF, CD, IT
}}
}}
|-id=Plutonium-226
|-
| {{sup|226}}Pu<ref>{{Cite web |url=http://www1.jinr.ru/Preprints/2024/50(P7-2024-50).pdf |title=Свойства радиоактивного распада нового ядра <sup>227</sup>Pu |trans-title=Properties of Radioactive Decay of the New Nucleus <sup>227</sup>Pu |vauthors=Kuznetsova AA, Svirikhin AI, Isaev AV, Bychkov MA, Danilkin VD, Devarazha KM, Zamyatin NI, Izosimov IN, Liu Z, Malyshev ON, Mukhin RS, Popeko AG, Popov YA, Rachkov VA, Saylaubekov B, Sokol EA, Tezekbaeva MS, Ulanova II, Zhang FS, Chepigin VI, Chelnokov ML, Eremin AV |date=2024 |website=jinr.ru |publisher=[[Joint Institute for Nuclear Research]] |access-date=9 November 2024 |lang=ru}}</ref>
| rowspan=2|<sup>228</sup>Pu
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 134
| rowspan=2|228.03874(3)
| rowspan=2|1.1(+20−5)&nbsp;s
| α (99.9%)
| <sup>224</sup>U
| rowspan=2|0+
| rowspan=2|
|-
| [[beta decay|β<sup>+</sup>]] (.1%)
| <sup>228</sup>Np
|-
| <sup>229</sup>Pu
| style="text-align:right" | 94
| style="text-align:right" | 94
| style="text-align:right" | 135
| style="text-align:right" | 132
| 229.04015(6)
| 226.03825(22)#
| ≥1 ms
| 120(50)&nbsp;s
| α
| α
| <sup>225</sup>U
| {{sup|222}}U
| 3/2+#
| 0+
|
|
|-id=Plutonium-227
| {{sup|227}}Pu<ref>{{cite journal |last1=Yang |first1=H. B. |last2=Gan |first2=Z. G. |last3=Zhang |first3=Z. Y. |last4=Huang |first4=M. H. |last5=Ma |first5=L. |last6=Yang |first6=C. L. |last7=Zhang |first7=M. M. |last8=Tian |first8=Y. L. |last9=Wang |first9=Y. S. |last10=Wang |first10=J. G. |last11=Zhou |first11=H. B. |last12=Hua |first12=W. |last13=Wang |first13=J. Y. |last14=Qiang |first14=Y. H. |last15=Zhao |first15=Z. |last16=Huang |first16=X. Y. |last17=Wen |first17=X. J. |last18=Li |first18=Z. Y. |last19=Zhang |first19=H. T. |last20=Xu |first20=S. Y. |last21=Li |first21=Z. C. |last22=Zhou |first22=H. |last23=Zhang |first23=X. |last24=Zhu |first24=L. |last25=Wang |first25=Z. |last26=Guan |first26=F. |last27=Yang |first27=H. R. |last28=Huang |first28=W. X. |last29=Ren |first29=Z. Z. |last30=Zhou |first30=S. G. |last31=Xu |first31=H. S. |title=α decay of the new isotope Pu 227 |journal=Physical Review C |date=3 October 2024 |volume=110 |issue=4 |doi=10.1103/PhysRevC.110.044302}}</ref>
| style="text-align:right" | 94
| style="text-align:right" | 133
| 227.03947(11)#
| {{val|0.78|0.39|0.19|u=s}}
| α
| {{sup|223}}U
| 5/2+#
|
|-id=Plutonium-228
| {{sup|228}}Pu
| style="text-align:right" | 94
| style="text-align:right" | 134
| 228.038763(25)
| 2.1(13)&nbsp;s
| α
| {{sup|224}}U
| 0+
|
|-id=Plutonium-229
| rowspan=3|{{sup|229}}Pu
| rowspan=3 style="text-align:right" | 94
| rowspan=3 style="text-align:right" | 135
| rowspan=3|229.040145(65)
| rowspan=3|91(26)&nbsp;s
| α (~50%)
| {{sup|225}}U
| rowspan=3|3/2+#
| rowspan=3|
|-
|-
| β{{sup|+}} (~50%)
| rowspan=2|<sup>230</sup>Pu
| {{sup|229}}Np
|-
| [[spontaneous fission|SF]] (<7%)
| (various)
|-id=Plutonium-230
| rowspan=2|{{sup|230}}Pu
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 136
| rowspan=2 style="text-align:right" | 136
| rowspan=2|230.039650(16)
| rowspan=2|230.039648(16)
| rowspan=2|1.70(17)&nbsp;min
| rowspan=2|105(10)&nbsp;s
| α (>73%)<ref>{{cite journal |last1=Wilson |first1=G. L. |last2=Takeyama |first2=M. |last3=Andreyev |first3=A. N. |last4=Andel |first4=B. |last5=Antalic |first5=S. |last6=Catford |first6=W. N. |last7=Ghys |first7=L. |last8=Haba |first8=H. |last9=Heßberger |first9=F. P. |last10=Huang |first10=M. |last11=Kaji |first11=D. |last12=Kalaninova |first12=Z. |last13=Morimoto |first13=K. |last14=Morita |first14=K. |last15=Murakami |first15=M. |last16=Nishio |first16=K. |last17=Orlandi |first17=R. |last18=Smith |first18=A. G. |last19=Tanaka |first19=K. |last20=Wakabayashi |first20=Y. |last21=Yamaki |first21=S. |title=β -delayed fission of Am 230 |journal=Physical Review C |date=13 October 2017 |volume=96 |issue=4 |page=044315 |doi=10.1103/PhysRevC.96.044315 |language=en |issn=2469-9985|doi-access=free }}</ref>
| α
| <sup>226</sup>U
| {{sup|226}}U
| rowspan=2|0+
| rowspan=2|0+
| rowspan=2|
| rowspan=2|
|-
|-
| β<sup>+</sup> (rare)
| β{{sup|+}} (<27%)
| <sup>230</sup>Np
| {{sup|230}}Np
|-id=Plutonium-231
|-
| rowspan=2|<sup>231</sup>Pu
| rowspan=2|{{sup|231}}Pu
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 137
| rowspan=2 style="text-align:right" | 137
| rowspan=2|231.041101(28)
| rowspan=2|231.041126(24)
| rowspan=2|8.6(5)&nbsp;min
| rowspan=2|8.6(5)&nbsp;min
| β<sup>+</sup>
| β{{sup|+}} (87%)
| <sup>231</sup>Np
| {{sup|231}}Np
| rowspan=2|3/2+#
| rowspan=2|(3/2+)
| rowspan=2|
| rowspan=2|
|-
|-
| α (rare)
| α (13%)
| <sup>227</sup>U
| {{sup|227}}U
|-id=Plutonium-232
|-
| rowspan=2|<sup>232</sup>Pu
| rowspan=2|{{sup|232}}Pu
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 138
| rowspan=2 style="text-align:right" | 138
| rowspan=2|232.041187(19)
| rowspan=2|232.041182(18)
| rowspan=2|33.7(5)&nbsp;min
| rowspan=2|33.7(5)&nbsp;min
| [[Electron capture|EC]] (89%)
| [[Electron capture|EC]] (>80%)
| <sup>232</sup>Np
| {{sup|232}}Np
| rowspan=2|0+
| rowspan=2|0+
| rowspan=2|
| rowspan=2|
|-
|-
| α (11%)
| α (<20%)
| <sup>228</sup>U
| {{sup|228}}U
|-id=Plutonium-233
|-
| rowspan=2|<sup>233</sup>Pu
| rowspan=2|{{sup|233}}Pu
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 139
| rowspan=2 style="text-align:right" | 139
| rowspan=2|233.04300(5)
| rowspan=2|233.042997(58)
| rowspan=2|20.9(4)&nbsp;min
| rowspan=2|20.9(4)&nbsp;min
| β<sup>+</sup> (99.88%)
| β{{sup|+}} (99.88%)
| <sup>233</sup>Np
| {{sup|233}}Np
| rowspan=2|5/2+#
| rowspan=2|5/2+#
| rowspan=2|
| rowspan=2|
|-
|-
| α (.12%)
| α (0.12%)
| <sup>229</sup>U
| {{sup|229}}U
|-id=Plutonium-234
|-
| rowspan=2|<sup>234</sup>Pu
| rowspan=2|{{sup|234}}Pu
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 140
| rowspan=2 style="text-align:right" | 140
| rowspan=2|234.043317(7)
| rowspan=2|234.0433175(73)
| rowspan=2|8.8(1)&nbsp;h
| rowspan=2|8.8(1)&nbsp;h
| EC (94%)
| EC (94%)
| <sup>234</sup>Np
| {{sup|234}}Np
| rowspan=2|0+
| rowspan=2|0+
| rowspan=2|
| rowspan=2|
|-
|-
| α (6%)
| α (6%)
| <sup>230</sup>U
| {{sup|230}}U
|-id=Plutonium-235
|-
| rowspan=2|<sup>235</sup>Pu
| rowspan=2|{{sup|235}}Pu
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 141
| rowspan=2 style="text-align:right" | 141
| rowspan=2|235.045286(22)
| rowspan=2|235.045285(22)
| rowspan=2|25.3(5)&nbsp;min
| rowspan=2|25.3(5)&nbsp;min
| β<sup>+</sup> (99.99%)
| β{{sup|+}}
| <sup>235</sup>Np
| {{sup|235}}Np
| rowspan=2|(5/2+)
| rowspan=2|(5/2+)
| rowspan=2|
| rowspan=2|
|-
|-
| α (.0027%)
| α (0.0028%)
| <sup>231</sup>U
| {{sup|231}}U
|-id=Plutonium-236
|-
| rowspan=4|<sup>236</sup>Pu
| rowspan=3|{{sup|236}}Pu
| rowspan=4 style="text-align:right" | 94
| rowspan=3 style="text-align:right" | 94
| rowspan=4 style="text-align:right" | 142
| rowspan=3 style="text-align:right" | 142
| rowspan=4|236.0460580(24)
| rowspan=3|236.0460567(19)
| rowspan=4|2.858(8)&nbsp;y
| rowspan=3|2.858(8)&nbsp;y
| α<ref group="n">Theorized to also undergo β<sup>−</sup>β<sup>−</sup> decay to <sup>236</sup>U</ref>
| α
| <sup>232</sup>U
| {{sup|232}}U
| rowspan=4|0+
| rowspan=3|0+
| rowspan=4|
| rowspan=3|
|-
|-
| [[Spontaneous fission|SF]] (1.37×10<sup>−7</sup>%)
| SF (1.9×10{{sup|−7}}%)
| (various)
| (various)
|-
|-
| [[Cluster decay|CD]] (2×10<sup>−12</sup>%)
| [[Cluster decay|CD]] (2×10{{sup|−12}}%)
| '''<sup>208</sup>Pb'''<br><sup>28</sup>Mg
| '''{{sup|208}}Pb'''<br/>{{sup|28}}Mg
|-id=Plutonium-236m
|-
| style="text-indent:1em" | {{sup|236m}}Pu
| β<sup>+</sup>β<sup>+</sup> (rare)
| colspan="3" style="text-indent:2em" | 1185.45(15)&nbsp;keV
| <sup>236</sup>U
| 1.2(3)&nbsp;μs
|-
| [[Isomeric transition|IT]]
| rowspan=2|<sup>237</sup>Pu
| {{sup|236}}Pu
| 5−
|
|-id=Plutonium-237
| rowspan=2|{{sup|237}}Pu
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 143
| rowspan=2 style="text-align:right" | 143
| rowspan=2|237.0484097(24)
| rowspan=2|237.0484079(18)
| rowspan=2|45.2(1)&nbsp;d
| rowspan=2|45.64(4)&nbsp;d
| EC
| EC
| <sup>237</sup>Np
| {{sup|237}}Np
| rowspan=2|7/2−
| rowspan=2|7/2−
| rowspan=2|
| rowspan=2|
|-
|-
| α (.0042%)
| α (0.0042%)
| <sup>233</sup>U
| {{sup|233}}U
|-id=Plutonium-237m1
|-
| style="text-indent:1em" | <sup>237m1</sup>Pu
| style="text-indent:1em" | {{sup|237m1}}Pu
| colspan="3" style="text-indent:2em" | 145.544(10)2&nbsp;keV
| colspan="3" style="text-indent:2em" | 145.543(8)&nbsp;keV
| 180(20)&nbsp;ms
| 180(20)&nbsp;ms
| IT
| [[Isomeric transition|IT]]
| <sup>237</sup>Pu
| {{sup|237}}Pu
| 1/2+
| 1/2+
|
|
|-id=Plutonium-237m2
|-
| style="text-indent:1em" | <sup>237m2</sup>Pu
| style="text-indent:1em" | {{sup|237m2}}Pu
| colspan="3" style="text-indent:2em" | 2900(250)&nbsp;keV
| colspan="3" style="text-indent:2em" | 2900(250)&nbsp;keV
| 1.1(1)&nbsp;μs
| 1.1(1)&nbsp;μs
|
| SF
| (various)
|
|
|
|
|
|-
|-
| rowspan=4|[[Plutonium-238|<sup>238</sup>Pu]]
| rowspan=5|[[Plutonium-238|{{sup|238}}Pu]]
| rowspan=4 style="text-align:right" | 94
| rowspan=5 style="text-align:right" | 94
| rowspan=4 style="text-align:right" | 144
| rowspan=5 style="text-align:right" | 144
| rowspan=4|238.0495599(20)
| rowspan=5|238.0495582(12)
| rowspan=4|87.7(1)&nbsp;y
| rowspan=5|87.7(1)&nbsp;y
| α
| α
| <sup>234</sup>U
| {{sup|234}}U
| rowspan=4|0+
| rowspan=5|0+
| rowspan=4|Trace<ref group=n>[[Double beta decay]] product of [[uranium-238|<sup>238</sup>U]]</ref>
| rowspan=5|Trace<ref group=n>[[Double beta decay]] product of [[uranium-238|{{sup|238}}U]]</ref>
|-
|-
| SF (1.9×10<sup>−7</sup>%)
| SF (1.9×10{{sup|−7}}%)
| (various)
| (various)
|-
|-
| CD (1.4×10<sup>−14</sup>%)
| CD (1.4×10{{sup|−14}}%)
| <sup>206</sup>Hg<br><sup>32</sup>Si
| {{sup|206}}Hg<br>{{sup|32}}Si
|-
|-
| CD (6×10<sup>−15</sup>%)
| CD (<6×10{{sup|−15}}%)
| <sup>180</sup>Yb<br><sup>30</sup>Mg<br><sup>28</sup>Mg
| {{sup|210}}Pb<br>{{sup|28}}Mg
|-
|-
| CD (<6×10{{sup|−15}}%)
| rowspan=2|[[Plutonium-239|<sup>239</sup>Pu]]<ref group="n" name="f">fissile nuclide</ref><ref group="n">Most useful isotope for nuclear weapons</ref>
| '''{{sup|208}}Pb'''<br>{{sup|30}}Mg
|-
| rowspan=2|[[Plutonium-239|{{sup|239}}Pu]]<ref group="n" name="f">fissile nuclide</ref><ref group="n">Most useful isotope for nuclear weapons</ref>
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 145
| rowspan=2 style="text-align:right" | 145
| rowspan=2|239.0521634(20)
| rowspan=2|239.0521616(12)
| rowspan=2|2.411(3)×10<sup>4</sup>&nbsp;y
| rowspan=2|2.411(3)×10<sup>4</sup>&nbsp;y
| α
| α
| '''''<sup>235</sup>U'''''
| '''''{{sup|235}}U'''''
| rowspan=2|1/2+
| rowspan=2|1/2+
| rowspan=2|Trace<ref group=n>[[Neutron capture]] product of [[uranium-238|<sup>238</sup>U]]</ref>
| rowspan=2|Trace<ref group=n>[[Neutron capture]] product of [[uranium-238|{{sup|238}}U]]</ref>
|-
|-
| SF (3.1×10<sup>−10</sup>%)
| SF (3.1×10{{sup|−10}}%)
| (various)
| (various)
|-id=Plutonium-239m1
|-
| style="text-indent:1em" | <sup>239m1</sup>Pu
| style="text-indent:1em" | {{sup|239m1}}Pu
| colspan="3" style="text-indent:2em" | 391.584(3)&nbsp;keV
| colspan="3" style="text-indent:2em" | 391.584(3)&nbsp;keV
| 193(4)&nbsp;ns
| 193(4)&nbsp;ns
|
| IT
| <sup>239</sup>Pu
|
| 7/2−
| 7/2−
|
|
|-id=Plutonium-239m2
|-
| style="text-indent:1em" | <sup>239m2</sup>Pu
| style="text-indent:1em" | {{sup|239m2}}Pu
| colspan="3" style="text-indent:2em" | 3100(200)&nbsp;keV
| colspan="3" style="text-indent:2em" | 3100(200)&nbsp;keV
| 7.5(10)&nbsp;μs
| 7.5(10)&nbsp;μs
|
| SF
| (various)
|
| (5/2+)
| (5/2+)
|
|
|-
|-
| rowspan=3|[[plutonium-240|<sup>240</sup>Pu]]
| rowspan=3|[[plutonium-240|{{sup|240}}Pu]]
| rowspan=3 style="text-align:right" | 94
| rowspan=3 style="text-align:right" | 94
| rowspan=3 style="text-align:right" | 146
| rowspan=3 style="text-align:right" | 146
| rowspan=3|240.0538135(20)
| rowspan=3|240.0538117(12)
| rowspan=3|6.561(7)×10<sup>3</sup> y
| rowspan=3|6.561(7)×10{{sup|3}}&nbsp;y
| α
| α
| <sup>236</sup>U
| {{sup|236}}U
| rowspan=3|0+
| rowspan=3|0+
| rowspan=3|Trace<ref group=n>Intermediate decay product of [[plutonium-244|<sup>244</sup>Pu]]</ref>
| rowspan=3|Trace<ref group=n>Intermediate decay product of [[plutonium-244|{{sup|244}}Pu]]</ref>
|-
|-
| SF (5.7×10<sup>−6</sup>%)
| SF (5.796×10{{sup|−6}}%)
| (various)
| (various)
|-
|-
| CD (1.3×10<sup>−13</sup>%)
| CD (<1.3×10{{sup|−11}}%)
| <sup>206</sup>Hg<br><sup>34</sup>Si
| {{sup|206}}Hg<br>{{sup|34}}Si
|-id=Plutonium-240m
| style="text-indent:1em" | {{sup|240m}}Pu
| colspan="3" style="text-indent:2em" | 1308.74(5)&nbsp;keV
| 165(10)&nbsp;ns
| IT
| <sup>240</sup>Pu
| 5−
|
|-
|-
| rowspan=3|[[plutonium-241|<sup>241</sup>Pu]]<ref group="n" name="f" />
| rowspan=3|[[plutonium-241|{{sup|241}}Pu]]<ref group="n" name="f" />
| rowspan=3 style="text-align:right" | 94
| rowspan=3 style="text-align:right" | 94
| rowspan=3 style="text-align:right" | 147
| rowspan=3 style="text-align:right" | 147
| rowspan=3|241.0568515(20)
| rowspan=3|241.0568497(12)
| rowspan=3|14.290(6)&nbsp;y
| rowspan=3|14.329(29)&nbsp;y
| β<sup></sup> (99.99%)
| β{{sup|}}
| <sup>241</sup>Am
| {{sup|241}}Am
| rowspan=3|5/2+
| rowspan=3|5/2+
| rowspan=3|
| rowspan=3|
|-
|-
| α (.00245%)
| α (0.00245%)
| <sup>237</sup>U
| {{sup|237}}U
|-
|-
| SF (2.4×10<sup>−14</sup>%)
| SF (<2.4×10{{sup|−14}}%)
| (various)
| (various)
|-id=Plutonium-241m1
|-
| style="text-indent:1em" | <sup>241m1</sup>Pu
| style="text-indent:1em" | {{sup|241m1}}Pu
| colspan="3" style="text-indent:2em" | 161.6(1)&nbsp;keV
| colspan="3" style="text-indent:2em" | 161.6853(9)&nbsp;keV
| 0.88(5)&nbsp;μs
| 0.88(5)&nbsp;μs
|
| IT
| <sup>241</sup>Pu
|
| 1/2+
| 1/2+
|
|
|-id=Plutonium-241m2
|-
| style="text-indent:1em" | <sup>241m2</sup>Pu
| style="text-indent:1em" | {{sup|241m2}}Pu
| colspan="3" style="text-indent:2em" | 2200(200)&nbsp;keV
| colspan="3" style="text-indent:2em" | 2200(200)&nbsp;keV
| 21(3)&nbsp;μs
| 20.5(22)&nbsp;μs
|
| SF
| (various)
|
|
|
|
|
|-
|-
| rowspan=2|[[plutonium-242|<sup>242</sup>Pu]]
| rowspan=2|[[plutonium-242|{{sup|242}}Pu]]
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 94
| rowspan=2 style="text-align:right" | 148
| rowspan=2 style="text-align:right" | 148
| rowspan=2|242.0587426(20)
| rowspan=2|242.0587410(13)
| rowspan=2|3.75(2)×10<sup>5</sup>&nbsp;y
| rowspan=2|3.75(2)×10{{sup|5}}&nbsp;y
| α
| α
| '''''<sup>238</sup>U'''''
| '''''{{sup|238}}U'''''
| rowspan=2|0+
| rowspan=2|0+
| rowspan=2|
| rowspan=2|
|-
|-
| SF (5.5×10<sup>−4</sup>%)
| SF (5.510×10{{sup|−4}}%)
| (various)
| (various)
|-id=Plutonium-243
|-
| <sup>243</sup>Pu<ref group="n" name="f" />
| {{sup|243}}Pu<ref group="n" name="f" />
| style="text-align:right" | 94
| style="text-align:right" | 94
| style="text-align:right" | 149
| style="text-align:right" | 149
| 243.062003(3)
| 243.0620021(27)
| 4.956(3)&nbsp;h
| 4.9553(25)&nbsp;h
| β<sup></sup>
| β{{sup|}}
| <sup>243</sup>Am
| {{sup|243}}Am
| 7/2+
| 7/2+
|
|
|-id=Plutonium-243m
|-
| style="text-indent:1em" | <sup>243m</sup>Pu
| style="text-indent:1em" | {{sup|243m}}Pu
| colspan="3" style="text-indent:2em" | 383.6(4)&nbsp;keV
| colspan="3" style="text-indent:2em" | 383.64(25)&nbsp;keV
| 330(30)&nbsp;ns
| 330(30)&nbsp;ns
|
| IT
| <sup>243</sup>Pu
|
| (1/2+)
| (1/2+)
|
|
|-
|-
| rowspan=3|[[plutonium-244|<sup>244</sup>Pu]]
| rowspan=3|[[plutonium-244|{{sup|244}}Pu]]
| rowspan=3 style="text-align:right" | 94
| rowspan=3 style="text-align:right" | 94
| rowspan=3 style="text-align:right" | 150
| rowspan=3 style="text-align:right" | 150
| rowspan=3|244.064204(5)
| rowspan=3|244.0642044(25)
| rowspan=3|8.00(9)×10<sup>7</sup>&nbsp;y
| rowspan=3|81.3(3)×10{{sup|7}}&nbsp;y
| α (99.88%)
| α (99.88%)
| <sup>240</sup>U
| {{sup|240}}U
| rowspan=3|0+
| rowspan=3|0+
| rowspan=3|Trace<ref group=n>Interstellar, some may also be [[primordial nuclide|primordial]] but such claims are disputed</ref>
| rowspan=3|Trace<ref group=n>Interstellar, some may also be [[primordial nuclide|primordial]] but such claims are disputed</ref>
|-
|-
| SF (.123%)
| SF (0.123%)
| (various)
| (various)
|-
|-
| β<sup></sup>β<sup></sup> (7.3×10<sup>−9</sup>%)
| [[Double beta decay|β{{sup|}}β{{sup|}}]] (<7.3×10{{sup|−9}}%)
| <sup>244</sup>Cm
| {{sup|244}}Cm
|-id=Plutonium-244m
|-
| style="text-indent:1em" | {{sup|244m}}Pu
| <sup>245</sup>Pu
| colspan="3" style="text-indent:2em" | 1216.0(5)&nbsp;keV
| 1.75(12)&nbsp;s
| IT
| <sup>244</sup>Pu
| 8−
|
|-id=Plutonium-245
| {{sup|245}}Pu
| style="text-align:right" | 94
| style="text-align:right" | 94
| style="text-align:right" | 151
| style="text-align:right" | 151
| 245.067747(15)
| 245.067825(15)
| 10.5(1)&nbsp;h
| 10.5(1)&nbsp;h
| β<sup></sup>
| β{{sup|}}
| <sup>245</sup>Am
| {{sup|245}}Am
| (9/2−)
| (9/2−)
|
|
|-id=Plutonium-245m1
|-
| style="text-indent:1em" | {{sup|245m1}}Pu
| <sup>246</sup>Pu
| colspan="3" style="text-indent:2em" | 264.5(3)&nbsp;keV
| 330(20)&nbsp;ns
| IT
| <sup>245</sup>Pu
| (5/2+)
|
|-id=Plutonium-245m2
| style="text-indent:1em" | {{sup|245m2}}Pu
| colspan="3" style="text-indent:2em" | 2000(400)&nbsp;keV
| 90(30)&nbsp;ns
| SF
| (various)
|
|
|-id=Plutonium-246
| {{sup|246}}Pu
| style="text-align:right" | 94
| style="text-align:right" | 94
| style="text-align:right" | 152
| style="text-align:right" | 152
| 246.070205(16)
| 246.070204(16)
| 10.84(2)&nbsp;d
| 10.84(2)&nbsp;d
| β<sup></sup>
| β{{sup|}}
| <sup>246m</sup>Am
| {{sup|246}}Am
| 0+
| 0+
|
|
|-id=Plutonium-247
|-
| <sup>247</sup>Pu
| {{sup|247}}Pu
| style="text-align:right" | 94
| style="text-align:right" | 94
| style="text-align:right" | 153
| style="text-align:right" | 153
| 247.07407(32)#
| 247.07430(22)#
| 2.27(23)&nbsp;d
| 2.27(23)&nbsp;d
| β<sup></sup>
| β{{sup|}}
| <sup>247</sup>Am
| {{sup|247}}Am
| 1/2+#
| 1/2+#
|
|
Line 340: Line 407:


== Notable isotopes ==
== Notable isotopes ==
*[[Plutonium-238]] has a half-life of 87.74 years<ref>{{cite magazine|last1=Makhijani|first1=Arjun|last2=Seth|first2=Anita|date=July 1997|title=The Use of Weapons Plutonium as Reactor Fuel|url=http://ieer.org/wp/wp-content/uploads/1997/07/no-3.pdf|magazine=Energy and Security|location=Takoma Park, MD|publisher=Institute for Energy and Environmental Research|access-date=4 July 2016}}</ref> and emits [[alpha particle]]s. Pure <sup>238</sup>Pu for [[radioisotope thermoelectric generator]]s that power some [[spacecraft]] is produced by neutron capture on [[neptunium-237]] but plutonium from [[spent nuclear fuel]] can contain as much as a few percent <sup>238</sup>Pu, originating from <sup>237</sup>Np, [[alpha decay]] of <sup>242</sup>Cm, or (n,2n) reactions.
*[[Plutonium-238]] has a half-life of 87.74 years<ref>{{cite magazine|last1=Makhijani|first1=Arjun|last2=Seth|first2=Anita|date=July 1997|title=The Use of Weapons Plutonium as Reactor Fuel|url=http://ieer.org/wp/wp-content/uploads/1997/07/no-3.pdf|magazine=Energy and Security|location=Takoma Park, MD|publisher=Institute for Energy and Environmental Research|access-date=4 July 2016}}</ref> and emits [[alpha particle]]s. Pure {{sup|238}}Pu for [[radioisotope thermoelectric generator]]s that power some [[spacecraft]] is produced by neutron capture on [[neptunium-237]] but plutonium from [[spent nuclear fuel]] can contain as much as a few percent {{sup|238}}Pu, originating from {{sup|237}}Np, [[alpha decay]] of {{sup|242}}Cm, or (n,2n) reactions.
*[[Plutonium-239]] is the most important isotope of plutonium{{Citation needed|date=July 2015}}, with a half-life of 24,100&nbsp;years. <sup>239</sup>Pu and <sup>241</sup>Pu are [[fissile]], meaning that the nuclei of their atoms can [[nuclear fission|break apart]] by being bombarded by [[neutron temperature|slow moving]] thermal neutrons, releasing energy, [[gamma radiation]] and [[neutron radiation|more neutrons]]. It can therefore sustain a [[nuclear chain reaction]], leading to applications in [[nuclear weapon]]s and [[nuclear reactor]]s. <sup>239</sup>Pu is synthesized by irradiating [[uranium-238]] with neutrons in a nuclear reactor, then recovered via [[nuclear reprocessing]] of the fuel. Further [[neutron capture]] produces successively heavier isotopes.
*[[Plutonium-239]] has half-life 24,100 years. {{sup|239}}Pu and {{sup|241}}Pu are [[fissile]]; meaning their nuclei can [[nuclear fission|split]] by being bombarded by [[neutron temperature|slow]] thermal neutrons, releasing energy, [[gamma radiation]] and [[neutron radiation|more neutrons]]. It can therefore sustain a [[nuclear chain reaction]], leading to applications in [[nuclear weapon]]s and [[nuclear reactor]]s. {{sup|239}}Pu is synthesized by irradiating [[uranium-238]] with neutrons in a nuclear reactor, then recovered via [[nuclear reprocessing]] of the fuel. Further [[neutron capture]] produces successively heavier isotopes.
*[[Plutonium-240]] has a high rate of spontaneous fission, raising the background [[neutron radiation]] of plutonium containing it. Plutonium is graded by proportion of <sup>240</sup>Pu: [[weapons grade]] (<&nbsp;7%), [[fuel grade]] (7–19%) and [[reactor grade]] (>&nbsp;19%). Lower grades are less suited for nuclear weapons and [[thermal reactor]]s but can fuel [[fast reactor]]s.
*[[Plutonium-240]] has a high rate of spontaneous fission, raising the background [[neutron radiation]] of plutonium. Plutonium is graded by proportion of {{sup|240}}Pu: [[weapons grade]] (<7%), [[fuel grade]] (7–19%) and [[reactor grade]] (>19%). Lower grades are less suited for bombs and [[thermal reactor]]s but can fuel [[fast reactor]]s.
*[[Plutonium-241]] is fissile, but also [[beta decay]]s with a half-life of 14 years to [[americium-241]].
*[[Plutonium-241]] is fissile, but [[beta decay]]s with a half-life of 14 years to [[americium-241]].
*[[Plutonium-242]] is not fissile, not very fertile (requiring 3 more neutron captures to become fissile), has a low neutron capture [[Neutron cross-section|cross section]], and a longer half-life than any of the lighter isotopes.
*[[Plutonium-242]] is not fissile, nor very fertile (requiring 3 more neutron captures to become fissile); and has a low neutron capture [[Neutron cross-section|cross section]], and a longer half-life than any of the lighter isotopes.
*[[Plutonium-244]] is the most stable isotope of plutonium, with a half-life of about 80&nbsp;million years. It is not significantly produced in nuclear reactors because <sup>243</sup>Pu has a short half-life, but some is produced in nuclear explosions. Plutonium-244 has been found in interstellar space<ref name="WallnerFaestermann2015">{{cite journal|last1=Wallner|first1=A.|last2=Faestermann|first2=T.|last3=Feige|first3=J.|last4=Feldstein|first4=C.|last5=Knie|first5=K.|last6=Korschinek|first6=G.|last7=Kutschera|first7=W.|last8=Ofan|first8=A.|last9=Paul|first9=M.|last10=Quinto|first10=F.|last11=Rugel|first11=G.|last12=Steier|first12=P.|title=Abundance of live 244Pu in deep-sea reservoirs on Earth points to rarity of actinide nucleosynthesis|journal=Nature Communications|volume=6|year=2015|pages=5956|issn=2041-1723|doi=10.1038/ncomms6956|pmid=25601158|pmc=4309418|arxiv=1509.08054|bibcode=2015NatCo...6.5956W}}</ref> and is has the longest half-life of any non-primordial radioisotope.
*[[Plutonium-244]] is the most stable isotope of plutonium, with a half-life of about 80&nbsp;million years. It is not significantly produced in nuclear reactors because {{sup|243}}Pu has a short half-life, but some is produced in nuclear explosions. {{sup|244}}Pu has been found in interstellar space<ref name="WallnerFaestermann2015">{{cite journal |last1=Wallner |first1=A. |last2=Faestermann |first2=T. |last3=Feige |first3=J. |last4=Feldstein |first4=C. |last5=Knie |first5=K. |last6=Korschinek |first6=G. |last7=Kutschera |first7=W. |last8=Ofan |first8=A. |last9=Paul |first9=M. |last10=Quinto |first10=F. |last11=Rugel |first11=G. |last12=Steier |first12=P. |title=Abundance of live 244Pu in deep-sea reservoirs on Earth points to rarity of actinide nucleosynthesis|journal=Nature Communications |volume=6 |year=2015 |pages=5956 |issn=2041-1723 |doi=10.1038/ncomms6956 |pmid=25601158 |pmc=4309418 |arxiv=1509.08054 |bibcode=2015NatCo...6.5956W}}</ref> and has the second longest half-life of any non-primordial radioisotope.


==Production and uses==
==Production and uses==
[[File:Plutonium pellet.jpg|right|thumb|250px|A pellet of [[plutonium-238]], glowing from its own heat, used for [[radioisotope thermoelectric generator]]s.]]
[[File:Plutonium pellet.jpg|right|thumb|A pellet of {{sup|238}}Pu, glowing from its own heat, used for [[radioisotope thermoelectric generator]]s.]]
[[File:Sasahara.svg|thumb|375px|[[Nuclear transmutation|Transmutation]] flow between <sup>238</sup>Pu and <sup>244</sup>Cm in [[Light water reactor|LWR]].<ref>{{cite journal|title=Neutron and Gamma Ray Source Evaluation of LWR High Burn-up UO2 and MOX Spent Fuels |journal=Journal of Nuclear Science and Technology |volume=41 |issue=4 |pages=448–456 |date=April 2004 |doi=10.3327/jnst.41.448 |last1=Sasahara |first1=Akihiro |last2=Matsumura |first2=Tetsuo |last3=Nicolaou |first3=Giorgos |last4=Papaioannou |first4=Dimitri |doi-access=free }}</ref><br/>Transmutation speed not shown and varies greatly by nuclide.<br/><sup>245</sup>Cm&ndash;<sup>248</sup>Cm are long-lived with negligible decay.]]
[[File:Sasahara.svg|thumb|upright=1.5|[[Nuclear transmutation|Transmutation]] flow between {{sup|238}}Pu and {{sup|244}}Cm in [[Light water reactor|LWR]].<ref>{{cite journal|title=Neutron and Gamma Ray Source Evaluation of LWR High Burn-up UO2 and MOX Spent Fuels |journal=Journal of Nuclear Science and Technology |volume=41 |issue=4 |pages=448–456 |date=April 2004 |doi=10.3327/jnst.41.448 |last1=Sasahara |first1=Akihiro |last2=Matsumura |first2=Tetsuo |last3=Nicolaou |first3=Giorgos |last4=Papaioannou |first4=Dimitri |doi-access=free }}</ref><br/>Transmutation speed not shown and varies greatly by nuclide. {{sup|245}}Cm&ndash;{{sup|248}}Cm are long-lived with negligible decay.]]
<sup>239</sup>Pu, a fissile isotope that is the second most used [[nuclear fuel]] in nuclear reactors after [[uranium-235]], and the most used fuel in the [[Nuclear fission|fission]] portion of [[nuclear weapon]]s, is produced from [[uranium-238]] by neutron capture followed by two beta decays.
{{sup|239}}Pu, a fissile isotope that is the second most used [[nuclear fuel]] in nuclear reactors after [[uranium-235]], and the most used fuel in the [[Nuclear fission|fission]] portion of [[nuclear weapon]]s, is produced from [[uranium-238]] by neutron capture followed by two beta decays.


<sup>240</sup>Pu, <sup>241</sup>Pu, and <sup>242</sup>Pu are produced by further neutron capture. The odd-mass isotopes <sup>239</sup>Pu and <sup>241</sup>Pu have about a 3/4 chance of undergoing [[Nuclear fission|fission]] on capture of a [[thermal neutron]] and about a 1/4 chance of retaining the [[neutron]] and becoming the next heavier isotope. The even-mass isotopes are [[fertile material]] but not fissile and also have a lower overall probability ([[Neutron cross-section|cross section]]) of neutron capture; therefore, they tend to accumulate in nuclear fuel used in a thermal reactor, the design of nearly all [[nuclear power plant]]s today. In plutonium that has been used a second time in thermal reactors in [[MOX fuel]], <sup>240</sup>Pu may even be the most common isotope. All plutonium isotopes and other [[actinide]]s, however, are [[fissionable]] with [[fast neutron]]s. <sup>240</sup>Pu does have a moderate thermal neutron absorption cross section, so that <sup>241</sup>Pu production in a thermal reactor becomes a significant fraction as large as <sup>239</sup>Pu production.
{{sup|240}}Pu, {{sup|241}}Pu, and {{sup|242}}Pu are produced by further neutron capture. The odd-mass isotopes {{sup|239}}Pu and {{sup|241}}Pu have about a 3/4 chance of undergoing fission on capture of a [[thermal neutron]] and about a 1/4 chance of retaining the [[neutron]] and becoming the next heavier isotope. The even-mass isotopes are [[fertile material|fertile]] but not fissile and also have a lower probability ([[Neutron cross-section|cross section]]) of neutron capture; therefore, they tend to accumulate in nuclear fuel used in a thermal reactor, the design of nearly all [[nuclear power plant]]s today. In plutonium that has been used a second time in thermal reactors in [[MOX fuel]], {{sup|240}}Pu may even be the most common isotope. All plutonium isotopes and other [[actinide]]s, however, are [[fissionable]] with [[fast neutron]]s. {{sup|240}}Pu does have a moderate thermal neutron absorption cross section, so that {{sup|241}}Pu production in a thermal reactor becomes a significant fraction as large as {{sup|239}}Pu production.


<sup>241</sup>Pu has a half-life of 14 years, and has slightly higher thermal neutron cross sections than <sup>239</sup>Pu for both fission and absorption. While nuclear fuel is being used in a reactor, a <sup>241</sup>Pu nucleus is much more likely to fission or to capture a neutron than to decay. <sup>241</sup>Pu accounts for a significant proportion of fissions in thermal reactor fuel that has been used for some time. However, in [[spent nuclear fuel]] that does not quickly undergo nuclear reprocessing but instead is cooled for years after use, much or most of the <sup>241</sup>Pu will beta decay to [[americium-241]], one of the [[minor actinide]]s, a strong alpha emitter, and difficult to use in thermal reactors.
{{sup|241}}Pu has a half-life of 14 years, and has slightly higher thermal neutron cross sections than {{sup|239}}Pu for both fission and absorption. While nuclear fuel is being used in a reactor, a {{sup|241}}Pu nucleus is much more likely to fission or to capture a neutron than to decay. {{sup|241}}Pu accounts for a significant portion of fissions in thermal reactor fuel that has been used for some time. However, in [[spent nuclear fuel]] that does not quickly undergo nuclear reprocessing but instead is cooled for years after use, much or most of the {{sup|241}}Pu will beta decay to [[americium-241]], one of the [[minor actinide]]s, a strong alpha emitter, and difficult to use in thermal reactors.


<sup>242</sup>Pu has a particularly low cross section for thermal neutron capture; and it takes three neutron absorptions to become another fissile isotope (either [[curium]]-245 or <sup>241</sup>Pu) and fission. Even then, there is a chance either of those two fissile isotopes will fail to fission but instead absorb a fourth neutron, becoming curium-246 (on the way to even heavier actinides like [[californium]], which is a neutron emitter by spontaneous fission and difficult to handle) or becoming <sup>242</sup>Pu again; so the mean number of neutrons absorbed before fission is even higher than 3. Therefore, <sup>242</sup>Pu is particularly unsuited to recycling in a thermal reactor and would be better used in a [[fast reactor]] where it can be fissioned directly. However, <sup>242</sup>Pu's low cross section means that relatively little of it will be transmuted during one cycle in a thermal reactor. <sup>242</sup>Pu's half-life is about 15 times as long as <sup>239</sup>Pu's half-life; therefore, it is 1/15 as radioactive and not one of the larger contributors to [[nuclear waste]] radioactivity.
{{sup|242}}Pu has a particularly low cross section for thermal neutron capture; and it takes three neutron absorptions to become another fissile isotope (either [[curium]]-245 or {{sup|241}}Pu) and fission. Even then, there is a chance either of those two fissile isotopes will fail to fission but instead absorb a fourth neutron, becoming curium-246 (on the way to even heavier actinides like [[californium]], which is a neutron emitter by spontaneous fission and difficult to handle) or becoming {{sup|242}}Pu again; so the mean number of neutrons absorbed before fission is even higher than 3. Therefore, {{sup|242}}Pu is particularly unsuited to recycling in a thermal reactor and would be better used in a [[fast reactor]] where it can be fissioned directly. However, {{sup|242}}Pu's low cross section means that relatively little of it will be transmuted during one cycle in a thermal reactor. {{sup|242}}Pu's half-life is about 15 times as long as {{sup|239}}Pu's half-life; therefore, it is 1/15 as radioactive and not one of the larger contributors to [[nuclear waste]] radioactivity.
<sup>242</sup>Pu's [[gamma ray]] emissions are also weaker than those of the other isotopes.<ref>{{cite web|url=http://www.wmsym.org/archives/2001/21B/21B-18.pdf|title=Plutonium Isotopic Results of Known Samples Using the Snap Gamma Spectroscopy Analysis Code and the Robwin Spectrum Fitting Routine|access-date=2013-03-15|archive-date=2017-08-13|archive-url=https://web.archive.org/web/20170813191754/http://www.wmsym.org/archives/2001/21B/21B-18.pdf|url-status=dead}}</ref>
{{sup|242}}Pu's [[gamma ray]] emissions are also weaker than those of the other isotopes.<ref>{{cite web|url=http://www.wmsym.org/archives/2001/21B/21B-18.pdf|title=Plutonium Isotopic Results of Known Samples Using the Snap Gamma Spectroscopy Analysis Code and the Robwin Spectrum Fitting Routine|access-date=2013-03-15|archive-date=2017-08-13|archive-url=https://web.archive.org/web/20170813191754/http://www.wmsym.org/archives/2001/21B/21B-18.pdf|url-status=dead}}</ref>


<sup>243</sup>Pu has a half-life of only 5 hours, beta decaying to [[americium-243]]. Because <sup>243</sup>Pu has little opportunity to capture an additional neutron before decay, the [[nuclear fuel cycle]] does not produce the long-lived <sup>244</sup>Pu in significant quantity.
{{sup|243}}Pu has a half-life of only 5 hours, beta decaying to [[americium-243]]. Because {{sup|243}}Pu has little opportunity to capture an additional neutron before decay, the [[nuclear fuel cycle]] does not produce the long-lived {{sup|244}}Pu in significant quantity.


<sup>238</sup>Pu is not normally produced in as large quantity by the nuclear fuel cycle, but some is produced from [[neptunium-237]] by neutron capture (this reaction can also be used with purified neptunium to produce <sup>238</sup>Pu relatively free of other plutonium isotopes for use in [[radioisotope thermoelectric generator]]s), by the (n,2n) reaction of fast neutrons on <sup>239</sup>Pu, or by alpha decay of [[curium]]-242, which is produced by neutron capture from <sup>241</sup>Am. It has significant thermal neutron cross section for fission, but is more likely to capture a neutron and become <sup>239</sup>Pu.
{{sup|238}}Pu is not normally produced in as large quantity by the nuclear fuel cycle, but some is produced from [[neptunium-237]] by neutron capture (this reaction can also be used with purified neptunium to produce {{sup|238}}Pu relatively free of other plutonium isotopes for use in [[radioisotope thermoelectric generator]]s), by the (n,2n) reaction of fast neutrons on {{sup|239}}Pu, or by alpha decay of [[curium]]-242, which is produced by neutron capture of {{sup|241}}Am. It has significant thermal neutron cross section for fission, but is more likely to capture a neutron and become {{sup|239}}Pu.


==Manufacture==<!-- This section is linked from [[Radioactive waste]] -->
==Manufacture==<!-- This section is linked from [[Radioactive waste]] -->
Line 367: Line 434:
===Plutonium-240, -241 and -242===
===Plutonium-240, -241 and -242===


The fission [[Cross section (physics)|cross section]] for <sup>239</sup>Pu is 747.9 [[Barn (unit)|barns]] for thermal neutrons, while the activation cross section is 270.7 barns (the ratio approximates to 11 fissions for every 4 neutron captures). The higher plutonium isotopes are created when the uranium fuel is used for a long time. For high burnup used fuel, the concentrations of the higher plutonium isotopes will be higher than the low burnup fuel that is reprocessed to obtain [[weapons grade]] plutonium.
The fission [[Cross section (physics)|cross section]] for {{sup|239}}Pu is 747.9 [[Barn (unit)|barns]] for thermal neutrons, while the activation cross section is 270.7 barns (the ratio approximates to 11 fissions for every 4 neutron captures). The higher plutonium isotopes are created when the uranium fuel is used for a long time. For high burnup used fuel, the concentrations of the higher plutonium isotopes will be higher than the low burnup fuel that is reprocessed to obtain [[weapons grade]] plutonium.


{| class="wikitable"
{| class="wikitable"
Line 392: Line 459:
===Plutonium-239===
===Plutonium-239===
{{Main|Plutonium-239}}
{{Main|Plutonium-239}}
Plutonium-239 is one of the three fissile materials used for the production of nuclear weapons and in some nuclear reactors as a source of energy. The other fissile materials are [[uranium-235]] and [[uranium-233]]. Plutonium-239 is virtually nonexistent in nature. It is made by bombarding [[uranium-238]] with neutrons in a nuclear reactor. Uranium-238 is present in quantity in most reactor fuel; hence plutonium-239 is continuously made in these reactors. Since plutonium-239 can itself be split by neutrons to release energy, plutonium-239 provides a portion of the energy generation in a nuclear reactor.
[[File:Plutonium ring.jpg|right|upright=1.35|thumb|A 5.3 kg ring of weapons-grade electrorefined plutonium, 99.96% purity. This is enough plutonium for an efficient nuclear weapon. The ring shape is needed to depart from a spherical shape and avoid [[critical mass|criticality]].]]
{{sup|239}}Pu is one of the three fissile materials used for the production of nuclear weapons and in some nuclear reactors as a source of energy. The other fissile materials are [[uranium-235]] and [[uranium-233]]. {{sup|239}}Pu is virtually nonexistent in nature. It is made by bombarding [[uranium-238]] with neutrons. Uranium-238 is present in quantity in most reactor fuel; hence {{sup|239}}Pu is continuously made in these reactors. Since {{sup|239}}Pu can itself be split by neutrons to release energy, {{sup|239}}Pu provides a portion of the energy generation in a nuclear reactor.
[[File:Plutonium ring.jpg|right|300px|thumb|A ring of weapons-grade electrorefined plutonium, with 99.96% purity. This 5.3 kg ring is enough plutonium for use in an efficient nuclear weapon. The ring shape is needed to depart from a spherical shape and avoid [[critical mass|criticality]].]]


{| class="wikitable"
{| class="wikitable"
|+ The formation of <sup>239</sup>Pu from <sup>238</sup>U<ref name="Miner1968p541">{{harvnb|Miner|1968|p=541}}</ref>
|+ The formation of {{sup|239}}Pu from {{sup|238}}U<ref name="Miner1968p541">{{harvnb|Miner|1968|p=541}}</ref>
! Element !! Isotope !! Thermal neutron capture<br/>cross section (barn) !! Thermal neutron fission <br/>Cross section (barn) !! decay mode !! Half-life
! Element !! Isotope !! Thermal neutron capture<br/>cross section (barn) !! Thermal neutron fission <br/>Cross section (barn) !! decay mode !! Half-life
|-
|-
! [[uranium|U]]
! [[uranium|U]]
| 238 || 2.68 || 5·10<sup>−6</sup> || α || 4.47 x 10<sup>9</sup> years
| 238 || 2.68 || 5·10{{sup|−6}} || α || 4.47 x 10{{sup|9}} years
|-
|-
! [[uranium|U]]
! [[uranium|U]]
| 239 || 22 || 15 || β<sup></sup> || 23 minutes
| 239 || 22 || 15 || β{{sup|}} || 23 minutes
|-
|-
! [[neptunium|Np]]
! [[neptunium|Np]]
| 239 || 30 || 1 || β<sup></sup> || 2.36 days
| 239 || 30 || 1 || β{{sup|}} || 2.36 days
|-
|-
! [[plutonium|Pu]]
! [[plutonium|Pu]]
Line 414: Line 481:
===Plutonium-238===
===Plutonium-238===
{{Main|Plutonium-238}}
{{Main|Plutonium-238}}
There are small amounts of <sup>238</sup>Pu in the plutonium of usual plutonium-producing reactors. However, isotopic separation would be quite expensive compared to another method: when a <sup>235</sup>U atom captures a neutron, it is converted to an excited state of <sup>236</sup>U. Some of the excited <sup>236</sup>U nuclei undergo fission, but some decay to the ground state of <sup>236</sup>U by emitting gamma radiation. Further neutron capture creates <sup>237</sup>U, which has a half-life of 7 days and thus quickly decays to <sup>237</sup>Np. Since nearly all neptunium is produced in this way or consists of isotopes that decay quickly, one gets nearly pure <sup>237</sup>Np by chemical separation of neptunium. After this chemical separation, <sup>237</sup>Np is again irradiated by reactor neutrons to be converted to <sup>238</sup>Np, which decays to <sup>238</sup>Pu with a half-life of 2 days.
There are small amounts of {{sup|238}}Pu in the plutonium from usual reactors. However, isotopic separation would be quite expensive compared to another method: when {{sup|235}}U captures a neutron, it is converted to an excited state of {{sup|236}}U. Some of the excited {{sup|236}}U nuclei undergo fission, but some decay to the ground state of {{sup|236}}U by emitting gamma radiation. Further neutron capture creates {{sup|237}}U; which, with a half-life of 7 days, decays to {{sup|237}}Np. Since nearly all neptunium is produced in this way or consists of isotopes that decay quickly, one gets nearly pure {{sup|237}}Np. After chemical separation of neptunium, {{sup|237}}Np is again irradiated by reactor neutrons to be converted to {{sup|238}}Np, which decays to {{sup|238}}Pu with a half-life of 2 days.


{| class="wikitable"
{| class="wikitable"
|+ The formation of <sup>238</sup>Pu from <sup>235</sup>U
|+ The formation of {{sup|238}}Pu from {{sup|235}}U
! Element !! Isotope !! Thermal neutron<br/>cross section !! decay mode !! Half-life
! Element !! Isotope !! Thermal neutron<br/>cross section !! decay mode !! Half-life
|-
|-
Line 427: Line 494:
|-
|-
! [[uranium|U]]
! [[uranium|U]]
| 237 || — || β<sup></sup> || 6.75 days
| 237 || — || β{{sup|}} || 6.75 days
|-
|-
! [[neptunium|Np]]
! [[neptunium|Np]]
Line 433: Line 500:
|-
|-
! [[neptunium|Np]]
! [[neptunium|Np]]
| 238 || — || β<sup></sup> || 2.11 days
| 238 || — || β{{sup|}} || 2.11 days
|-
|-
! [[plutonium|Pu]]
! [[plutonium|Pu]]
Line 439: Line 506:
|}
|}


==<sup>240</sup>Pu as an obstacle to nuclear weapons==
==Plutonium-240 as an obstacle to nuclear weapons==
[[Plutonium-240]] undergoes spontaneous fission as a secondary decay mode at a small but significant rate. The presence of <sup>240</sup>Pu limits the plutonium's use in a [[nuclear bomb]], because the neutron flux from spontaneous fission initiates the [[chain reaction]] prematurely, causing an early release of energy that physically disperses the core before full [[implosion (mechanical process)|implosion]] is reached. This prevents most of the core from participation in the chain reaction and reduces the bomb's power.
{{sup|240}}Pu undergoes [[spontaneous fission]] at a small but significant rate ({{val|5.8|e=-6}}%).{{NUBASE2020|ref}} The presence of {{sup|240}}Pu limits the plutonium's use in a [[nuclear bomb]], because a neutron from spontaneous fission starts the [[chain reaction]] prematurely, causing an early release of energy that disperses the core before full [[implosion (mechanical process)|implosion]] is reached. This prevents most of the core from participation in the chain reaction and reduces the bomb's yield.


Plutonium consisting of more than about 90% <sup>239</sup>Pu is called [[weapons-grade plutonium]]; plutonium from [[spent nuclear fuel]] from commercial power reactors generally contains at least 20% <sup>240</sup>Pu and is called [[reactor-grade plutonium]]. However, modern nuclear weapons use [[fusion boosting]], which mitigates the predetonation problem; if the [[pit (nuclear weapon)|pit]] can generate a [[nuclear weapon yield]] of even a fraction of a [[kiloton]], which is enough to start [[nuclear fusion|deuterium-tritium fusion]], the resulting burst of neutrons will fission enough plutonium to ensure a yield of tens of kilotons.
Plutonium consisting of more than about 90% {{sup|239}}Pu is called [[weapons-grade plutonium]]; plutonium from [[spent nuclear fuel]] from commercial power reactors generally contains at least 20% {{sup|240}}Pu and is called [[reactor-grade plutonium]]. However, modern nuclear weapons use [[fusion boosting]], which mitigates the predetonation problem; if the [[pit (nuclear weapon)|pit]] can generate a [[nuclear weapon yield]] of even a fraction of a [[kiloton]], which is enough to start [[nuclear fusion|deuterium–tritium fusion]], the resulting burst of neutrons will fission enough plutonium to ensure a yield of tens of kilotons.


<sup>240</sup>Pu contamination is the reason plutonium weapons must use the [[Nuclear weapon design#Implosion-type weapon|implosion method]]. Theoretically, pure <sup>239</sup>Pu could be used in a [[gun-type nuclear weapon]], but achieving this level of purity is prohibitively difficult. <sup>240</sup>Pu contamination has proven a mixed blessing to [[nuclear weapons design]]. While it created delays and headaches during the [[Manhattan Project]] because of the need to develop implosion technology, those same difficulties are currently a barrier to [[nuclear proliferation]]. Implosion devices are also inherently more efficient and less prone to accidental detonation than are gun-type weapons.
Contamination due to {{sup|240}}Pu is the reason plutonium weapons must use the [[Nuclear weapon design#Implosion-type weapon|implosion method]]. Theoretically, pure {{sup|239}}Pu could be used in a [[gun-type bomb]], but achieving this level of purity is prohibitively difficult. {{sup|240}}Pu contamination has proven a mixed blessing. While it created delays and headaches during the [[Manhattan Project]] because of the need to develop implosion technology, those same difficulties are a barrier to [[nuclear proliferation]]. Implosion bombs are also inherently more efficient and less prone to accidental detonation than are gun-type bombs.


== References ==
== References ==
* Isotope masses from:
* Isotope masses from:
**{{NUBASE 2003}}
**{{NUBASE 2003 |ref=none}}
* Isotopic compositions and standard atomic masses from:
**{{CIAAW2003}}
**{{CIAAW 2005}}
* Half-life, spin, and isomer data selected from the following sources.
* Half-life, spin, and isomer data selected from the following sources.
**{{NUBASE 2003}}
**{{NUBASE 2003 |ref=none}}
**{{NNDC}}
**{{NNDC |ref=none}}
**{{CRC85|chapter=11}}
**{{CRC85|chapter=11 |ref=none}}


{{Reflist}}
{{Reflist}}

==Sources==
* {{Cite book |url=https://www-nds.iaea.org/publications/indc/indc_usa_0085_II.pdf |title=Proceedings of the conference on nuclear data evaluation methods and procedures. BNL-NCS 51363. |date=1981 |publisher=[[Brookhaven National Laboratory]] |editor-last=Magurno |editor-first=B. A. |volume=II |location=Upton |access-date=August 6, 2014 |editor-last2=Pearlstein |editor-first2=S. |archive-url=https://web.archive.org/web/20210308125416/https://www-nds.iaea.org/publications/indc/indc_usa_0085_II.pdf |archive-date=March 8, 2021 |url-status=live}}
* {{Cite book |last1=Miner |first1=William N. |title=The Encyclopedia of the Chemical Elements |last2=Schonfeld, Fred W. |publisher=Reinhold Book Corporation |year=1968 |editor-last=Clifford A. Hampel |location=New York (NY) |pages=[https://archive.org/details/encyclopediaofch00hamp/page/540 540–546] |chapter=Plutonium |lccn=68029938 |ref=CITEREFMiner1968 |chapter-url=https://archive.org/details/encyclopediaofch00hamp |chapter-url-access=registration}}


{{Navbox element isotopes}}
{{Navbox element isotopes}}

Latest revision as of 23:03, 13 November 2024

Isotopes of plutonium (94Pu)
Main isotopes[1] Decay
abun­dance half-life (t1/2) mode pro­duct
238Pu trace 87.7 y[2] α 234U
SF
239Pu trace 2.411×104 y α 235U
SF
240Pu trace 6.561×103 y α 236U
SF
241Pu synth 14.329 y β 241Am
α 237U
SF
242Pu synth 3.75×105 y α 238U
SF
244Pu trace 8.00×107 y α 240U
SF

Plutonium (94Pu) is an artificial element, except for trace quantities resulting from neutron capture by uranium, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was synthesized long before being found in nature, the first isotope synthesized being 238Pu in 1940. Twenty-two plutonium radioisotopes have been characterized. The most stable are 244Pu with a half-life of 80.8 million years; 242Pu with a half-life of 373,300 years; and 239Pu with a half-life of 24,110 years; and 240Pu with a half-life of 6,560 years. This element also has eight meta states; all have half-lives of less than one second.

The known isotopes of plutonium range from 226Pu to 247Pu. The primary decay modes before the most stable isotope, 244Pu, are spontaneous fission and alpha decay; the primary mode after is beta emission. The primary decay products before 244Pu are isotopes of uranium and neptunium (not considering fission products), and the primary decay products after are isotopes of americium.

List of isotopes

[edit]


Nuclide
[n 1]
Z N Isotopic mass (Da)[3]
[n 2][n 3]
Half-life[1]
Decay
mode
[1]
[n 4]
Daughter
isotope

[n 5][n 6]
Spin and
parity[1]
[n 7][n 8]
Isotopic
abundance
Excitation energy
226Pu[4] 94 132 226.03825(22)# ≥1 ms α 222U 0+
227Pu[5] 94 133 227.03947(11)# 0.78+0.39
−0.19
 s
α 223U 5/2+#
228Pu 94 134 228.038763(25) 2.1(13) s α 224U 0+
229Pu 94 135 229.040145(65) 91(26) s α (~50%) 225U 3/2+#
β+ (~50%) 229Np
SF (<7%) (various)
230Pu 94 136 230.039648(16) 105(10) s α (>73%)[6] 226U 0+
β+ (<27%) 230Np
231Pu 94 137 231.041126(24) 8.6(5) min β+ (87%) 231Np (3/2+)
α (13%) 227U
232Pu 94 138 232.041182(18) 33.7(5) min EC (>80%) 232Np 0+
α (<20%) 228U
233Pu 94 139 233.042997(58) 20.9(4) min β+ (99.88%) 233Np 5/2+#
α (0.12%) 229U
234Pu 94 140 234.0433175(73) 8.8(1) h EC (94%) 234Np 0+
α (6%) 230U
235Pu 94 141 235.045285(22) 25.3(5) min β+ 235Np (5/2+)
α (0.0028%) 231U
236Pu 94 142 236.0460567(19) 2.858(8) y α[n 9] 232U 0+
SF (1.9×10−7%) (various)
CD (2×10−12%) 208Pb
28Mg
236mPu 1185.45(15) keV 1.2(3) μs IT 236Pu 5−
237Pu 94 143 237.0484079(18) 45.64(4) d EC 237Np 7/2−
α (0.0042%) 233U
237m1Pu 145.543(8) keV 180(20) ms IT 237Pu 1/2+
237m2Pu 2900(250) keV 1.1(1) μs SF (various)
238Pu 94 144 238.0495582(12) 87.7(1) y α 234U 0+ Trace[n 10]
SF (1.9×10−7%) (various)
CD (1.4×10−14%) 206Hg
32Si
CD (<6×10−15%) 210Pb
28Mg
CD (<6×10−15%) 208Pb
30Mg
239Pu[n 11][n 12] 94 145 239.0521616(12) 2.411(3)×104 y α 235U 1/2+ Trace[n 13]
SF (3.1×10−10%) (various)
239m1Pu 391.584(3) keV 193(4) ns IT 239Pu 7/2−
239m2Pu 3100(200) keV 7.5(10) μs SF (various) (5/2+)
240Pu 94 146 240.0538117(12) 6.561(7)×103 y α 236U 0+ Trace[n 14]
SF (5.796×10−6%) (various)
CD (<1.3×10−11%) 206Hg
34Si
240mPu 1308.74(5) keV 165(10) ns IT 240Pu 5−
241Pu[n 11] 94 147 241.0568497(12) 14.329(29) y β 241Am 5/2+
α (0.00245%) 237U
SF (<2.4×10−14%) (various)
241m1Pu 161.6853(9) keV 0.88(5) μs IT 241Pu 1/2+
241m2Pu 2200(200) keV 20.5(22) μs SF (various)
242Pu 94 148 242.0587410(13) 3.75(2)×105 y α 238U 0+
SF (5.510×10−4%) (various)
243Pu[n 11] 94 149 243.0620021(27) 4.9553(25) h β 243Am 7/2+
243mPu 383.64(25) keV 330(30) ns IT 243Pu (1/2+)
244Pu 94 150 244.0642044(25) 81.3(3)×107 y α (99.88%) 240U 0+ Trace[n 15]
SF (0.123%) (various)
ββ (<7.3×10−9%) 244Cm
244mPu 1216.0(5) keV 1.75(12) s IT 244Pu 8−
245Pu 94 151 245.067825(15) 10.5(1) h β 245Am (9/2−)
245m1Pu 264.5(3) keV 330(20) ns IT 245Pu (5/2+)
245m2Pu 2000(400) keV 90(30) ns SF (various)
246Pu 94 152 246.070204(16) 10.84(2) d β 246Am 0+
247Pu 94 153 247.07430(22)# 2.27(23) d β 247Am 1/2+#
This table header & footer:
  1. ^ mPu – Excited nuclear isomer.
  2. ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ^ Modes of decay:
    CD: Cluster decay
    EC: Electron capture
    IT: Isomeric transition
    SF: Spontaneous fission
  5. ^ Bold italics symbol as daughter – Daughter product is nearly stable.
  6. ^ Bold symbol as daughter – Daughter product is stable.
  7. ^ ( ) spin value – Indicates spin with weak assignment arguments.
  8. ^ # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  9. ^ Theorized to also undergo ββ decay to 236U
  10. ^ Double beta decay product of 238U
  11. ^ a b c fissile nuclide
  12. ^ Most useful isotope for nuclear weapons
  13. ^ Neutron capture product of 238U
  14. ^ Intermediate decay product of 244Pu
  15. ^ Interstellar, some may also be primordial but such claims are disputed

Actinides vs fission products

[edit]
Actinides[7] by decay chain Half-life
range (a)
Fission products of 235U by yield[8]
4n 4n + 1 4n + 2 4n + 3 4.5–7% 0.04–1.25% <0.001%
228Ra 4–6 a 155Euþ
248Bk[9] > 9 a
244Cmƒ 241Puƒ 250Cf 227Ac 10–29 a 90Sr 85Kr 113mCdþ
232Uƒ 238Puƒ 243Cmƒ 29–97 a 137Cs 151Smþ 121mSn
249Cfƒ 242mAmƒ 141–351 a

No fission products have a half-life
in the range of 100 a–210 ka ...

241Amƒ 251Cfƒ[10] 430–900 a
226Ra 247Bk 1.3–1.6 ka
240Pu 229Th 246Cmƒ 243Amƒ 4.7–7.4 ka
245Cmƒ 250Cm 8.3–8.5 ka
239Puƒ 24.1 ka
230Th 231Pa 32–76 ka
236Npƒ 233Uƒ 234U 150–250 ka 99Tc 126Sn
248Cm 242Pu 327–375 ka 79Se
1.33 Ma 135Cs
237Npƒ 1.61–6.5 Ma 93Zr 107Pd
236U 247Cmƒ 15–24 Ma 129I
244Pu 80 Ma

... nor beyond 15.7 Ma[11]

232Th 238U 235Uƒ№ 0.7–14.1 Ga

Notable isotopes

[edit]

Production and uses

[edit]
A pellet of 238Pu, glowing from its own heat, used for radioisotope thermoelectric generators.
Transmutation flow between 238Pu and 244Cm in LWR.[14]
Transmutation speed not shown and varies greatly by nuclide. 245Cm–248Cm are long-lived with negligible decay.

239Pu, a fissile isotope that is the second most used nuclear fuel in nuclear reactors after uranium-235, and the most used fuel in the fission portion of nuclear weapons, is produced from uranium-238 by neutron capture followed by two beta decays.

240Pu, 241Pu, and 242Pu are produced by further neutron capture. The odd-mass isotopes 239Pu and 241Pu have about a 3/4 chance of undergoing fission on capture of a thermal neutron and about a 1/4 chance of retaining the neutron and becoming the next heavier isotope. The even-mass isotopes are fertile but not fissile and also have a lower probability (cross section) of neutron capture; therefore, they tend to accumulate in nuclear fuel used in a thermal reactor, the design of nearly all nuclear power plants today. In plutonium that has been used a second time in thermal reactors in MOX fuel, 240Pu may even be the most common isotope. All plutonium isotopes and other actinides, however, are fissionable with fast neutrons. 240Pu does have a moderate thermal neutron absorption cross section, so that 241Pu production in a thermal reactor becomes a significant fraction as large as 239Pu production.

241Pu has a half-life of 14 years, and has slightly higher thermal neutron cross sections than 239Pu for both fission and absorption. While nuclear fuel is being used in a reactor, a 241Pu nucleus is much more likely to fission or to capture a neutron than to decay. 241Pu accounts for a significant portion of fissions in thermal reactor fuel that has been used for some time. However, in spent nuclear fuel that does not quickly undergo nuclear reprocessing but instead is cooled for years after use, much or most of the 241Pu will beta decay to americium-241, one of the minor actinides, a strong alpha emitter, and difficult to use in thermal reactors.

242Pu has a particularly low cross section for thermal neutron capture; and it takes three neutron absorptions to become another fissile isotope (either curium-245 or 241Pu) and fission. Even then, there is a chance either of those two fissile isotopes will fail to fission but instead absorb a fourth neutron, becoming curium-246 (on the way to even heavier actinides like californium, which is a neutron emitter by spontaneous fission and difficult to handle) or becoming 242Pu again; so the mean number of neutrons absorbed before fission is even higher than 3. Therefore, 242Pu is particularly unsuited to recycling in a thermal reactor and would be better used in a fast reactor where it can be fissioned directly. However, 242Pu's low cross section means that relatively little of it will be transmuted during one cycle in a thermal reactor. 242Pu's half-life is about 15 times as long as 239Pu's half-life; therefore, it is 1/15 as radioactive and not one of the larger contributors to nuclear waste radioactivity. 242Pu's gamma ray emissions are also weaker than those of the other isotopes.[15]

243Pu has a half-life of only 5 hours, beta decaying to americium-243. Because 243Pu has little opportunity to capture an additional neutron before decay, the nuclear fuel cycle does not produce the long-lived 244Pu in significant quantity.

238Pu is not normally produced in as large quantity by the nuclear fuel cycle, but some is produced from neptunium-237 by neutron capture (this reaction can also be used with purified neptunium to produce 238Pu relatively free of other plutonium isotopes for use in radioisotope thermoelectric generators), by the (n,2n) reaction of fast neutrons on 239Pu, or by alpha decay of curium-242, which is produced by neutron capture of 241Am. It has significant thermal neutron cross section for fission, but is more likely to capture a neutron and become 239Pu.

Manufacture

[edit]

Plutonium-240, -241 and -242

[edit]

The fission cross section for 239Pu is 747.9 barns for thermal neutrons, while the activation cross section is 270.7 barns (the ratio approximates to 11 fissions for every 4 neutron captures). The higher plutonium isotopes are created when the uranium fuel is used for a long time. For high burnup used fuel, the concentrations of the higher plutonium isotopes will be higher than the low burnup fuel that is reprocessed to obtain weapons grade plutonium.

The formation of 240Pu, 241Pu, and 242Pu from 238U
Isotope Thermal neutron
cross section[16]
(barns)
Decay
Mode
Half-life
Capture Fission
238U 2.683 0.000 α 4.468 x 109 years
239U 20.57 14.11 β 23.45 minutes
239Np 77.03 β 2.356 days
239Pu 270.7 747.9 α 24,110 years
240Pu 287.5 0.064 α 6,561 years
241Pu 363.0 1012 β 14.325 years
242Pu 19.16 0.001 α 373,300 years

Plutonium-239

[edit]
A 5.3 kg ring of weapons-grade electrorefined plutonium, 99.96% purity. This is enough plutonium for an efficient nuclear weapon. The ring shape is needed to depart from a spherical shape and avoid criticality.

239Pu is one of the three fissile materials used for the production of nuclear weapons and in some nuclear reactors as a source of energy. The other fissile materials are uranium-235 and uranium-233. 239Pu is virtually nonexistent in nature. It is made by bombarding uranium-238 with neutrons. Uranium-238 is present in quantity in most reactor fuel; hence 239Pu is continuously made in these reactors. Since 239Pu can itself be split by neutrons to release energy, 239Pu provides a portion of the energy generation in a nuclear reactor.

The formation of 239Pu from 238U[17]
Element Isotope Thermal neutron capture
cross section (barn)
Thermal neutron fission
Cross section (barn)
decay mode Half-life
U 238 2.68 5·10−6 α 4.47 x 109 years
U 239 22 15 β 23 minutes
Np 239 30 1 β 2.36 days
Pu 239 271 750 α 24,110 years

Plutonium-238

[edit]

There are small amounts of 238Pu in the plutonium from usual reactors. However, isotopic separation would be quite expensive compared to another method: when 235U captures a neutron, it is converted to an excited state of 236U. Some of the excited 236U nuclei undergo fission, but some decay to the ground state of 236U by emitting gamma radiation. Further neutron capture creates 237U; which, with a half-life of 7 days, decays to 237Np. Since nearly all neptunium is produced in this way or consists of isotopes that decay quickly, one gets nearly pure 237Np. After chemical separation of neptunium, 237Np is again irradiated by reactor neutrons to be converted to 238Np, which decays to 238Pu with a half-life of 2 days.

The formation of 238Pu from 235U
Element Isotope Thermal neutron
cross section
decay mode Half-life
U 235 99 α 703,800,000 years
U 236 5.3 α 23,420,000 years
U 237 β 6.75 days
Np 237 165 (capture) α 2,144,000 years
Np 238 β 2.11 days
Pu 238 α 87.7 years

Plutonium-240 as an obstacle to nuclear weapons

[edit]

240Pu undergoes spontaneous fission at a small but significant rate (5.8×10−6%).[1] The presence of 240Pu limits the plutonium's use in a nuclear bomb, because a neutron from spontaneous fission starts the chain reaction prematurely, causing an early release of energy that disperses the core before full implosion is reached. This prevents most of the core from participation in the chain reaction and reduces the bomb's yield.

Plutonium consisting of more than about 90% 239Pu is called weapons-grade plutonium; plutonium from spent nuclear fuel from commercial power reactors generally contains at least 20% 240Pu and is called reactor-grade plutonium. However, modern nuclear weapons use fusion boosting, which mitigates the predetonation problem; if the pit can generate a nuclear weapon yield of even a fraction of a kiloton, which is enough to start deuterium–tritium fusion, the resulting burst of neutrons will fission enough plutonium to ensure a yield of tens of kilotons.

Contamination due to 240Pu is the reason plutonium weapons must use the implosion method. Theoretically, pure 239Pu could be used in a gun-type bomb, but achieving this level of purity is prohibitively difficult. 240Pu contamination has proven a mixed blessing. While it created delays and headaches during the Manhattan Project because of the need to develop implosion technology, those same difficulties are a barrier to nuclear proliferation. Implosion bombs are also inherently more efficient and less prone to accidental detonation than are gun-type bombs.

References

[edit]
  • Isotope masses from:
    • Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
  • Half-life, spin, and isomer data selected from the following sources.
  1. ^ a b c d e Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. ^ Magurno & Pearlstein 1981, pp. 835 ff.
  3. ^ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  4. ^ Kuznetsova AA, Svirikhin AI, Isaev AV, Bychkov MA, Danilkin VD, Devarazha KM, Zamyatin NI, Izosimov IN, Liu Z, Malyshev ON, Mukhin RS, Popeko AG, Popov YA, Rachkov VA, Saylaubekov B, Sokol EA, Tezekbaeva MS, Ulanova II, Zhang FS, Chepigin VI, Chelnokov ML, Eremin AV (2024). "Свойства радиоактивного распада нового ядра 227Pu" [Properties of Radioactive Decay of the New Nucleus 227Pu] (PDF). jinr.ru (in Russian). Joint Institute for Nuclear Research. Retrieved 9 November 2024.
  5. ^ Yang, H. B.; Gan, Z. G.; Zhang, Z. Y.; Huang, M. H.; Ma, L.; Yang, C. L.; Zhang, M. M.; Tian, Y. L.; Wang, Y. S.; Wang, J. G.; Zhou, H. B.; Hua, W.; Wang, J. Y.; Qiang, Y. H.; Zhao, Z.; Huang, X. Y.; Wen, X. J.; Li, Z. Y.; Zhang, H. T.; Xu, S. Y.; Li, Z. C.; Zhou, H.; Zhang, X.; Zhu, L.; Wang, Z.; Guan, F.; Yang, H. R.; Huang, W. X.; Ren, Z. Z.; Zhou, S. G.; Xu, H. S. (3 October 2024). "α decay of the new isotope Pu 227". Physical Review C. 110 (4). doi:10.1103/PhysRevC.110.044302.
  6. ^ Wilson, G. L.; Takeyama, M.; Andreyev, A. N.; Andel, B.; Antalic, S.; Catford, W. N.; Ghys, L.; Haba, H.; Heßberger, F. P.; Huang, M.; Kaji, D.; Kalaninova, Z.; Morimoto, K.; Morita, K.; Murakami, M.; Nishio, K.; Orlandi, R.; Smith, A. G.; Tanaka, K.; Wakabayashi, Y.; Yamaki, S. (13 October 2017). "β -delayed fission of Am 230". Physical Review C. 96 (4): 044315. doi:10.1103/PhysRevC.96.044315. ISSN 2469-9985.
  7. ^ Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
  8. ^ Specifically from thermal neutron fission of uranium-235, e.g. in a typical nuclear reactor.
  9. ^ Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. Bibcode:1965NucPh..71..299M. doi:10.1016/0029-5582(65)90719-4.
    "The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk248 with a half-life greater than 9 [years]. No growth of Cf248 was detected, and a lower limit for the β half-life can be set at about 104 [years]. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 [years]."
  10. ^ This is the heaviest nuclide with a half-life of at least four years before the "sea of instability".
  11. ^ Excluding those "classically stable" nuclides with half-lives significantly in excess of 232Th; e.g., while 113mCd has a half-life of only fourteen years, that of 113Cd is eight quadrillion years.
  12. ^ Makhijani, Arjun; Seth, Anita (July 1997). "The Use of Weapons Plutonium as Reactor Fuel" (PDF). Energy and Security. Takoma Park, MD: Institute for Energy and Environmental Research. Retrieved 4 July 2016.
  13. ^ Wallner, A.; Faestermann, T.; Feige, J.; Feldstein, C.; Knie, K.; Korschinek, G.; Kutschera, W.; Ofan, A.; Paul, M.; Quinto, F.; Rugel, G.; Steier, P. (2015). "Abundance of live 244Pu in deep-sea reservoirs on Earth points to rarity of actinide nucleosynthesis". Nature Communications. 6: 5956. arXiv:1509.08054. Bibcode:2015NatCo...6.5956W. doi:10.1038/ncomms6956. ISSN 2041-1723. PMC 4309418. PMID 25601158.
  14. ^ Sasahara, Akihiro; Matsumura, Tetsuo; Nicolaou, Giorgos; Papaioannou, Dimitri (April 2004). "Neutron and Gamma Ray Source Evaluation of LWR High Burn-up UO2 and MOX Spent Fuels". Journal of Nuclear Science and Technology. 41 (4): 448–456. doi:10.3327/jnst.41.448.
  15. ^ "Plutonium Isotopic Results of Known Samples Using the Snap Gamma Spectroscopy Analysis Code and the Robwin Spectrum Fitting Routine" (PDF). Archived from the original (PDF) on 2017-08-13. Retrieved 2013-03-15.
  16. ^ National Nuclear Data Center Interactive Chart of Nuclides Archived 2011-07-21 at the Wayback Machine
  17. ^ Miner 1968, p. 541

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