Sodium carbonate: Difference between revisions

Sodium carbonate
Names
	IUPAC name Sodium carbonate
	Other names Soda ash, washing soda, soda crystals, sodium trioxocarbonate
Identifiers
CAS Number	497-19-8 (anhydrous) ; 5968-11-6 (monohydrate) ; 6132-02-1 (decahydrate) ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:29377 ;
ChEMBL	ChEMBL186314 ;
ChemSpider	9916 ;
ECHA InfoCard	100.007.127
EC Number	207-838-8;
E number	E500(i) (acidity regulators, ...)
PubChem CID	10340;
RTECS number	VZ4050000;
UNII	45P3261C7T ; 2A1Q1Q3557 (monohydrate) ; LS505BG22I (decahydrate) ;
CompTox Dashboard (EPA)	DTXSID1029621 ;
	InChI InChI=1S/CH2O3.2Na/c2-1(3)4;;/h(H2,2,3,4);;/q;2+1/p-2 Key: CDBYLPFSWZWCQE-UHFFFAOYSA-L ; InChI=1/NaHCO3.2Na/c2-1(3)4;;/h(H2,2,3,4);;/q;2+1/p-2 Key: CDBYLPFSWZWCQE-NUQVWONBAP;
	SMILES [Na+].[Na+].[O-]C([O-])=O;
Properties
Chemical formula	Na2CO3
Molar mass	105.9888 g/mol (anhydrous); 286.1416 g/mol (decahydrate)
Appearance	White solid, hygroscopic
Odor	Odorless
Density	2.54 g/cm3 (25 °C, anhydrous); 1.92 g/cm3 (856 °C); 2.25 g/cm3 (monohydrate); 1.51 g/cm3 (heptahydrate); 1.46 g/cm3 (decahydrate);
Melting point	851 °C (1,564 °F; 1,124 K) (Anhydrous); 100 °C (212 °F; 373 K); decomposes (monohydrate); 33.5 °C (92.3 °F; 306.6 K); decomposes (heptahydrate); 34 °C (93 °F; 307 K); (decahydrate)
Solubility in water	Anhydrous, g/100 mL: 7 (0 °C); 16.4 (15 °C); 34.07 (27.8 °C); 48.69 (34.8 °C); 48.1 (41.9 °C); 45.62 (60 °C); 43.6 (100 °C);
Solubility	Soluble in aq. alkalis, glycerol; Slightly soluble in aq. alcohol; Insoluble in CS2, acetone, alkyl acetates, alcohol, benzonitrile, liquid ammonia
Solubility in glycerine	98.3 g/100 g (155 °C)
Solubility in ethanediol	3.46 g/100 g (20 °C)
Solubility in dimethylformamide	0.5 g/kg
Acidity (pKa)	10.33
Magnetic susceptibility (χ)	−4.1·10−5 cm3/mol
Refractive index (nD)	1.485 (anhydrous); 1.420 (monohydrate); 1.405 (decahydrate)
Viscosity	3.4 cP (887 °C)
Structure
Crystal structure	Monoclinic (γ-form, β-form, δ-form, anhydrous); Orthorhombic (monohydrate, heptahydrate)
Space group	C2/m, No. 12 (γ-form, anhydrous, 170 K); C2/m, No. 12 (β-form, anhydrous, 628 K); P21/n, No. 14 (δ-form, anhydrous, 110 K); Pca21, No. 29 (monohydrate); Pbca, No. 61 (heptahydrate)
Point group	2/m (γ-form, β-form, δ-form, anhydrous); mm2 (monohydrate); 2/m 2/m 2/m (heptahydrate)
Lattice constant	a = 8.920(7) Å, b = 5.245(5) Å, c = 6.050(5) Å (γ-form, anhydrous, 295 K) α = 90°, β = 101.35(8)°, γ = 90°
Coordination geometry	Octahedral (Na+, anhydrous)
Thermochemistry
Heat capacity (C)	112.3 J/mol·K
Std molar; entropy (S⦵298)	135 J/mol·K
Std enthalpy of; formation (ΔfH⦵298)	−1130.7 kJ/mol
Gibbs free energy (ΔfG⦵)	−1044.4 kJ/mol
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	Irritant
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H313+H333, H319
Precautionary statements	P305+P351+P338
NFPA 704 (fire diamond)	2 0 0
	Lethal dose or concentration (LD, LC):
LD50 (median dose)	4090 mg/kg (rat, oral)
Safety data sheet (SDS)	MSDS
Related compounds
Other anions	Sodium bicarbonate
Other cations	Lithium carbonate; Potassium carbonate; Rubidium carbonate; Cesium carbonate
Related compounds	Sodium sesquicarbonate; Sodium percarbonate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

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Sodium carbonate (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na₂CO₃ and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood (once used to produce potash), sodium carbonate became known as "soda ash".^[12] It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the chloralkali process.

Hydrates

Sodium carbonate is obtained as three hydrates and as the anhydrous salt:

sodium carbonate decahydrate (natron), Na₂CO₃·10H₂O, which readily effloresces to form the monohydrate.
sodium carbonate heptahydrate (not known in mineral form), Na₂CO₃·7H₂O.
sodium carbonate monohydrate (thermonatrite), Na₂CO₃·H₂O. Also known as crystal carbonate.
anhydrous sodium carbonate (natrite), also known as calcined soda, is formed by heating the hydrates. It is also formed when sodium hydrogencarbonate is heated (calcined) e.g. in the final step of the Solvay process.

The decahydrate is formed from water solutions crystallizing in the temperature range −2.1 to +32.0 °C, the heptahydrate in the narrow range 32.0 to 35.4 °C and above this temperature the monohydrate forms.^[13] In dry air the decahydrate and heptahydrate lose water to give the monohydrate. Other hydrates have been reported, e.g. with 2.5 units of water per sodium carbonate unit ("Penta hemihydrate").^[14]

Washing soda

Sodium carbonate decahydrate (Na₂CO₃·10H₂O), also known as washing soda, is the most common hydrate of sodium carbonate containing 10 molecules of water of crystallization. Soda ash is dissolved in water and crystallized to get washing soda.

${\ce {Na2CO3 + 10H2O -> Na2CO3.10H2O}}$

It is one of the few metal carbonates that is soluble in water.

Applications

Some common applications of sodium carbonate include:

As a cleansing agent for domestic purposes like washing clothes. Sodium carbonate is a component of many dry soap powders. It has detergent properties through the process of saponification, which converts fats and grease to water-soluble salts (specifically, soaps).^[15]
It is used for lowering the hardness of water^[16] (see § Water softening).
It is used in the manufacture of glass,^[17] soap,^[17] and paper (see § Glass manufacture).
It is used in the manufacture of sodium compounds like borax (sodium borate).

Glass manufacture

Sodium carbonate serves as a flux for silica (SiO₂, melting point 1,713 °C), lowering the melting point of the mixture to something achievable without special materials. This "soda glass" is mildly water-soluble, so some calcium carbonate is added to the melt mixture to make the glass insoluble. Bottle and window glass ("soda–lime glass" with transition temperature ~570 °C) is made by melting such mixtures of sodium carbonate, calcium carbonate, and silica sand (silicon dioxide (SiO₂)). When these materials are heated, the carbonates release carbon dioxide. In this way, sodium carbonate is a source of sodium oxide. Soda–lime glass has been the most common form of glass for centuries. It is also a key input for tableware glass manufacturing.^[15]

Water softening

Hard water usually contains calcium or magnesium ions. Sodium carbonate is used for removing these ions and replacing them with sodium ions.^[16]

Sodium carbonate is a water-soluble source of carbonate. The calcium and magnesium ions form insoluble solid precipitates upon treatment with carbonate ions:

Ca²⁺ + CO2−3 → CaCO₃ (s)

The water is softened because it no longer contains dissolved calcium ions and magnesium ions.^[16]

Food additive and cooking

Sodium carbonate has several uses in cuisine, largely because it is a stronger base than baking soda (sodium bicarbonate) but weaker than lye (which may refer to sodium hydroxide or, less commonly, potassium hydroxide). Alkalinity affects gluten production in kneaded doughs, and also improves browning by reducing the temperature at which the Maillard reaction occurs. To take advantage of the former effect, sodium carbonate is therefore one of the components of kansui (かん水), a solution of alkaline salts used to give Japanese ramen noodles their characteristic flavour and chewy texture; a similar solution is used in Chinese cuisine to make lamian, for similar reasons. Cantonese bakers similarly use sodium carbonate as a substitute for lye-water to give moon cakes their characteristic texture and improve browning. In German cuisine (and Central European cuisine more broadly), breads such as pretzels and lye rolls traditionally treated with lye to improve browning can be treated instead with sodium carbonate; sodium carbonate does not produce quite as strong a browning as lye, but is much safer and easier to work with.^[18]

Sodium carbonate is used in the production of sherbet powder. The cooling and fizzing sensation results from the endothermic reaction between sodium carbonate and a weak acid, commonly citric acid, releasing carbon dioxide gas, which occurs when the sherbet is moistened by saliva.

Sodium carbonate also finds use in the food industry as a food additive (European Food Safety Authority number E500) as an acidity regulator, anticaking agent, raising agent, and stabilizer. It is also used in the production of snus to stabilize the pH of the final product.

While it is less likely to cause chemical burns than lye, care must still be taken when working with sodium carbonate in the kitchen, as it is corrosive to aluminum cookware, utensils, and foil.^[tone]^[19]^{[unreliable source?]}

Other applications

Sodium carbonate is also used as a relatively strong base in various fields. As a common alkali, it is preferred in many chemical processes because it is cheaper than sodium hydroxide and far safer to handle. Its mildness especially recommends its use in domestic applications.

For example, it is used as a pH regulator to maintain stable alkaline conditions necessary for the action of the majority of photographic film developing agents. It is also a common additive in swimming pools and aquarium water to maintain a desired pH and carbonate hardness (KH). In dyeing with fiber-reactive dyes, sodium carbonate (often under a name such as soda ash fixative or soda ash activator) is used as mordant to ensure proper chemical bonding of the dye with cellulose (plant) fiber. It is also used in the froth flotation process to maintain a favourable pH as a float conditioner besides CaO and other mildly basic compounds.

Precursor to other compounds

Sodium bicarbonate (NaHCO₃) or baking soda, also a component in fire extinguishers, is often generated from sodium carbonate. Although NaHCO₃ is itself an intermediate product of the Solvay process, the heating needed to remove the ammonia that contaminates it decomposes some NaHCO₃, making it more economical to react finished Na₂CO₃ with CO₂:

Na₂CO₃ + CO₂ + H₂O → 2NaHCO₃

In a related reaction, sodium carbonate is used to make sodium bisulfite (NaHSO₃), which is used for the "sulfite" method of separating lignin from cellulose. This reaction is exploited for removing sulfur dioxide from flue gases in power stations:

Na₂CO₃ + SO₂ + H₂O → NaHCO₃ + NaHSO₃

This application has become more common, especially where stations have to meet stringent emission controls.

Sodium carbonate is used by the cotton industry to neutralize the sulfuric acid needed for acid delinting of fuzzy cottonseed.

It is also used to form carbonates of other metals by ion exchange, often with the other metals' sulphates.

Miscellaneous

Sodium carbonate is used by the brick industry as a wetting agent to reduce the amount of water needed to extrude the clay. In casting, it is referred to as "bonding agent" and is used to allow wet alginate to adhere to gelled alginate. Sodium carbonate is used in toothpastes, where it acts as a foaming agent and an abrasive, and to temporarily increase mouth pH.

Sodium carbonate is also used in the processing and tanning of animal hides.^[20]

Physical properties

The integral enthalpy of solution of sodium carbonate is −28.1 kJ/mol for a 10% w/w aqueous solution.^[21] The Mohs hardness of sodium carbonate monohydrate is 1.3.^[6]

Occurrence as natural mineral

Sodium carbonate is soluble in water, and can occur naturally in arid regions, especially in mineral deposits (evaporites) formed when seasonal lakes evaporate. Deposits of the mineral natron have been mined from dry lake bottoms in Egypt since ancient times, when natron was used in the preparation of mummies and in the early manufacture of glass.

The anhydrous mineral form of sodium carbonate is quite rare and called nitrite. Sodium carbonate also erupts from Ol Doinyo Lengai, Tanzania's unique volcano, and it is presumed to have erupted from other volcanoes in the past, but due to these minerals' instability at the Earth's surface, are likely to be eroded. All three mineralogical forms of sodium carbonate, as well as trona, trisodium hydrogendi carbonate dihydrate, are also known from ultra-alkaline pegmatitic rocks, that occur for example in the Kola Peninsula in Russia.

Extra terrestrially, known sodium carbonate is rare. Deposits have been identified as the source of bright spots on Ceres, interior material that has been brought to the surface.^[22] While there are carbonates on Mars, and these are expected to include sodium carbonate,^[23] deposits have yet to be confirmed, this absence is explained by some as being due to a global dominance of low pH in previously aqueous Martian soil.^[24]

Production

The initial large-scale chemical procedure was established in England in 1823 to manufacture soda ash.^[17]

Mining

Trona, also known as trisodium hydrogendicarbonate dihydrate (Na₃HCO₃CO₃·2H₂O), is mined in several areas of the US and provides nearly all the US consumption of sodium carbonate. Large natural deposits found in 1938, such as the one near Green River, Wyoming, have made mining more economical than industrial production in North America. There are important reserves of trona in Turkey;^[25] two million tons of soda ash have been extracted from the reserves near Ankara.

Barilla and kelp

Several "halophyte" (salt-tolerant) plant species and seaweed species can be processed to yield an impure form of sodium carbonate, and these sources predominated in Europe and elsewhere until the early 19th century. The land plants (typically glassworts or saltworts) or the seaweed (typically Fucus species) were harvested, dried, and burned. The ashes were then "lixivated" (washed with water) to form an alkali solution. This solution was boiled dry to create the final product, which was termed "soda ash"; this very old name derives from the Arabic word soda, in turn applied to Salsola soda, one of the many species of seashore plants harvested for production. "Barilla" is a commercial term applied to an impure form of potash obtained from coastal plants or kelp.^[26]

The sodium carbonate concentration in soda ash varied very widely, from 2–3 percent for the seaweed-derived form ("kelp"), to 30 percent for the best barilla produced from saltwort plants in Spain. Plant and seaweed sources for soda ash, and also for the related alkali "potash", became increasingly inadequate by the end of the 18th century, and the search for commercially viable routes to synthesizing soda ash from salt and other chemicals intensified.^[27]

Leblanc process

In 1792, the French chemist Nicolas Leblanc patented a process for producing sodium carbonate from salt, sulfuric acid, limestone, and coal. In the first step, sodium chloride is treated with sulfuric acid in the Mannheim process. This reaction produces sodium sulfate (salt cake) and hydrogen chloride:

2NaCl + H₂SO₄ → Na₂SO₄ + 2HCl

The salt cake and crushed limestone (calcium carbonate) was reduced by heating with coal.^[15] This conversion entails two parts. First is the carbothermic reaction whereby the coal, a source of carbon, reduces the sulfate to sulfide:

Na₂SO₄ + 2C → Na₂S + 2CO₂

The second stage is the reaction to produce sodium carbonate and calcium sulfide:

Na₂S + CaCO₃ → Na₂CO₃ + CaS

This mixture is called black ash. The soda ash is extracted from the black ash with water. Evaporation of this extract yields solid sodium carbonate. This extraction process was termed lixiviating.

The hydrochloric acid produced by the Leblanc process was a major source of air pollution, and the calcium sulfide byproduct also presented waste disposal issues. However, it remained the major production method for sodium carbonate until the late 1880s.^[27]^[28]

Solvay process

In 1861, the Belgian industrial chemist Ernest Solvay developed a method to make sodium carbonate by first reacting sodium chloride, ammonia, water, and carbon dioxide to generate sodium bicarbonate and ammonium chloride:^[15]

NaCl + NH₃ + CO₂ + H₂O → NaHCO₃ + NH₄Cl

The resulting sodium bicarbonate was then converted to sodium carbonate by heating it, releasing water and carbon dioxide:

2NaHCO₃ → Na₂CO₃ + H₂O + CO₂

Meanwhile, the ammonia was regenerated from the ammonium chloride byproduct by treating it with the lime (calcium oxide) left over from carbon dioxide generation:

2NH₄Cl + CaO → 2NH₃ + CaCl₂ + H₂O

The Solvay process recycles its ammonia. It consumes only brine and limestone, and calcium chloride is its only waste product. The process is substantially more economical than the Leblanc process, which generates two waste products, calcium sulfide and hydrogen chloride. The Solvay process quickly came to dominate sodium carbonate production worldwide. By 1900, 90% of sodium carbonate was produced by the Solvay process, and the last Leblanc process plant closed in the early 1920s.^[15]

The second step of the Solvay process, heating sodium bicarbonate, is used on a small scale by home cooks and in restaurants to make sodium carbonate for culinary purposes (including pretzels and alkali noodles). The method is appealing to such users because sodium bicarbonate is widely sold as baking soda, and the temperatures required (250 °F (121 °C) to 300 °F (149 °C)) to convert baking soda to sodium carbonate are readily achieved in conventional kitchen ovens.^[18]

Hou's process

This process was developed by Chinese chemist Hou Debang in the 1930s. The earlier steam reforming by-product carbon dioxide was pumped through a saturated solution of sodium chloride and ammonia to produce sodium bicarbonate by these reactions:

CH₄ + 2H₂O → CO₂ + 4H₂

3H₂ + N₂ → 2NH₃

NH₃ + CO₂ + H₂O → NH₄HCO₃

NH₄HCO₃ + NaCl → NH₄Cl + NaHCO₃

The sodium bicarbonate was collected as a precipitate due to its low solubility and then heated up to approximately 80 °C (176 °F) or 95 °C (203 °F) to yield pure sodium carbonate similar to last step of the Solvay process. More sodium chloride is added to the remaining solution of ammonium and sodium chlorides; also, more ammonia is pumped at 30-40 °C to this solution. The solution temperature is then lowered to below 10 °C. Solubility of ammonium chloride is higher than that of sodium chloride at 30 °C and lower at 10 °C. Due to this temperature-dependent solubility difference and the common-ion effect, ammonium chloride is precipitated in a sodium chloride solution.

The Chinese name of Hou's process, lianhe zhijian fa (联合制碱法), means "coupled manufacturing alkali method": Hou's process is coupled to the Haber process and offers better atom economy by eliminating the production of calcium chloride, since ammonia no longer needs to be regenerated. The by-product ammonium chloride can be sold as a fertilizer.

References

^ ^a ^b ^c ^d Harper, J. P. (1936). Antipov, Evgeny; Bismayer, Ulrich; Huppertz, Hubert; Petrícek, Václav; Pöttgen, Rainer; Schmahl, Wolfgang; Tiekink, E. R. T.; Zou, Xiaodong (eds.). "Crystal Structure of Sodium Carbonate Monohydrate, Na₂CO₃. H₂O". Zeitschrift für Kristallographie - Crystalline Materials. 95 (1): 266–273. doi:10.1524/zkri.1936.95.1.266. ISSN 2196-7105. Retrieved 2014-07-25.
^ ^a ^b ^c ^d ^e ^f ^g Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.
^ ^a ^b Seidell, Atherton; Linke, William F. (1919). Solubilities of Inorganic and Organic Compounds (2nd ed.). New York: D. Van Nostrand Company. p. 633.
^ ^a ^b Comey, Arthur Messinger; Hahn, Dorothy A. (February 1921). A Dictionary of Chemical Solubilities: Inorganic (2nd ed.). New York: The MacMillan Company. pp. 208–209.
^ ^a ^b ^c ^d Anatolievich, Kiper Ruslan. "sodium carbonate". chemister.ru. Retrieved 2014-07-25.
^ ^a ^b ^c Pradyot, Patnaik (2003). Handbook of Inorganic Chemicals. McGraw-Hill. p. 861. ISBN 978-0-07-049439-8.
^ ^a ^b ^c ^d Dusek, Michal; Chapuis, Gervais; Meyer, Mathias; Petricek, Vaclav (2003). "Sodium carbonate revisited" (PDF). Acta Crystallographica Section B. 59 (3): 337–352. Bibcode:2003AcCrB..59..337D. doi:10.1107/S0108768103009017. ISSN 0108-7681. PMID 12761404. Retrieved 2014-07-25.
^ ^a ^b ^c Betzel, C.; Saenger, W.; Loewus, D. (1982). "Sodium Carbonate Heptahydrate". Acta Crystallographica Section B. 38 (11): 2802–2804. Bibcode:1982AcCrB..38.2802B. doi:10.1107/S0567740882009996.
^ ^a ^b ^c Sigma-Aldrich Co., Sodium carbonate. Retrieved on 2014-05-06.
^ Chambers, Michael. "ChemIDplus - 497-19-8 - CDBYLPFSWZWCQE-UHFFFAOYSA-L - Sodium carbonate [NF] - Similar structures search, synonyms, formulas, resource links, and other chemical information".
^ "Material Safety Data Sheet – Sodium Carbonate, Anhydrous" (PDF). conservationsupportsystems.com. ConservationSupportSystems. Retrieved 2014-07-25.
^ "Soda Ash Statistics and Information". United States Geographical Survey. Retrieved 2024-03-03.
^ T.W.Richards and A.H. Fiske (1914). "On the transition temperatures of the transition temperatures of the hydrates of sodium carbonate as fix points in thermometry". Journal of the American Chemical Society. 36 (3): 485–490. doi:10.1021/ja02180a003.
^ A. Pabst. "On the hydrates of sodium carbonate" (PDF).
^ ^a ^b ^c ^d ^e Christian Thieme (2000). "Sodium Carbonates". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a24_299. ISBN 978-3527306732.
^ ^a ^b ^c "Water Hardness Reading" (PDF). Cornell Center for Materials Research.
^ ^a ^b ^c Himmelblau, David M.; Riggs, James B. (2022). Basic principles and calculations in chemical engineering. International series in the physical and chemical engineering sciences (Ninth ed.). Boston: Pearson. ISBN 978-0-13-732717-1.
^ ^a ^b McGee, Harold (24 September 2010). "For Old-Fashioned Flavor, Bake the Baking Soda". The New York Times. Retrieved 25 April 2019.
^ "Sodium Carbonate". corrosionpedia. Janalta Interactive. Retrieved 9 November 2020.
^ "Home Tanning Hides and Furs" (PDF). Retrieved 16 April 2024.
^ "Tatachemicals.com/north-america/product/images/fig_2_1.jpg".
^ De Sanctis, M. C.; et al. (29 June 2016). "Bright carbonate deposits as evidence of aqueous alteration on (1) Ceres". Nature. 536 (7614): 54–57. Bibcode:2016Natur.536...54D. doi:10.1038/nature18290. PMID 27362221. S2CID 4465999.
^ Jeffrey S. Kargel (23 July 2004). Mars - A Warmer, Wetter Planet. Springer Science & Business Media. pp. 399–. ISBN 978-1-85233-568-7.
^ Grotzinger, J. and R. Milliken (eds.) 2012. Sedimentary Geology of Mars. SEPM
^ "Ciner Weighs Sale of Stake in $5 Billion Soda Ash Unit". Bloomberg.com. 2021-08-09. Retrieved 2023-12-04.
^ Hooper, Robert (1802). Lexicon Medicum (1848 ed.). London: Longman. pp. 1198–9. OCLC 27671024.
^ ^a ^b Clow, Archibald and Clow, Nan L. (June 1952). Chemical Revolution. Ayer. pp. 65–90. ISBN 0-8369-1909-2.
^ Kiefer, David M. (January 2002). "It was all about alkali". Today's Chemist at Work. 11 (1): 45–6.

External links

American Natural Soda Ash Company
International Chemical Safety Card 1135
FMC Wyoming Corporation
Use of sodium carbonate in dyeing
Sodium carbonate manufacturing by synthetic processes

[cod-1] Harper, J. P. (1936). Antipov, Evgeny; Bismayer, Ulrich; Huppertz, Hubert; Petrícek, Václav; Pöttgen, Rainer; Schmahl, Wolfgang; Tiekink, E. R. T.; Zou, Xiaodong (eds.). "Crystal Structure of Sodium Carbonate Monohydrate, Na₂CO₃. H₂O". Zeitschrift für Kristallographie - Crystalline Materials. 95 (1): 266–273. doi:10.1524/zkri.1936.95.1.266. ISSN 2196-7105. Retrieved 2014-07-25.

[crc-2] ^ ^a ^b ^c ^d ^e ^f ^g Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.

[sioc-3] Seidell, Atherton; Linke, William F. (1919). Solubilities of Inorganic and Organic Compounds (2nd ed.). New York: D. Van Nostrand Company. p. 633.

[doc00-4] Comey, Arthur Messinger; Hahn, Dorothy A. (February 1921). A Dictionary of Chemical Solubilities: Inorganic (2nd ed.). New York: The MacMillan Company. pp. 208–209.

[chemister-5] Anatolievich, Kiper Ruslan. "sodium carbonate". chemister.ru. Retrieved 2014-07-25.

[pphoic-6] Pradyot, Patnaik (2003). Handbook of Inorganic Chemicals. McGraw-Hill. p. 861. ISBN 978-0-07-049439-8.

[scr-7] Dusek, Michal; Chapuis, Gervais; Meyer, Mathias; Petricek, Vaclav (2003). "Sodium carbonate revisited" (PDF). Acta Crystallographica Section B. 59 (3): 337–352. Bibcode:2003AcCrB..59..337D. doi:10.1107/S0108768103009017. ISSN 0108-7681. PMID 12761404. Retrieved 2014-07-25.

[7h2o-8] Betzel, C.; Saenger, W.; Loewus, D. (1982). "Sodium Carbonate Heptahydrate". Acta Crystallographica Section B. 38 (11): 2802–2804. Bibcode:1982AcCrB..38.2802B. doi:10.1107/S0567740882009996.

[sigma-9] Sigma-Aldrich Co., Sodium carbonate. Retrieved on 2014-05-06.

[10] Chambers, Michael. "ChemIDplus - 497-19-8 - CDBYLPFSWZWCQE-UHFFFAOYSA-L - Sodium carbonate [NF] - Similar structures search, synonyms, formulas, resource links, and other chemical information".

[css-11] "Material Safety Data Sheet – Sodium Carbonate, Anhydrous" (PDF). conservationsupportsystems.com. ConservationSupportSystems. Retrieved 2014-07-25.

[12] "Soda Ash Statistics and Information". United States Geographical Survey. Retrieved 2024-03-03.

[13] T.W.Richards and A.H. Fiske (1914). "On the transition temperatures of the transition temperatures of the hydrates of sodium carbonate as fix points in thermometry". Journal of the American Chemical Society. 36 (3): 485–490. doi:10.1021/ja02180a003.

[14] A. Pabst. "On the hydrates of sodium carbonate" (PDF).

[Ullmann-15] Christian Thieme (2000). "Sodium Carbonates". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a24_299. ISBN 978-3527306732.

[Cornell-16] "Water Hardness Reading" (PDF). Cornell Center for Materials Research.

[Himmel-17] Himmelblau, David M.; Riggs, James B. (2022). Basic principles and calculations in chemical engineering. International series in the physical and chemical engineering sciences (Ninth ed.). Boston: Pearson. ISBN 978-0-13-732717-1.

[McGee-18] McGee, Harold (24 September 2010). "For Old-Fashioned Flavor, Bake the Baking Soda". The New York Times. Retrieved 25 April 2019.

[19] "Sodium Carbonate". corrosionpedia. Janalta Interactive. Retrieved 9 November 2020.

[20] "Home Tanning Hides and Furs" (PDF). Retrieved 16 April 2024.

[21] "Tatachemicals.com/north-america/product/images/fig_2_1.jpg".

[22] De Sanctis, M. C.; et al. (29 June 2016). "Bright carbonate deposits as evidence of aqueous alteration on (1) Ceres". Nature. 536 (7614): 54–57. Bibcode:2016Natur.536...54D. doi:10.1038/nature18290. PMID 27362221. S2CID 4465999.

[Kargel2004-23] Jeffrey S. Kargel (23 July 2004). Mars - A Warmer, Wetter Planet. Springer Science & Business Media. pp. 399–. ISBN 978-1-85233-568-7.

[24] Grotzinger, J. and R. Milliken (eds.) 2012. Sedimentary Geology of Mars. SEPM

[25] "Ciner Weighs Sale of Stake in $5 Billion Soda Ash Unit". Bloomberg.com. 2021-08-09. Retrieved 2023-12-04.

[26] Hooper, Robert (1802). Lexicon Medicum (1848 ed.). London: Longman. pp. 1198–9. OCLC 27671024.

[Clow52-27] Clow, Archibald and Clow, Nan L. (June 1952). Chemical Revolution. Ayer. pp. 65–90. ISBN 0-8369-1909-2.

[Kiefer-28] Kiefer, David M. (January 2002). "It was all about alkali". Today's Chemist at Work. 11 (1): 45–6.

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@@ Line 105: / Line 105: @@
 |GHSPictograms = {{GHS07}}<ref name="sigma">{{Sigma-Aldrich|id=451614|name=Sodium carbonate|accessdate=2014-05-06}}</ref>
 |GHSSignalWord = Warning
-|HPhrases = {{H-phrases|319}}<ref name="sigma" />
+|HPhrases = {{H-phrases|319|313+333}}<ref name="sigma" />
 |PPhrases = {{P-phrases|305+351+338}}<ref name="sigma" />
 |NFPA-H = 2
@@ Line 120: / Line 120: @@
 }}
-'''Sodium carbonate''' (also known as '''washing soda''', '''soda ash''' and '''soda crystals''') is the [[inorganic compound]] with the formula {{chem2|Na2CO3|}} and its various [[hydrate]]s. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood (once used to produce [[potash]]), sodium carbonate became known as "soda ash".<ref>{{cite web|url=http://minerals.usgs.gov/minerals/pubs/commodity/soda_ash/soda-ash-industry.pdf|title=minerals.usgs.gov/minerals|publisher=United States Geographical Survey}}</ref>{{fcn|date=January 2023}} It is produced in large quantities from [[sodium chloride]] and [[limestone]] by the [[Solvay process]], as well as by carbonating sodium hydroxide which is made using the [[Chlor-alkali]] process.
+'''Sodium carbonate''' (also known as '''washing soda''', '''soda ash''' and '''soda crystals''') is the [[inorganic compound]] with the formula {{chem2|Na2CO3|}} and its various [[hydrate]]s. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood (once used to produce [[potash]]), sodium carbonate became known as "soda ash".<ref>{{cite web|url=https://www.usgs.gov/centers/national-minerals-information-center/soda-ash-statistics-and-information|title=Soda Ash Statistics and Information|publisher=United States Geographical Survey|access-date=2024-03-03}}</ref> It is produced in large quantities from [[sodium chloride]] and [[limestone]] by the [[Solvay process]], as well as by carbonating sodium hydroxide which is made using the [[chloralkali process]].
 ==Hydrates==
@@ Line 127: / Line 127: @@
 * sodium carbonate heptahydrate (not known in mineral form), Na<sub>2</sub>CO<sub>3</sub>·7H<sub>2</sub>O.
 * sodium carbonate monohydrate ([[thermonatrite]]), Na<sub>2</sub>CO<sub>3</sub>·H<sub>2</sub>O. Also known as '''crystal carbonate'''.
-* anhydrous sodium carbonate ([[natrite]]), also known as calcined soda, is formed by heating the hydrates. It is also formed when sodium hydrogencarbonate is heated (calcined) e.g. in the final step of the [[Solvay process]].
+* anhydrous sodium carbonate (natrite), also known as calcined soda, is formed by heating the hydrates. It is also formed when sodium hydrogencarbonate is heated (calcined) e.g. in the final step of the [[Solvay process]].
 The decahydrate is formed from water solutions crystallizing in the temperature range −2.1 to +32.0&nbsp;°C, the heptahydrate in the narrow range 32.0 to 35.4&nbsp;°C and above this temperature the monohydrate forms.<ref>{{cite journal|title=On the transition temperatures of the transition temperatures of the hydrates of sodium carbonate as fix points in thermometry |journal=Journal of the American Chemical Society |volume=36 |issue=3 |pages=485–490 |author= T.W.Richards and A.H. Fiske|doi=10.1021/ja02180a003 |year=1914 |url=https://zenodo.org/record/1428987}}</ref> In dry air the decahydrate and heptahydrate lose water to give the monohydrate. Other hydrates have been reported, e.g. with 2.5 units of water per sodium carbonate unit ("Penta hemihydrate").<ref>{{cite web |url=http://www.minsocam.org/ammin/am15/am15_69.pdf |author=A. Pabst |title=On the hydrates of sodium carbonate }}</ref>
@@ Line 140: / Line 140: @@
 Some common applications of sodium carbonate include:
 * As a cleansing agent for domestic purposes like washing clothes. Sodium carbonate is a component of many dry soap powders. It has [[detergent]] properties through the process of [[saponification]], which converts fats and grease to water-soluble [[Salt (chemistry)|salt]]s (specifically, soaps).<ref name=Ullmann/>
-* It is used for lowering the [[hardness of water]]<ref name=":0" /> (see {{section link|#Water softening}}).
+* It is used for lowering the [[hardness of water]]<ref name="Cornell" /> (see {{section link|#Water softening}}).
-* It is used in the manufacture of [[glass]], [[soap]], and [[paper]] (see {{section link|#Glass manufacture}}).
+* It is used in the manufacture of [[glass]],<ref name="Himmel">{{Cite book |last=Himmelblau |first=David M. |title=Basic principles and calculations in chemical engineering |last2=Riggs |first2=James B. |date=2022 |publisher=Pearson |isbn=978-0-13-732717-1 |edition=Ninth |series=International series in the physical and chemical engineering sciences |location=Boston}}</ref> [[soap]],<ref name="Himmel" /> and [[paper]] (see {{section link|#Glass manufacture}}).
-* It is used in the manufacture of sodium compounds like [[borax]].
+* It is used in the manufacture of sodium compounds like [[borax]] (sodium borate).
 ===Glass manufacture===
-Sodium carbonate serves as a [[Flux (metallurgy)|flux]] for [[silica]] (SiO<sub>2</sub>, melting point 1,713 °C), lowering the melting point of the mixture to something achievable without special materials. This "soda glass" is mildly water-soluble, so some [[calcium carbonate]] is added to the melt mixture to make the glass insoluble. Bottle and window glass ("[[soda–lime glass]]" with transition temperature ~570 °C) is made by melting such mixtures of sodium carbonate, calcium carbonate, and silica sand ([[silicon dioxide]] (SiO<sub>2</sub>)). When these materials are heated, the carbonates release carbon dioxide. In this way, sodium carbonate is a source of sodium oxide. Soda–lime glass has been the most common form of glass for centuries. It is also a key input for tableware glass manufacturing.<ref name=Ullmann/>
+Sodium carbonate serves as a [[Flux (metallurgy)|flux]] for [[silica]] (SiO<sub>2</sub>, melting point 1,713&nbsp;°C), lowering the melting point of the mixture to something achievable without special materials. This "soda glass" is mildly water-soluble, so some [[calcium carbonate]] is added to the melt mixture to make the glass insoluble. Bottle and window glass ("[[soda–lime glass]]" with transition temperature ~570&nbsp;°C) is made by melting such mixtures of sodium carbonate, calcium carbonate, and silica sand ([[silicon dioxide]] (SiO<sub>2</sub>)). When these materials are heated, the carbonates release carbon dioxide. In this way, sodium carbonate is a source of sodium oxide. Soda–lime glass has been the most common form of glass for centuries. It is also a key input for tableware glass manufacturing.<ref name=Ullmann/>
 ===Water softening===
+{{See also|Hard water|Water softening}}
-Hard water usually contains calcium or magnesium ions. Sodium carbonate is used for removing these ions and replacing them with sodium ions.<ref name=":0">{{cite web |url=https://www.ccmr.cornell.edu/wp-content/uploads/sites/2/2015/11/Water-Hardness-Reading.pdf |title=Water Hardness Reading |website=Cornell Center for Materials Research}}</ref>
+Hard water usually contains calcium or magnesium ions. Sodium carbonate is used for removing these ions and replacing them with sodium ions.<ref name="Cornell">{{cite web |url=https://www.ccmr.cornell.edu/wp-content/uploads/sites/2/2015/11/Water-Hardness-Reading.pdf |title=Water Hardness Reading |website=Cornell Center for Materials Research}}</ref>
 Sodium carbonate is a water-soluble source of carbonate. The calcium and magnesium ions form insoluble solid precipitates upon treatment with [[carbonate]] ions:
 {{block indent|{{chem2|Ca(2+)  +  CO3(2-) -> CaCO3 (s)}}}}
-The water is softened because it no longer contains dissolved calcium ions and magnesium ions.<ref name=":0" />
+The water is softened because it no longer contains dissolved calcium ions and magnesium ions.<ref name="Cornell" />
 ===Food additive and cooking===
-{{See also|Hard water}}
 Sodium carbonate has several uses in cuisine, largely because it is a stronger base than baking soda ([[sodium bicarbonate]]) but weaker than [[lye]] (which may refer to [[sodium hydroxide]] or, less commonly, [[potassium hydroxide]]). Alkalinity affects [[gluten]] production in kneaded doughs, and also improves browning by reducing the temperature at which the [[Maillard reaction]] occurs. To take advantage of the former effect, sodium carbonate is therefore one of the components of {{nihongo3||かん水|kansui}}, a solution of alkaline salts used to give [[Japanese cuisine|Japanese]] [[ramen]] noodles their characteristic flavour and chewy texture; a similar solution is used in [[Chinese cuisine]] to make [[lamian]], for similar reasons. [[Cantonese cuisine|Cantonese]] bakers similarly use sodium carbonate as a substitute for lye-water to give [[moon cake]]s their characteristic texture and improve browning. In [[German cuisine]] (and Central European cuisine more broadly), breads such as [[pretzel]]s and [[lye roll]]s traditionally treated with lye to improve browning can be treated instead with sodium carbonate; sodium carbonate does not produce quite as strong a browning as lye, but is much safer and easier to work with.<ref name="McGee">{{cite news |last1=McGee |first1=Harold |author-link=Harold McGee |title=For Old-Fashioned Flavor, Bake the Baking Soda |url=https://www.nytimes.com/2010/09/15/dining/15curious.html |access-date=25 April 2019 |work=[[The New York Times]] |date=24 September 2010}}</ref>
 Sodium carbonate is used in the production of [[sherbet (powder)|sherbet]] powder. The cooling and fizzing sensation results from the endothermic reaction between sodium carbonate and a weak acid, commonly [[citric acid]], releasing carbon dioxide gas, which occurs when the sherbet is moistened by saliva.
-Sodium carbonate also finds use in [[food industry]] as a [[food additive]] (E500) as an acidity regulator, [[anticaking agent]], [[leavening agent|raising agent]], and stabilizer. It is also used in the production of {{lang|no|[[snus]]}} to stabilize the pH of the final product.
+Sodium carbonate also finds use in the [[food industry]] as a [[food additive]] ([[E number|European Food Safety Authority number]] E500) as an acidity regulator, [[anticaking agent]], [[leavening agent|raising agent]], and stabilizer. It is also used in the production of {{lang|no|[[snus]]}} to stabilize the pH of the final product.
-While it is less likely to cause chemical burns than lye, care must still be taken when working with sodium carbonate in the kitchen, as it is corrosive to aluminum cookware, utensils, and foil.<ref>{{cite web |title=Sodium Carbonate |url=https://www.corrosionpedia.com/definition/2782/sodium-carbonate |website=corrosionpedia |publisher=Janalta Interactive |access-date=9 November 2020}}</ref>
+While it is less likely to cause chemical burns than lye, care must still be taken when working with sodium carbonate in the kitchen, as it is corrosive to aluminum cookware, utensils, and foil.{{tone inline|date=November 2024}}<ref>{{cite web |title=Sodium Carbonate |url=https://www.corrosionpedia.com/definition/2782/sodium-carbonate |website=corrosionpedia |publisher=Janalta Interactive |access-date=9 November 2020}}</ref>{{unreliable source|date=November 2024}}
 ===Other applications===
 Sodium carbonate is also used as a relatively strong [[Base (chemistry)|base]] in various fields. As a common alkali, it is preferred in many chemical processes because it is cheaper than [[sodium hydroxide]] and far safer to handle. Its mildness especially recommends its use in domestic applications.
-For example, it is used as a [[pH]] regulator to maintain stable alkaline conditions necessary for the action of the majority of photographic [[Developer (photography)|film developing]] agents. It is also a common additive in [[swimming pool]]s and [[aquarium]] water to maintain a desired pH and carbonate hardness (KH). In [[dyeing]] with fiber-reactive dyes, sodium carbonate (often under a name such as soda ash fixative or soda ash activator) is used to ensure proper chemical bonding of the dye with cellulose (plant) fibers, typically before dyeing (for tie dyes), mixed with the dye (for dye painting), or after dyeing (for immersion dyeing). It is also used in the [[froth flotation process]] to maintain a favourable [[pH]] as a float conditioner besides [[CaO]] and other mildly basic compounds.
+For example, it is used as a [[pH]] regulator to maintain stable alkaline conditions necessary for the action of the majority of photographic [[Developer (photography)|film developing]] agents. It is also a common additive in [[swimming pool]]s and [[aquarium]] water to maintain a desired pH and carbonate hardness (KH). In [[dyeing]] with fiber-reactive dyes, sodium carbonate (often under a name such as soda ash fixative or soda ash activator) is used as [[mordant]] to ensure proper chemical bonding of the dye with cellulose (plant) fiber. It is also used in the [[froth flotation process]] to maintain a favourable [[pH]] as a float conditioner besides [[CaO]] and other mildly basic compounds.
 ===Precursor to other compounds===
@@ Line 184: / Line 184: @@
 Sodium carbonate is used by the brick industry as a wetting agent to reduce the amount of water needed to extrude the clay. In casting, it is referred to as "bonding agent" and is used to allow wet [[alginate]] to adhere to gelled alginate. Sodium carbonate is used in toothpastes, where it acts as a foaming agent and an abrasive, and to temporarily increase mouth pH.
-Sodium carbonate is also used in the processing and tanning of animal hides.{{citation needed|date=February 2020}}
+Sodium carbonate is also used in the processing and tanning of animal hides.<ref>{{cite web|title=Home Tanning Hides and Furs|url= https://shareok.org/bitstream/handle/11244/331379/oksa_ANSI-3998_2007-06.pdf?sequence=1&isAllowed=y|access-date=16 April 2024}}</ref>
 ==Physical properties==
@@ Line 194: / Line 194: @@
 Sodium carbonate is soluble in water, and can occur naturally in arid regions, especially in mineral deposits (''evaporites'') formed when seasonal lakes evaporate. Deposits of the mineral [[natron]] have been mined from dry lake bottoms in Egypt since ancient times, when natron was used in the preparation of [[mummy|mummies]] and in the early manufacture of glass.
-The anhydrous mineral form of sodium carbonate is quite rare and called nitrite. Sodium carbonate also erupts from [[Ol Doinyo Lengai]], Tanzania's unique volcano, and it is presumed to have erupted from other volcanoes in the past, but due to these minerals' instability at the earth's surface, are likely to be eroded. All three mineralogical forms of sodium carbonate, as well as [[trona]], trisodium hydrogendi carbonate dihydrate, are also known from ultra-alkaline [[pegmatite|pegmatitic rocks]], that occur for example in the [[Kola Peninsula]] in Russia.
+The anhydrous mineral form of sodium carbonate is quite rare and called nitrite. Sodium carbonate also erupts from [[Ol Doinyo Lengai]], Tanzania's unique volcano, and it is presumed to have erupted from other volcanoes in the past, but due to these minerals' instability at the Earth's surface, are likely to be eroded. All three mineralogical forms of sodium carbonate, as well as [[trona]], trisodium hydrogendi carbonate dihydrate, are also known from ultra-alkaline [[pegmatite|pegmatitic rocks]], that occur for example in the [[Kola Peninsula]] in Russia.
 Extra terrestrially, known sodium carbonate is rare. Deposits have been identified as the source of [[bright spots on Ceres]], interior material that has been brought to the surface.<ref>{{cite journal |title=Bright carbonate deposits as evidence of aqueous alteration on (1) Ceres |journal=Nature |date= 29 June 2016 |last=De Sanctis |first=M. C. |display-authors=etal |volume=536 |issue= 7614|doi=10.1038/nature18290 |pages=54–57 |pmid=27362221|bibcode=2016Natur.536...54D |s2cid=4465999 }}</ref> While there are [[carbonates on Mars]], and these are expected to include sodium carbonate,<ref name="Kargel2004">{{cite book|author=Jeffrey S. Kargel|title=Mars - A Warmer, Wetter Planet|url=https://books.google.com/books?id=0QY0U6qJKFUC&pg=PA399|date=23 July 2004|publisher=Springer Science & Business Media|isbn=978-1-85233-568-7|pages=399–}}</ref> deposits have yet to be confirmed, this absence is explained by some as being due to a global dominance of low [[pH]] in previously aqueous [[Martian soil]].<ref>Grotzinger, J. and R. Milliken (eds.) 2012. Sedimentary Geology of Mars. SEPM</ref>
 ==Production==
+The initial large-scale chemical procedure was established in England in 1823 to manufacture soda ash.<ref name="Himmel" />
 ===Mining===
 [[Trona]], also known as [[sodium sesquicarbonate|trisodium hydrogendicarbonate dihydrate]] (Na<sub>3</sub>HCO<sub>3</sub>CO<sub>3</sub>·2H<sub>2</sub>O), is mined in several areas of the US and provides nearly all the US consumption of sodium carbonate. Large natural deposits found in 1938, such as the one near [[Green River, Wyoming]], have made mining more economical than industrial production in North America. There are important reserves of trona in Turkey;<ref>{{cite news |date=2021-08-09 |title=Ciner Weighs Sale of Stake in $5 Billion Soda Ash Unit |language=en |work=Bloomberg.com |url=https://www.bloomberg.com/news/articles/2021-08-09/ciner-said-to-weigh-sale-of-stake-in-5-billion-soda-ash-unit |access-date=2023-12-04}}</ref> two million tons of soda ash have been extracted from the reserves near Ankara.