Fluoroanion: Difference between revisions

Fluoroanion
Identifiers
ChEBI	CHEBI:51527;
Related compounds
Other anions	Chloroanion; Bromoanion; Iodoanion; Oxyanion; Thioanion; Selenoanion
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

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In chemistry, a fluoroanion or fluorometallate anion is a polyatomic anion that contains one or more fluorine atoms. The ions and salts form from them are also known as complex fluorides. They can occur in salts, or in solution, but seldom as pure acids. Fluoroanions often contain elements in higher oxidation states. They mostly can be considered as fluorometallates, which are a subclass of halometallates.^[1]^[2]

Anions that contain both fluorine and oxygen can be called "oxofluoroanions" (or rarely "fluorooxoanions").

The following is a list of fluoroanions in atomic number order.

trifluoroberyllate
tetrafluoroberyllate
tetrafluoroborate
magnesium tetrafluoride
trifluoroaluminate AlOF2−3
tetrafluoroaluminate
pentafluoroaluminate
hexafluoroaluminate
heptafluoroaluminate
hexafluorosilicate
hexafluorophosphate
Sulfur trifluoride anion
pentafluorosulfate aka pentafluorosulfite or Sulfur pentafluoride ion
sulfur pentafluoride anion
tetrafluorochlorate
hexafluorotitanate
hexafluorovanadate(III)
hexafluorovanadate(IV)
hexafluorovanadate(V)
trifluoromanganate MnF−3
hexafluoromanganate(III)
hexafluoromanganate(IV)
heptafluoromanganate IV
Tetrafluoroferrate 1− and 2−
hexafluoroferrate 4− and 3−
tetrafluorocobaltate II
Hexafluorocobaltate III and IV^[3]
Heptafluorocobaltate IV^[3]
Tetrafluoronickelate
Hexafluoronickelate II, III and IV
hexafluorocuprate
tetrafluorozincate
Hexafluorogallate
hexafluorogermanate
hexafluoroarsenate
tetrafluorobromate
hexafluorobromate
pentafluorozirconate ZrF−5
hexafluorozirconate
octafluorozirconate ZrF4−8
hexafluoroniobate
heptafluoroniobate
octafluoromolybdate MoF2−8
tetrafluoropalladate
hexafluororhodate
hexafluororuthenate(IV)
hexafluororuthenate(V)
hexafluoroindate
hexafluorostannate
fluoroantimonate
hexafluoroiodate 1−
octafluoroxenate
tetrafluorolanthanate LaF−4
pentafluorocerate IV
Hexafluorocerate IV^[4]
Heptafluorocerate IV^[4]
octafluorocerate IV^[4]
pentafluorohafnate
hexafluorohafnate
heptafluorotantalate TaF−7
octafluorotantalate
heptafluorotungstate
octafluorotungstate WF2−8
octafluororhenate
hexafluoroplatinate
tetrafluoroaurate AuF−4
hexafluoroaurate AuF−6
hexafluorothallate(III)
tetrafluorobismuthate BiF−4
hexafluorobismuthate
hexafluorothorate
hexafluorouranate(IV)
hexafluorouranate(V)
octafluorouranate(IV)
octafluorouranate(V)

References

^ "fluorometallate anion (CHEBI:51527)". www.ebi.ac.uk.
^ "fluorometallate anion - Ontology Browser - Rat Genome Database". rgd.mcw.edu.
^ ^a ^b Klemm, W.; Brandt, W.; Hoppe, R. (March 1961). "Über Fluorocobaltate(III) und -(IV) und Fluoroniccolate(III)". Zeitschrift für anorganische und allgemeine Chemie. 308 (1–6): 179–189. doi:10.1002/zaac.19613080119.
^ ^a ^b ^c Macintyre, Jane E. (1992). Dictionary of Inorganic Compounds. CRC Press. p. 2819. ISBN 9780412301209.

[1] "fluorometallate anion (CHEBI:51527)". www.ebi.ac.uk.

[2] "fluorometallate anion - Ontology Browser - Rat Genome Database". rgd.mcw.edu.

[Klemm-3] Klemm, W.; Brandt, W.; Hoppe, R. (March 1961). "Über Fluorocobaltate(III) und -(IV) und Fluoroniccolate(III)". Zeitschrift für anorganische und allgemeine Chemie. 308 (1–6): 179–189. doi:10.1002/zaac.19613080119.

[doic-4] Macintyre, Jane E. (1992). Dictionary of Inorganic Compounds. CRC Press. p. 2819. ISBN 9780412301209.

[1]

[2]

[3]

[4]

@@ Line 1: / Line 1: @@
+{{Short description|Negatively-charged ion containing a fluorine atom}}
-A '''fluoroanion''' is an [[anion]] contain an element, and fluorine atoms. They are also known as '''complex fluorides'''. They can occur in salts, or in solution, but not as pure acids. They often contain elements in higher oxidation states. They mostly can be considered as fluorometalates which are a subclass of halometalates.
+{{Chembox
+|ImageFile = F-.svg
+|ImageSize = 75px
+|Section1={{Chembox Identifiers
+| ChEBI = 51527
+ }}
+|Section8={{Chembox Related
+| OtherAnions = [[Chloroanion]]; [[Bromoanion]]; [[Iodoanion]]; [[Oxyanion]]; [[Thioanion]]; [[Selenoanion]]
+ }}
+}}
+In [[chemistry]], a '''fluoroanion''' or '''fluorometallate anion''' is a [[polyatomic anion]] that contains one or more [[fluorine]] atoms. The ions and salts form from them are also known as '''complex fluorides'''. They can occur in [[salts]], or in solution, but seldom as pure [[acid]]s. Fluoroanions often contain elements in higher [[oxidation state]]s. They mostly can be considered as fluorometallates, which are a subclass of halometallates.<ref>{{cite web |title=fluorometallate anion (CHEBI:51527) |url=https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI%3A51527 |website=www.ebi.ac.uk}}</ref><ref>{{cite web |title=fluorometallate anion - Ontology Browser - Rat Genome Database |url=https://rgd.mcw.edu/rgdweb/ontology/view.html?acc_id=CHEBI:51527 |website=rgd.mcw.edu}}</ref>
+Anions that contain both fluorine and oxygen can be called "oxofluoroanions" (or rarely "fluorooxoanions").
 The following is a list of fluoroanions in [[atomic number]] order.
 *[[trifluoroberyllate]]
 *[[tetrafluoroberyllate]]
 *[[tetrafluoroborate]]
+*[[magnesium tetrafluoride]]
-*[[pentafluorocyclopentadienide]]
+*[[trifluoroaluminate]] {{chem2|AlOF3(2−)}}
+*[[tetrafluoroaluminate]]
+*[[pentafluoroaluminate]]
+*[[hexafluoroaluminate]]
+*[[heptafluoroaluminate]]
 *[[hexafluorosilicate]]
 *[[hexafluorophosphate]]
 *[[Sulfur trifluoride anion]]
+*[[pentafluorosulfate]] aka pentafluorosulfite or Sulfur pentafluoride ion
 *[[sulfur pentafluoride anion]]
 *[[tetrafluorochlorate]]
+*[[hexafluorotitanate]]
-*[[trifluoromanganate]] MnF<sub>3</sub><sup>−</sup>
+*[[hexafluorovanadate(III)]]
+*[[hexafluorovanadate(IV)]]
+*[[hexafluorovanadate(V)]]
+*[[trifluoromanganate]] {{chem2|MnF3(-)}}
 *[[hexafluoromanganate(III)]]
 *[[hexafluoromanganate(IV)]]
+*[[heptafluoromanganate]] IV
-*[[Tetrafluoroferrate]] 1- and 2-
+*[[Tetrafluoroferrate]] 1− and 2−
 *[[hexafluoroferrate]] 4− and 3−
+*[[tetrafluorocobaltate]] II
+*[[Hexafluorocobaltate]] III and IV<ref name="Klemm">{{cite journal|last1=Klemm|first1=W.|last2=Brandt|first2=W.|last3=Hoppe|first3=R.|title=Über Fluorocobaltate(III) und -(IV) und Fluoroniccolate(III)|journal=Zeitschrift für anorganische und allgemeine Chemie|date=March 1961|volume=308|issue=1–6|pages=179–189|doi=10.1002/zaac.19613080119}}</ref>
+*[[Heptafluorocobaltate]] IV<ref name="Klemm"/>
+*[[Tetrafluoronickelate]]
+*[[Hexafluoronickelate]] II, III and IV
 *[[hexafluorocuprate]]
 *[[tetrafluorozincate]]
@@ Line 23: / Line 55: @@
 *[[tetrafluorobromate]]
 *[[hexafluorobromate]]
-*[[pentafluorozirconate]] ZrF<sub>5</sub><sup>−</sup>
+*[[pentafluorozirconate]] {{chem2|ZrF5(-)}}
-*[[Hexafluorozirconate]]
+*[[hexafluorozirconate]]
-*[[octafluorozirconate]] (ZrF<sub>8</sub><sup>4−</sup>)
+*[[octafluorozirconate]] {{chem2|ZrF8(4-)}}
 *[[hexafluoroniobate]]
 *[[heptafluoroniobate]]
-*[[octafluoromolybdate]] (MoF<sub>8</sub><sup>2−</sup>)
+*[[octafluoromolybdate]] {{chem2|MoF8(2-)}}
 *[[tetrafluoropalladate]]
 *[[hexafluororhodate]]
@@ Line 38: / Line 70: @@
 *[[hexafluoroiodate]] 1−
 *[[octafluoroxenate]]
+*[[tetrafluorolanthanate]] {{chem2|LaF4(-)}}
+*[[pentafluorocerate]] IV
+*[[Hexafluorocerate]] IV<ref name=doic/>
+*[[Heptafluorocerate]] IV<ref name=doic/>
+*[[octafluorocerate]] IV<ref name=doic>{{cite book|last1=Macintyre|first1=Jane E.|title=Dictionary of Inorganic Compounds|date=1992|publisher=CRC Press|isbn=9780412301209|page=2819|url=https://books.google.com/books?id=9eJvoNCSCRMC&pg=PA2819|language=en}}</ref>
 *[[pentafluorohafnate]]
 *[[hexafluorohafnate]]
-*[[heptafluorotantalate]]  TaF<sub>7</sub><sup>−</sup>
+*[[heptafluorotantalate]] {{chem2|TaF7(-)}}
 *[[octafluorotantalate]]
 *[[heptafluorotungstate]]
-*[[octafluorotungstate]] (WF<sub>8</sub><sup>2−</sup>),
+*[[octafluorotungstate]] {{chem2|WF8(2-)}}
 *[[octafluororhenate]]
 *[[hexafluoroplatinate]]
+*[[tetrafluoroaurate]] {{chem2|AuF4(-)}}
-*[[tetrafluorobismuthate]] BiF<sub>4</sub><sup>−</sup>
+*[[hexafluoroaurate]] {{chem2|AuF6(-)}}
+*[[hexafluorothallate(III)]]
+*[[tetrafluorobismuthate]] {{chem2|BiF4(-)}}
+*[[hexafluorobismuthate]]
+*[[hexafluorothorate]]
+*[[hexafluorouranate(IV)]]
+*[[hexafluorouranate(V)]]
+*[[octafluorouranate(IV)]]
+*[[octafluorouranate(V)]]
+==References==
+{{Reflist}}
 [[Category:Fluorine compounds]]