Thiogermanate: Difference between revisions
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{{Short description|Class of chemical compounds}} |
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'''Sulfidogermanates or thiogermanates''' are chemical compounds containing anions with [[sulfur]] atoms bound to [[germanium]]. They are in the class of [[Chalcogenidotetrelate|chalcogenidotetrelates]]. Related compounds include [[Thiosilicate|thiosilicates]], [[Thiostannate|thiostannates]], [[Selenidogermanate|selenidogermanates]], [[Telluridogermanate|telluridogermanates]] and [[Selenidostannate|selenidostannates]]. |
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'''Sulfidogermanates or thiogermanates''' are chemical compounds containing anions with [[sulfur]] atoms bound to [[germanium]]. They are in the class of [[chalcogenidotetrelate]]s. Related compounds include [[thiosilicate]]s, [[thiostannate]]s, [[selenidogermanate]]s, [[telluridogermanate]]s and [[selenidostannate]]s. |
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Coordination of sulfur around germanium is tetrahedral meaning there are four |
Coordination of sulfur around germanium is tetrahedral meaning there are four sulfur atoms symmetrically arranged. This basic structure can form ortho salts with GeS<sub>4</sub><sup>4−</sup>, oligomers, or polymeric structures.<ref name=wang>{{cite journal |last1=Wang |first1=Kai-Yao |last2=Feng |first2=Mei-Ling |last3=Huang |first3=Xiao-Ying |last4=Li |first4=Jing |title=Organically directed heterometallic chalcogenidometalates containing group 12(II)/13(III)/14(IV) metal ions and antimony(III) |journal=Coordination Chemistry Reviews |date=September 2016 |volume=322 |pages=41–68 |doi=10.1016/j.ccr.2016.04.021}}</ref> Similar structures are also formed with heavy group 13 and group 14 elements due to their relatively stronger bonds with sulfur. Light elements from these groups have lower affinity for sulfur, so there are fewer compounds like this for boron, aluminium, carbon, and silicon.<ref name=wang/> Other heavy group 12 and 15 elements also form chalcogenidometallates which may have other kinds of coordination. Selenium forms similar compounds to sulfur in this family.<ref name=wang/> |
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Where sulfur is deficient, an anion is not formed, and instead cation-like covalent compounds can exist with halogens, such as Ge<sub>4</sub>S<sub>6</sub>Br<sub>4</sub>,<ref>{{cite journal |last1=Pohl |first1=Siegfried |title=Ge<sub>4</sub>S<sub>6</sub>Br<sub>4</sub>—The First Sulfide Halide of Germanium |journal=Angewandte Chemie International Edition in English |date=March 1976 |volume=15 |issue=3 |pages=162 |doi=10.1002/anie.197601621}}</ref> or Ge<sub>4</sub>S<sub>6</sub>I<sub>4</sub>.<ref>{{cite journal |last1=Pohl |first1=Siegfried |last2=Seyer |first2=Ulrich |last3=Krebs |first3=Bernt |title=Sulfidhalogenide des Germaniums: Darstellung und Strukturen von Ge 4 S 6 Br 4 und Ge 4 S 6 I 4 / Thiohalides of Germanium: Preparation and Structures of Ge 4 SeBr 4 and Ge 4 S 6 I 4 |journal=Zeitschrift für Naturforschung B |date=1 November 1981 |volume=36 |issue=11 |pages=1432–1443 |doi=10.1515/znb-1981-1116|s2cid=93779728 }}</ref> |
Where sulfur is deficient, an anion is not formed, and instead cation-like covalent compounds can exist with halogens, such as Ge<sub>4</sub>S<sub>6</sub>Br<sub>4</sub>,<ref>{{cite journal |last1=Pohl |first1=Siegfried |title=Ge<sub>4</sub>S<sub>6</sub>Br<sub>4</sub>—The First Sulfide Halide of Germanium |journal=Angewandte Chemie International Edition in English |date=March 1976 |volume=15 |issue=3 |pages=162 |doi=10.1002/anie.197601621}}</ref> or Ge<sub>4</sub>S<sub>6</sub>I<sub>4</sub>.<ref>{{cite journal |last1=Pohl |first1=Siegfried |last2=Seyer |first2=Ulrich |last3=Krebs |first3=Bernt |title=Sulfidhalogenide des Germaniums: Darstellung und Strukturen von Ge 4 S 6 Br 4 und Ge 4 S 6 I 4 / Thiohalides of Germanium: Preparation and Structures of Ge 4 SeBr 4 and Ge 4 S 6 I 4 |journal=Zeitschrift für Naturforschung B |date=1 November 1981 |volume=36 |issue=11 |pages=1432–1443 |doi=10.1515/znb-1981-1116|s2cid=93779728 |doi-access=free }}</ref> |
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==Production== |
==Production== |
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The solvochemical method of production involves dissolving germanium oxide, sulfur and other salts in a heated solvent under pressure. The solvents can include simple alcohols, amines or ''N'',''N''-dimethyl formamide. The containers can be glass tubes, quartz tubes, or teflon lined stainless steel.<ref name=wang/> |
The solvochemical method of production involves dissolving germanium oxide, sulfur and other salts in a heated solvent under pressure. The solvents can include simple alcohols, amines or ''N'',''N''-dimethyl formamide. The containers can be glass tubes, quartz tubes, or teflon lined stainless steel.<ref name=wang/> |
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== List == |
== List == |
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{| class="wikitable" |
{| class="wikitable" |
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|<ref name=":3" /> |
|<ref name=":3" /> |
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|Li |
|Li<sub>2</sub>GeS<sub>3</sub> |
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|hexagonal |
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|monoclinic |
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|'' |
|''P''6<sub>1</sub> |
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|a= |
|''a'' = 6.79364 ''c'' = 17.9072 |
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|1139.1 |
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|2.637 |
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|<ref>{{Cite journal| |
|<ref>{{Cite journal |last=Roh |first=Jihun |last2=Do |first2=Namgyu |last3=Manjón-Sanz |first3=Alicia |last4=Hong |first4=Seung-Tae |date=2023-10-02 |title=Li 2 GeS 3 : Lithium Ionic Conductor with an Unprecedented Structural Type |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c01431 |journal=Inorganic Chemistry |language=en |volume=62 |issue=39 |pages=15856–15863 |doi=10.1021/acs.inorgchem.3c01431 |issn=0020-1669}}</ref> |
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|[CH<sub>3</sub>NH<sub>3</sub>]<sub>4</sub>Ge<sub>2</sub>S<sub>6</sub> |
|[CH<sub>3</sub>NH<sub>3</sub>]<sub>4</sub>Ge<sub>2</sub>S<sub>6</sub> |
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|<ref name=":8" |
|<ref name=":8" /><ref>{{Cite journal|last1=Eußner|first1=Jens P.|last2=Dehnen|first2=Stefanie|date=September 2012|title=Formation of Thiosemicarbazone-Functionalized Complexes with (GeS 2 ) 2 and (SnS 2 ) 2 Units|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.201200292|journal=Zeitschrift für anorganische und allgemeine Chemie|language=de|volume=638|issue=11|pages=1827–1832|doi=10.1002/zaac.201200292|doi-access=free}}</ref> |
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|(trenH<small><sub>2</sub></small>)<small><sub>2</sub></small>[Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
|(trenH<small><sub>2</sub></small>)<small><sub>2</sub></small>[Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
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|SHG 0.7 ×AGS |
|SHG 0.7 ×AGS |
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|<ref name=":20">{{Cite journal | |
|<ref name=":20">{{Cite journal |last1=Wang |first1=Peng |last2=Abudoureheman |first2=Maierhaba |last3=Zhang |first3=Kewang |last4=Zheng |first4=Juanjuan |last5=Chen |first5=Zhaohui |last6=Wu |first6=Qi |date=2022-10-03 |title=Ag 4 SnGe 2 S 7 : A Noncentrosymmetric Chalcogenide in I 4 –II–IV 2 –VI 7 System with Non-Diamond-Like Structure Featuring 1D ∞ [SnGe 2 S 8 ] 6– Infinite Chain |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c01828 |journal=Inorganic Chemistry |language=en |volume=61 |issue=39 |pages=15303–15309 |doi=10.1021/acs.inorgchem.2c01828 |pmid=36126330 |s2cid=252405280 |issn=0020-1669}}</ref> |
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|Na(AlS<sub>2</sub>)(GeS<sub>2</sub>)<sub>4</sub> |
|Na(AlS<sub>2</sub>)(GeS<sub>2</sub>)<sub>4</sub> |
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|<ref name=":5">{{Cite journal|last1=Alahmari|first1=Fatimah|last2=Davaasuren|first2=Bambar|last3=Emwas|first3=Abdul-Hamid|last4=Rothenberger|first4=Alexander|date=2018-04-02|title=Thioaluminogermanate M (AlS 2 )(GeS 2 ) 4 ( M = Na, Ag, Cu): Synthesis, Crystal Structures, Characterization, Ion-Exchange and Solid-State 27 Al and 23 Na NMR Spectroscopy|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02980|journal=Inorganic Chemistry|language=en|volume=57|issue=7|pages=3713–3719|doi=10.1021/acs.inorgchem.7b02980|pmid=29537828|hdl=10754/627415|issn=0020-1669}}</ref> |
|<ref name=":5">{{Cite journal|last1=Alahmari|first1=Fatimah|last2=Davaasuren|first2=Bambar|last3=Emwas|first3=Abdul-Hamid|last4=Rothenberger|first4=Alexander|date=2018-04-02|title=Thioaluminogermanate M (AlS 2 )(GeS 2 ) 4 ( M = Na, Ag, Cu): Synthesis, Crystal Structures, Characterization, Ion-Exchange and Solid-State 27 Al and 23 Na NMR Spectroscopy|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02980|journal=Inorganic Chemistry|language=en|volume=57|issue=7|pages=3713–3719|doi=10.1021/acs.inorgchem.7b02980|pmid=29537828|hdl=10754/627415|issn=0020-1669|hdl-access=free}}</ref> |
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|Li<sub>10</sub>GeP<sub>2</sub>S<sub>12</sub> |
|Li<sub>10</sub>GeP<sub>2</sub>S<sub>12</sub> |
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|lithium ion conductor |
|lithium ion conductor |
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|<ref>{{Cite journal|last1=Xu|first1=Miao|last2=Song|first2=Subin|last3=Daikuhara|first3=Shugo|last4=Matsui|first4=Naoki|last5=Hori|first5=Satoshi|last6=Suzuki|first6=Kota|last7=Hirayama|first7=Masaaki|last8=Shiotani|first8=Shinya|last9=Nakanishi|first9=Shinji|last10=Yonemura|first10=Masao|last11=Saito|first11=Takashi|date=2022-01-10|title=Li 10 GeP 2 S 12 -Type Structured Solid Solution Phases in the Li 9+δ P 3+δ′ S 12– k O k System: Controlling Crystallinity by Synthesis to Improve the Air Stability|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c01748|journal=Inorganic Chemistry|language=en|volume=61|issue=1|pages=52–61|doi=10.1021/acs.inorgchem.1c01748|pmid=34914367|s2cid=245270702|issn=0020-1669}}</ref> |
|<ref>{{Cite journal|last1=Xu|first1=Miao|last2=Song|first2=Subin|last3=Daikuhara|first3=Shugo|last4=Matsui|first4=Naoki|last5=Hori|first5=Satoshi|last6=Suzuki|first6=Kota|last7=Hirayama|first7=Masaaki|last8=Shiotani|first8=Shinya|last9=Nakanishi|first9=Shinji|last10=Yonemura|first10=Masao|last11=Saito|first11=Takashi|date=2022-01-10|title=Li 10 GeP 2 S 12 -Type Structured Solid Solution Phases in the Li 9+δ P 3+δ′ S 12– k O k System: Controlling Crystallinity by Synthesis to Improve the Air Stability|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c01748|journal=Inorganic Chemistry|language=en|volume=61|issue=1|pages=52–61|doi=10.1021/acs.inorgchem.1c01748|pmid=34914367|s2cid=245270702|issn=0020-1669|doi-access=free}}</ref> |
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|K<sub>6</sub>Ge<sub>2</sub>S<sub>7</sub> |
|K<sub>6</sub>Ge<sub>2</sub>S<sub>7</sub> |
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|dap = 1,2-diaminopropane |
|dap = 1,2-diaminopropane |
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|hexagonal |
|hexagonal |
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|''R''{{overbar|2}}c |
|''R''{{overbar|2}}c ? |
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|a=38.284 c=11.170 Z=18 |
|a=38.284 c=11.170 Z=18 |
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|14178 |
|14178 |
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|1.619 |
|1.619 |
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|purple; hexagonal nanotubes |
|purple; hexagonal nanotubes |
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|<ref name=":10" /> |
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|<ref name=":10">{{Cite journal|last1=Qian|first1=Li-Wen|last2=Zhao|first2=Xiao-Wei|last3=Su|first3=Hu-Chao|last4=Bian|first4=Guo-Qing|last5=Zhu|first5=Qin-Yu|last6=Dai|first6=Jie|date=2016|title=Supramolecular hexagonal nano tubes assembled by vanadium diamine complexes with thiogermanates|url=http://xlink.rsc.org/?DOI=C5RA27088J|journal=RSC Advances|language=en|volume=6|issue=20|pages=16268–16273|doi=10.1039/C5RA27088J|bibcode=2016RSCAd...616268Q|issn=2046-2069}}</ref> |
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|Li<sub>4</sub>MnGe<sub>2</sub>S<sub>7</sub> |
|Li<sub>4</sub>MnGe<sub>2</sub>S<sub>7</sub> |
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|monoclinic |
|monoclinic |
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|''Cc'' |
|''Cc'' |
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|a=16.833 b=6.709 c=10.121 β=94.76° |
|a=16.833 b=6.709 c=10.121 β=94.76° Z=4 |
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|1139.1 |
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|<ref name=":20" /><ref>{{Cite journal |last1=Kaib |first1=Thomas |last2=Haddadpour |first2=Sima |last3=Andersen |first3=Hanne Flåten |last4=Mayrhofer |first4=Leonhard |last5=Järvi |first5=Tommi T. |last6=Moseler |first6=Michael |last7=Möller |first7=Kai-Christian |last8=Dehnen |first8=Stefanie |date=2013-12-10 |title=Quaternary Diamond-Like Chalcogenidometalate Networks as Efficient Anode Material in Lithium-Ion Batteries |url=https://onlinelibrary.wiley.com/doi/10.1002/adfm.201301025 |journal=Advanced Functional Materials |language=en |volume=23 |issue=46 |pages=5693–5699 |doi=10.1002/adfm.201301025 |s2cid=93236286}}</ref> |
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|<ref name=":20" /> |
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|{[Mn(2,2′-bipy)<sub>2</sub>(H<sub>2</sub>O)]<sub>2</sub>Ge<sub>4</sub>S<sub>10</sub>}'''·'''3H<sub>2</sub>O |
|{[Mn(2,2′-bipy)<sub>2</sub>(H<sub>2</sub>O)]<sub>2</sub>Ge<sub>4</sub>S<sub>10</sub>}'''·'''3H<sub>2</sub>O |
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|<ref name=":7">{{Cite journal|last1=Luo|first1=Hai-Ying|last2=Zhou|first2=Jian|last3=Cao|first3=Shumei|date=2019|title=A series of new hybrid chalcogenogermanates: the rare examples of chalcogenogermanates combined with trivalent vanadium complexes|url=http://xlink.rsc.org/?DOI=C9DT02077B|journal=Dalton Transactions|language=en|volume=48|issue=29|pages=10907–10914|doi=10.1039/C9DT02077B|pmid=31282904|s2cid=195828996|issn=1477-9226}}</ref> |
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|H<small><sub>2</sub></small>dienMnGeS<small><sub>4</sub></small> |
|H<small><sub>2</sub></small>dienMnGeS<small><sub>4</sub></small> |
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|<ref name=":7" /> |
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|<ref name=":7">{{Cite journal|last1=Luo|first1=Hai-Ying|last2=Zhou|first2=Jian|last3=Cao|first3=Shumei|date=2019|title=A series of new hybrid chalcogenogermanates: the rare examples of chalcogenogermanates combined with trivalent vanadium complexes|url=http://xlink.rsc.org/?DOI=C9DT02077B|journal=Dalton Transactions|language=en|volume=48|issue=29|pages=10907–10914|doi=10.1039/C9DT02077B|pmid=31282904|s2cid=195828996|issn=1477-9226}}</ref> |
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|[(dien)<sub>2</sub>Mn]Ge<sub>2</sub>S<sub>4</sub> |
|[(dien)<sub>2</sub>Mn]Ge<sub>2</sub>S<sub>4</sub> |
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|1.643 |
|1.643 |
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|<ref name=":4" /> |
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|<ref name=":4">{{Cite journal|last1=Danker|first1=Felix|last2=Näther|first2=Christian|last3=Pielnhofer|first3=Florian|last4=Bensch|first4=Wolfgang|date=2017-10-10|title=Room‐Temperature Synthesis of Three Compounds Featuring the [Ge 4 S 10 ] 4– Anion from a Water‐Soluble Thiogermanate Precursor|url=https://onlinelibrary.wiley.com/doi/10.1002/ejic.201700795|journal=European Journal of Inorganic Chemistry|language=en|volume=2017|issue=37|pages=4317–4323|doi=10.1002/ejic.201700795|issn=1434-1948}}</ref> |
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|{Fe(tepa)}<sub>2</sub>(μ-Ge<sub>2</sub>Se<sub>6</sub>) |
|{Fe(tepa)}<sub>2</sub>(μ-Ge<sub>2</sub>Se<sub>6</sub>) |
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|<ref name=":6">{{Cite journal|last1=Chen|first1=Jiang-Fang|last2=Jin|first2=Qin-Yan|last3=Pan|first3=Ying-Li|last4=Zhang|first4=Yong|last5=Jia|first5=Ding-Xian|date=January 2010|title=Solvothermal Syntheses and Characterization of New Transition Metal Chalcogenidogermanates [{Co(tepa)} 2 (μ-Ge 2 S 6 )] and [{M(tepa)} 2 (μ-Ge 2 Se 6 )] (M = Mn, Fe) (tepa = Tetraethylenepentamine)|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.200900141|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=636|issue=1|pages=230–235|doi=10.1002/zaac.200900141}}</ref> |
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|K<sub>2</sub>FeGe<sub>3</sub>S<sub>8</sub> |
|K<sub>2</sub>FeGe<sub>3</sub>S<sub>8</sub> |
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|<ref name="bing">{{cite journal|last1=Ji|first1=Bingheng|last2=Pandey|first2=Krishna|last3=Harmer|first3=Colin P.|last4=Wang|first4=Fei|last5=Wu|first5=Kui|last6=Hu|first6=Jin|last7=Wang|first7=Jian|date=29 June 2021|title=Centrosymmetric or Noncentrosymmetric? Transition Metals Talking in K 2 TGe 3 S 8 (T = Co, Fe)|journal=Inorganic Chemistry|volume=60|issue=14|pages=10603–10613|doi=10.1021/acs.inorgchem.1c01149|pmid=34185995|s2cid=235685892}}</ref> |
|<ref name="bing">{{cite journal|last1=Ji|first1=Bingheng|last2=Pandey|first2=Krishna|last3=Harmer|first3=Colin P.|last4=Wang|first4=Fei|last5=Wu|first5=Kui|last6=Hu|first6=Jin|last7=Wang|first7=Jian|date=29 June 2021|title=Centrosymmetric or Noncentrosymmetric? Transition Metals Talking in K 2 TGe 3 S 8 (T = Co, Fe)|journal=Inorganic Chemistry|volume=60|issue=14|pages=10603–10613|doi=10.1021/acs.inorgchem.1c01149|pmid=34185995|osti=1810574 |s2cid=235685892}}</ref> |
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|K<sub>2</sub>CoGe<sub>3</sub>S<sub>8</sub> |
|K<sub>2</sub>CoGe<sub>3</sub>S<sub>8</sub> |
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|<ref name=":6">{{Cite journal|last1=Chen|first1=Jiang-Fang|last2=Jin|first2=Qin-Yan|last3=Pan|first3=Ying-Li|last4=Zhang|first4=Yong|last5=Jia|first5=Ding-Xian|date=January 2010|title=Solvothermal Syntheses and Characterization of New Transition Metal Chalcogenidogermanates [{Co(tepa)} 2 (μ-Ge 2 S 6 )] and [{M(tepa)} 2 (μ-Ge 2 Se 6 )] (M = Mn, Fe) (tepa = Tetraethylenepentamine)|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.200900141|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=636|issue=1|pages=230–235|doi=10.1002/zaac.200900141}}</ref> |
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|[dienH<small><sub>2</sub></small>][Co(dien)<small><sub>2</sub></small>][Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
|[dienH<small><sub>2</sub></small>][Co(dien)<small><sub>2</sub></small>][Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
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|1.715 |
|1.715 |
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|yellow |
|yellow |
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|<ref name=":11">{{Cite journal|last1=Lichte|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2014-05-02|title=Polymorphism and tautomerism in [dienH 2 ][Co(dien) 2 ][Ge 2 S 6 ] leading to different hydrogen bonded networks|url=http://xlink.rsc.org/?DOI=C4CE00312H|journal=CrystEngComm|language=en|volume=16|issue=25|pages=5551–5559|doi=10.1039/C4CE00312H|issn=1466-8033}}</ref> |
|<ref name=":11">{{Cite journal|last1=Lichte|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2014-05-02|title=Polymorphism and tautomerism in [dienH 2 ][Co(dien) 2 ][Ge 2 S 6 ] leading to different hydrogen bonded networks|url=http://xlink.rsc.org/?DOI=C4CE00312H|journal=CrystEngComm|language=en|volume=16|issue=25|pages=5551–5559|doi=10.1039/C4CE00312H|s2cid=94547016 |issn=1466-8033|doi-access=free}}</ref> |
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|[dienH<small><sub>2</sub></small>][Co(dien)<small><sub>2</sub></small>][Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
|[dienH<small><sub>2</sub></small>][Co(dien)<small><sub>2</sub></small>][Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
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|1.730 |
|1.730 |
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|yellow |
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|<ref name=":11" /> |
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|<ref name=":11">{{Cite journal|last1=Lichte|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2014-05-02|title=Polymorphism and tautomerism in [dienH 2 ][Co(dien) 2 ][Ge 2 S 6 ] leading to different hydrogen bonded networks|url=http://xlink.rsc.org/?DOI=C4CE00312H|journal=CrystEngComm|language=en|volume=16|issue=25|pages=5551–5559|doi=10.1039/C4CE00312H|issn=1466-8033}}</ref> |
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|[dienH<small><sub>2</sub></small>][Co(dien)<small><sub>2</sub></small>][Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
|[dienH<small><sub>2</sub></small>][Co(dien)<small><sub>2</sub></small>][Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
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| Line 407: | Line 409: | ||
|1.692 |
|1.692 |
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|yellow |
|yellow |
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|<ref name=":11" /> |
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|<ref name=":11">{{Cite journal|last1=Lichte|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2014-05-02|title=Polymorphism and tautomerism in [dienH 2 ][Co(dien) 2 ][Ge 2 S 6 ] leading to different hydrogen bonded networks|url=http://xlink.rsc.org/?DOI=C4CE00312H|journal=CrystEngComm|language=en|volume=16|issue=25|pages=5551–5559|doi=10.1039/C4CE00312H|issn=1466-8033}}</ref> |
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|[dienH<small><sub>2</sub></small>][Co(dien)<small><sub>2</sub></small>][Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
|[dienH<small><sub>2</sub></small>][Co(dien)<small><sub>2</sub></small>][Ge<small><sub>2</sub></small>S<small><sub>6</sub></small>] |
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| Line 417: | Line 419: | ||
|1.655 |
|1.655 |
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|yellow |
|yellow |
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|<ref name=":11" /> |
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|<ref name=":11">{{Cite journal|last1=Lichte|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2014-05-02|title=Polymorphism and tautomerism in [dienH 2 ][Co(dien) 2 ][Ge 2 S 6 ] leading to different hydrogen bonded networks|url=http://xlink.rsc.org/?DOI=C4CE00312H|journal=CrystEngComm|language=en|volume=16|issue=25|pages=5551–5559|doi=10.1039/C4CE00312H|issn=1466-8033}}</ref> |
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|[Ni(cyclam)]<sub>3</sub>[Ni(cyclam)(H<sub>2</sub>O)<sub>2</sub>][Ge<sub>4</sub>S<sub>10</sub>]<sub>2</sub>'''·'''21H<sub>2</sub>O |
|[Ni(cyclam)]<sub>3</sub>[Ni(cyclam)(H<sub>2</sub>O)<sub>2</sub>][Ge<sub>4</sub>S<sub>10</sub>]<sub>2</sub>'''·'''21H<sub>2</sub>O |
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| Line 527: | Line 529: | ||
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|<ref name=":5" /> |
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|<ref name=":5">{{Cite journal|last1=Alahmari|first1=Fatimah|last2=Davaasuren|first2=Bambar|last3=Emwas|first3=Abdul-Hamid|last4=Rothenberger|first4=Alexander|date=2018-04-02|title=Thioaluminogermanate M (AlS 2 )(GeS 2 ) 4 ( M = Na, Ag, Cu): Synthesis, Crystal Structures, Characterization, Ion-Exchange and Solid-State 27 Al and 23 Na NMR Spectroscopy|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02980|journal=Inorganic Chemistry|language=en|volume=57|issue=7|pages=3713–3719|doi=10.1021/acs.inorgchem.7b02980|pmid=29537828|hdl=10754/627415|issn=0020-1669}}</ref> |
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|- |
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|Cu<sub>4</sub>MnGe<sub>2</sub>S<sub>7</sub> |
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| |
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|monoclinic |
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|''Cc'' |
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|a=16.7443 b=6.47893 c=9.8060 β=93.188° |
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|<ref name=":20" /> |
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|Cu<sub>4</sub>FeGe<sub>2</sub>S<sub>7</sub> |
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| |
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|monoclinic |
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|''C''2 |
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|a=11.7405 b=5.3589 c=8.3420 β=98.661° |
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|<ref name=":20" /> |
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|Cu<sub>4</sub>CoGe<sub>2</sub>S<sub>7</sub> |
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| |
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|monoclinic |
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|''C''2 |
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|a=11.7280 b=5.3399 c=8.3313 β=98.668° |
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|<ref name=":20" /> |
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|Cu<sub>4</sub>NiGe<sub>2</sub>S<sub>7</sub> |
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| |
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|monoclinic |
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|''C''2 |
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|a=11.703 b=5.333 c=8.311 β=98.37° |
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|<ref name=":20" /> |
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|Sr<sub>2</sub>CoGe<sub>2</sub>OS<sub>6</sub> |
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| |
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|tetrahedral |
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|''P''{{overbar|4}}2<sub>1</sub>''m'' |
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|''a''=9.4056 ''c''=6.1741 Z=2 |
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|546.19 |
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|3.574 |
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|dark green; oxysulfide |
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|<ref>{{Cite journal |last1=Zhang |first1=Nan |last2=Xu |first2=Qian-Ting |last3=Shi |first3=Zhi-Hui |last4=Yang |first4=Mei |last5=Guo |first5=Sheng-Ping |date=2022-10-31 |title=Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr 2 CoGe 2 OS 6 |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c03283 |journal=Inorganic Chemistry |language=en |volume=61 |issue=43 |pages=17002–17006 |doi=10.1021/acs.inorgchem.2c03283 |pmid=36265201 |s2cid=253044751 |issn=0020-1669}}</ref> |
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|- |
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|Y<sub>3</sub>LiGeS<sub>7</sub> |
|Y<sub>3</sub>LiGeS<sub>7</sub> |
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| Line 548: | Line 600: | ||
|colourless |
|colourless |
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|<ref name=":15" /> |
|<ref name=":15" /> |
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|KYGeS<sub>4</sub> |
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|<ref name=":21">{{Cite journal |last=Liu |first=Yang |last2=Li |first2=Xiangming |last3=Wu |first3=Shuchang |last4=Ma |first4=Mengjie |last5=Jiang |first5=Xiaoming |last6=Wu |first6=Yuandong |last7=Mei |first7=Dajiang |date=2024-06-03 |title=A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS 4 : Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c00842 |journal=Inorganic Chemistry |language=en |doi=10.1021/acs.inorgchem.4c00842 |issn=0020-1669}}</ref> |
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|[{R<sup>N</sup>Ge(μ-S)<sub>3</sub>}<sub>4</sub>Pd<sub>6</sub>]·MeOH |
|[{R<sup>N</sup>Ge(μ-S)<sub>3</sub>}<sub>4</sub>Pd<sub>6</sub>]·MeOH |
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| Line 557: | Line 619: | ||
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|<ref name=":8" /> |
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|<ref name=":8">{{Cite journal|last1=Halvagar|first1=Mohammad Reza|last2=Hassanzadeh Fard|first2=Zohreh|last3=Xiong|first3=Lin|last4=Dehnen|first4=Stefanie|date=2009-08-03|title=Facile Access to the Hydrazone Functionalized PdGeS Cluster [{R N Ge(μ-S) 3 } 4 Pd 6 ] from the Thiogermanate Anion [{R N Ge} 2 (μ-S) 2 S 2 ] 2−|url=https://pubs.acs.org/doi/10.1021/ic900853e|journal=Inorganic Chemistry|language=en|volume=48|issue=15|pages=7373–7377|doi=10.1021/ic900853e|pmid=19586024|issn=0020-1669}}</ref> |
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|- |
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|Ag<sub>10</sub>Ge<sub>3</sub>S<sub>11</sub> |
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| |
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|monoclinic |
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|''Cc'' |
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|''a'' = 2.6244 ''b'' = 0.65020 ''c'' = 2.5083 ''β'' = 109.910° |
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| |
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|<ref>{{Cite journal |last1=Fedorchuk |first1=A.O. |last2=Lakshminarayana |first2=G. |last3=Tokaychuk |first3=Y.O. |last4=Parasyuk |first4=O.V. |date=November 2013 |title=The crystal structure of novel silver sulphogermanate Ag10Ge3S11 |url=https://linkinghub.elsevier.com/retrieve/pii/S0925838813010220 |journal=Journal of Alloys and Compounds |language=en |volume=576 |pages=134–139 |doi=10.1016/j.jallcom.2013.04.110}}</ref> |
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|- |
|- |
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|[(CH<sub>3</sub>CH<sub>2</sub>)<sub>4</sub>N]<sub>3</sub>AgGe<sub>4</sub>S<sub>10</sub> |
|[(CH<sub>3</sub>CH<sub>2</sub>)<sub>4</sub>N]<sub>3</sub>AgGe<sub>4</sub>S<sub>10</sub> |
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| Line 577: | Line 649: | ||
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|<ref name=":5" /> |
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|<ref name=":5">{{Cite journal|last1=Alahmari|first1=Fatimah|last2=Davaasuren|first2=Bambar|last3=Emwas|first3=Abdul-Hamid|last4=Rothenberger|first4=Alexander|date=2018-04-02|title=Thioaluminogermanate M (AlS 2 )(GeS 2 ) 4 ( M = Na, Ag, Cu): Synthesis, Crystal Structures, Characterization, Ion-Exchange and Solid-State 27 Al and 23 Na NMR Spectroscopy|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02980|journal=Inorganic Chemistry|language=en|volume=57|issue=7|pages=3713–3719|doi=10.1021/acs.inorgchem.7b02980|pmid=29537828|hdl=10754/627415|issn=0020-1669}}</ref> |
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|- |
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|Li<sub>4</sub>CdGe<sub>2</sub>S<sub>7</sub> |
|Li<sub>4</sub>CdGe<sub>2</sub>S<sub>7</sub> |
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| Line 597: | Line 669: | ||
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|<ref name=":20" /> |
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|<ref>{{Cite journal |last=Wang |first=Peng |last2=Abudoureheman |first2=Maierhaba |last3=Zhang |first3=Kewang |last4=Zheng |first4=Juanjuan |last5=Chen |first5=Zhaohui |last6=Wu |first6=Qi |date=2022-10-03 |title=Ag 4 SnGe 2 S 7 : A Noncentrosymmetric Chalcogenide in I 4 –II–IV 2 –VI 7 System with Non-Diamond-Like Structure Featuring 1D ∞ [SnGe 2 S 8 ] 6– Infinite Chain |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c01828 |journal=Inorganic Chemistry |language=en |volume=61 |issue=39 |pages=15303–15309 |doi=10.1021/acs.inorgchem.2c01828 |issn=0020-1669}}</ref> |
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|Y<sub>3</sub>Cd<sub>0.5</sub>GeS<sub>7</sub> |
|Y<sub>3</sub>Cd<sub>0.5</sub>GeS<sub>7</sub> |
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| Line 647: | Line 719: | ||
| |
| |
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|microporous, can exchange dimethyl ammonium for alkalis |
|microporous, can exchange dimethyl ammonium for alkalis |
||
|<ref name=":11" |
|<ref name=":11" /><ref>{{Cite journal|last1=Feng|first1=Mei-Ling|last2=Kong|first2=De-Nian|last3=Xie|first3=Zai-Lai|last4=Huang|first4=Xiao-Ying|date=2008-10-27|title=Three-Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion-Exchange Properties|url=https://onlinelibrary.wiley.com/doi/10.1002/anie.200803406|journal=Angewandte Chemie International Edition|language=en|volume=47|issue=45|pages=8623–8626|doi=10.1002/anie.200803406|pmid=18846520}}</ref> |
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|- |
|- |
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|[dabcoH]<sub>2</sub>[Ge<sub>2</sub>Sb<sub>3</sub>S<sub>10</sub>] |
|[dabcoH]<sub>2</sub>[Ge<sub>2</sub>Sb<sub>3</sub>S<sub>10</sub>] |
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| Line 657: | Line 729: | ||
| |
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|<ref name=":11" /> |
|||
|<ref name=":11">{{Cite journal|last1=Lichte|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2014-05-02|title=Polymorphism and tautomerism in [dienH 2 ][Co(dien) 2 ][Ge 2 S 6 ] leading to different hydrogen bonded networks|url=http://xlink.rsc.org/?DOI=C4CE00312H|journal=CrystEngComm|language=en|volume=16|issue=25|pages=5551–5559|doi=10.1039/C4CE00312H|issn=1466-8033}}</ref> |
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|- |
|- |
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|DMAH[dabcoH]<sub>2</sub>[Ge<sub>2</sub>Sb<sub>3</sub>S<sub>10</sub>] |
|DMAH[dabcoH]<sub>2</sub>[Ge<sub>2</sub>Sb<sub>3</sub>S<sub>10</sub>] |
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| Line 687: | Line 759: | ||
|2.303 |
|2.303 |
||
|yellow |
|yellow |
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|<ref name=":11" |
|<ref name=":11" /><ref>{{Cite journal|last1=Feng|first1=Mei-Ling|last2=Hu|first2=Chun-Li|last3=Wang|first3=Kai-Yao|last4=Du|first4=Cheng-Feng|last5=Huang|first5=Xiao-Ying|date=2013|title=[AEPH2][GeSb2S6]·CH3OH: a thiogermanate–thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye|url=http://xlink.rsc.org/?DOI=c3ce40143j|journal=CrystEngComm|language=en|volume=15|issue=25|pages=5007|doi=10.1039/c3ce40143j|issn=1466-8033}}</ref> |
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|- |
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|[CH<sub>3</sub>NH<sub>3</sub>]<sub>20</sub>Ge<sub>10</sub>Sb<sub>28</sub>S<sub>72</sub>·7H<sub>2</sub>O |
|[CH<sub>3</sub>NH<sub>3</sub>]<sub>20</sub>Ge<sub>10</sub>Sb<sub>28</sub>S<sub>72</sub>·7H<sub>2</sub>O |
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| Line 707: | Line 779: | ||
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|<ref name=":14" /> |
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|<ref name=":14">{{Cite journal|last1=Zhang|first1=Bo|last2=Feng|first2=Mei-Ling|last3=Cui|first3=Hong-Hua|last4=Du|first4=Cheng-Feng|last5=Qi|first5=Xing-Hui|last6=Shen|first6=Nan-Nan|last7=Huang|first7=Xiao-Ying|date=2015-09-08|title=Syntheses, Crystal Structures, Ion-Exchange, and Photocatalytic Properties of Two Amine-Directed Ge–Sb–S Compounds|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.5b01181|journal=Inorganic Chemistry|language=en|volume=54|issue=17|pages=8474–8481|doi=10.1021/acs.inorgchem.5b01181|pmid=26291119|issn=0020-1669}}</ref> |
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|- |
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|[Mn(en)<sub>3</sub>][GeSb<sub>2</sub>S<sub>6</sub>] |
|[Mn(en)<sub>3</sub>][GeSb<sub>2</sub>S<sub>6</sub>] |
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| Line 717: | Line 789: | ||
|2.26 |
|2.26 |
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|yellow |
|yellow |
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|<ref name=":11" |
|<ref name=":11" /><ref name=":12">{{Cite journal|last1=Zhou|first1=Jian|last2=An|first2=Litao|last3=Liu|first3=Xing|last4=Huang|first4=Lijun|last5=Huang|first5=Xijiao|date=2011|title=Solvothermal synthesis and characterization of two 2-D layered germanium thioantimonates with transition-metal complexes|url=http://xlink.rsc.org/?DOI=c1dt11280e|journal=Dalton Transactions|language=en|volume=40|issue=43|pages=11419–11424|doi=10.1039/c1dt11280e|pmid=21931916|issn=1477-9226}}</ref> |
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|- |
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|[Co(en)<sub>3</sub>][GeSb<sub>2</sub>S<sub>6</sub>] |
|[Co(en)<sub>3</sub>][GeSb<sub>2</sub>S<sub>6</sub>] |
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| Line 737: | Line 809: | ||
|2.205 |
|2.205 |
||
|yellow |
|yellow |
||
|<ref name=":11" /><ref name=":12" /> |
|||
|<ref name=":11">{{Cite journal|last1=Lichte|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2014-05-02|title=Polymorphism and tautomerism in [dienH 2 ][Co(dien) 2 ][Ge 2 S 6 ] leading to different hydrogen bonded networks|url=http://xlink.rsc.org/?DOI=C4CE00312H|journal=CrystEngComm|language=en|volume=16|issue=25|pages=5551–5559|doi=10.1039/C4CE00312H|issn=1466-8033}}</ref><ref name=":12">{{Cite journal|last1=Zhou|first1=Jian|last2=An|first2=Litao|last3=Liu|first3=Xing|last4=Huang|first4=Lijun|last5=Huang|first5=Xijiao|date=2011|title=Solvothermal synthesis and characterization of two 2-D layered germanium thioantimonates with transition-metal complexes|url=http://xlink.rsc.org/?DOI=c1dt11280e|journal=Dalton Transactions|language=en|volume=40|issue=43|pages=11419–11424|doi=10.1039/c1dt11280e|pmid=21931916|issn=1477-9226}}</ref> |
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|[Ni(en)<sub>3</sub>][GeSb<sub>2</sub>S<sub>6</sub>] |
|[Ni(en)<sub>3</sub>][GeSb<sub>2</sub>S<sub>6</sub>] |
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| Line 757: | Line 829: | ||
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|<ref name=":11" /> |
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|<ref name=":11">{{Cite journal|last1=Lichte|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2014-05-02|title=Polymorphism and tautomerism in [dienH 2 ][Co(dien) 2 ][Ge 2 S 6 ] leading to different hydrogen bonded networks|url=http://xlink.rsc.org/?DOI=C4CE00312H|journal=CrystEngComm|language=en|volume=16|issue=25|pages=5551–5559|doi=10.1039/C4CE00312H|issn=1466-8033}}</ref> |
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|La(dien)<small><sub>2</sub></small>(μ–η<small><sup>1</sup></small>,η<small><sup>2</sup></small>-GeS<small><sub>3</sub></small>(SH)) |
|La(dien)<small><sub>2</sub></small>(μ–η<small><sup>1</sup></small>,η<small><sup>2</sup></small>-GeS<small><sub>3</sub></small>(SH)) |
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| Line 768: | Line 840: | ||
|red |
|red |
||
|<ref name=":19">{{Cite journal |last1=Zhou |first1=Jian |last2=Li |first2=Rong |last3=Ling |first3=Xing |last4=Chen |first4=Rong |last5=Hu |first5=Feilong |last6=Zeng |first6=Yanfang |date=2013 |title=The first examples of thiogermanate anion [GeS 3 (SH)] 3− as a bridging ligand to a lanthanide complex |url=http://xlink.rsc.org/?DOI=C2DT32389C |journal=Dalton Trans. |language=en |volume=42 |issue=6 |pages=1961–1964 |doi=10.1039/C2DT32389C |pmid=23165504 |issn=1477-9226}}</ref> |
|<ref name=":19">{{Cite journal |last1=Zhou |first1=Jian |last2=Li |first2=Rong |last3=Ling |first3=Xing |last4=Chen |first4=Rong |last5=Hu |first5=Feilong |last6=Zeng |first6=Yanfang |date=2013 |title=The first examples of thiogermanate anion [GeS 3 (SH)] 3− as a bridging ligand to a lanthanide complex |url=http://xlink.rsc.org/?DOI=C2DT32389C |journal=Dalton Trans. |language=en |volume=42 |issue=6 |pages=1961–1964 |doi=10.1039/C2DT32389C |pmid=23165504 |issn=1477-9226}}</ref> |
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|- |
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|KLaGeS<sub>4</sub> |
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| |
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|monoclinic |
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|''P''2<sub>1</sub> |
|||
|''a''=6.6645 ''b''=6.7079 ''c''=8.7248 ''β''=107.519° Z=2 |
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|371.95 |
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| |
|||
|SHG 1.2×AgGaS<sub>2</sub>; band gap 3.34 eV; birefringence 0.098 @ 1064 nm |
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|<ref name=":21" /> |
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|- |
|- |
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|Nd(dien)<small><sub>2</sub></small>(μ–η<small><sup>1</sup></small>,η<small><sup>2</sup></small>-GeS<small><sub>3</sub></small>(SH)) |
|Nd(dien)<small><sub>2</sub></small>(μ–η<small><sup>1</sup></small>,η<small><sup>2</sup></small>-GeS<small><sub>3</sub></small>(SH)) |
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| Line 897: | Line 979: | ||
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|<ref name=":9" /> |
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|<ref name=":9">{{Cite journal|last1=Tang|first1=Shimei|last2=Cao|first2=Shumei|last3=Zhou|first3=Jian|date=July 2018|title=A Series of Lanthanide Chalcogenidogermanates Displaying Two Types of 1-D Polymeric Chains|url=http://link.springer.com/10.1007/s10876-018-1402-6|journal=Journal of Cluster Science|language=en|volume=29|issue=4|pages=777–783|doi=10.1007/s10876-018-1402-6|s2cid=103263516|issn=1040-7278}}</ref> |
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|- |
|- |
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|Li<sub>4</sub>HgGe<sub>2</sub>S<sub>7</sub> |
|Li<sub>4</sub>HgGe<sub>2</sub>S<sub>7</sub> |
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| Line 904: | Line 986: | ||
|''Cc'' |
|''Cc'' |
||
|a=16.876 b=6.7764 c=10.161 β=93.360° |
|a=16.876 b=6.7764 c=10.161 β=93.360° |
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| |
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| |
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| |
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|<ref name=":20" /> |
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|- |
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|Ag<sub>4</sub>HgGe<sub>2</sub>S<sub>7</sub> |
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| |
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|monoclinic |
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|''Cc'' |
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Latest revision as of 15:17, 11 December 2024
Sulfidogermanates or thiogermanates are chemical compounds containing anions with sulfur atoms bound to germanium. They are in the class of chalcogenidotetrelates. Related compounds include thiosilicates, thiostannates, selenidogermanates, telluridogermanates and selenidostannates.
Coordination of sulfur around germanium is tetrahedral meaning there are four sulfur atoms symmetrically arranged. This basic structure can form ortho salts with GeS44−, oligomers, or polymeric structures.[1] Similar structures are also formed with heavy group 13 and group 14 elements due to their relatively stronger bonds with sulfur. Light elements from these groups have lower affinity for sulfur, so there are fewer compounds like this for boron, aluminium, carbon, and silicon.[1] Other heavy group 12 and 15 elements also form chalcogenidometallates which may have other kinds of coordination. Selenium forms similar compounds to sulfur in this family.[1]
Where sulfur is deficient, an anion is not formed, and instead cation-like covalent compounds can exist with halogens, such as Ge4S6Br4,[2] or Ge4S6I4.[3]
Production
[edit]The solvochemical method of production involves dissolving germanium oxide, sulfur and other salts in a heated solvent under pressure. The solvents can include simple alcohols, amines or N,N-dimethyl formamide. The containers can be glass tubes, quartz tubes, or teflon lined stainless steel.[1]
List
[edit]| formula | name | system | space group | cell Å | volume | density | comments | ref |
|---|---|---|---|---|---|---|---|---|
| H4Ge4S10 | thiogermanic acid | triclinic | P1 | a = 8.621, b = 9.899, c = 10.009, α = 85.963°, β = 64.714°, γ = 89.501°, Z = 2 | [4][5] | |||
| H2Ge4S9 | thiogermanic acid | [4] | ||||||
| Li2GeS3 | hexagonal | P61 | a = 6.79364 c = 17.9072 | [6] | ||||
| [CH3NH3]4Ge2S6 | tetrakis(methylammonium) bis(μ-sulfido)-tetrakis(sulfido)-di-germanium | triclinic | P1 | a 7.3336 b 7.3760 c 10.0007, α 108.598° β 111.332° γ 90.297° | [7] | |||
| [CH3CH2NH3]4Ge2S6•CH3CH2NH2 | tetrakis(ethylammonium) bis(μ-sulfido)-tetrakis(sulfido)-di-germanium ethylamine | orthorhombic | Pnma | a 7.8501 b 18.3444 c 17.4386 | [7] | |||
| [CH3CH2NH3]3[CH3NH3]Ge4S10 | tris(diethylammonium) methylammonium hexakis(μ-sulfido)-tris(sulfido)-tetra-germanium | Pa3 | a 17.9402 c 17.9402 | [7] | ||||
| (NH4)2[NH2(CH3)2]2Ge2S6 | monoclinic | P21/c | a = 6.965, b = 15.7195, c = 7.2045, β = 92.765° | band gap 3.50 eV | [8] | |||
| (NH3NH2)2[(RNGe)2(μ-S)2S2] | [9] | |||||||
| [(R1Ge)4(μ-S)6] | R1 = CMe2CH2COMe | [9][10] | ||||||
| (trenH2)2[Ge2S6] | tren = tris(2-aminoethyl)amine | monoclinic | C2/c | a=25.264 b=7.313 c=16.584 β=122.616 Z=4 | 2581 | 1.632 | colourless | [11] |
| (enH)4Ge2S6 | en = ethylenediamine | triclinic | P1 | a 7.859 b 9.514 c 9.727, α 64.21° β 66.80° γ 84.92° | [12] | |||
| Na4Ge2S6 · 14H2O | triclinic | P1 | a = 9.978, b = 7.202, c = 9.601, α = 108.41 β = 92.39, γ = 91.69° Z = 1 | [13] | ||||
| Na6Ge2S7 | [14] | |||||||
| Li4MgGe2S7 | monoclinic | Cc | a=16.872 b=6.771 c=10.156 β=95.169° | SHG 0.7 ×AGS | [15] | |||
| Na(AlS2)(GeS2)4 | monoclinic | P21/n | a = 6.803, b = 38.207, c = 6.947, β = 119.17° | [16] | ||||
| Li10GeP2S12 | tetragonal | lithium ion conductor | [17] | |||||
| K6Ge2S7 | [14] | |||||||
| [VO(dien)]2GeS4 | orthorhombic | Pna21 | a =19.831, b = 8.0814, c = 12.0889, Z = 4 | 1937.4 | [18] | |||
| {[V(en)2]2O}Ge2S6 | en = ethylenediamine | monoclinic | P21/n | a=8.352 b=12.682 c=11.339 β=94.75 Z=2 | 1196.9 | 1.931 | black | [19] |
| [VO(dap)2]2Ge2S6·dap | dap = 1,2-diaminopropane | hexagonal | R2c ? | a=38.284 c=11.170 Z=18 | 14178 | 1.619 | purple; hexagonal nanotubes | [19] |
| Li4MnGe2S7 | monoclinic | Cc | a=16.833 b=6.709 c=10.121 β=94.76° Z=4 | 1139.1 | 2.637 | light pink | [15][20] | |
| {[Mn(2,2′-bipy)2(H2O)]2Ge4S10}·3H2O | bipy = bipyridine | triclinic | P1 | a=10.6511 b=13.0443 c=22.995, α=79.539 β=77.653° γ=79.737° Z=2 | 3036.6 | 1.570 | [21] | |
| {Mn(tepa)}2(μ-Ge2Se6) | tetragonal | I41/a | [22] | |||||
| Mn2(en)4Ge2S6 | en=ethylenediamine | [23] | ||||||
| [Mn(en)3]2Ge2S6 | monoclinic | C2/c | a 15.115 b 10.530 c 22.897, 118.777° | [12] | ||||
| Mn2(dap)4Ge2S6 | dap = 1,2-diaminopropane | [23] | ||||||
| H2dienMnGeS4 | dien = diethylenetriamine | [23] | ||||||
| [(dien)2Mn]Ge2S4 | dien=diethylenetriamine | orthorhombic | P212121 | a=9.113, b=12.475, c=17.077, Z=4 | 1941 | 1D [Ge2S4]2− chains | [24] | |
| Mn3Ge2S7(NH3)4 | orthorhombic | Pbcn | a=9.107 b=13.923 c=12.750 Z=4 | 1616.6 | 2.476 | green | [25] | |
| [MnII(tren)]2(μ2-Ge2S6) | tren = N,N,N-tris(2-aminoethyl)amine | triclinic | P1 | a 7.631 b 8.039 c 11.957, α 98.952° β 101.263° γ 109.696° | [26] | |||
| [MnII(tepa)]2(μ2-Ge2S6) | tepa= tetraethylenepentaamine | orthorhombic | I 41/a | a =25.770 b =25.770 c =9.812 | [26] | |||
| [Fe(2,2′-bipy)3]2[Ge4S10]·10H2O | monoclinic | P21/c | a=23.8411 b=13.6462 c=22.9029 β=93.400° Z=4 | 7438.1 | 1.643 | [21] | ||
| {Fe(tepa)}2(μ-Ge2Se6) | tetragonal | I41/a | [22] | |||||
| K2FeGe3S8 | triclinic | P1 | a = 7.016, b= 7.770, c = 14.342, α = 93.80°, β = 92.65°, γ = 114.04° | [27] | ||||
| K2CoGe3S8 | monoclinic | P21 | a = 7.1089, b = 11.8823, c = 16.759, β = 96.604° | [27] | ||||
| [{Co(tepa)}2(μ-Ge2S6)] | tepa= tetraethylenepentaamine | tetragonal | I41/a | [22] | ||||
| [dienH2][Co(dien)2][Ge2S6] | dien = diethylenetriamine | triclinic | P1 | a 11.3224 b 14.6492 c 18.3710, α 71.000° β 78.352° γ 73.441° Z=4 | 2741.5 | 1.715 | yellow | [28] |
| [dienH2][Co(dien)2][Ge2S6] | triclinic | P1 | a 11.3224 b 14.6492 c 18.3710, α 71.000° β 78.352° γ 73.441° Z=1 | 679.62 | 1.730 | yellow | [28] | |
| [dienH2][Co(dien)2][Ge2S6] | orthorhombic | Pbca | a=15.2110 b=16.7025 c=21.8821 Z=8 | 5559.4 | 1.692 | yellow | [28] | |
| [dienH2][Co(dien)2][Ge2S6] | orthorhombic | Pca21 | a=a=14.7043 b=9.0099 c=21.4540 Z=4 | 2842.3 | 1.655 | yellow | [28] | |
| [Ni(cyclam)]3[Ni(cyclam)(H2O)2][Ge4S10]2·21H2O | cyclam = 1,4,8,11-tetraazacyclotetradecane | monoclinic | Cc | a=35.915 b=10.047 c=30.607 β =115.32 Z=4 | 9983 | 1.778 | [21] | |
| [Ni(en)3]2Ge2S6 | en=ethylenediamine | orthorhombic | Pbca | a 15.56 b 11.226 c 18.07 | [12] | |||
| [Ni(dien)2]3[Ge3Sb8S21]·0.5H2O | dien = diethylenetriamine | [29] | ||||||
| [Ni(trien)2]2Ge4S10 | bis(bis(triethylenetetramine)-nickel) hexakis(μ2-sulfido)-tetrasulfido-tetra-germanium | monoclinic | C2/c | a =21.618 b =10.957 c =22.719, β=111.224° | [30] | |||
| [{Ni(tepa)}2(μ-Ge2S6)] | tetrakis(μ2-sulfido)-disulfido-bis(tetraethylenepentamine)-di-germanium-di-nickel | orthorhombic | Pbca | a =15.151 b =13.083 c =15.255 | [30] | |||
| [NiII(dien)2]2(Ge2S6) | dien = diethylenetriamine | monoclinic | P 21/n | a 10.093 b 14.219 c 11.703, β 91.631° | [26] | |||
| [NiII(dien)2](H2pipe)(Ge2S6) | pipe = piperazine | triclinic | P1 | a 6.980 b 8.530 c 11.527, α 93.03° β 106.29° γ 101.95° | [26] | |||
| [NiII(tepa)]2(μ2-Ge2S6) | tepa = tetraethylenepentamine | orthorhombic | Pbca | a =15.147 b =13.0552 c =15.238 | [26] | |||
| [(CH3CH2)4N]3CuGe4S10 | catena-[hexakis(tetraethylammonium) hexadecakis(μ-sulfido)-tetrakis(sulfido)-octa-germanium-di-copper] | monoclinic | P 21/n | a 15.0956 b 14.2127 c =19.5889, β 91.131° | [7] | |||
| [H4teta]5[Cu40Ge15S60]·2.5(teta) | [31] | |||||||
| Cu(AlS2)(GeS2)4 | monoclinic | P21/n | a 6.796 b 37.628 c 6.8797, β 119.52° | [16] | ||||
| Cu4MnGe2S7 | monoclinic | Cc | a=16.7443 b=6.47893 c=9.8060 β=93.188° | [15] | ||||
| Cu4FeGe2S7 | monoclinic | C2 | a=11.7405 b=5.3589 c=8.3420 β=98.661° | [15] | ||||
| Cu4CoGe2S7 | monoclinic | C2 | a=11.7280 b=5.3399 c=8.3313 β=98.668° | [15] | ||||
| Cu4NiGe2S7 | monoclinic | C2 | a=11.703 b=5.333 c=8.311 β=98.37° | [15] | ||||
| Sr2CoGe2OS6 | tetrahedral | P421m | a=9.4056 c=6.1741 Z=2 | 546.19 | 3.574 | dark green; oxysulfide | [32] | |
| Y3LiGeS7 | [33] | |||||||
| [Y2(tepa)2(μ-OH)2(μ-Ge2S6)](tepa)0.5·H2O | monoclinic | C2/c | a=19.638 b=14.415 c=16.910 β=122.47 Z=4 | 4038.6 | 1.863 | colourless | [11] | |
| KYGeS4 | [34] | |||||||
| [{RNGe(μ-S)3}4Pd6]·MeOH | RN = CMe2CH2CMeNNH2 | [9] | ||||||
| Ag10Ge3S11 | monoclinic | Cc | a = 2.6244 b = 0.65020 c = 2.5083 β = 109.910° | [35] | ||||
| [(CH3CH2)4N]3AgGe4S10 | catena-[hexakis(tetraethylammonium) hexadecakis(μ-sulfido)-tetrakis(sulfido)-di-silver-octa-germanium] | monoclinic | P 21/n | a 15.1898 b 14.3043 c 19.5059, β 91.056° | [7] | |||
| Ag(AlS2)(GeS2)4 | monoclinic | P21/n | a 6.799 b 38.4169 c 6.813 β 119.65° | [16] | ||||
| Li4CdGe2S7 | monoclinic | Cc | a=17.4432 b=6.9353 c=10.3271 β=93.9042° | [15] | ||||
| Na4CdGe2S7 | monoclinic | P21/c | a=7.0813 b=11.9007 c=15.5759 β=90.791° | [15] | ||||
| Y3Cd0.5GeS7 | [33] | |||||||
| Ag4SnGe2S7 | monoclinic | Cc | a=11.3398 b=6.9706 c=15.4885 β=91.213° | yellow; ∞[SnGe2S8]6– chains | [15] | |||
| Na9Sb(Ge2S6)2 | monoclinic | C2/m | a=7.5857 b=11.574 c=6.817 β=106.587 Z=1 | 573.7 | 2.905 | yellow | [36] | |
| [Ge(en)3][GeSb2S6] | orthorhombic | Pbca | [1] | |||||
| [(Me)2NH2]6[Ge2Sb2S7][Ge4S10] | triclinic | P1 | microporous, can exchange dimethyl ammonium for alkalis | [28][37] | ||||
| [dabcoH]2[Ge2Sb3S10] | dabco = 1,4-diazabicyclo[2.2.2]octane | [28] | ||||||
| DMAH[dabcoH]2[Ge2Sb3S10] | dabco = 1,4-diazabicyclo[2.2.2]octane | monoclinic | C2 | [1] | ||||
| [DMAH]2GeSb3S6 | P41212 | [1] | ||||||
| [AEPH2][GeSb2S6]·CH3OH | AEP = N-(2-aminoethyl)piperazine | orthorhombic | Pbca | a=6.7183 b=18.3065 c=31.5007 Z=8 | 3874.2 | 2.303 | yellow | [28][38] |
| [CH3NH3]20Ge10Sb28S72·7H2O | monoclinic | C2/c | a =29.2964 b=29.3261 c=41.601 β=100.084° | [39] | ||||
| [(CH3CH2CH2)2NH2]3Ge3Sb5S15·0.5(C2H5OH) | triclinic | P1 | a=9.7628 b=15.7590 c=17.0313, α=79.868° β=75.010° γ=81.094° | [39] | ||||
| [Mn(en)3][GeSb2S6] | dien = diethylenetriamine | orthorhombic | Pbca | a=13.374 b=17.607 c=18.562 Z=8 | 4370.8 | 2.26 | yellow | [28][40] |
| [Co(en)3][GeSb2S6] | orthorhombic | Pbca | ||||||
| [Co(dien)2]2[GeSb4S10] | dien = diethylenetriamine | orthorhombic | Pbca | a=14.684 b=17.133 c=33.478 Z=8 | 8422 | 2.205 | yellow | [28][40] |
| [Ni(en)3][GeSb2S6] | orthorhombic | Pbca | ||||||
| [Ni(dien)2]3[Ge3Sb8S21]·0.5H2O | monoclinic | C2/m | a =17.604 b =30.660 c =15.348 β =114.69° | [28] | ||||
| La(dien)2(μ–η1,η2-GeS3(SH)) | monoclinic | C2/c | a=27.837 b=16.993 c=8.318 β =103.96 Z=8 | 3818.7 | 1.903 | red | [41] | |
| KLaGeS4 | monoclinic | P21 | a=6.6645 b=6.7079 c=8.7248 β=107.519° Z=2 | 371.95 | SHG 1.2×AgGaS2; band gap 3.34 eV; birefringence 0.098 @ 1064 nm | [34] | ||
| Nd(dien)2(μ–η1,η2-GeS3(SH)) | monoclinic | C2/c | a=27.694 b=16.845 c=8.287 β =103.791 Z=8 | 3754.4 | 1.955 | red | [41] | |
| [Pr(dien)3]2[Ge2S6]Cl2 | dien = diethylenetriamine | monoclinic | P21/n | a=11.637 b=14.143 c=15.120 β=98.149° Z=4 | 2463 | 1.765 | green | [42] |
| [Sm(dien)3]2[Ge2S6]Cl2 | dien = diethylenetriamine | monoclinic | P21/n | 11.532 b=14.423 c=14.573 β=97.105° Z=4 | 2405 | 1.834 | light yellow | [42] |
| Sm3Zn0.5GeS7 | [33] | |||||||
| Eu3Ge3S9 | a=8.468 b=11.76 c=8.389 α=90.49° β=104.56° γ=69.53° Z=2 | 4.22 meas | [43] | |||||
| [Eu(dien)3]2[Ge2S6]Cl2 | dien = diethylenetriamine | monoclinic | P21/n | a=11.567 b=14.633 c=14.465 β=96.434 Z=4 | 2432.9 | 1.818 | yellow | [11] |
| Gd3Cd0.5GeS7 | [33] | |||||||
| [Gd(dien)3]2[Ge2S6]Cl2 | dien = diethylenetriamine | monoclinic | P21/n | 11.548 b=14.677 c=14.427 β=96.332° Z=4 | 2430.4 | 1.834 | colourless | [42] |
| [Dy(dien)3]2[Ge2S6]Cl2 | dien = diethylenetriamine | monoclinic | P21/n | a=11.503 b=14.645 c=14.340 β=96.178° Z=4 | 2401.8 | 1.870 | light yellow | [42] |
| [Ho(trien)(en)GeS3(SH)] | trien = triethylenetetramine | [42] | ||||||
| Er2(tepa)2(μ-OH)2(μ-Ge2S6)]n·nH2O | tepa = tetraethylenepentamine | [44] | ||||||
| [Er2(dien)4(μ-OH)2][Ge2S6] | dien = diethylenetriamine | monoclinic | P21/n | 11.710 b=11.318 c=13.548 β=97.635° Z=4 | 1779.6 | 2.088 | red | [42] |
| Tm2(tepa)2(μ-OH)2(μ-Ge2S6)]n·nH2O | tepa = tetraethylenepentamine | [44] | ||||||
| Li4HgGe2S7 | monoclinic | Cc | a=16.876 b=6.7764 c=10.161 β=93.360° | [15] | ||||
| Ag4HgGe2S7 | monoclinic | Cc | a=17.4546 b=6.8093 c=10.5342 β=93.3980° | [15] | ||||
| [(Me)2NH2][BiGeS4] | monoclinic | P21 | a=6.7290 b c=10.6748 β=105.789 Z=2 | 479.72 | 3.156 | red | [45] |
References
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