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←Created page with '{{Chembox | Name = Cerium(III) acetate | ImageFile = Cerium(III)_acetate.jpg | ImageName = | IUPACName = Cerium(III) acetate | OtherNames = Cerium triacetate<br>Cerium acetate | Section1 = {{Chembox Identifiers | CASNo = 537-00-8 | CASNo_Ref = {{cascite|correct|CAS}} | CASNo_Comment = anhydrous | CASNo1 = 206996-60-3 | CASNo1_Ref = {{cascite|correct|CAS}} | CASNo1_Comment = hydrate }} | Section2 = {{Chembox Properties | Formula = Ce(CH<sub>3<...'
 
Rescuing 1 sources and tagging 0 as dead.) #IABot (v2.0.9.3) (Materialscientist - 13188
 
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| OtherNames = Cerium triacetate<br>Cerium acetate
| OtherNames = Cerium triacetate<br>Cerium acetate
| Section1 = {{Chembox Identifiers
| Section1 = {{Chembox Identifiers
⚫
| index_label=anhydrous
| index1_label=sesquihydrate
| CASNo = 537-00-8
| CASNo = 537-00-8
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo_Ref = {{cascite|correct|CAS}}
⚫
| CASNo_Comment = anhydrous
| CASNo1 = 206996-60-3
| CASNo1 = 206996-60-3
| CASNo1_Ref = {{cascite|correct|CAS}}
| CASNo1_Ref = {{cascite|correct|CAS}}
| ChemSpiderID = 10369
| CASNo1_Comment = hydrate
| EINECS = 208-654-0
| PubChem = 10826
| PubChem1 = 22833299
| UNII = YYB5291R2H
| UNII1 = 779OQ1RB37
| SMILES = CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Ce+3]
| SMILES1 = CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Ce+3].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Ce+3].O.O.O
| StdInChI=1S/3C2H4O2.Ce/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
| StdInChIKey = VGBWDOLBWVJTRZ-UHFFFAOYSA-K
| InChI1=1S/6C2H4O2.2Ce.3H2O/c6*1-2(3)4;;;;;/h6*1H3,(H,3,4);;;3*1H2/q;;;;;;2*+3;;;/p-6
| InChIKey1=FLEYCIHWCBGBLG-UHFFFAOYSA-H
}}
}}
| Section2 = {{Chembox Properties
| Section2 = {{Chembox Properties
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| MolarMass = 317.26
| MolarMass = 317.26
| Appearance = white powder
| Appearance = white powder
| MeltingPt = 308℃
| MeltingPt = 308°C
| BoilingPt =
| BoilingPt =
| Solvent =
| Solvent =
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}}
}}
| Section7 = {{Chembox Hazards
| Section7 = {{Chembox Hazards
| ExternalMSDS =
| ExternalSDS =
| NFPA-H =
| NFPA-H =
| NFPA-F =
| NFPA-F =
| NFPA-R =
| NFPA-R =
| FlashPt =
| FlashPt =
| GHS_ref=<ref>{{cite web |title=Cerium triacetate |url=https://pubchem.ncbi.nlm.nih.gov/compound/10826#section=Safety-and-Hazards |website=pubchem.ncbi.nlm.nih.gov |language=en}}</ref>
| RPhrases =
| GHSPictograms = {{GHS07}}{{GHS09}}
| SPhrases =
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|315|319|335|410}}
| PPhrases = {{P-phrases|261|264|264+265|271|273|280|302+352|304+340|305+351+338|305+354+338|317|319|321|332+317|337+317|362+364|391|403+233|405|501}}
}}
}}
| Section8 = {{Chembox Related
| Section8 = {{Chembox Related
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}}
}}


'''Cerium acetate''' is an [[inorganic compound]] with the [[chemical formula]] of Ce(CH<sub>3</sub>COO)<sub>3</sub>. It is a white powder that is soluble in water. Its 1.5 hydrate loses water at 133°C to obtain an amorphous anhydrate, and the amorphous phase changes to crystal at 212°C, and phase changes again at 286°C.<ref name=Arii />
'''Cerium acetate''' is an [[inorganic compound]] with the [[chemical formula]] of Ce(CH<sub>3</sub>COO)<sub>3</sub>. It is a white powder that is soluble in water. Its 1.5 hydrate loses water at 133°C to obtain an amorphous [[anhydrous]] form, and the amorphous phase changes to crystal at 212°C, and phase changes again at 286°C.<ref name=Arii />


==Preparation==
== Preparation ==


Cerium acetate can be prepared by reacting [[cerium(III) carbonate]] and 50% acetic acid in an aqueous solution:<ref name=product >《无机化合物制备手册》.朱文祥 主编. 化学工业出版社.第十四章 碳族元素.P<sub>512</sub>.XIV-124 醋酸铈(III)</ref>
Cerium acetate can be prepared by reacting [[cerium(III) carbonate]] and 50% [[acetic acid]] in an aqueous solution:<ref name=product >《无机化合物制备手册》.朱文祥 主编. 化学工业出版社.第十四章 碳族元素.P<sub>512</sub>.XIV-124 醋酸铈(III)</ref>


: Ce<sub>2</sub>(CO<sub>3</sub>)<sub>3</sub> + 6 CH<sub>3</sub>COOH → 2 Ce(CH<sub>3</sub>COO)<sub>3</sub> + 3 H<sub>2</sub>O + 3 CO<sub>2</sub>↑
: Ce<sub>2</sub>(CO<sub>3</sub>)<sub>3</sub> + 6 CH<sub>3</sub>COOH → 2 Ce(CH<sub>3</sub>COO)<sub>3</sub> + 3 H<sub>2</sub>O + 3 CO<sub>2</sub>↑
Line 50: Line 65:
==Properties==
==Properties==


Cerium acetate is soluble in water and ethanol in its anhydrous form (its hydrate is insoluble in ethanol), easily soluble in pyridine, and insoluble in acetone.<ref name=jca>《无机化合物合成手册》.第二卷.日本化学会 编. 曹惠民 译. 化学工业出版社. 1988.7第一版.【1260】稀土元素的乙酸盐.P<sub>582</sub></ref> Its thermal decomposition (310 °C) will generate basic cerium(III) acetate, which will be further decomposed to obtain Ce<sub>2</sub>O<sub>2</sub>CO<sub>3</sub>, and continue to heat to generate CeO<sub>2</sub> and CO.<ref name=Arii>Arii T, Kishi A, Ogawa M, et al. [https://www.jstage.jst.go.jp/article/analsci/17/7/17_7_875/_pdf Thermal decomposition of cerium (III) acetate hydrate by a three-dimensional thermal analysis] {{WayBack|url=https://www.jstage.jst.go.jp/article/analsci/17/7/17_7_875/_pdf |date=20181024112958 }}[J]. Analytical sciences, 2001, 17(7): 875-880.</ref>
Cerium acetate is [[solubility (chemistry)|soluble]] in [[water]] and [[ethanol]] in its anhydrous form (its hydrate is insoluble in ethanol), easily soluble in [[pyridine]], and insoluble in [[acetone]].<ref name=jca>《无机化合物合成手册》.第二卷.日本化学会 编. 曹惠民 译. 化学工业出版社. 1988.7第一版.【1260】稀土元素的乙酸盐.P<sub>582</sub></ref> Its thermal decomposition at 310 °C will generate basic cerium(III) acetate, which will be further decomposed to obtain Ce<sub>2</sub>O<sub>2</sub>CO<sub>3</sub> (a basic carbonate), and continued heating generates [[cerium(IV) oxide|CeO<sub>2</sub>]] and [[carbon monoxide|CO]].<ref name=Arii>Arii T, Kishi A, Ogawa M, et al. [https://www.jstage.jst.go.jp/article/analsci/17/7/17_7_875/_pdf Thermal decomposition of cerium (III) acetate hydrate by a three-dimensional thermal analysis] {{Webarchive|url=https://web.archive.org/web/20181024112958/https://www.jstage.jst.go.jp/article/analsci/17/7/17_7_875/_pdf |date=2018-10-24 }}[J]. Analytical sciences, 2001, 17(7): 875-880.</ref>


==References==
==References==

Latest revision as of 03:09, 11 April 2023

Cerium(III) acetate
Names
IUPAC name
Cerium(III) acetate
Other names
Cerium triacetate
Cerium acetate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.869 Edit this at Wikidata
EC Number
  • anhydrous: 208-654-0
UNII
  • InChI=1S/3C2H4O2.Ce/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
    Key: VGBWDOLBWVJTRZ-UHFFFAOYSA-K
  • sesquihydrate: InChI=1S/6C2H4O2.2Ce.3H2O/c6*1-2(3)4;;;;;/h6*1H3,(H,3,4);;;3*1H2/q;;;;;;2*+3;;;/p-6
    Key: FLEYCIHWCBGBLG-UHFFFAOYSA-H
  • anhydrous: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Ce+3]
  • sesquihydrate: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Ce+3].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Ce+3].O.O.O
Properties
Ce(CH3COO)3
Molar mass 317.26
Appearance white powder
Melting point 308°C
Hazards
GHS labelling:[1]
GHS07: Exclamation markGHS09: Environmental hazard
Warning
H315, H319, H335, H410
P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, P501
Related compounds
Other cations
 Lanthanum(III) acetate
Praseodymium(III) acetate
Neodymium acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Cerium acetate is an inorganic compound with the chemical formula of Ce(CH3COO)3. It is a white powder that is soluble in water. Its 1.5 hydrate loses water at 133°C to obtain an amorphous anhydrous form, and the amorphous phase changes to crystal at 212°C, and phase changes again at 286°C.[2]

Preparation

[edit]

Cerium acetate can be prepared by reacting cerium(III) carbonate and 50% acetic acid in an aqueous solution:[3]

Ce2(CO3)3 + 6 CH3COOH → 2 Ce(CH3COO)3 + 3 H2O + 3 CO2↑

Properties

[edit]

Cerium acetate is soluble in water and ethanol in its anhydrous form (its hydrate is insoluble in ethanol), easily soluble in pyridine, and insoluble in acetone.[4] Its thermal decomposition at 310 °C will generate basic cerium(III) acetate, which will be further decomposed to obtain Ce2O2CO3 (a basic carbonate), and continued heating generates CeO2 and CO.[2]

References

[edit]
  1. ^ "Cerium triacetate". pubchem.ncbi.nlm.nih.gov.
  2. ^ a b Arii T, Kishi A, Ogawa M, et al. Thermal decomposition of cerium (III) acetate hydrate by a three-dimensional thermal analysis Archived 2018-10-24 at the Wayback Machine[J]. Analytical sciences, 2001, 17(7): 875-880.
  3. ^ 《无机化合物制备手册》.朱文祥 主编. 化学工业出版社.第十四章 碳族元素.P512.XIV-124 醋酸铈(III)
  4. ^ 《无机化合物合成手册》.第二卷.日本化学会 编. 曹惠民 译. 化学工业出版社. 1988.7第一版.【1260】稀土元素的乙酸盐.P582
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