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{{User sandbox}}
{{User sandbox}}
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The [[Hammett acidity function|Hammett acidity]] of various acids
{|class="wikitable sortable
{|class="wikitable sortable
|+ List of acids by Hammett acidity
|+ List of acids by Hammett acidity
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| [[Trifluoroacetic acid]]
| [[Trifluoroacetic acid]]
| -2.7
| -2.7
| <ref name = "b">{{cite journal |last1=Saito |first1=Shoichi |last2=Saito |first2=Shin-ichi |last3=Ohwada |first3=Tomohiko |last4=Shudo |first4=Koichi |title=The Hammett Acidity Function H0 of Trifluoromethanesulfonic Acid-Trifluoroacetic Acid and Related Acid Systems. A Versatile Nonaqueous Acid System. |journal=Chemical and Pharmaceutical Bulletin |date=1991 |volume=39 |issue=10 |pages=2718–2720 |doi=10.1248/cpb.39.2718}}</ref>
| https://doi.org/10.1248/cpb.39.2718
|-
| [[Nitric acid]]
| -6.3
| <ref>{{cite journal |last1=Dawber |first1=J. G. |last2=Wyatt |first2=P. A. H. |title=718. The Hammett acidity function in aqueous nitric acid |journal=Journal of the Chemical Society (Resumed) |date=1960 |pages=3589 |doi=10.1039/JR9600003589}}</ref>
|-
|-
| [[Sulfuric acid]]
| [[Sulfuric acid]]
| -11.93
| -11.93
| <ref name = "a">{{cite thesis |last=Peel |first=Terence Edward |date=September 1971 |title= The Hammett Acidity Function for Some Superacid Media |url=https://macsphere.mcmaster.ca/handle/11375/19972}}</ref>
| https://macsphere.mcmaster.ca/bitstream/11375/19972/1/Peel_Terence_E._1971Sept_Ph.D..pdf
|-
|-
| [[Triflic acid]]
| [[Triflic acid]]
| -13.7
| -13.7
| <ref name = "b"></ref>
| https://doi.org/10.1248/cpb.39.2718
|-
|-
| [[Chlorosulfuric acid]]
| [[Chlorosulfuric acid]]
| -13.79
| -13.79
| <ref name = "a"></ref>
| https://macsphere.mcmaster.ca/bitstream/11375/19972/1/Peel_Terence_E._1971Sept_Ph.D..pdf
|-
|-
| [[Fluorosulfuric acid]]
| [[Fluorosulfuric acid]]
| -15.07
| -15.07
| <ref name = "a"></ref>
| https://macsphere.mcmaster.ca/bitstream/11375/19972/1/Peel_Terence_E._1971Sept_Ph.D..pdf
|}
|}
==References==
{{reflist}}

Latest revision as of 03:06, 15 December 2024


The Hammett acidity of various acids

List of acids by Hammett acidity
Name Hammett acidity Ref
Trifluoroacetic acid -2.7 [1]
Nitric acid -6.3 [2]
Sulfuric acid -11.93 [3]
Triflic acid -13.7 [1]
Chlorosulfuric acid -13.79 [3]
Fluorosulfuric acid -15.07 [3]

References

[edit]
  1. ^ a b Saito, Shoichi; Saito, Shin-ichi; Ohwada, Tomohiko; Shudo, Koichi (1991). "The Hammett Acidity Function H0 of Trifluoromethanesulfonic Acid-Trifluoroacetic Acid and Related Acid Systems. A Versatile Nonaqueous Acid System". Chemical and Pharmaceutical Bulletin. 39 (10): 2718–2720. doi:10.1248/cpb.39.2718.
  2. ^ Dawber, J. G.; Wyatt, P. A. H. (1960). "718. The Hammett acidity function in aqueous nitric acid". Journal of the Chemical Society (Resumed): 3589. doi:10.1039/JR9600003589.
  3. ^ a b c Peel, Terence Edward (September 1971). The Hammett Acidity Function for Some Superacid Media (Thesis).
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