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{{short description|Liquid consisting mainly of acetic acid and water}}
[[File:Eguilles 20110828 14.jpg|thumb|A variety of flavored vinegars on sale in France]]
'''Vinegar''' is an [[aqueous solution]] of [[acetic acid]] and trace chemicals that may include flavorings. Vinegar typically contains 5–20% by volume acetic acid. Usually the acetic acid is produced by the [[fermentation]] of [[ethanol]] or sugars by [[acetic acid bacteria]].<ref>{{cite journal|url=http://jb.oxfordjournals.org/content/46/9/1217.extract|title=Studies on acetic acid-bacteria I. Biochemical studies on ethanol oxidation|journal=J Biochem|volume=46|issue=9|year=1959|author=Nakayama T|pages=1217–25}}</ref> Vinegar is now mainly used as a [[cooking ingredient]], or in [[pickling]]. There are many [[Vinegar#Varieties|types of vinegar]], depending upon the source materials.


[[File:Eguilles 20110828 14.jpg|thumb|upright=1.3|A variety of flavored vinegars, for culinary use, on sale in [[France]]]]
As the most easily manufactured mild [[acid]], it has historically had a wide variety of industrial, [[folk medicine|medical]], and domestic uses. Some of these are still commonly practiced, such as its use as a [[household cleaner]].


'''Vinegar''' ({{ety|fro|vyn egre|sour [[wine]]}}) is an [[aqueous solution]] of [[acetic acid]] and trace compounds that may include [[flavorings]]. Vinegar typically contains from 5% to 18% acetic acid by volume.<ref>{{cite web |title=Acetic acid: general information |url=https://www.gov.uk/government/publications/acetic-acid-properties-uses-and-incident-management/acetic-acid-general-information |website=GOV.UK |publisher=[[Government Digital Service]] |access-date=19 March 2024 |language=en}}</ref> Usually, the acetic acid is produced by a double [[fermentation]], converting simple [[sugars]] to [[ethanol]] using yeast and ethanol to acetic acid using [[acetic acid bacteria]].<ref>{{cite journal |last1=Nakayama |first1=Takeyoshi |title=Studies on acetic acid-bacteria I. Biochemical studies on ethanol oxidation |journal=[[The Journal of Biochemistry]] |volume=46 |issue=9 |date=September 1959 |pages=1217–1225 |doi=10.1093/oxfordjournals.jbchem.a127022 }}</ref> Many types of vinegar are made, depending on source materials. The product is now mainly used in the [[culinary arts]] as a flavorful, acidic [[cooking ingredient]] or in [[pickling]]. Various types are used as [[condiment]]s or garnishes, including [[balsamic vinegar]] and [[#Grains|malt vinegar]].
== Production ==
[[File:Wiener Essigbrauerei 40.JPG|thumb|Fast aerobic [[fermentation]] stainless steel vessels]]
Commercial vinegar is produced either by a fast or a slow fermentation process. In general, slow methods are used in traditional vinegars, where fermentation proceeds over the course of a few months to a year. The longer fermentation period allows for the accumulation of a nontoxic slime composed of acetic acid bacteria.


As the most easily manufactured mild [[acid]], it has a wide variety of industrial and domestic uses, including functioning as a [[Cleaning agent|household cleaner]].<ref name=harvard/>
Fast methods add [[mother of vinegar]] ([[bacterial culture]]) to the source liquid before adding air to oxygenate and promote the fastest fermentation. In fast production processes, vinegar may be produced in one to three days.


==Chemistry==
==Etymology==
[[File:Wiener Essigbrauerei 40.JPG|thumb|Fast [[aerobic fermentation]] stainless steel vessels]]
The conversion of ethanol (CH<sub>3</sub>CH<sub>2</sub>OH) and oxygen (O<sub>2</sub>) to acetic acid (CH<sub>3</sub>COOH) takes place by the following reaction:<ref>{{Citation |last=Saladin |first=Kenneth S. |year=2015 |title=Anatomy & Physiology: The Unity of Form and Function |publisher=McGraw-Hill Education |publication-place= |page=55 |url= |isbn= 9814646431 }}</ref>
The word "vinegar" arrived in [[Middle English]] from [[Old French]] (''vyn egre''; sour wine), which in turn derives from [[Latin]]: {{lang|la|vīnum}} (wine) + {{lang|la|ācre}} ([[neuter gender]] of {{lang|la|ācer}}, sour).<ref name=harvard/><ref>{{cite web|url=https://en.oxforddictionaries.com/definition/vinegar|archive-url=https://web.archive.org/web/20180320170957/https://en.oxforddictionaries.com/definition/vinegar|url-status=dead|archive-date=20 March 2018|title=Definition of vinegar in English by Oxford Dictionaries|website=Oxford Dictionaries}}</ref> Vinegar was formerly also called {{linktext|eisel}}.
:CH<sub>3</sub>CH<sub>2</sub>OH + O<sub>2</sub> → CH<sub>3</sub>COOH + H<sub>2</sub>O


The word "acetic" derives from Latin {{lang|la|acētum}} (vinegar, or more properly ''vinum acetum'': "wine turned sour").<ref>{{Cite web|url=https://www.etymonline.com/word/acetic|title=acetic &#124; Etymology, origin and meaning of acetic by etymonline|website=www.etymonline.com}}</ref>
===Polyphenols===


== History ==
Vinegar contains numerous [[flavonoid]]s, [[phenolic acid]]s, and [[aldehyde]]s,<ref>{{cite journal|last1=Cerezo|first1=Ana B.|last2=Tesfaye|first2=Wendu|last3=Torija|first3=M. Jesús|last4=Mateo|first4=Estíbaliz|last5=García-Parrilla|first5=M. Carmen|last6=Troncoso|first6=Ana M.|year=2008|title=The phenolic composition of red wine vinegar produced in barrels made from different woods|journal=Food Chemistry|volume=109|issue=3|pages=606–615|doi=10.1016/j.foodchem.2008.01.013}}</ref> which vary in content depending on the source material used to make the vinegar, such as [[Peel (fruit)|orange peel]] or various [[fruit juice]] [[concentrate]]s.<ref>{{cite journal|author1=Cejudo-Bastante|first1=C|last2=Castro-Mejías|first2=R|last3=Natera-Marín|first3=R|last4=García-Barroso|first4=C|last5=Durán-Guerrero|first5=E|year=2016|title=Chemical and sensory characteristics of orange based vinegar|journal=Journal of Food Science and Technology|volume=53|issue=8|pages=3147–3156|doi=10.1007/s13197-016-2288-7|pmc=5055879|pmid=27784909}}</ref><ref>{{cite journal|author1=Coelho|first1=E|last2=Genisheva|first2=Z|last3=Oliveira|first3=J. M|last4=Teixeira|first4=J. A|last5=Domingues|first5=L|year=2017|title=Vinegar production from fruit concentrates: Effect on volatile composition and antioxidant activity|journal=Journal of Food Science and Technology|volume=54|issue=12|pages=4112–4122|doi=10.1007/s13197-017-2783-5|pmc=5643795|pmid=29085154}}</ref>
While vinegar making may be as old as [[brewing]], the first documented evidence of vinegar making and use was by the ancient [[Babylonia]]ns around 3000 BCE.<ref name="bourg">{{Cite journal |last1=Bourgeois |first1=Jacques |last2=Barja |first2=François |date=December 2009 |title=The history of vinegar and its acetification systems |url=https://www.unige.ch/sphn/Publications/ArchivesSciences/AdS%202004-2015/AdS%202009%20Vol%2062%20Fasc%202/147-160_05_Bourgeois_62_2.pdf |url-status=live |journal=Archives des Sciences |volume=62 |issue=2 |pages=147–160 |archive-url=https://web.archive.org/web/20190128141836/https://www.unige.ch/sphn/Publications/ArchivesSciences/AdS%202004-2015/AdS%202009%20Vol%2062%20Fasc%202/147-160_05_Bourgeois_62_2.pdf |archive-date=28 January 2019 |access-date=28 January 2019}}</ref> They primarily made vinegar from dates, figs, and beer and used it for both culinary and medicinal purposes. Traces of it also have been found in [[Egypt]]ian [[urn]]s. In East Asia, the Chinese began professionalizing vinegar production in the [[Zhou dynasty]].<ref name="Smith-2019">{{Cite book |last=Smith |first=Reginald |title=Vinegar, the Eternal Condiment |publisher=Spikehorn Press |year=2019 |isbn=978-1-943015-03-0 |location=Southport, NC |pages=29–31}}</ref> The book ''[[Rites of Zhou|Zhou Li]]'' mentions that many noble or royal households had a "vinegar maker" as a specialized occupation. Most vinegar-making then was concentrated in what is now [[Shanxi|Shanxi province]] near the city of [[Taiyuan]], which remains a famous vinegar-making region today. Many Chinese kinds of vinegar and their uses for culinary and medicinal purposes were written down in the agricultural manual ''[[Qimin Yaoshu]]'' (齊民要術).<ref name="Smith-2019" />


The Greeks and Romans frequently used vinegar made from wine. The Spartans had vinegar as a part of their traditional [[blood soup]] [[Black soup|''melas zomos'']]; in addition to flavoring the broth, the acidity of the vinegar prevented the blood from coagulating (a purpose for which vinegar is still used in modern blood soups around the world). The Roman [[Columella]] described the ingredients and process for making several types of vinegar in his work ''Res Rustica''.<ref name="Smith-2019" />
==Etymology==
The word ''vinegar'' arrived in [[Middle English]] from [[Old French]] ''vyn egre'', which in turn derives from [[Latin]] ''vinum'' (wine) + ''acer'' (sour).<ref>{{cite web|title=Definition of vinegar in English by Oxford Dictionaries|url=https://en.oxforddictionaries.com/definition/vinegar|website=Oxford Dictionaries}}</ref>


In the late Middle Ages, vinegar making was slowly being professionalized in Europe, with the French city of [[Orléans]] becoming particularly famous for the quality of its vinegar through a formalized fermentation and aging process, which became known as the Orléans process.<ref name="bourg" /><ref name="Smith-2019" /> During this time, [[malt]] vinegar also began to develop in England, where it was first known as ''alegar''.<ref>{{Cite journal |last=Smith |first=Reginald |date=2019 |title=From Alegar to Sarson's: A History of Malt Vinegar |journal=Petits Propos Culinaires |volume=113 |pages=95–119|doi=10.1558/ppc.27928 }}</ref> Balsamic vinegar also began its evolution in the [[Duchy of Modena and Reggio|Duchy of Modena]] in Italy, though it would not become widely known until the [[Napoleonic Wars]] after being sold abroad by French troops.<ref>{{cite book |doi=10.1007/978-3-319-13758-2 |title=Balsamic Vinegars |date=2015 |last1=Giudici |first1=Paolo |last2=Lemmetti |first2=Federico |last3=Mazza |first3=Stefano |isbn=978-3-319-13757-5 |s2cid=193305710 }}{{pn|date=February 2024}}</ref>
==History==
{{section-stub|date=February 2018}}
Vinegar was used as a condiment and for conservation by the [[Babylonia]]ns as much as 5,000 years ago.<ref name=VotW1>{{cite book|last1=Holzapfel|first1=Lisa Solieri, Paolo Giudici, editors ; preface by Wilhelm|title=Vinegars of the world|date=2009|publisher=Springer|location=Milan|isbn=9788847008663|pages=22–23|edition=Online-Ausg.|url=https://books.google.com/?id=XuPWgEMx_eIC&pg=PA38&dq=history+of+vinegar#v=onepage&q=history%20of%20vinegar&f=false|quote=Cleopatra dissolves pearls in vinegar [...] vinegar is quite often mentioned, is the Bible, both in the Old and in the New Testament.}}</ref> Traces of it also have been found in Egyptian urns from around 3000 [[Before Christ|BC]].{{citation needed|date=November 2016}}


In the 19th century, vinegar production underwent many dramatic changes, such as rapid industrialization and scientific analysis. Karl Sebastian Schüzenbach invented the first large-scale industrial process for vinegar production in the [[Baden|Kingdom of Baden]] in 1823.<ref name="Smith-2019" /> Known as the packed generator, it circulated alcohol over [[beech]]wood shavings to reduce fermentation times from several months down to 1–2 weeks. This process also facilitated the rise of vinegar made from pure alcohol called spirit vinegar or distilled white vinegar. Japan also began industrializing vinegar production during the last days of the [[Tokugawa shogunate]], when Matazaemon Nakano, a man from a traditional [[sake]] brewing family, discovered that sake [[Lees (fermentation)|lees]] could be used to make rice vinegar. This helped provide ample vinegar for the burgeoning popularity of [[sushi]] in Japan. The company he founded, now known as [[Mizkan]], is headquartered in [[Handa, Aichi|Handa]] (near Nagoya) and is the largest vinegar producer in the world.<ref name="Smith-2019" />
== Varieties ==
{{refimprove|section|date=March 2018}}


Meanwhile, vinegar fermentation became understood as a natural and biological process. [[Louis Pasteur]] made the decisive discovery that a special type of bacteria, later known as [[acetic acid bacteria]], was the agent of fermentation for vinegar production.<ref>{{cite journal |last1=Berche |first1=P. |date=October 2012 |title=Louis Pasteur, from crystals of life to vaccination |journal=Clinical Microbiology and Infection |volume=18 |pages=1–6 |doi=10.1111/j.1469-0691.2012.03945.x |pmid=22882766 |doi-access=free}}</ref>
Source materials for making vinegar are varied, including different fruits, grains, [[alcoholic beverage]]s or other [[fermentation|fermentable]] materials.

In the 20th century, vinegar production was again revolutionized by the invention of the [[solid-state fermentation|submerged fermentation process]] that cut production times down to 1–2 days.<ref>{{Cite journal |last1=Yun |first1=Jeong Hyun |last2=Kim |first2=Jae Ho |last3=Lee |first3=Jang-Eun |date=2019-04-03 |title=Surface Film Formation in Static-Fermented Rice Vinegar: A Case Study |url= |journal=Mycobiology |volume=47 |issue=2 |pages=250–255 |doi=10.1080/12298093.2019.1575585 |issn=1229-8093 |pmc=6691759 |pmid=31448145}}</ref> This allowed the mass production of cheap vinegar around the world.

== Chemistry ==
The conversion of [[ethanol]] ({{chem2|CH3CH2OH}}) and [[oxygen]] ({{chem2|O2}}) to [[acetic acid]] ({{chem2|CH3COOH}}) takes place by the following reaction:<ref>{{cite book |last1=Saladin |first1=Kenneth S. |last2=Sullivan |first2=Stephen J. |last3=Gan |first3=Christina A. |title=Anatomy and Physiology: The Unity of Form and Function |date=2015 |publisher=McGraw-Hill Education |isbn=978-981-4646-43-7 |page=55 }}</ref>

:<chem>CH3CH2OH + O2 -> CH3COOH + H2O</chem>

===Polyphenols===
Vinegar contains numerous [[flavonoid]]s, [[phenolic acid]]s, and [[aldehyde]]s,<ref>{{cite journal |last1=Cerezo |first1=Ana B. |last2=Tesfaye |first2=Wendu |last3=Torija |first3=M. Jesús |last4=Mateo |first4=Estíbaliz |last5=García-Parrilla |first5=M. Carmen |last6=Troncoso |first6=Ana M. |title=The phenolic composition of red wine vinegar produced in barrels made from different woods |journal=Food Chemistry |date=August 2008 |volume=109 |issue=3 |pages=606–615 |doi=10.1016/j.foodchem.2008.01.013 }}</ref> which vary in content depending on the source material used to make the vinegar, such as [[orange peel]] or various [[fruit juice concentrate]]s.<ref>{{cite journal |last1=Cejudo-Bastante |first1=Cristina |last2=Castro-Mejías |first2=Remedios |last3=Natera-Marín |first3=Ramón |last4=García-Barroso |first4=Carmelo |last5=Durán-Guerrero |first5=Enrique |title=Chemical and sensory characteristics of orange based vinegar |journal=Journal of Food Science and Technology |date=August 2016 |volume=53 |issue=8 |pages=3147–3156 |doi=10.1007/s13197-016-2288-7 |pmc=5055879 |pmid=27784909 }}</ref><ref>{{cite journal |last1=Coelho |first1=Eduardo |last2=Genisheva |first2=Zlatina |last3=Oliveira |first3=José Maria |last4=Teixeira |first4=José António |last5=Domingues |first5=Lucília |title=Vinegar production from fruit concentrates: effect on volatile composition and antioxidant activity |journal=Journal of Food Science and Technology |date=November 2017 |volume=54 |issue=12 |pages=4112–4122 |doi=10.1007/s13197-017-2783-5 |pmc=5643795 |pmid=29085154 }}</ref>

== Production ==
{{main|Acetic acid#Production}}
Commercial vinegar is produced either by a fast or a slow fermentation process. In general, slow methods are used in traditional vinegars, where fermentation proceeds over the course of a few months to a year. The longer fermentation period allows for the accumulation of a nontoxic slime composed of acetic acid bacteria and their cellulose [[biofilm]], known as [[mother of vinegar]].

Fast methods add the aforementioned mother of vinegar as a [[bacterial culture]] to the source liquid before adding air to oxygenate and promote the fastest fermentation. In fast production processes, vinegar may be produced in 1–3 days.

== Varieties ==
The source materials for making vinegar are varied – different fruits, grains, [[alcoholic beverage]]s, and other fermentable materials are used.<ref name=harvard/>


===Fruit===
===Fruit===
[[File:Persimmonvinegar.jpg|thumb|upright|[[Persimmon]] vinegar produced in South Korea]]
[[File:Raisinvinegar.jpg|thumb|left|upright|[[Raisin]] vinegar]]
[[File:Raisinvinegar.jpg|thumb|left|upright|Raisin vinegar]]


Fruit vinegars are made from [[fruit wine]]s, usually without any additional flavoring. Common flavors of fruit vinegar include apple, [[blackcurrant]], raspberry, [[quince]], and tomato. Typically, the flavors of the original fruits remain in the final product. Most fruit vinegars are produced in Europe, where there is a growing market for high-price vinegars made solely from specific fruits (as opposed to non-fruit vinegars that are infused with fruits or fruit flavors).<ref>{{cite web
Fruit vinegars are made from [[fruit wine]]s, usually without any additional flavoring. Common flavors of fruit vinegar include [[apple]], [[blackcurrant]], [[raspberry]], [[quince]], and [[tomato]]. Typically, the flavors of the original fruits remain in the final product. Most fruit vinegars are produced in Europe, where a market exists for high-priced vinegars made solely from specific fruits (as opposed to nonfruit vinegars that are infused with fruits or fruit flavors).<ref>{{cite web
|url=http://www.vinegarbook.net/Fruit_vinegar.shtml
|url=http://www.vinegarbook.net/Fruit_vinegar.shtml
|title=What is Fruit Vinegar?
|title=What is Fruit Vinegar?
|work=vinegarbook.net
|work=vinegarbook.net
|access-date=10 June 2010
|accessdate=June 10, 2010}}</ref> Several varieties, however, also are produced in Asia. [[Persimmon vinegar]], called ''gam sikcho'', is popular in [[South Korea]]. [[Jujube]] vinegar, called ''zaocu'' or ''hongzaocu'', and [[wolfberry]] vinegar are produced in China.
|archive-date=26 June 2010
|archive-url=https://web.archive.org/web/20100626192157/http://www.vinegarbook.net/Fruit_vinegar.shtml
|url-status=live
}}</ref> Several varieties are produced in Asia. [[Persimmon vinegar]], called ''gam sikcho'', is common in [[South Korea]]. [[Jujube]] vinegar, called ''zaocu'' or ''hongzaocu'', and [[Goji|wolfberry]] vinegar are produced in China.[[File:Persimmonvinegar.jpg|thumb|upright|[[Persimmon]] vinegar produced in [[South Korea]]]] [[Apple cider vinegar]] is made from [[cider]] or apple [[must]], and has a brownish-gold color. It is sometimes sold [[Filtration|unfiltered]] and [[Pasteurization|unpasteurized]] with the [[mother of vinegar]] present. It can be diluted with fruit juice or water or sweetened (usually with honey) for consumption.


A byproduct of commercial [[kiwifruit]] growing is a large amount of waste in the form of [[Unusually shaped vegetable|misshapen or otherwise-rejected fruit]] (which may constitute up to 30% of the crop) and kiwifruit [[pomace]]. One of the uses for pomace is the production of kiwifruit vinegar, produced commercially in New Zealand since at least the early 1990s, and in China in 2008.<ref>{{cite web |url=http://www.apctt.org/publication/pdf/tm_dec_biotechnz.pdf |title=Biotechnology in New Zealand |access-date=2010-03-15 |archive-url=https://web.archive.org/web/20110717190104/http://www.apctt.org/publication/pdf/tm_dec_biotechnz.pdf |archive-date=2011-07-17 |url-status=dead}}</ref><ref>{{cite web |url=http://www.versatilevinegar.org/latestnews_2008_12.html |title=The Vinegar Institute |publisher=Versatilevinegar.org |date=2008-10-20 |access-date=2010-03-15 |archive-url=https://web.archive.org/web/20100329023350/http://www.versatilevinegar.org/latestnews_2008_12.html |archive-date=2010-03-29 |url-status=dead}}</ref>
[[Apple cider vinegar]] is made from [[cider]] or apple [[must]], and has a brownish-gold color. It is sometimes sold [[Filtration|unfiltered]] and [[Pasteurization|unpasteurized]] with the [[mother of vinegar]] present, as a natural product. It can be diluted with fruit juice or water or sweetened (usually with honey) for consumption.<ref>Sejo Regular del Vino y Brandy de Jerez (Council regulating the production of Jerezy wine and braef)</ref>


Vinegar made from [[raisin]]s is used in cuisines of the Middle East. It is cloudy and medium brown in color, with a mild flavor. Vinegar made from [[Phoenix dactylifera|dates]] is a traditional product of the [[Middle East]], and used in [[Eastern Arabian cuisine|Eastern Arabia]].<ref>{{cite journal | doi = 10.1021/ie50319a016 | title = Vinegar from Dates | year = 1936 | last1 = Das | first1 = Bhagwan | last2 = Sarin | first2 = J. L. | journal = Industrial & Engineering Chemistry | volume = 28 | issue = 7 | page = 814}}</ref><ref>{{cite journal |last1=Forbes |first1=Robert James |year=1971 |title=Studies in Ancient Technology, Volume 3 |url=https://books.google.com/books?id=Y84UAAAAIAAJ&pg=PA78 |url-status=live |journal=[[Brill Publishers]] |volume= |archive-url=https://web.archive.org/web/20230317154434/https://books.google.com/books?id=Y84UAAAAIAAJ&pg=PA78 |archive-date=17 March 2023 |access-date=8 January 2016}}</ref>
A byproduct of commercial [[kiwifruit]] growing is a large amount of waste in the form of misshapen or otherwise-rejected fruit (which may constitute up to 30 percent of the crop) and kiwifruit [[pomace]], the presscake residue left after kiwifruit juice manufacture. One of the uses for this waste is the production of kiwifruit vinegar, produced commercially in New Zealand since at least the early 1990s, and in China in 2008.<ref>{{cite web |url=http://www.apctt.org/publication/pdf/tm_dec_biotechnz.pdf |title=Biotechnology in New Zealand |format=PDF |date= |accessdate=2010-03-15 |archive-url=https://web.archive.org/web/20110717190104/http://www.apctt.org/publication/pdf/tm_dec_biotechnz.pdf |archive-date=2011-07-17 |dead-url=yes |df= }}</ref><ref>{{cite web |url=http://www.versatilevinegar.org/latestnews_2008_12.html |title=The Vinegar Institute |publisher=Versatilevinegar.org |date=2008-10-20 |accessdate=2010-03-15 |archive-url=https://web.archive.org/web/20100329023350/http://www.versatilevinegar.org/latestnews_2008_12.html |archive-date=2010-03-29 |dead-url=yes |df= }}</ref>


===Palm===
Pomegranate vinegar (Hebrew: חומץ רימונים) is used widely in [[Israel]] as a dressing for salad but also in meat stew and in dips.<ref>{{cite web|url=http://www.timesofisrael.com/the-poetic-goodness-of-pomegranates/|title=The poetic goodness of pomegranates|publisher=}}</ref> Vinegar made from raisins, called ''{{transl|ar|ALA-LC|khall ʻinab}}'' ({{lang-ar|خل عنب}} "grape vinegar") is used in cuisines of the Middle East, and is produced there. It is cloudy and medium brown in color, with a mild flavor.
[[File:Coconut Vinegar (8681608491).jpg|thumb|upright=0.7|Coconut vinegar from the Philippines]]


[[Coconut]] vinegar, made from fermented coconut sap or [[coconut water]], is used extensively in Southeast Asian cuisine (notably the Philippines, where it is known as ''[[sukang tuba]]''), as well as in some cuisines of [[India]] and [[Sri Lanka]], especially [[Goan cuisine]]. A cloudy, white liquid, it has a particularly sharp, acidic taste with a slightly yeasty note.<ref name="polistico">{{cite book |last1=Polistico |first1=Edgie |title=Philippine Food, Cooking, & Dining Dictionary |date=2017 |publisher=Anvil Publishing, Inc. |isbn=978-621-420-087-0 }}{{pn|date=February 2024}}</ref>
Vinegar made from [[Phoenix dactylifera|dates]] is a traditional product of the [[Middle East]].<ref>{{cite journal | doi = 10.1021/ie50319a016 | title = Vinegar from Dates | year = 1936 | last1 = Das | first1 = Bhagwan | last2 = Sarin | first2 = J. L. | journal = Industrial & Engineering Chemistry | volume = 28 | issue = 7 | page = 814}}</ref><ref>{{cite journal | url = https://books.google.com/books?id=Y84UAAAAIAAJ&pg=PA78#v=onepage&q&f=false | title = Studies in Ancient Technology | author1 = Forbes | first1 = Robert James | year = 1971}}</ref>

===Palm===
Coconut vinegar, made from fermented [[coconut water]] or sap, is used extensively in Southeast Asian cuisine (notably the Philippines, where it is known as ''[[sukang tuba]]''), as well as in some cuisines of [[India]] and [[Sri Lanka]], especially [[Goan cuisine]]. A cloudy white liquid, it has a particularly sharp, acidic taste with a slightly yeasty note.<ref name="polistico">{{cite book|author=Edgie Polistico|title =Philippine Food, Cooking, & Dining Dictionary|publisher =Anvil Publishing, Incorporated|year =2017|isbn =9786214200870|url =https://books.google.com.ph/books?id=iz8_DwAAQBAJ&dq=Arroz+caldo&source=gbs_navlinks_s}}</ref>


In the Philippines, there are other types of vinegar also made from palm sap. Like coconut vinegar, they are by-products of ''[[tubâ]]'' (palm wine) production. The two of the most widely produced are [[nipa palm vinegar]] (''sukang nipa'' or ''sukang sasa'') and [[kaong palm vinegar]] (''sukang kaong'' or ''sukang irok''). Along with coconut and cane vinegar, they are the four main traditional vinegar types in the Philippines and are an important part of [[Filipino cuisine]].<ref name="hosking">{{cite book|author=Lim-Castillo, Pia|editor =Hosking, Richard|title =Authenticity in the Kitchen|chapter =Traditional Philippine Vinegars and their Role in Shaping the Culinary Culture|publisher =Prospect Books|series =Proceedings of the Oxford Symposium on Food and Cookery 2005|year =2006|page=296&ndash;298|isbn =9781903018477|url =https://books.google.com.ph/books?id=HflTVd898PAC&printsec=frontcover#v=onepage&q&f=false}}</ref> Nipa palm vinegar is made from the leaf stalks of [[nipa palm]]. It has a citrusy flavor note to it and imparts a distinctly musky aroma.<ref>{{cite web|last=Lumpia |first=Burnt |url=http://burntlumpiablog.com/2009/05/suka-filipino-vinegar.html |title=I’m Gonna Git You Suka (Filipino Vinegar) |publisher=Burntlumpiablog.com |date=2009-05-17 |accessdate=2015-01-03}}</ref><ref name="polistico">{{cite book|author=Edgie Polistico|title =Philippine Food, Cooking, & Dining Dictionary|publisher =Anvil Publishing, Incorporated|year =2017|isbn =9786214200870|url =https://books.google.com.ph/books?id=iz8_DwAAQBAJ&dq=Arroz+caldo&source=gbs_navlinks_s}}</ref> [[Kaong palm vinegar]] is made from the flower stalks of the [[kaong palm]]. It is sweeter than all the other Philippine vinegar types and are commonly used in salad dressing.<ref name="hosking"/> Vinegar from the [[Corypha|buri palm]] sap is also produced, but not the same prevalence as coconut, nipa, and kaong vinegars. <ref name="dagoon">{{cite book |last1=Dagoon |first1=Jesse D. |title=Applied nutrition and food technology |date=1989 |publisher=Rex Book Store |isbn=9789712305054 |page=273}}</ref> Kaong palm vinegar is also produced in Indonesia and Malaysia, though it's not as prevalent as in the Philippines because the palm wine industry is not as widespread in these Muslim-majority countries.<ref>{{cite journal |last1=Siebert |first1=Stephen F. |title=Where There is no Beer: ''Arenga pinnata'' and Sagueir in Sulawesi, Indones |journal=Palms |date=1999 |volume=43 |issue=4 |pages=177-181 |url=http://www.palms.org/palmsjournal/1999/vol43n4p177-181.pdf |accessdate=23 December 2018}}</ref><ref name="Clove Garden">{{cite web |title=Toddy Palm - Sugar Palm |url=https://www.clovegarden.com/ingred/pm_toddy.html |website=Clove Garden |accessdate=23 December 2018}}</ref>
In the Philippines, other types of vinegar are made from palm sap. Like coconut vinegar, they are by-products of ''[[tubâ]]'' (palm wine) production. Two of the most widely produced are [[nipa palm vinegar]] (''sukang nipa'' or ''sukang sasa'') and [[kaong palm vinegar]] (''sukang kaong'' or ''sukang irok''). Along with coconut and cane vinegar, they are the four main traditional vinegar types in the Philippines and are an important part of [[Filipino cuisine]].<ref name="hosking">{{cite book |last1=Lim-Castillo |first1=Pia |chapter=Traditional Philippine Vinegars and their Role in Shaping the Culinary Culture |pages=295–306 |chapter-url=https://books.google.com/books?id=HflTVd898PAC&pg=PT295 |editor1-last=Hosking |editor1-first=Richard |title=Authenticity in the Kitchen: Proceedings of the Oxford Symposium on Food and Cookery 2005 |date=2006 |publisher=Oxford Symposium |isbn=978-1-903018-47-7 }}</ref> Nipa palm vinegar is made from the sap of the leaf stalks of [[nipa palm]]. Its flavor has notes of citrus and imparts a distinctly musky aroma.<ref>{{cite web |last=Lumpia |first=Burnt |url=http://burntlumpiablog.com/2009/05/suka-filipino-vinegar.html |title=I'm Gonna Git You Suka (Filipino Vinegar) |publisher=Burntlumpiablog.com |date=2009-05-17 |access-date=2015-01-03 |archive-date=4 January 2015 |archive-url=https://web.archive.org/web/20150104023426/http://burntlumpiablog.com/2009/05/suka-filipino-vinegar.html |url-status=live}}</ref><ref name="polistico"/> Kaong palm vinegar is made from the sap of flower stalks of the [[kaong palm]]. It is sweeter than all the other Philippine vinegar types and is commonly used in salad dressing.<ref name="hosking"/> Vinegar from the [[Corypha|buri palm]] sap is also produced, but not with the same prevalence as coconut, nipa, and kaong vinegars.<ref name="dagoon">{{cite book |last1=Dagoon |first1=Jesse D. |title=Applied Nutrition and Food Technology |date=1989 |publisher=Rex Bookstore, Inc. |isbn=978-971-23-0505-4 |page=273 }}</ref> Kaong palm vinegar is also produced in Indonesia and Malaysia, though it is not as prevalent as in the Philippines because the palm wine industry is not as widespread in these Muslim-majority countries.<ref>{{cite journal |last1=Siebert |first1=Stephen F. |title=Where there is no beer: ''Arenga pinnata'' and sagueir in Sulawesi, Indonesia |journal=Palms |volume=43 |issue=4 |date=1999 |pages=177–181 |url=https://palms.org/wp-content/uploads/2016/05/vol43n4.pdf }}</ref><ref name="Clove Garden">{{cite web |title=Toddy Palm Sugar Palm |url=https://www.clovegarden.com/ingred/pm_toddy.html |website=Clove Garden |access-date=23 December 2018 |archive-date=12 February 2018 |archive-url=https://web.archive.org/web/20180212065521/http://www.clovegarden.com/ingred/pm_toddy.html |url-status=live}}</ref>


=== Balsamic ===
=== Balsamic ===
{{Main article|Traditional Balsamic Vinegar|Balsamic vinegar}}
{{Main|Traditional Balsamic Vinegar|Balsamic vinegar}}
Balsamic vinegar is an aromatic aged vinegar produced in the [[Modena]] and [[Reggio Emilia]] provinces of Italy. The original product{{emdash}}Traditional Balsamic Vinegar{{emdash}}is made from the concentrated juice, or must, of white [[Trebbiano]] grapes. It is very dark brown, rich, sweet, and complex, with the finest grades being aged in successive casks made variously of oak, mulberry, chestnut, cherry, juniper, and ash wood. Originally a costly product available to only the Italian upper classes, traditional balsamic vinegar is marked "tradizionale" or "DOC" to denote its [[Protected Designation of Origin#Protected designation of origin|Protected Designation of Origin]] status, and is aged for 12 to 25 years. A cheaper non-DOC commercial form described as "aceto balsamico di Modena" (balsamic vinegar of Modena)<ref>{{cite web|url=http://www.bbcgoodfood.com/glossary/balsamic-vinegar|title=Balsamic vinegar|work=BBC Good Food}}</ref> became widely known and available around the world in the late 20th century, typically made with concentrated grape juice mixed with a strong vinegar, then coloured and slightly sweetened with caramel and sugar.
Balsamic vinegar is an aromatic, aged vinegar produced in the [[Modena]] and [[Reggio Emilia]] provinces of Italy. The original product — traditional balsamic vinegar — is made from the concentrated juice, or [[must]], of white [[Trebbiano]] grapes. It is dark brown, rich, sweet, and complex, with the finest grades being aged in successive casks made variously of oak, mulberry, chestnut, cherry, juniper, and ash wood. Originally a costly product available to only the Italian upper classes, traditional balsamic vinegar is marked ''tradizionale'' or "DOC" to denote its [[protected designation of origin]] status, and is aged for 12 to 25 years. A cheaper non-DOC commercial form described as ''aceto balsamico di Modena'' (balsamic vinegar of Modena)<ref>{{cite web|url=http://www.bbcgoodfood.com/glossary/balsamic-vinegar|title=Balsamic vinegar|work=BBC Good Food|access-date=16 March 2014|archive-date=16 March 2014|archive-url=https://web.archive.org/web/20140316213447/http://www.bbcgoodfood.com/glossary/balsamic-vinegar|url-status=live}}</ref> became widely known and available around the world in the late 20th century, typically made with concentrated grape juice mixed with a strong vinegar, then coloured and slightly sweetened with caramel and sugar.


Balsamic vinegar is made from a [[grape]] product. It contains no [[balsam]], though was traditionally aged in balsam as one of the steps. A high acidity level is somewhat hidden by the sweetness of the other ingredients, making it mellow. In terms of its nutrition content, balsamic vinegar contains the carbohydrates of grape sugars (some 17% of total composition), making it some five times higher in caloric content than typical distilled or wine vinegar.<ref name="ndbal">{{cite web|url=https://nutritiondata.self.com/facts/spices-and-herbs/9744/2|title=Nutrition facts for balsamic vinegar|date=2018|publisher=Nutritiondata.com, Conde Nast; from the US Department of Agriculture National Nutrient Database, standard reference 21|access-date=18 March 2019|archive-date=1 April 2019|archive-url=https://web.archive.org/web/20190401203327/https://nutritiondata.self.com/facts/spices-and-herbs/9744/2|url-status=live}}</ref>
Regardless of how it is produced, balsamic vinegar must be made from a grape product. It contains no [[balsam]] fruit. A high acidity level is somewhat hidden by the sweetness of the other ingredients, making it very mellow.


=== Cane ===
=== Cane ===
Vinegar made from [[sugarcane juice]] is most popular in the [[Philippines]], in particular in the northern [[Ilocos Region]] (where it is called ''sukang Iloko'' or ''sukang [[basi]]''), although it also is produced in France and the United States. It ranges from dark yellow to golden brown in color, and has a mellow flavor, similar in some respects to rice vinegar, though with a somewhat "fresher" taste. Because it contains no residual sugar, it is no sweeter than any other vinegar. In the Philippines it often is labeled as ''sukang maasim'' ([[Tagalog language|Tagalog]] for "sour vinegar").
Vinegar made from [[sugarcane juice]] is traditional to and is most popular in the [[Philippines]], in particular in the northern [[Ilocos Region]] (where it is called ''sukang Iloko'' or ''sukang [[basi]]''). It ranges from dark yellow to golden brown in color, and has a mellow flavor, similar in some respects to rice vinegar, though with a somewhat "fresher" taste. Because it contains no residual sugar, it is no sweeter than any other vinegar. In the Philippines, it often is labeled as ''sukang maasim'' ([[Tagalog language|Tagalog]] for "sour vinegar").


Cane vinegars from Ilocos are made in two different ways. One way is to simply place sugar cane juice in large jars; it becomes sour by the direct action of bacteria on the sugar. The other way is through fermentation to produce a local wine known as ''basi''. Low-quality ''basi'' is then allowed to undergo acetic acid fermentation that converts alcohol into acetic acid. Contaminated ''basi'' also becomes vinegar.
Cane vinegars from Ilocos are made in two different ways. One way is to simply place sugar cane juice in large jars; it becomes sour by the direct action of bacteria on the sugar. The other way is through fermentation to produce a traditional wine known as ''[[basi]]''. Low-quality ''basi'' is then allowed to undergo acetic acid fermentation that converts alcohol into acetic acid. Contaminated ''basi'' also becomes vinegar.


A white variation has become quite popular in Brazil in recent years, where it is the cheapest type of vinegar sold. It is now common for other types of vinegar (made from wine, rice and apple cider) to be sold mixed with cane vinegar to lower the cost.{{citation needed|date=May 2014}}
Cane vinegar is also produced in other countries, like France and the United States.<ref>{{Cite book |last=Bamforth |first=Charles W. |title=The Oxford Handbook of Food Fermentations |date=2014 |publisher=Oxford University Press, Incorporated |others=Robert E. Ward |isbn=978-0-19-974270-7 |edition=1st |series=Oxford Handbooks Series |location=Oxford |pages=376}}</ref> A white variation has become quite popular in Brazil in recent years, where it is the cheapest type of vinegar sold. It is now common for other types of vinegar (made from wine, rice, and apple cider) to be sold mixed with cane vinegar to lower the cost.{{citation needed|date=May 2014}}


Sugarcane sirka is made from sugarcane juice in Punjab, India. During summer people put cane juice in earthenware pots with iron nails. The fermentation takes place due to the action of wild yeast. The cane juice is converted to vinegar having a blackish color. The sirka is used to preserve pickles and for flavoring curries.
Sugarcane ''sirka'' is made from sugarcane juice in parts of northern India. During summer, people put cane juice in earthenware pots with iron nails. The fermentation takes place due to the action of wild yeast. The cane juice is converted to vinegar having a blackish color (from ferrous oxide and acetate). The ''sirka'' is used to preserve pickles and for flavoring curries.


===Grains===
===Grains===
{{vanchor|Malt}} vinegar made from [[ale]], also called "alegar",<ref name="od">{{cite web|url=https://en.oxforddictionaries.com/definition/alegar|archive-url=https://web.archive.org/web/20171214014610/https://en.oxforddictionaries.com/definition/alegar|url-status=dead|archive-date=14 December 2017|title=Alegar|publisher=Oxford Dictionaries, Oxford University Press|date=2018|access-date=2 March 2018}}</ref> is made by [[malting]] [[barley]], causing the starch in the grain to turn to [[maltose]]. Then an ale is [[Brewing|brewed]] from the maltose and allowed to turn into vinegar, which is then aged.<ref name=od /> It is typically light-brown in color. Malt vinegar (along with salt) is a traditional seasoning for [[fish and chips]], and in the United Kingdom and Canada, a popular seasoning for [[French fries]] in general. Some fish and chip shops replace it with [[non-brewed condiment]]. Salt and vinegar are combined as a common, traditional flavouring for [[Potato chip|crisps]];<ref>{{cite web |url=http://www.huffingtonpost.com/2012/04/20/joe-spud-murphy-the-man-w_n_1437270.html |title=Joe 'Spud' Murphy: The Man Who Gave Potato Chips Flavor |website=[[Huffington Post]] |date=20 April 2012 |author=<!--Staff writer(s); no by-line.--> |url-status=live |archive-url=https://web.archive.org/web/20141031011922/http://www.huffingtonpost.com/2012/04/20/joe-spud-murphy-the-man-w_n_1437270.html |archive-date=31 October 2014}}</ref><ref name="Wacky">{{cite news |title=31 Wacky and Weird Flavors of British Potato Crisps |url=http://www.bbcamerica.com/anglophenia/2013/04/british-crisps |access-date=4 July 2019 |agency=BBC America |archive-date=4 July 2019 |archive-url=https://web.archive.org/web/20190704140723/http://www.bbcamerica.com/anglophenia/2013/04/british-crisps |url-status=live}}</ref><ref name="Flavour variety">{{cite news |title=Walkers launches six new limited-edition crisp flavours to mark 70th anniversary |url=https://www.independent.co.uk/life-style/food-and-drink/walkers-limited-edition-crisp-flavours-launch-700th-anniversary-cheese-fondue-coronation-chicken-a8257701.html |archive-url=https://ghostarchive.org/archive/20220817/https://www.independent.co.uk/life-style/food-and-drink/walkers-limited-edition-crisp-flavours-launch-700th-anniversary-cheese-fondue-coronation-chicken-a8257701.html |archive-date=17 August 2022 |url-access=subscription |url-status=live |access-date=4 July 2019 |work=Independent}}</ref> in some varieties this involves the conversion of the vinegar to [[sodium acetate]] or [[sodium diacetate]], to avoid dampening the product in manufacture.<ref>{{Cite news|url=https://www.nytimes.com/2018/06/08/world/canada/the-secret-story-of-salt-and-vinegar-chips-the-canada-letter.html|title=The Secret Story of Salt and Vinegar Chips: the Canada Letter|first=Ian|last=Austen|newspaper=The New York Times|date=8 June 2018|access-date=23 December 2019|archive-date=23 December 2019|archive-url=https://web.archive.org/web/20191223190614/https://www.nytimes.com/2018/06/08/world/canada/the-secret-story-of-salt-and-vinegar-chips-the-canada-letter.html|url-status=live}}</ref>
[[File:Chinese Vinegar.jpg|thumb|Chinese black vinegar]]
[[File:黒酢.jpg|thumb|upright|Chinese [[black vinegar]]]]


Chinese [[Rice vinegar|black vinegar]] is an aged product made from rice, wheat, [[millet]], [[sorghum]], or a combination thereof. It has an inky black color and a complex, malty flavor. There is no fixed recipe, so some Chinese black vinegars may contain [[added sugar]], spices, or caramel color. The most popular variety, [[Zhenjiang vinegar]], originates in the city of [[Zhenjiang]] in [[Jiangsu Province]], eastern China.<ref>[http://news.asianweek.com/news/view_article.html?article_id=dcd86dc7c83d91f2079714cf8e3a053a AsianWeek.com] {{webarchive |url=https://web.archive.org/web/20080220130707/http://news.asianweek.com/news/view_article.html?article_id=dcd86dc7c83d91f2079714cf8e3a053a |date=February 20, 2008 }}</ref> Shanxi mature vinegar is another popular type of Chinese vinegar that is made exclusively from sorghum and other grains. Nowadays in Shanxi province, there are still some traditional vinegar workshops producing handmade vinegar which is aged for at least five years with a high acidity. Only the vinegar made in Taiyuan and some counties in Jinzhong and aged for at least three years is considered authentic Shanxi mature vinegar according to the latest national standard. A somewhat lighter form of black vinegar, made from rice, is produced in Japan, where it is called ''kurozu''.
Chinese [[black vinegar]] is an aged product made from [[rice]], [[wheat]], [[millet]], [[sorghum]], or a combination thereof. It has an inky black color and a complex, malty flavor. The recipe is not fixed, so some Chinese black vinegars may contain [[added sugar]], spices, or caramel color. The most popular variety, [[Zhenjiang vinegar]], originates in the city of [[Zhenjiang]] in [[Jiangsu Province]], eastern China.<ref>{{Cite web|url=http://news.asianweek.com/news/view_article.html?article_id=dcd86dc7c83d91f2079714cf8e3a053a|archive-url=https://web.archive.org/web/20080220130707/http://news.asianweek.com/news/view_article.html?article_id=dcd86dc7c83d91f2079714cf8e3a053a|url-status=dead|title=AsianWeek.com|archive-date=20 February 2008}}</ref> Shanxi mature vinegar is another popular type of Chinese vinegar that is made exclusively from sorghum and other grains. Nowadays in Shanxi province, some traditional vinegar workshops still produce handmade vinegar with a high acidity that is aged for at least five years. Only the vinegars made in Taiyuan and some counties in Jinzhong and aged for at least three years are considered authentic Shanxi mature vinegar according to the latest national standard. A somewhat lighter form of black vinegar, made from rice, is produced in Japan, where it is called ''kurozu''.

[[Rice vinegar]] is most popular in the cuisines of East and Southeast Asia. It is available in "white" (light yellow), red, and black varieties. The Japanese prefer a light rice vinegar for the preparation of [[Sushi#Shari|sushi rice]] and salad dressings. Red rice vinegar traditionally is colored with [[red yeast rice]]. Black rice vinegar (made with black glutinous rice) is most popular in China, and it is also widely used in other East Asian countries. White rice vinegar has a mild acidity with a somewhat "flat" and uncomplex flavor. Some varieties of rice vinegar are sweetened or otherwise seasoned with spices or other added flavorings.

{{vanchor|Malt}} vinegar made from [[ale]], also called ''alegar''<ref name="od">{{cite web|url=https://en.oxforddictionaries.com/definition/alegar|title=Alegar|publisher=Oxford Dictionaries, Oxford University Press|date=2018|accessdate=2 March 2018}}</ref>, is made by [[Malting process|malting]] [[barley]], causing the starch in the grain to turn to [[maltose]]. Then an [[ale]] is [[Brewing|brewed]] from the maltose and allowed to turn into vinegar, which is then aged.<ref name=od/> It is typically light-brown in color. In the United Kingdom and Canada, malt vinegar (along with salt) is a traditional seasoning for [[fish and chips]]. Some fish and chip shops replace it with [[non-brewed condiment]].

According to Canadian regulations, malt vinegar is defined as a vinegar that includes undistilled [[malt]] that has not yet undergone acetous fermentation. It must be dextro-rotary and cannot contain less than 1.8 grams of solids and 0.2 grams of ash per 100 millilitres at 20 degrees Celsius. It may contain additional cereals or caramel.<ref>{{cite web|url=http://laws-lois.justice.gc.ca/eng/regulations/c.r.c.,_c._870/page-74.html#h-113|title=Vinegar, Division 19|publisher=Justice Laws Website, Government of Canada|date=27 December 2017|accessdate=2 March 2018}}</ref>


[[Rice vinegar]] is most popular in the cuisines of East and Southeast Asia. It is available in "white" (light yellow), red, and black varieties. The Japanese prefer a light rice vinegar for the preparation of [[sushi rice]] and salad dressings. Red rice vinegar traditionally is colored with [[red yeast rice]]. Black rice vinegar (made with black glutinous rice) is most popular in China, and it is also widely used in other East Asian countries. White rice vinegar has a mild acidity with a somewhat "flat" and uncomplex flavor. Some varieties of rice vinegar are sweetened or otherwise seasoned with spices or other added flavorings.
{{Anchor|Spirit}}
=== Spirits ===
=== Spirits ===
[[File:Sherryvinegar.jpg|thumb|upright|[[Sherry vinegar]]]]
[[File:Sherryvinegar.jpg|thumb|upright|[[Sherry vinegar]]]]
The term "spirit vinegar" is sometimes reserved for the stronger variety (5% to 24%<ref>{{citation |asin=B072ZYZQHQ |title=Perstorps 24% Acetic Vinegar 300ml }}</ref> acetic acid) made from sugar cane or chemically produced acetic acid.<ref name="sinclair" /> To be called "spirit vinegar", the product must come from an agricultural source and must be made by "double fermentation". The first fermentation is sugar to alcohol, and the second is alcohol to acetic acid. Products made from synthetically produced acetic acid cannot be called "vinegar" in the UK, where the term allowed is "[[non-brewed condiment]]".


[[Sherry vinegar]] is linked to the production of [[sherry]] wines of [[Jerez]]. Dark mahogany in color, it is made exclusively from the acetic fermentation of wines. It is concentrated and has generous aromas, including a note of wood, ideal for vinaigrettes and flavoring various foods.<ref>{{cite book |last1=Clutton |first1=Angela |title=The Vinegar Cupboard: Winner of the Fortnum & Mason Debut Cookery Book Award |date=2019 |publisher=Bloomsbury Publishing |isbn=978-1-4729-5809-9 |oclc=1100963349 }}{{pn|date=February 2024}}</ref> '''Wine vinegar''' is made from red or white wine, and is the most commonly used vinegar in [[Southern Europe|Southern]] and [[Central Europe]], [[Cyprus]], and [[Israel]]. As with wine, the range in quality is considerable. Better-quality wine vinegars are matured in wood for up to two years, and exhibit a complex, mellow flavor. Wine vinegar tends to have a lower acidity than white or cider vinegar. More expensive wine vinegars are made from individual varieties of wine, such as champagne, sherry, or pinot gris.
The term '''spirit vinegar''' is sometimes reserved for the stronger variety (5% to 21% acetic acid) made from sugar cane or from chemically produced acetic acid.<ref name="sinclair" /> To be called "Spirit Vinegar", the product must come from an agricultural source and must be made by "double fermentation". The first fermentation is sugar to alcohol and the second alcohol to acetic acid. Product made from chemically produced acetic acid cannot be called "vinegar" in the UK, where the term allowed is "[[Non-brewed condiment]]".


The term "distilled vinegar" as used in the United States (called "spirit vinegar" in the UK, "white vinegar" in Canada<ref>{{cite web|url=http://www.inspection.gc.ca/food/labelling/food-labelling-for-industry/list-of-ingredients-and-allergens/eng/1383612857522/1383612932341?chap=1|title=List of Ingredients and Allergens: Requirements; Exemptions, Prepackaged Products that Do Not Require a List of Ingredients; Standardized vinegars B.01.008(2)(g), FDR|publisher=Canadian Food Inspection Agency|date=29 July 2016|access-date=20 April 2017|archive-date=21 April 2017|archive-url=https://web.archive.org/web/20170421093214/http://www.inspection.gc.ca/food/labelling/food-labelling-for-industry/list-of-ingredients-and-allergens/eng/1383612857522/1383612932341?chap=1|url-status=live}}</ref>) is something of a misnomer because it is not produced by distillation, but by fermentation of distilled alcohol. The fermentate is diluted to produce a colorless solution of 5 to 8% acetic acid in water, with a pH of about 2.6. This is variously known as distilled spirit, "virgin" vinegar,<ref>{{cite book |doi=10.1016/S0065-2164(08)70125-4 |chapter=Newer Developments in Vinegar Manufacture |title=Advances in Applied Microbiology |date=1960 |last1=Allgeier |first1=Rudolph J. |last2=Hildebrandt |first2=Frank M. |volume=2 |pages=163–182 |pmid=13682571 |isbn=978-0-12-002602-9 }}</ref> or white vinegar, and is used in cooking, baking, meat preservation, and [[pickling]], as well as for medicinal, laboratory, and cleaning purposes.<ref name="sinclair">Sinclair C, ''International Dictionary of Food and Cooking'', Peter Collin Publishing, 1998 {{ISBN|0-948549-87-4}}{{Page needed|date=September 2010}}</ref> The most common starting material in some regions, because of its low cost, is barley [[malt]],<ref name="ind">{{cite web | url=https://www.independent.co.uk/arts-entertainment/food-bliss-and-vinegar-why-malt-makes-a-pretty-pickle-its-time-for-a-revival-of-a-very-british-1541895.html |archive-url=https://ghostarchive.org/archive/20220817/https://www.independent.co.uk/arts-entertainment/food-bliss-and-vinegar-why-malt-makes-a-pretty-pickle-its-time-for-a-revival-of-a-very-british-1541895.html |archive-date=17 August 2022 |url-access=subscription |url-status=live | title=Bliss and vinegar - why malt makes a pretty pickle: It's time for a revival of a very British condiment | publisher=The Independent, Independent Digital News & Media, London, UK | author= Bateman, Michael|date=2 May 2016 | access-date=2 September 2016}}</ref> or in the United States, corn. It is sometimes derived from petroleum.<ref>{{cite web |url=https://www.fda.gov/ICECI/ComplianceManuals/CompliancePolicyGuidanceManual/ucm074550.htm |title=CPG Sec. 555.100 Alcohol; Use of Synthetic Alcohol in Foods |publisher=Fda.gov |date=2014-09-18 |access-date=2015-01-03 |archive-date=22 April 2019 |archive-url=https://web.archive.org/web/20190422125429/https://www.fda.gov/ICECI/ComplianceManuals/CompliancePolicyGuidanceManual/ucm074550.htm |url-status=live}}</ref> Distilled vinegar is used predominantly for cooking, although in the UK it is used as an alternative to brown or light malt vinegar. White distilled vinegar can also be used for cleaning, and some types are sold specifically for this purpose.
[[Sherry vinegar]] is linked to the production of [[sherry]] wines of [[Jerez]]. Dark mahogany in color, it is made exclusively from the acetic fermentation of wines. It is concentrated and has generous aromas, including a note of wood, ideal for vinaigrettes and flavoring various foods. Wine vinegar is made from red or white wine, and is the most commonly used vinegar in [[Southern Europe|Southern]] and [[Central Europe]], [[Cyprus]] and [[Israel]]. As with wine, there is a considerable range in quality. Better-quality wine vinegars are matured in wood for up to two years, and exhibit a complex, mellow flavor. Wine vinegar tends to have a lower acidity than white or cider vinegars. More expensive wine vinegars are made from individual varieties of wine, such as champagne, sherry, or pinot gris.


== Culinary uses ==
The term "distilled vinegar" as used in the United States (called "spirit vinegar" in the UK, "white vinegar" in Canada<ref>{{cite web|url=http://www.inspection.gc.ca/food/labelling/food-labelling-for-industry/list-of-ingredients-and-allergens/eng/1383612857522/1383612932341?chap=1|title=List of Ingredients and Allergens: Requirements; Exemptions, Prepackaged Products that Do Not Require a List of Ingredients; Standardized vinegars B.01.008(2)(g), FDR|publisher=Canadian Food Inspection Agency|date=29 July 2016|accessdate=20 April 2017}}</ref>) is something of a misnomer because it is not produced by distillation but by fermentation of distilled alcohol. The fermentate is diluted to produce a colorless solution of 5% to 8% acetic acid in water, with a pH of about 2.6. This is variously known as distilled spirit, "virgin" vinegar,<ref>Allgeier RJ et al., ''Newer Developments in Vinegar Manufacture'', 1960 ("manufacture of white or spirit vinegar"), in Umbreit WW, ''Advances in Microbiology: Volume 2'', Elsevier/Academic Press Inc., {{ISBN|0-12-002602-3}}, accessed at Google Books 2009-04-22{{Page needed|date=September 2010}}</ref> or white vinegar, and is used in cooking, baking, meat preservation, and [[pickling]], as well as for medicinal, laboratory, and cleaning purposes.<ref name="sinclair">Sinclair C, ''International Dictionary of Food and Cooking'', Peter Collin Publishing, 1998 {{ISBN|0-948549-87-4}}{{Page needed|date=September 2010}}</ref> The most common starting material in some regions, because of its low cost, is [[malt]],<ref name="ind">{{cite web | url=https://www.independent.co.uk/arts-entertainment/food-bliss-and-vinegar-why-malt-makes-a-pretty-pickle-its-time-for-a-revival-of-a-very-british-1541895.html | title=Bliss and vinegar - why malt makes a pretty pickle: It's time for a revival of a very British condiment | publisher=The Independent, Independent Digital News & Media, London, UK | author= Bateman, Michael|date=2 May 2016 | accessdate=2 September 2016}}</ref> or in the United States, corn. It is sometimes derived from petroleum.<ref>{{cite web|url=http://www.fda.gov/ICECI/ComplianceManuals/CompliancePolicyGuidanceManual/ucm074550.htm |title=CPG Sec. 555.100 Alcohol; Use of Synthetic Alcohol in Foods |publisher=Fda.gov |date=2014-09-18 |accessdate=2015-01-03}}</ref> Distilled vinegar in the UK is produced by the distillation of malt to give a clear vinegar which maintains some of the malt flavour.<ref name=ind/> Distilled vinegar is used predominantly for cooking, although in Scotland it is used as an alternative to brown or light malt vinegar. White distilled vinegar can also be used for cleaning, and some is actually sold specifically for this purpose.
Vinegar is commonly used in [[food preparation]],<ref name=harvard/> in particular as [[pickling]] liquids, [[vinaigrette]]s, and other [[salad dressing]]s. It is an ingredient in [[sauce]]s, such as [[hot sauce]], mustard, ketchup, and mayonnaise. Vinegar is sometimes used in [[chutney]]s. It is often used as a [[condiment]] on its own, or as a part of other condiments. [[Marination|Marinades]] often contain vinegar. [[Soup]]s sometimes have vinegar added to them, as is the case with [[hot and sour soup]]. In terms of its [[shelf life]], vinegar's acidic nature allows it to last indefinitely without the use of [[refrigeration]]; it is essentially already "spoiled".<ref>{{cite web|title=Shelf Life of Vinegar|url=http://www.eatbydate.com/other/condiments/how-long-does-vinegar-last/|publisher=Eatbydate.com|access-date=10 October 2012|archive-date=3 October 2012|archive-url=https://web.archive.org/web/20121003210335/http://www.eatbydate.com/other/condiments/how-long-does-vinegar-last/|url-status=live}}</ref>


=== Kombucha ===
=== Beverages ===
[[File:Apple vinegar beverage 1.jpg|thumb|upright|A beverage made from apple vinegar in [[China]]]]
Kombucha vinegar is made from [[kombucha]], a symbiotic culture of [[yeast]] and bacteria. The bacteria produce a complex array of bacteria. Kombucha vinegar primarily is used to make a [[vinaigrette]], and is flavored by adding strawberries, blackberries, mint, or blueberries at the beginning of fermentation.
Several beverages are made using vinegar, for instance ''[[posca]]'' in [[ancient Rome]]. The [[Ancient Greece|ancient Greek]] drink ''[[oxymel]]'' is made from vinegar and honey, and ''[[sekanjabin]]'' is a traditional [[Persian cuisine|Persian drink]] similar to ''oxymel''. Other preparations, known colloquially as "[[Shrub (drink)|shrubs]]", range from simply mixing sugar water or honey water with small amounts of fruity vinegar, to making syrup by laying fruit or mint in vinegar <!-- essence --> for several days, then [[sieving]] off solid parts and adding considerable amounts of sugar. Some prefer to boil the "shrub" as a final step. These recipes have lost much of their popularity with the rise of [[carbonated beverages]], such as soft drinks.


== Uses ==
===Diet and metabolism===
Preliminary research indicates that consuming 2–4 [[tablespoon]]s of vinegar may cause small reductions in post-meal levels of [[blood glucose]] and [[insulin]] in people with [[diabetes]].<ref>{{cite journal |last1=Shishehbor |first1=Farideh |last2=Mansoori |first2=Anahita |last3=Shirani |first3=Fatemeh |title=Vinegar consumption can attenuate postprandial glucose and insulin responses; a systematic review and meta-analysis of clinical trials |journal=Diabetes Research and Clinical Practice |date=May 2017 |volume=127 |pages=1–9 |doi=10.1016/j.diabres.2017.01.021 |pmid=28292654 }}</ref>


=== Culinary ===
===Nutrition===
Distilled or red wine vinegar is 95% water, with no [[fat]] or [[Protein (nutrient)|protein]].<ref name="nd">{{cite web|url=https://nutritiondata.self.com/facts/spices-and-herbs/7162/2|title=Nutrition facts for distilled vinegar|date=2018|publisher=Nutritiondata.com, Conde Nast; from the US Department of Agriculture National Nutrient Database, standard reference 21|access-date=18 March 2019|archive-date=1 April 2019|archive-url=https://web.archive.org/web/20190401192159/https://nutritiondata.self.com/facts/spices-and-herbs/7162/2|url-status=live}}</ref> In a {{convert|100|mL|USfloz|abbr=on|frac=2|adj=on}} reference amount, distilled vinegar supplies {{convert|18|kcal|kJ|order=flip|abbr=on}} of [[food energy]] and no [[micronutrient]]s in significant content.<ref name=nd/> The composition (and absence of nutrient content) for red wine vinegar and [[apple cider vinegar]] are the same, whereas [[balsamic vinegar]] is 77% water with 17% carbohydrates, {{convert|88|kcal|kJ|order=flip|abbr=on}} per 100&nbsp;mL, and contains no fat, protein, or micronutrients.<ref name="ndbal" />
Vinegar is commonly used in [[food preparation]], in particular [[pickling]] liquids, and [[Vinaigrette|vinaigrettes]] and other [[salad dressings]]. It is an ingredient in sauces, such as [[hot sauce]], mustard, ketchup, and mayonnaise. Vinegar is sometimes used in [[chutney]]s. It is often used as a [[condiment]] on its own or as part of other condiments. [[Marination|Marinades]] often contain vinegar. In terms of its [[shelf life]], vinegar's acidic nature allows it to last indefinitely without the use of refrigeration.<ref>{{cite web|title=Shelf Life of Vinegar|url=http://www.eatbydate.com/other/condiments/how-long-does-vinegar-last/|publisher=Eatbydate.com}}</ref>

==== Beverages ====
Several beverages are made using vinegar, for instance [[Posca]] in ancient Rome. The ancient Greek [[oxymel]] is a drink made from vinegar and honey, and [[sekanjabin]] is a traditional Persian drink similar to oxymel. Other preparations, known colloquially as "[[Shrub (drink)|shrubs]]", range from simply mixing sugar water or honey water with small amounts of fruity vinegar, to making syrup by laying fruit or mint in vinegar <!-- essence --> for several days, then sieving off solid parts, and adding considerable amounts of sugar. Some prefer to boil the "shrub" as a final step. These recipes have lost much of their popularity with the rise of carbonated beverages, such as soft drinks.

====Diet and metabolism====
Small amounts of vinegar (2 to 4 [[tablespoon]]s) may reduce post-meal levels of [[blood glucose]] and [[insulin]] in people with and without [[diabetes]].<ref name="harvard" /><ref>{{cite journal|author1=Shishehbor|first1=F|last2=Mansoori|first2=A|last3=Shirani|first3=F|year=2017|title=Vinegar consumption can attenuate postprandial glucose and insulin responses; a systematic review and meta-analysis of clinical trials|url=https://www.diabetesresearchclinicalpractice.com/article/S0168-8227(16)30851-8/fulltext|journal=Diabetes Research and Clinical Practice|volume=127|pages=1–9|doi=10.1016/j.diabres.2017.01.021|pmid=28292654}}</ref><ref>{{cite journal|last1=Liatis|first1=S|last2=Grammatikou|first2=S|last3=Poulia|first3=K-A|last4=Perrea|first4=D|last5=Makrilakis|first5=K|last6=Diakoumopoulou|first6=E|last7=Katsilambros|first7=N|year=2010|title=Vinegar reduces postprandial hyperglycaemia in patients with type II diabetes when added to a high, but not to a low, glycaemic index meal|journal=European Journal of Clinical Nutrition|volume=64|issue=7|pages=727|doi=10.1038/ejcn.2010.89|pmid=20502468}}</ref>


==Non-culinary uses==
===Folk medicine===
===Folk medicine===
Since antiquity, [[traditional medicine|folk medicine]] treatments have used vinegar, but no conclusive evidence from clinical research supports health claims of benefits for diabetes, weight loss, [[cancer]], or use as a [[probiotic]].<ref name=harvard/><ref>{{cite journal |last1=Budak |first1=Nilgün H. |last2=Aykin |first2=Elif |last3=Seydim |first3=Atif C. |last4=Greene |first4=Annel K. |last5=Guzel-Seydim |first5=Zeynep B. |title=Functional Properties of Vinegar |journal=Journal of Food Science |date=May 2014 |volume=79 |issue=5 |pages=R757-64 |doi=10.1111/1750-3841.12434 |pmid=24811350 }}</ref> A systematic review and meta-analysis later suggested it could help type 2 diabetics reduce insulin and glucose after meals.<ref>{{cite journal |last1=Cheng |first1=Ling Jie |last2=Jiang |first2=Ying |last3=Wu |first3=Vivien Xi |last4=Wang |first4=Wenru |title=A systematic review and meta-analysis: Vinegar consumption on glycaemic control in adults with type 2 diabetes mellitus |journal=Journal of Advanced Nursing |date=February 2020 |volume=76 |issue=2 |pages=459–474 |doi=10.1111/jan.14255 |pmid=31667860 |s2cid=204975904 }}</ref>


Applying vinegar to common [[jellyfish]] stings deactivates the [[nematocyst]]s, although not as effectively as hot water.<ref>{{cite journal |last1=Nomura |first1=Jason T. |last2=Sato |first2=Renee L. |last3=Ahern |first3=Reina M. |last4=Snow |first4=Joanne L. |last5=Kuwaye |first5=Todd T. |last6=Yamamoto |first6=Loren G. |title=A randomized paired comparison trial of cutaneous treatments for acute jellyfish (Carybdea alata) stings |journal=The American Journal of Emergency Medicine |date=November 2002 |volume=20 |issue=7 |pages=624–626 |doi=10.1053/ajem.2002.35710 |pmid=12442242 }}</ref> This also applies to the [[Portuguese man o' war]], which, although generally considered to be a jellyfish, is not (it is a [[Siphonophorae|siphonophore]]).<ref>{{cite web |url=https://www.hawaii.edu/news/2017/05/02/man-o-war-stings-first-aid/ |title=UH scientists scrutinize first aid for man o' war stings |date=2 May 2017 |publisher=hawaii.edu |access-date=2020-07-17 |archive-date=8 May 2021 |archive-url=https://web.archive.org/web/20210508132053/https://www.hawaii.edu/news/2017/05/02/man-o-war-stings-first-aid/ |url-status=live}}</ref>
For millennia, [[traditional medicine|folk medicine]] treatments have used vinegar, but there is no evidence from [[clinical research]] to support [[health claim]]s of benefits for [[diabetes]], [[weight loss]], [[cancer]] or use as a [[probiotic]].<ref name="harvard">{{cite web|title=Vinegar|url=https://www.hsph.harvard.edu/nutritionsource/vinegar/|publisher=TH Chan School of Public Health, Harvard University|accessdate=26 May 2018|date=2018}}</ref> Some treatments with vinegar pose risks to health.<ref name="Johnston">{{cite journal |first1=Carol S. |last1=Johnston |first2=Cindy A. |last2=Gaas |title=Vinegar: medicinal uses and antiglycemic effect |journal=MedGenMed |volume=8 |issue=2 |page=61 |year=2006 |pmid=16926800 |pmc=1785201 |url=http://www.medscape.com/viewarticle/531649}}</ref> [[Esophagus|Esophageal]] injury by [[apple cider vinegar]] has been reported, and because vinegar products sold for medicinal purposes are neither regulated nor standardized, such products may vary widely in content and [[acidity]].<ref name="pmid15983536">{{cite journal|last1=Hill|first1=L|last2=Woodruff|first2=L|last3=Foote|first3=J|last4=Barreto-Alcoba|first4=M|year=2005|title=Esophageal Injury by Apple Cider Vinegar Tablets and Subsequent Evaluation of Products|journal=Journal of the American Dietetic Association|volume=105|issue=7|pages=1141–4|doi=10.1016/j.jada.2005.04.003|pmid=15983536}}</ref>

=== Pests ===
Twenty percent acetic acid vinegar can be used as a [[herbicide]],<ref>{{cite web|url=http://ars.usda.gov/is/pr/2002/020515.htm|title=Spray Weeds With Vinegar?|date=|publisher=Ars.usda.gov|accessdate=2010-03-15}}</ref> but acetic acid is not absorbed into root systems so the vinegar will only kill the top growth and [[perennial plant]]s may reshoot.<ref>{{cite web|url=http://www.cahe.nmsu.edu/CES/yard/2004/041004.html|title=Vinegar as herbicide|date=2004-04-10|publisher=Cahe.nmsu.edu|accessdate=2010-03-15|archive-url=https://web.archive.org/web/20080504131319/http://www.cahe.nmsu.edu/CES/yard/2004/041004.html|archive-date=2008-05-04|dead-url=yes|df=}}</ref>


Some treatments with vinegar pose risks to health.<ref name="Johnston">{{cite journal |last1=Johnston |first1=Carol S. |last2=Gaas |first2=Cindy A. |title=Vinegar: Medicinal Uses and Antiglycemic Effect |journal=Medscape General Medicine |date=30 May 2006 |volume=8 |issue=2 |pages=61 |pmid=16926800 |pmc=1785201 }}</ref> [[Esophagus|Esophageal]] injury by apple cider vinegar has been reported, and because vinegar products sold for medicinal purposes are neither regulated nor standardized, such products may vary widely in content and acidity.<ref name="pmid15983536">{{cite journal |last1=Hill |first1=Laura L. |last2=Woodruff |first2=Logan H. |last3=Foote |first3=Jerald C. |last4=Barreto-Alcoba |first4=Morela |title=Esophageal Injury by Apple Cider Vinegar Tablets and Subsequent Evaluation of Products |journal=Journal of the American Dietetic Association |date=July 2005 |volume=105 |issue=7 |pages=1141–1144 |doi=10.1016/j.jada.2005.04.003 |pmid=15983536 }}</ref>
Applying vinegar to common [[jellyfish]] stings deactivates the [[nematocyst]]s, although not as effectively as hot water.<ref>{{cite journal |last1=Nomura |first1=J |last2=Sato |first2=RL |last3=Ahern |first3=RM |last4=Snow |first4=JL |last5=Kuwaye |first5=TT |last6=Yamamoto |first6=LG |title=A randomized paired comparison trial of cutaneous treatments for acute jellyfish (Carybdea alata) stings |journal=The American Journal of Emergency Medicine |volume=20 |issue=7 |pages=624–6 |year=2002 |pmid=12442242 |doi=10.1053/ajem.2002.35710}}</ref> This does not apply to the [[Portuguese man o' war]], which, although generally considered to be a jellyfish, is not; vinegar applied to Portuguese man o' war stings can cause their nematocysts to discharge venom, making the pain worse.<ref>{{cite web|url=http://www.cinemaquatics.co.uk/portuguesesaladdressing.html |title=Portuguese Man 'o Wars and their sting treatment |publisher=Cinemaquatics.co.uk |date= |accessdate=2010-03-15}}</ref>


=== Cleaning ===
Vinegar is not effective against [[lice]].<ref>{{cite journal |last1=Takanolee |first1=M |last2=Edman |first2=J |last3=Mullens |first3=B |last4=Clark |first4=J |title=Home Remedies to Control Head Lice Assessment of Home Remedies to Control the Human Head Louse, Pediculus humanus capitis (Anoplura: Pediculidae) |journal=Journal of Pediatric Nursing |volume=19 |issue=6 |pages=393–8 |year=2004 |pmid=15637580 |doi=10.1016/j.pedn.2004.11.002}}</ref>
White vinegar is often used as a household cleaning agent.<ref name=harvard/> For most uses, dilution with water is recommended for safety and to avoid damaging the surfaces being cleaned. Because it is acidic, it can dissolve [[Mineral Deposits|mineral deposits]] from glass, [[coffee maker]]s, and other smooth surfaces.<ref>[http://www.ene.gov.on.ca/en/myenvironment/home/cleaningproducts.php "My Environment: Cleaning Products"] {{Webarchive|url=https://web.archive.org/web/20100401232858/http://www.ene.gov.on.ca/en/myenvironment/home/cleaningproducts.php |date=1 April 2010}}, Ontario Ministry of the Environment</ref> Vinegar is known as an effective cleaner of [[stainless steel]] and glass. Malt vinegar sprinkled onto crumpled newspaper is a traditional, and still-popular, method of cleaning grease-smeared windows and mirrors in the United Kingdom.<ref>[https://www.bbc.co.uk/homes/housekeeping/bettystips_index.shtml "Trade Secrets: Betty's Tips"] {{Webarchive|url=https://web.archive.org/web/20221120143316/https://www.bbc.co.uk/homes/housekeeping/bettystips_index.shtml |date=20 November 2022}}, BBC/Lifestyle/Homes/Housekeeping. Retrieved 2009-04-22.</ref>


Vinegar can be used for [[Polishing (metalworking)|polishing]] copper, brass, bronze or silver. It is an excellent [[solvent]] for cleaning [[epoxy resin]] as well as the gum on sticker-type [[price tag]]s. It has been reported as an effective [[drain cleaner]].<ref>{{cite web |url=http://www.rd.com/home/150-household-uses-for-vinegar |title=95+ Household Uses for Vinegar &#124; Reader's Digest |publisher=Rd.com |access-date=2015-01-03 |archive-date=25 March 2013 |archive-url=https://web.archive.org/web/20130325033936/http://www.rd.com/home/150-household-uses-for-vinegar/ |url-status=live}}</ref>
=== Household ===
[[White vinegar]] is often used as a household cleaning agent. For most uses, dilution with water is recommended for safety and to avoid damaging the surfaces being cleaned. Because it is acidic, it can dissolve [[Mineral Deposits|mineral deposits]] from glass, [[coffee maker]]s, and other smooth surfaces.<ref>[http://www.ene.gov.on.ca/en/myenvironment/home/cleaningproducts.php "My Environment: Cleaning Products"], Ontario Ministry of the Environment</ref> Vinegar is known as an effective cleaner of [[stainless steel]] and glass. [[Malt vinegar]] sprinkled onto crumpled newspaper is a traditional, and still-popular, method of cleaning grease-smeared windows and mirrors in the United Kingdom.<ref>[http://www.bbc.co.uk/homes/housekeeping/bettystips_index.shtml "Trade Secrets: Betty's Tips"], BBC/Lifestyle/Homes/Housekeeping. Retrieved 2009-04-22.</ref>


The use of vinegar in [[dishwasher]]s and [[washing machine]]s can cause damage to their rubber seals and hoses, leading to leaks. According to testing done by [[Consumer Reports]], vinegar is ineffective as a [[rinse aid]] and in removing hard-water film while used in a dishwasher. According to Brian Sansoni, chief spokesperson for the [[American Cleaning Institute]], vinegar "isn't very useful with stains that have already set into clothing, including food stains and bloodstains."<ref name="consumerreports">{{cite web |last1=Santanachote |first1=Perry |last2=Yao |first2=Daphne |title=9 Things You Should Never Clean With Vinegar |url=https://www.consumerreports.org/home-garden/cleaning/things-you-should-never-clean-with-vinegar-distilled-white-vinegar-a3336471803/ |website=consumerreports.org |publisher=[[Consumer Reports]] |access-date=30 March 2023 |date=5 February 2020}}</ref><ref>{{cite web |title=How to clean your LG Washing Machine: 15 things you should know |url=https://www.lg.com/uk/lg-experience/helpful-hints/how-to-clean-washing-machine |website=lg.com |publisher=LG Electronics |access-date=30 March 2023 |quote=Make sure not to do this too frequently, especially near the seal of the machine as the vinegar can corrode the rubber seal.}}</ref> Other household items and surfaces that can be damaged by vinegar include flooring, stone countertops, knives, the screens of electronic devices, clothes iron water tanks, and rubber components of various [[small appliance]]s. Common metals that can be damaged by vinegar include aluminum, copper, and lower-quality grades of stainless steel often used in small appliances.<ref name="consumerreports"/>
Vinegar can be used for [[Polishing of Metal|polishing]] copper, brass, bronze or silver. It is an excellent [[solvent]] for cleaning [[epoxy resin]] as well as the gum on sticker-type [[Price tag|price tags]]. It has been reported as an effective [[drain cleaner]].<ref>{{cite web|url=http://www.rd.com/home/150-household-uses-for-vinegar |title=95+ Household Uses for Vinegar &#124; Reader's Digest |publisher=Rd.com |date= |accessdate=2015-01-03}}</ref>


== Miscellaneous ==
===Herbicide===
Twenty percent acetic acid vinegar can be used as an [[herbicide]],<ref>{{cite web|url=http://ars.usda.gov/is/pr/2002/020515.htm|title=Spray Weeds With Vinegar?|publisher=Ars.usda.gov|access-date=2010-03-15|archive-date=11 June 2011|archive-url=https://web.archive.org/web/20110611043626/http://ars.usda.gov/is/pr/2002/020515.htm|url-status=live}}</ref> but acetic acid is not absorbed into root systems so the vinegar will only kill the top growth and [[perennial plant]]s may reshoot.<ref>{{cite web|url=http://www.cahe.nmsu.edu/CES/yard/2004/041004.html|title=Vinegar as herbicide|date=2004-04-10|publisher=Cahe.nmsu.edu|access-date=2010-03-15|archive-url=https://web.archive.org/web/20080504131319/http://www.cahe.nmsu.edu/CES/yard/2004/041004.html|archive-date=2008-05-04|url-status=dead}}</ref>
Most commercial vinegar solutions available to consumers for household use do not exceed 5%. Solutions above 10% require careful handling, as they are corrosive and damaging to the skin.<ref>{{cite web|url=http://www.hort.purdue.edu/ext/vinegar.html |title=Conquer Weeds with Vinegar? |publisher=Hort.purdue.edu |date=2006-03-24 |accessdate=2010-03-15}}</ref>


== Reactions, byproducts and contaminants ==
When a bottle of vinegar is opened, [[mother of vinegar]] may develop. It is considered harmless and can be removed by filtering.<ref>{{cite web |url=http://www.reinhartfoods.com/vinegarstats.asp |title=Vinegar Information |publisher=Reinhart Foods |date=2004-01-01 |accessdate=2013-06-23 |archive-url=https://web.archive.org/web/20121228054431/http://www.reinhartfoods.com/vinegarstats.asp |archive-date=2012-12-28 |dead-url=yes |df= }}</ref>
Most commercial vinegar solutions available to consumers for household use do not exceed 5%.{{cn|date=March 2024}} Solutions above 10% require careful handling, as they are corrosive and damaging to the skin.<ref>{{cite web |url=http://www.hort.purdue.edu/ext/vinegar.html |title=Conquer Weeds with Vinegar? |publisher=Hort.purdue.edu |date=2006-03-24 |access-date=2010-03-15 |archive-date=26 October 2006 |archive-url=https://web.archive.org/web/20061026111425/http://www.hort.purdue.edu/ext/vinegar.html |url-status=live}}</ref>


When a bottle of vinegar is opened, [[mother of vinegar]] may develop. It is considered harmless and can be removed by filtering.<ref>{{cite web |url=http://www.reinhartfoods.com/vinegarstats.asp |title=Vinegar Information |publisher=Reinhart Foods |date=2004-01-01 |access-date=2013-06-23 |archive-url=https://web.archive.org/web/20121228054431/http://www.reinhartfoods.com/vinegarstats.asp |archive-date=2012-12-28 |url-status=dead}}</ref>
[[Vinegar eels]] (''Turbatrix aceti''), a form of [[nematode]], may occur in some forms of vinegar unless the vinegar is kept covered. These feed on the mother of vinegar and can occur in naturally fermenting vinegar.<ref name="autogenerated1">{{cite web|url=http://www.fda.gov/ICECI/ComplianceManuals/CompliancePolicyGuidanceManual/ucm074471.htm |title=FDA: Sec. 525.825 Vinegar, Definitions – Adulteration with Vinegar Eels (CPG 7109.22) |publisher=Food and Drug Administration |date=2009-07-27 |accessdate=2010-03-15}}</ref>


[[Vinegar eels]] (''Turbatrix aceti''), a form of [[nematode]], may occur in some forms of vinegar unless the vinegar is kept covered.{{cn|date=March 2024}} These feed on the mother of vinegar and can occur in naturally fermenting vinegar.<ref name="FDA-2009">{{cite web |url=https://www.fda.gov/ICECI/ComplianceManuals/CompliancePolicyGuidanceManual/ucm074471.htm |title=FDA: Sec. 525.825 Vinegar, Definitions – Adulteration with Vinegar Eels (CPG 7109.22) |publisher=Food and Drug Administration |date=2009-07-27 |access-date=2010-03-15 |archive-date=24 August 2017 |archive-url=https://web.archive.org/web/20170824074434/https://www.fda.gov/ICECI/ComplianceManuals/CompliancePolicyGuidanceManual/ucm074471.htm |url-status=live}}</ref>{{failed verification|date=March 2024}}
Some countries prohibit the selling of vinegar over a certain percentage acidity. As an example, the government of Canada limits the acetic acid of vinegars to between 4.1% and 12.3%.<ref>{{cite web|url=http://laws-lois.justice.gc.ca/PDF/C.R.C.,_c._870.pdf|title=Departmental Consolidation of the Food and Drugs Act and the Food and Drug Regulations – Part B – Division 19 |accessdate=2008-09-02 |publisher=Health Canada |date=March 2003}}</ref>


When [[baking soda]] and vinegar are combined, the [[bicarbonate]] ion of the baking soda reacts with acetic acid to form [[carbonic acid]], which [[Chemical decomposition|decomposes]] into carbon dioxide and water, completing the [[carbon cycle]]. [[Sodium acetate]] remains in solution with the water contained in the vinegar.<ref>{{Cite web|title=Kitchen Chemistry: The Chemical Reaction Powered Car|url=https://engineering.oregonstate.edu/momentum/k12/march04/index.html|website=engineering.oregonstate.edu|access-date=23 December 2019|archive-date=23 December 2019|archive-url=https://web.archive.org/web/20191223180609/https://engineering.oregonstate.edu/momentum/k12/march04/index.html|url-status=live}}</ref>
According to legend, in France during the [[Black Plague]], four thieves were able to rob houses of plague victims without being infected themselves. When finally caught, the judge offered to grant the men their freedom, on the condition that they revealed how they managed to stay healthy. They claimed that a medicine woman sold them a potion made of garlic soaked in soured red wine (vinegar). Variants of the recipe, called [[Four Thieves Vinegar]], have been passed down for hundreds of years and are a staple of [[New Orleans]] [[Hoodoo (folk magic)|hoodoo]] practices.<ref>{{cite book|last=Hunter|first=Robert|year=1894|title=The Encyclopaedic Dictionary|isbn=0-665-85186-3|publisher=T.J. Ford|location=Toronto}}{{Page needed|date=September 2010}}</ref><ref>{{cite book|last=Kacirk|first=Jeffery|year=2000|title=The Word Museum:The most remarkable English ever forgotten|publisher=Touchstone|isbn=0-684-85761-8}}{{Page needed|date=September 2010}}</ref>


== Regulation ==
A solution of vinegar can be used for [[water slide decal]] application as used on scale models and musical instruments, among other things. One part white distilled vinegar (5% acidity) diluted with two parts of distilled or filtered water creates a suitable solution for the application of water-slide decals to hard surfaces. The solution is very similar to the commercial products, often described as "decal softener", sold by hobby shops. The slight acidity of the solution softens the decal and enhances its flexibility, permitting the decal to cling to contours more efficiently.
Some countries have regulations on the permitted acidity percentage of vinegar. For example, the government of Canada limits acetic to between 4.1% and 12.3%, unless the vinegar is sold only for manufacturing use and identified as such.<ref>{{cite web |url=http://laws-lois.justice.gc.ca/PDF/C.R.C.,_c._870.pdf |title=Departmental Consolidation of the Food and Drugs Act and the Food and Drug Regulations – Part B – Division 19 |access-date=2008-09-02 |publisher=Health Canada |date=March 2003 |archive-date=10 April 2014 |archive-url=https://web.archive.org/web/20140410025000/http://laws-lois.justice.gc.ca/PDF/C.R.C.,_c._870.pdf |url-status=live}}</ref> In the United States, Australia, and New Zealand, vinegar must contain a minimum of 4% acetic acid by volume.<ref name="harvard">{{cite web |title=Vinegar |url=https://www.hsph.harvard.edu/nutritionsource/food-features/vinegar/ |publisher=TH Chan School of Public Health, Harvard University |access-date=4 March 2020 |date=1 October 2019 |archive-date=14 November 2022 |archive-url=https://web.archive.org/web/20221114123724/https://www.hsph.harvard.edu/nutritionsource/food-features/vinegar/ |url-status=live}}</ref><ref name="aus-law"/>


Many jurisdictions distinguish between brewed vinegar and preparations made with diluted acetic acid. The latter may not be sold as "vinegar" and is instead referred to as "[[non-brewed condiment]]" in the UK,<ref>{{cite book |title=Food Industries Manual |first1=M. D. |last1=Ranken |first2=R. C. |last2=Kill |edition=23 |year=2012 |page=328}}</ref> or "imitation vinegar" in Australia and New Zealand.<ref name="aus-law">{{cite web |title=Australia New Zealand Food Standards Code – Standard 2.10.1 – Vinegar and related products |url=https://www.legislation.gov.au/F2015L00484/latest/text |website=legislation.gov.au |publisher=Australian Government |access-date=19 March 2024 |date=2 April 2015}}</ref>
When [[baking soda]] and vinegar are combined, the [[bicarbonate]] ion of the baking soda reacts to form [[carbonic acid]], which [[Chemical decomposition|decomposes]] into carbon dioxide and water.<ref>http://engineering.oregonstate.edu/momentum/k12/march04/index.html</ref>


== See also ==
== See also ==
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* [[List of condiments]]
* [[List of condiments]]
* [[Vinegar tasters]]
* [[Vinegar tasters]]
* [[Vinegaroon]]


== References ==
== References ==
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== External links ==
== External links ==
* {{Commons category-inline}}
{{Commonscatinline}}
{{NSRW Poster}}
{{NSRW poster}}


{{Vinegar}}
{{Vinegar}}
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{{Authority control}}
{{Authority control}}
{{Use dmy dates|date=July 2019}}


[[Category:Vinegar| ]]
[[Category:Vinegar| ]]

Latest revision as of 12:20, 26 December 2024

A variety of flavored vinegars, for culinary use, on sale in France

Vinegar (from Old French vyn egre 'sour wine') is an aqueous solution of acetic acid and trace compounds that may include flavorings. Vinegar typically contains from 5% to 18% acetic acid by volume.[1] Usually, the acetic acid is produced by a double fermentation, converting simple sugars to ethanol using yeast and ethanol to acetic acid using acetic acid bacteria.[2] Many types of vinegar are made, depending on source materials. The product is now mainly used in the culinary arts as a flavorful, acidic cooking ingredient or in pickling. Various types are used as condiments or garnishes, including balsamic vinegar and malt vinegar.

As the most easily manufactured mild acid, it has a wide variety of industrial and domestic uses, including functioning as a household cleaner.[3]

Etymology

[edit]
Fast aerobic fermentation stainless steel vessels

The word "vinegar" arrived in Middle English from Old French (vyn egre; sour wine), which in turn derives from Latin: vīnum (wine) + ācre (neuter gender of ācer, sour).[3][4] Vinegar was formerly also called eisel.

The word "acetic" derives from Latin acētum (vinegar, or more properly vinum acetum: "wine turned sour").[5]

History

[edit]

While vinegar making may be as old as brewing, the first documented evidence of vinegar making and use was by the ancient Babylonians around 3000 BCE.[6] They primarily made vinegar from dates, figs, and beer and used it for both culinary and medicinal purposes. Traces of it also have been found in Egyptian urns. In East Asia, the Chinese began professionalizing vinegar production in the Zhou dynasty.[7] The book Zhou Li mentions that many noble or royal households had a "vinegar maker" as a specialized occupation. Most vinegar-making then was concentrated in what is now Shanxi province near the city of Taiyuan, which remains a famous vinegar-making region today. Many Chinese kinds of vinegar and their uses for culinary and medicinal purposes were written down in the agricultural manual Qimin Yaoshu (齊民要術).[7]

The Greeks and Romans frequently used vinegar made from wine. The Spartans had vinegar as a part of their traditional blood soup melas zomos; in addition to flavoring the broth, the acidity of the vinegar prevented the blood from coagulating (a purpose for which vinegar is still used in modern blood soups around the world). The Roman Columella described the ingredients and process for making several types of vinegar in his work Res Rustica.[7]

In the late Middle Ages, vinegar making was slowly being professionalized in Europe, with the French city of Orléans becoming particularly famous for the quality of its vinegar through a formalized fermentation and aging process, which became known as the Orléans process.[6][7] During this time, malt vinegar also began to develop in England, where it was first known as alegar.[8] Balsamic vinegar also began its evolution in the Duchy of Modena in Italy, though it would not become widely known until the Napoleonic Wars after being sold abroad by French troops.[9]

In the 19th century, vinegar production underwent many dramatic changes, such as rapid industrialization and scientific analysis. Karl Sebastian Schüzenbach invented the first large-scale industrial process for vinegar production in the Kingdom of Baden in 1823.[7] Known as the packed generator, it circulated alcohol over beechwood shavings to reduce fermentation times from several months down to 1–2 weeks. This process also facilitated the rise of vinegar made from pure alcohol called spirit vinegar or distilled white vinegar. Japan also began industrializing vinegar production during the last days of the Tokugawa shogunate, when Matazaemon Nakano, a man from a traditional sake brewing family, discovered that sake lees could be used to make rice vinegar. This helped provide ample vinegar for the burgeoning popularity of sushi in Japan. The company he founded, now known as Mizkan, is headquartered in Handa (near Nagoya) and is the largest vinegar producer in the world.[7]

Meanwhile, vinegar fermentation became understood as a natural and biological process. Louis Pasteur made the decisive discovery that a special type of bacteria, later known as acetic acid bacteria, was the agent of fermentation for vinegar production.[10]

In the 20th century, vinegar production was again revolutionized by the invention of the submerged fermentation process that cut production times down to 1–2 days.[11] This allowed the mass production of cheap vinegar around the world.

Chemistry

[edit]

The conversion of ethanol (CH3CH2OH) and oxygen (O2) to acetic acid (CH3COOH) takes place by the following reaction:[12]

Polyphenols

[edit]

Vinegar contains numerous flavonoids, phenolic acids, and aldehydes,[13] which vary in content depending on the source material used to make the vinegar, such as orange peel or various fruit juice concentrates.[14][15]

Production

[edit]

Commercial vinegar is produced either by a fast or a slow fermentation process. In general, slow methods are used in traditional vinegars, where fermentation proceeds over the course of a few months to a year. The longer fermentation period allows for the accumulation of a nontoxic slime composed of acetic acid bacteria and their cellulose biofilm, known as mother of vinegar.

Fast methods add the aforementioned mother of vinegar as a bacterial culture to the source liquid before adding air to oxygenate and promote the fastest fermentation. In fast production processes, vinegar may be produced in 1–3 days.

Varieties

[edit]

The source materials for making vinegar are varied – different fruits, grains, alcoholic beverages, and other fermentable materials are used.[3]

Fruit

[edit]
Raisin vinegar

Fruit vinegars are made from fruit wines, usually without any additional flavoring. Common flavors of fruit vinegar include apple, blackcurrant, raspberry, quince, and tomato. Typically, the flavors of the original fruits remain in the final product. Most fruit vinegars are produced in Europe, where a market exists for high-priced vinegars made solely from specific fruits (as opposed to nonfruit vinegars that are infused with fruits or fruit flavors).[16] Several varieties are produced in Asia. Persimmon vinegar, called gam sikcho, is common in South Korea. Jujube vinegar, called zaocu or hongzaocu, and wolfberry vinegar are produced in China.

Persimmon vinegar produced in South Korea

Apple cider vinegar is made from cider or apple must, and has a brownish-gold color. It is sometimes sold unfiltered and unpasteurized with the mother of vinegar present. It can be diluted with fruit juice or water or sweetened (usually with honey) for consumption.

A byproduct of commercial kiwifruit growing is a large amount of waste in the form of misshapen or otherwise-rejected fruit (which may constitute up to 30% of the crop) and kiwifruit pomace. One of the uses for pomace is the production of kiwifruit vinegar, produced commercially in New Zealand since at least the early 1990s, and in China in 2008.[17][18]

Vinegar made from raisins is used in cuisines of the Middle East. It is cloudy and medium brown in color, with a mild flavor. Vinegar made from dates is a traditional product of the Middle East, and used in Eastern Arabia.[19][20]

Palm

[edit]
Coconut vinegar from the Philippines

Coconut vinegar, made from fermented coconut sap or coconut water, is used extensively in Southeast Asian cuisine (notably the Philippines, where it is known as sukang tuba), as well as in some cuisines of India and Sri Lanka, especially Goan cuisine. A cloudy, white liquid, it has a particularly sharp, acidic taste with a slightly yeasty note.[21]

In the Philippines, other types of vinegar are made from palm sap. Like coconut vinegar, they are by-products of tubâ (palm wine) production. Two of the most widely produced are nipa palm vinegar (sukang nipa or sukang sasa) and kaong palm vinegar (sukang kaong or sukang irok). Along with coconut and cane vinegar, they are the four main traditional vinegar types in the Philippines and are an important part of Filipino cuisine.[22] Nipa palm vinegar is made from the sap of the leaf stalks of nipa palm. Its flavor has notes of citrus and imparts a distinctly musky aroma.[23][21] Kaong palm vinegar is made from the sap of flower stalks of the kaong palm. It is sweeter than all the other Philippine vinegar types and is commonly used in salad dressing.[22] Vinegar from the buri palm sap is also produced, but not with the same prevalence as coconut, nipa, and kaong vinegars.[24] Kaong palm vinegar is also produced in Indonesia and Malaysia, though it is not as prevalent as in the Philippines because the palm wine industry is not as widespread in these Muslim-majority countries.[25][26]

Balsamic

[edit]

Balsamic vinegar is an aromatic, aged vinegar produced in the Modena and Reggio Emilia provinces of Italy. The original product — traditional balsamic vinegar — is made from the concentrated juice, or must, of white Trebbiano grapes. It is dark brown, rich, sweet, and complex, with the finest grades being aged in successive casks made variously of oak, mulberry, chestnut, cherry, juniper, and ash wood. Originally a costly product available to only the Italian upper classes, traditional balsamic vinegar is marked tradizionale or "DOC" to denote its protected designation of origin status, and is aged for 12 to 25 years. A cheaper non-DOC commercial form described as aceto balsamico di Modena (balsamic vinegar of Modena)[27] became widely known and available around the world in the late 20th century, typically made with concentrated grape juice mixed with a strong vinegar, then coloured and slightly sweetened with caramel and sugar.

Balsamic vinegar is made from a grape product. It contains no balsam, though was traditionally aged in balsam as one of the steps. A high acidity level is somewhat hidden by the sweetness of the other ingredients, making it mellow. In terms of its nutrition content, balsamic vinegar contains the carbohydrates of grape sugars (some 17% of total composition), making it some five times higher in caloric content than typical distilled or wine vinegar.[28]

Cane

[edit]

Vinegar made from sugarcane juice is traditional to and is most popular in the Philippines, in particular in the northern Ilocos Region (where it is called sukang Iloko or sukang basi). It ranges from dark yellow to golden brown in color, and has a mellow flavor, similar in some respects to rice vinegar, though with a somewhat "fresher" taste. Because it contains no residual sugar, it is no sweeter than any other vinegar. In the Philippines, it often is labeled as sukang maasim (Tagalog for "sour vinegar").

Cane vinegars from Ilocos are made in two different ways. One way is to simply place sugar cane juice in large jars; it becomes sour by the direct action of bacteria on the sugar. The other way is through fermentation to produce a traditional wine known as basi. Low-quality basi is then allowed to undergo acetic acid fermentation that converts alcohol into acetic acid. Contaminated basi also becomes vinegar.

Cane vinegar is also produced in other countries, like France and the United States.[29] A white variation has become quite popular in Brazil in recent years, where it is the cheapest type of vinegar sold. It is now common for other types of vinegar (made from wine, rice, and apple cider) to be sold mixed with cane vinegar to lower the cost.[citation needed]

Sugarcane sirka is made from sugarcane juice in parts of northern India. During summer, people put cane juice in earthenware pots with iron nails. The fermentation takes place due to the action of wild yeast. The cane juice is converted to vinegar having a blackish color (from ferrous oxide and acetate). The sirka is used to preserve pickles and for flavoring curries.

Grains

[edit]

Malt vinegar made from ale, also called "alegar",[30] is made by malting barley, causing the starch in the grain to turn to maltose. Then an ale is brewed from the maltose and allowed to turn into vinegar, which is then aged.[30] It is typically light-brown in color. Malt vinegar (along with salt) is a traditional seasoning for fish and chips, and in the United Kingdom and Canada, a popular seasoning for French fries in general. Some fish and chip shops replace it with non-brewed condiment. Salt and vinegar are combined as a common, traditional flavouring for crisps;[31][32][33] in some varieties this involves the conversion of the vinegar to sodium acetate or sodium diacetate, to avoid dampening the product in manufacture.[34]

Chinese black vinegar

Chinese black vinegar is an aged product made from rice, wheat, millet, sorghum, or a combination thereof. It has an inky black color and a complex, malty flavor. The recipe is not fixed, so some Chinese black vinegars may contain added sugar, spices, or caramel color. The most popular variety, Zhenjiang vinegar, originates in the city of Zhenjiang in Jiangsu Province, eastern China.[35] Shanxi mature vinegar is another popular type of Chinese vinegar that is made exclusively from sorghum and other grains. Nowadays in Shanxi province, some traditional vinegar workshops still produce handmade vinegar with a high acidity that is aged for at least five years. Only the vinegars made in Taiyuan and some counties in Jinzhong and aged for at least three years are considered authentic Shanxi mature vinegar according to the latest national standard. A somewhat lighter form of black vinegar, made from rice, is produced in Japan, where it is called kurozu.

Rice vinegar is most popular in the cuisines of East and Southeast Asia. It is available in "white" (light yellow), red, and black varieties. The Japanese prefer a light rice vinegar for the preparation of sushi rice and salad dressings. Red rice vinegar traditionally is colored with red yeast rice. Black rice vinegar (made with black glutinous rice) is most popular in China, and it is also widely used in other East Asian countries. White rice vinegar has a mild acidity with a somewhat "flat" and uncomplex flavor. Some varieties of rice vinegar are sweetened or otherwise seasoned with spices or other added flavorings.

Spirits

[edit]
Sherry vinegar

The term "spirit vinegar" is sometimes reserved for the stronger variety (5% to 24%[36] acetic acid) made from sugar cane or chemically produced acetic acid.[37] To be called "spirit vinegar", the product must come from an agricultural source and must be made by "double fermentation". The first fermentation is sugar to alcohol, and the second is alcohol to acetic acid. Products made from synthetically produced acetic acid cannot be called "vinegar" in the UK, where the term allowed is "non-brewed condiment".

Sherry vinegar is linked to the production of sherry wines of Jerez. Dark mahogany in color, it is made exclusively from the acetic fermentation of wines. It is concentrated and has generous aromas, including a note of wood, ideal for vinaigrettes and flavoring various foods.[38] Wine vinegar is made from red or white wine, and is the most commonly used vinegar in Southern and Central Europe, Cyprus, and Israel. As with wine, the range in quality is considerable. Better-quality wine vinegars are matured in wood for up to two years, and exhibit a complex, mellow flavor. Wine vinegar tends to have a lower acidity than white or cider vinegar. More expensive wine vinegars are made from individual varieties of wine, such as champagne, sherry, or pinot gris.

The term "distilled vinegar" as used in the United States (called "spirit vinegar" in the UK, "white vinegar" in Canada[39]) is something of a misnomer because it is not produced by distillation, but by fermentation of distilled alcohol. The fermentate is diluted to produce a colorless solution of 5 to 8% acetic acid in water, with a pH of about 2.6. This is variously known as distilled spirit, "virgin" vinegar,[40] or white vinegar, and is used in cooking, baking, meat preservation, and pickling, as well as for medicinal, laboratory, and cleaning purposes.[37] The most common starting material in some regions, because of its low cost, is barley malt,[41] or in the United States, corn. It is sometimes derived from petroleum.[42] Distilled vinegar is used predominantly for cooking, although in the UK it is used as an alternative to brown or light malt vinegar. White distilled vinegar can also be used for cleaning, and some types are sold specifically for this purpose.

Culinary uses

[edit]

Vinegar is commonly used in food preparation,[3] in particular as pickling liquids, vinaigrettes, and other salad dressings. It is an ingredient in sauces, such as hot sauce, mustard, ketchup, and mayonnaise. Vinegar is sometimes used in chutneys. It is often used as a condiment on its own, or as a part of other condiments. Marinades often contain vinegar. Soups sometimes have vinegar added to them, as is the case with hot and sour soup. In terms of its shelf life, vinegar's acidic nature allows it to last indefinitely without the use of refrigeration; it is essentially already "spoiled".[43]

Beverages

[edit]
A beverage made from apple vinegar in China

Several beverages are made using vinegar, for instance posca in ancient Rome. The ancient Greek drink oxymel is made from vinegar and honey, and sekanjabin is a traditional Persian drink similar to oxymel. Other preparations, known colloquially as "shrubs", range from simply mixing sugar water or honey water with small amounts of fruity vinegar, to making syrup by laying fruit or mint in vinegar for several days, then sieving off solid parts and adding considerable amounts of sugar. Some prefer to boil the "shrub" as a final step. These recipes have lost much of their popularity with the rise of carbonated beverages, such as soft drinks.

Diet and metabolism

[edit]

Preliminary research indicates that consuming 2–4 tablespoons of vinegar may cause small reductions in post-meal levels of blood glucose and insulin in people with diabetes.[44]

Nutrition

[edit]

Distilled or red wine vinegar is 95% water, with no fat or protein.[45] In a 100 mL (3+12 US fl oz) reference amount, distilled vinegar supplies 75 kJ (18 kcal) of food energy and no micronutrients in significant content.[45] The composition (and absence of nutrient content) for red wine vinegar and apple cider vinegar are the same, whereas balsamic vinegar is 77% water with 17% carbohydrates, 370 kJ (88 kcal) per 100 mL, and contains no fat, protein, or micronutrients.[28]

Non-culinary uses

[edit]

Folk medicine

[edit]

Since antiquity, folk medicine treatments have used vinegar, but no conclusive evidence from clinical research supports health claims of benefits for diabetes, weight loss, cancer, or use as a probiotic.[3][46] A systematic review and meta-analysis later suggested it could help type 2 diabetics reduce insulin and glucose after meals.[47]

Applying vinegar to common jellyfish stings deactivates the nematocysts, although not as effectively as hot water.[48] This also applies to the Portuguese man o' war, which, although generally considered to be a jellyfish, is not (it is a siphonophore).[49]

Some treatments with vinegar pose risks to health.[50] Esophageal injury by apple cider vinegar has been reported, and because vinegar products sold for medicinal purposes are neither regulated nor standardized, such products may vary widely in content and acidity.[51]

Cleaning

[edit]

White vinegar is often used as a household cleaning agent.[3] For most uses, dilution with water is recommended for safety and to avoid damaging the surfaces being cleaned. Because it is acidic, it can dissolve mineral deposits from glass, coffee makers, and other smooth surfaces.[52] Vinegar is known as an effective cleaner of stainless steel and glass. Malt vinegar sprinkled onto crumpled newspaper is a traditional, and still-popular, method of cleaning grease-smeared windows and mirrors in the United Kingdom.[53]

Vinegar can be used for polishing copper, brass, bronze or silver. It is an excellent solvent for cleaning epoxy resin as well as the gum on sticker-type price tags. It has been reported as an effective drain cleaner.[54]

The use of vinegar in dishwashers and washing machines can cause damage to their rubber seals and hoses, leading to leaks. According to testing done by Consumer Reports, vinegar is ineffective as a rinse aid and in removing hard-water film while used in a dishwasher. According to Brian Sansoni, chief spokesperson for the American Cleaning Institute, vinegar "isn't very useful with stains that have already set into clothing, including food stains and bloodstains."[55][56] Other household items and surfaces that can be damaged by vinegar include flooring, stone countertops, knives, the screens of electronic devices, clothes iron water tanks, and rubber components of various small appliances. Common metals that can be damaged by vinegar include aluminum, copper, and lower-quality grades of stainless steel often used in small appliances.[55]

Herbicide

[edit]

Twenty percent acetic acid vinegar can be used as an herbicide,[57] but acetic acid is not absorbed into root systems so the vinegar will only kill the top growth and perennial plants may reshoot.[58]

Reactions, byproducts and contaminants

[edit]

Most commercial vinegar solutions available to consumers for household use do not exceed 5%.[citation needed] Solutions above 10% require careful handling, as they are corrosive and damaging to the skin.[59]

When a bottle of vinegar is opened, mother of vinegar may develop. It is considered harmless and can be removed by filtering.[60]

Vinegar eels (Turbatrix aceti), a form of nematode, may occur in some forms of vinegar unless the vinegar is kept covered.[citation needed] These feed on the mother of vinegar and can occur in naturally fermenting vinegar.[61][failed verification]

When baking soda and vinegar are combined, the bicarbonate ion of the baking soda reacts with acetic acid to form carbonic acid, which decomposes into carbon dioxide and water, completing the carbon cycle. Sodium acetate remains in solution with the water contained in the vinegar.[62]

Regulation

[edit]

Some countries have regulations on the permitted acidity percentage of vinegar. For example, the government of Canada limits acetic to between 4.1% and 12.3%, unless the vinegar is sold only for manufacturing use and identified as such.[63] In the United States, Australia, and New Zealand, vinegar must contain a minimum of 4% acetic acid by volume.[3][64]

Many jurisdictions distinguish between brewed vinegar and preparations made with diluted acetic acid. The latter may not be sold as "vinegar" and is instead referred to as "non-brewed condiment" in the UK,[65] or "imitation vinegar" in Australia and New Zealand.[64]

See also

[edit]

References

[edit]
  1. ^ "Acetic acid: general information". GOV.UK. Government Digital Service. Retrieved 19 March 2024.
  2. ^ Nakayama, Takeyoshi (September 1959). "Studies on acetic acid-bacteria I. Biochemical studies on ethanol oxidation". The Journal of Biochemistry. 46 (9): 1217–1225. doi:10.1093/oxfordjournals.jbchem.a127022.
  3. ^ a b c d e f g "Vinegar". TH Chan School of Public Health, Harvard University. 1 October 2019. Archived from the original on 14 November 2022. Retrieved 4 March 2020.
  4. ^ "Definition of vinegar in English by Oxford Dictionaries". Oxford Dictionaries. Archived from the original on 20 March 2018.
  5. ^ "acetic | Etymology, origin and meaning of acetic by etymonline". www.etymonline.com.
  6. ^ a b Bourgeois, Jacques; Barja, François (December 2009). "The history of vinegar and its acetification systems" (PDF). Archives des Sciences. 62 (2): 147–160. Archived (PDF) from the original on 28 January 2019. Retrieved 28 January 2019.
  7. ^ a b c d e f Smith, Reginald (2019). Vinegar, the Eternal Condiment. Southport, NC: Spikehorn Press. pp. 29–31. ISBN 978-1-943015-03-0.
  8. ^ Smith, Reginald (2019). "From Alegar to Sarson's: A History of Malt Vinegar". Petits Propos Culinaires. 113: 95–119. doi:10.1558/ppc.27928.
  9. ^ Giudici, Paolo; Lemmetti, Federico; Mazza, Stefano (2015). Balsamic Vinegars. doi:10.1007/978-3-319-13758-2. ISBN 978-3-319-13757-5. S2CID 193305710.[page needed]
  10. ^ Berche, P. (October 2012). "Louis Pasteur, from crystals of life to vaccination". Clinical Microbiology and Infection. 18: 1–6. doi:10.1111/j.1469-0691.2012.03945.x. PMID 22882766.
  11. ^ Yun, Jeong Hyun; Kim, Jae Ho; Lee, Jang-Eun (3 April 2019). "Surface Film Formation in Static-Fermented Rice Vinegar: A Case Study". Mycobiology. 47 (2): 250–255. doi:10.1080/12298093.2019.1575585. ISSN 1229-8093. PMC 6691759. PMID 31448145.
  12. ^ Saladin, Kenneth S.; Sullivan, Stephen J.; Gan, Christina A. (2015). Anatomy and Physiology: The Unity of Form and Function. McGraw-Hill Education. p. 55. ISBN 978-981-4646-43-7.
  13. ^ Cerezo, Ana B.; Tesfaye, Wendu; Torija, M. Jesús; Mateo, Estíbaliz; García-Parrilla, M. Carmen; Troncoso, Ana M. (August 2008). "The phenolic composition of red wine vinegar produced in barrels made from different woods". Food Chemistry. 109 (3): 606–615. doi:10.1016/j.foodchem.2008.01.013.
  14. ^ Cejudo-Bastante, Cristina; Castro-Mejías, Remedios; Natera-Marín, Ramón; García-Barroso, Carmelo; Durán-Guerrero, Enrique (August 2016). "Chemical and sensory characteristics of orange based vinegar". Journal of Food Science and Technology. 53 (8): 3147–3156. doi:10.1007/s13197-016-2288-7. PMC 5055879. PMID 27784909.
  15. ^ Coelho, Eduardo; Genisheva, Zlatina; Oliveira, José Maria; Teixeira, José António; Domingues, Lucília (November 2017). "Vinegar production from fruit concentrates: effect on volatile composition and antioxidant activity". Journal of Food Science and Technology. 54 (12): 4112–4122. doi:10.1007/s13197-017-2783-5. PMC 5643795. PMID 29085154.
  16. ^ "What is Fruit Vinegar?". vinegarbook.net. Archived from the original on 26 June 2010. Retrieved 10 June 2010.
  17. ^ "Biotechnology in New Zealand" (PDF). Archived from the original (PDF) on 17 July 2011. Retrieved 15 March 2010.
  18. ^ "The Vinegar Institute". Versatilevinegar.org. 20 October 2008. Archived from the original on 29 March 2010. Retrieved 15 March 2010.
  19. ^ Das, Bhagwan; Sarin, J. L. (1936). "Vinegar from Dates". Industrial & Engineering Chemistry. 28 (7): 814. doi:10.1021/ie50319a016.
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