Gadolinium(III) perchlorate: Difference between revisions
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'''Gadolinium(III) perchlorate''' is an [[inorganic compound]] with the chemical formula Gd(ClO<sub>4</sub>)<sub>3</sub>. It can be obtained by reacting [[gadolinium(III) oxide]] and [[perchloric acid]] (70~72%) at 80 °C.<ref name=jacs>{{cite journal|journal=Journal of the American Chemical Society|volume=139|issue=50|language=en|issn=0002-7863|date=2017-12-20|pages=18178–18181|doi=10.1021/jacs.7b11112|url=https://pubs.acs.org/doi/10.1021/jacs.7b11112|title=A Gigantic Molecular Wheel of {{(}}Gd 140 {{)}}: A New Member of the Molecular Wheel Family|accessdate=2023-03-15|author=Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng|archive-date=2023-03-15|archive-url=https://web.archive.org/web/20230315043932/https://pubs.acs.org/doi/10.1021/jacs.7b11112|url-status=live}}</ref> It can form colorless Gd(ClO<sub>4</sub>)<sub>3</sub>·9H<sub>2</sub>O·4C<sub>4</sub>H<sub>8</sub>O<sub>2</sub> complex crystals with [[1,4-dioxane]].<ref>{{Cite journal |last=Vicentini |first=Geraldo |last2=Perrier |first2=Madeleine |last3=Giesbrecht |first3=Ernesto |date=Apr 1961 |title=Notiz über die Reaktion von Dioxan mit Perchlorathydraten einiger Übergangselemente |url=http://dx.doi.org/10.1002/cber.19610940440 |journal=Chemische Berichte |volume=94 |issue=4 |pages=1153–1155 |doi=10.1002/cber.19610940440 |issn=0009-2940}}</ref> It reacts with [[inositol]], [[sodium acetate]], and [[sodium hydroxide]] to obtain complexes containing giant molecular clusters { |
'''Gadolinium(III) perchlorate''' is an [[inorganic compound]] with the chemical formula Gd(ClO<sub>4</sub>)<sub>3</sub>. It can be obtained by reacting [[gadolinium(III) oxide]] and [[perchloric acid]] (70~72%) at 80 °C.<ref name=jacs>{{cite journal|journal=Journal of the American Chemical Society|volume=139|issue=50|language=en|issn=0002-7863|date=2017-12-20|pages=18178–18181|doi=10.1021/jacs.7b11112|url=https://pubs.acs.org/doi/10.1021/jacs.7b11112|title=A Gigantic Molecular Wheel of {{(}}Gd 140 {{)}}: A New Member of the Molecular Wheel Family|accessdate=2023-03-15|author=Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng|archive-date=2023-03-15|archive-url=https://web.archive.org/web/20230315043932/https://pubs.acs.org/doi/10.1021/jacs.7b11112|url-status=live}}</ref> It can form colorless Gd(ClO<sub>4</sub>)<sub>3</sub>·9H<sub>2</sub>O·4C<sub>4</sub>H<sub>8</sub>O<sub>2</sub> complex crystals with [[1,4-dioxane]].<ref>{{Cite journal |last=Vicentini |first=Geraldo |last2=Perrier |first2=Madeleine |last3=Giesbrecht |first3=Ernesto |date=Apr 1961 |title=Notiz über die Reaktion von Dioxan mit Perchlorathydraten einiger Übergangselemente |url=http://dx.doi.org/10.1002/cber.19610940440 |journal=Chemische Berichte |volume=94 |issue=4 |pages=1153–1155 |doi=10.1002/cber.19610940440 |issn=0009-2940}}</ref> It reacts with [[inositol]], [[sodium acetate]], and [[sodium hydroxide]] to obtain complexes containing giant molecular clusters {Gd<sub>140</sub>}.<ref name=jacs /> It reacts with [[chromium(III) chloride]] and [[2,2'-bipyridine]] at pH=5.1 to obtain [GdCr(bipy)<sub>2</sub>(OH)<sub>2</sub>(H<sub>2</sub>O)<sub>6</sub>](ClO<sub>4</sub>)<sub>4</sub>·2H<sub>2</sub>O.<ref>{{cite journal|journal=European Journal of Inorganic Chemistry|volume=2015|issue=34|language=en|issn=1434-1948|date=2015-12|pages=5702–5707|doi=10.1002/ejic.201500786|url=https://onlinelibrary.wiley.com/doi/10.1002/ejic.201500786|title=Synthesis, Structures, and Magnetic Properties of Binuclear [CrLn] (Ln = Gd or Dy) and Trinuclear [Cr 2 Ln] (Ln = Gd, Dy, or Tb) Heterometallic Clusters with 2,2′‐Bipyridine as Ligand|accessdate=2023-03-15|author=Zhong‐Yi Li, Xiao‐Qun Wang, Jian‐Jun Zhang, Shu‐Qin Liu, Jun Ni, Ying‐Ji Sun}}</ref> |
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== References == |
== References == |
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Revision as of 18:18, 4 December 2023
  
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| Identifiers | |
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| Properties | |
| Cl3GdO12 | |
| Molar mass | 455.59 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Gadolinium(III) perchlorate is an inorganic compound with the chemical formula Gd(ClO4)3. It can be obtained by reacting gadolinium(III) oxide and perchloric acid (70~72%) at 80 °C.[1] It can form colorless Gd(ClO4)3·9H2O·4C4H8O2 complex crystals with 1,4-dioxane.[2] It reacts with inositol, sodium acetate, and sodium hydroxide to obtain complexes containing giant molecular clusters {Gd140}.[1] It reacts with chromium(III) chloride and 2,2'-bipyridine at pH=5.1 to obtain [GdCr(bipy)2(OH)2(H2O)6](ClO4)4·2H2O.[3]
References
- ^ a b Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng (2017-12-20). "A Gigantic Molecular Wheel of {Gd 140 }: A New Member of the Molecular Wheel Family". Journal of the American Chemical Society. 139 (50): 18178–18181. doi:10.1021/jacs.7b11112. ISSN 0002-7863. Archived from the original on 2023-03-15. Retrieved 2023-03-15.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - ^ Vicentini, Geraldo; Perrier, Madeleine; Giesbrecht, Ernesto (Apr 1961). "Notiz über die Reaktion von Dioxan mit Perchlorathydraten einiger Übergangselemente". Chemische Berichte. 94 (4): 1153–1155. doi:10.1002/cber.19610940440. ISSN 0009-2940.
- ^ Zhong‐Yi Li, Xiao‐Qun Wang, Jian‐Jun Zhang, Shu‐Qin Liu, Jun Ni, Ying‐Ji Sun (2015-12). "Synthesis, Structures, and Magnetic Properties of Binuclear [CrLn] (Ln = Gd or Dy) and Trinuclear [Cr 2 Ln] (Ln = Gd, Dy, or Tb) Heterometallic Clusters with 2,2′‐Bipyridine as Ligand". European Journal of Inorganic Chemistry. 2015 (34): 5702–5707. doi:10.1002/ejic.201500786. ISSN 1434-1948. Retrieved 2023-03-15.
{{cite journal}}: Check date values in:|date=(help)CS1 maint: multiple names: authors list (link)