Ceric ammonium nitrate: Difference between revisions
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[[Image:Ceric ammonium nitrate.jpg|thumb|Ammonium cerium(IV) nitrate]] |
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! {{chembox header}} | Ammonium cerium(IV) nitrate |
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| align="center" colspan="2" | [[Image:Ceric ammonium nitrate.jpg|200px|{{PAGENAME}}]] |
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! {{chembox header}} | General |
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| [[IUPAC nomenclature|Systematic name]] |
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| Diammonium cerium(IV) nitrate |
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| Other names |
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| Ceric ammonium nitrate (CAN) |
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| [[Chemical formula|Molecular formula]] |
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| (NH<sub>4</sub>)<sub>2</sub>Ce(NO<sub>3</sub>)<sub>6</sub> |
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| [[Molar mass]] |
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| 548.23 g/mol |
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| Appearance |
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| orange crystalline solid |
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| [[CAS registry number|CAS number]] |
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| [16774-21-3] |
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| [[EINECS number]] |
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| 240-827-6 |
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! {{chembox header}} | Properties |
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| [[Density]] and [[Phase (matter)|phase]] |
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| ? g/cm<sup>3</sup>, ? |
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| [[Soluble|Solubility]] in [[Water_(molecule)|water]] |
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| 141 g/100 ml (25°C) |
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| [[Melting point]] |
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| ? °C (? K) <!-- (mention any decomposition) --> |
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| [[Boiling point]] |
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| ? °C (? K) |
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! {{chembox header}} | Structure |
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| [[Coordination geometry|Coordination<br/>geometry]] <!-- for a metal complex or an ionic crystal, otherwise omit --> |
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| ? <!-- e.g. trigonal bipyramidal --> |
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| [[Crystal structure]] |
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| [[Monoclinic]] |
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! {{chembox header}} | Safety data <!-- INDEX no not listed --> |
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| [[Directive 67/548/EEC|EU classification]] |
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| not listed |
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<!-- | [[NFPA 704]] --> |
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<!-- | [[Image:nfpa_h4.png]][[Image:nfpa_f4_ox.png]][[Image:nfpa_r4.png]] --> |
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<!-- |- --> |
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| [[Permissible Exposure Limit|PEL-TWA]] ([[OSHA]]) |
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| ? |
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| [[IDLH]] ([[NIOSH]]) |
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| ? |
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| [[Flash point]] |
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| non flammable |
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| [[RTECS]] number |
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| ? |
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! {{chembox header}} | [[{{PAGENAME}} (data page)|Supplementary data page]] |
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| [[{{PAGENAME}} (data page)#Structure and properties|Structure and<br/>properties]] |
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| [[Refractive index|''n'']], [[Dielectric constant|''ε<sub>r</sub>'']], etc. |
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| [[{{PAGENAME}} (data page)#Thermodynamic properties|Thermodynamic<br/>data]] |
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| Phase behaviour<br>Solid, liquid, gas |
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| [[{{PAGENAME}} (data page)#Spectral data|Spectral data]] |
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| [[UV/VIS spectroscopy|UV]], [[Infrared spectroscopy|IR]], [[NMR spectroscopy|NMR]], [[Mass spectrometry|MS]] |
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! {{chembox header}} | Related compounds |
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| Other [[Ion|cation]]s <!-- please omit if not applicable --> |
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| [[Ammonium cerium(III) nitrate]] |
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| Related compounds |
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| [[Ammonium nitrate]]<br/>[[Cerium(IV) nitrate]] |
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| {{chembox header}} | <small>Except where noted otherwise, data are given for<br> materials in their [[standard state|standard state (at 25 °C, 100 kPa)]]<br/>[[wikipedia:Chemical infobox|Infobox disclaimer and references]]</small> |
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'''Ammonium cerium(IV) nitrate''', also called '''ceric ammonium nitrate''' or '''CAN''', is a compound of [[cerium]] that is widely used as an [[Redox|oxidising agent]]. It is a yellow compound with the chemical formula (NH<sub>4</sub>)<sub>2</sub>Ce(NO<sub>3</sub>)<sub>6</sub>. It is often used by [[organometallic]] chemists to detach a metal [[ion]] from an [[organic]] compound in a procedure called [[decomplexation]]. It is also used in [[organic synthesis]] to oxidise [[hydroquinone]]s to [[quinone]]s. |
'''Ammonium cerium(IV) nitrate''', also called '''ceric ammonium nitrate''' or '''CAN''', is a compound of [[cerium]] that is widely used as an [[Redox|oxidising agent]]. It is a yellow compound with the chemical formula (NH<sub>4</sub>)<sub>2</sub>Ce(NO<sub>3</sub>)<sub>6</sub>. It is often used by [[organometallic]] chemists to detach a metal [[ion]] from an [[organic]] compound in a procedure called [[decomplexation]]. It is also used in [[organic synthesis]] to oxidise [[hydroquinone]]s to [[quinone]]s. |
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Revision as of 21:09, 15 August 2005
| Ammonium cerium(IV) nitrate | |
|---|---|
| |
| General | |
| Systematic name | Diammonium cerium(IV) nitrate |
| Other names | Ceric ammonium nitrate (CAN) |
| Molecular formula | (NH4)2Ce(NO3)6 |
| Molar mass | 548.23 g/mol |
| Appearance | orange crystalline solid |
| CAS number | [16774-21-3] |
| EINECS number | 240-827-6 |
| Properties | |
| Density and phase | ? g/cm3, ? |
| Solubility in water | 141 g/100 ml (25°C) |
| Melting point | ? °C (? K) |
| Boiling point | ? °C (? K) |
| Structure | |
| Coordination geometry |
? |
| Crystal structure | Monoclinic |
| Safety data | |
| EU classification | not listed |
| PEL-TWA (OSHA) | ? |
| IDLH (NIOSH) | ? |
| Flash point | non flammable |
| RTECS number | ? |
| Supplementary data page | |
| Structure and properties |
n, εr, etc. |
| Thermodynamic data |
Phase behaviour Solid, liquid, gas |
| Spectral data | UV, IR, NMR, MS |
| Related compounds | |
| Other cations | Ammonium cerium(III) nitrate |
| Related compounds | Ammonium nitrate Cerium(IV) nitrate |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references | |
Ammonium cerium(IV) nitrate, also called ceric ammonium nitrate or CAN, is a compound of cerium that is widely used as an oxidising agent. It is a yellow compound with the chemical formula (NH4)2Ce(NO3)6. It is often used by organometallic chemists to detach a metal ion from an organic compound in a procedure called decomplexation. It is also used in organic synthesis to oxidise hydroquinones to quinones.
 | This inorganic compound–related article is a stub. You can help Wikipedia by expanding it. |