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Revision as of 17:55, 15 March 2013

Rubrocurcumin
Names
Other names
Rubrocurcumin
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C23H19BO10/c1-30-20-11-14(5-9-18(20)26)3-7-16(25)13-17(32-24-33-22(28)23(29)34-24)8-4-15-6-10-19(27)21(12-15)31-2/h3-13,26-27H,1-2H3/b7-3+,8-4+,17-13- checkY
    Key: CSMMVHRUFPYHCS-YRLHZMKXSA-N checkY
  • B1(OC(=O)C(=O)O1)O/C(=C\C(=O)/C=C/c2ccc(c(c2)OC)O)/C=C/c3ccc(c(c3)OC)O
Properties
C23H19BO10
Molar mass 466.19 g/mol
Appearance red solid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Rubrocurcumin is a red colored dye that is formed by the reaction of curcumin and borates.

Synthesis

The reaction of curcumin with borates in presence of oxalic acid produces rubrocurcumin.[1]

Characteristics

Rubrocurcumin produces a red colored solution.

Rubrocurcumin is a neutrally charged composition, while rosocyanine is build from ions. In rubrocurcumin, one molecule curcumin is replaced with oxalate compared to rosocyanine.

Complexes with boron such as rubrocurcumin are called 1,3,2-dioxaborines.[1]

Literature

  • Spicer, G. S.; Strickland, J. D. H. (1952). "Compounds of Curcumin and Boric Acid. Part II. The Structure of Rubrocurcumin". Journal of the Chemical Society. 1952 (article 907). London: 4650–4653. doi:10.1039/JR9520004650.{{cite journal}}: CS1 maint: multiple names: authors list (link)

References