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'''(+)-Larreatricin hydroxylase''' ({{EC number|1.14.99.47}}) is an [[enzyme]] with [[List of enzymes|systematic name]] ''(+)-larreatricin:oxygen 3'-hydroxylase''.<ref>{{cite journal | vauthors = Cho MH, Moinuddin SG, Helms GL, Hishiyama S, Eichinger D, Davin LB, Lewis NG | title = (+)-Larreatricin hydroxylase, an enantio-specific polyphenol oxidase from the creosote bush (Larrea tridentata) | journal = Proceedings of the National Academy of Sciences of the United States of America | volume = 100 | issue = 19 | pages = 10641–6 | date = September 2003 | pmid = 12960376 | pmc = 196857 | doi = 10.1073/pnas.1934562100 }}</ref> This enzyme [[catalysis|catalyses]] the following [[chemical reaction]]
'''(+)-Larreatricin hydroxylase''' ({{EC number|1.14.99.47}}) is an [[enzyme]] with [[List of enzymes|systematic name]] ''(+)-larreatricin:oxygen 3'-hydroxylase''.<ref>{{cite journal | vauthors = Cho MH, Moinuddin SG, Helms GL, Hishiyama S, Eichinger D, Davin LB, Lewis NG | title = (+)-Larreatricin hydroxylase, an enantio-specific polyphenol oxidase from the creosote bush (Larrea tridentata) | journal = Proceedings of the National Academy of Sciences of the United States of America | volume = 100 | issue = 19 | pages = 10641–6 | date = September 2003 | pmid = 12960376 | pmc = 196857 | doi = 10.1073/pnas.1934562100 | bibcode = 2003PNAS..10010641C | doi-access = free }}</ref> This enzyme [[catalysis|catalyses]] the following [[chemical reaction]]


: (+)-larreatricin + O<sub>2</sub> + AH<sub>2</sub> <math>\rightleftharpoons</math> (+)-3'-hydroxylarreatricin + A + H<sub>2</sub>O
: (+)-larreatricin + O<sub>2</sub> + AH<sub>2</sub> <math>\rightleftharpoons</math> (+)-3'-hydroxylarreatricin + A + H<sub>2</sub>O

Revision as of 05:18, 17 August 2021

(+)-Larreatricin hydroxylase
Identifiers
EC no.1.14.99.47
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum
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PMCarticles
PubMedarticles
NCBIproteins

(+)-Larreatricin hydroxylase (EC 1.14.99.47) is an enzyme with systematic name (+)-larreatricin:oxygen 3'-hydroxylase.[1] This enzyme catalyses the following chemical reaction

(+)-larreatricin + O2 + AH2 (+)-3'-hydroxylarreatricin + A + H2O

This enzyme is isolated from the plant Larrea tridentata (creosote bush) and can be produced recombinantly.[2]

References

  1. ^ Cho MH, Moinuddin SG, Helms GL, Hishiyama S, Eichinger D, Davin LB, Lewis NG (September 2003). "(+)-Larreatricin hydroxylase, an enantio-specific polyphenol oxidase from the creosote bush (Larrea tridentata)". Proceedings of the National Academy of Sciences of the United States of America. 100 (19): 10641–6. Bibcode:2003PNAS..10010641C. doi:10.1073/pnas.1934562100. PMC 196857. PMID 12960376.
  2. ^ Martin HJ, Kampatsikas I, Oost R, Pretzler M, Al-Sayed E, Roller A, et al. (October 2018). "Total Synthesis, Stereochemical Assignment, and Divergent Enantioselective Enzymatic Recognition of Larreatricin". Chemistry. 24 (59): 15756–15760. doi:10.1002/chem.201803785. PMC 6220842. PMID 30113748.