Potassium hexafluorocuprate(III): Difference between revisions
Content deleted Content added
Citation bot (talk | contribs) Misc citation tidying. | Use this bot. Report bugs. | Suggested by AManWithNoPlan | #UCB_CommandLine |
|||
| Line 8: | Line 8: | ||
The compound is prepared by oxidizing the mixture of [[potassium chloride]] and [[Copper(I) chloride|cuprous chloride]] with fluorine:<ref>{{cite journal|last=Popova|first=T. V.|author2=Aksenova, N. V.|title=Complexes of Copper in Unstable Oxidation States|journal=Russian Journal of Coordination Chemistry|date=1 November 2003|volume=29|issue=11|pages=743–765|doi=10.1023/B:RUCO.0000003432.39025.cc|s2cid=93464243}}</ref> |
The compound is prepared by oxidizing the mixture of [[potassium chloride]] and [[Copper(I) chloride|cuprous chloride]] with fluorine:<ref>{{cite journal|last=Popova|first=T. V.|author2=Aksenova, N. V.|title=Complexes of Copper in Unstable Oxidation States|journal=Russian Journal of Coordination Chemistry|date=1 November 2003|volume=29|issue=11|pages=743–765|doi=10.1023/B:RUCO.0000003432.39025.cc|s2cid=93464243}}</ref> |
||
:3 KCl + CuCl + 3 F<sub>2</sub> → K<sub>3</sub>CuF<sub>6</sub> + 2 Cl<sub>2</sub> |
:3 KCl + CuCl + 3 F<sub>2</sub> → K<sub>3</sub>CuF<sub>6</sub> + 2 Cl<sub>2</sub> |
||
A variety of analogues are known.<ref>R. Hoppe, G. Wingefeld "Zur Kenntnis der Hexafluorocuprate(III)" Zeitschrift für anorganische und allgemeine Chemie 1984, Vol. 519, pages 195–203. {{ |
A variety of analogues are known.<ref>R. Hoppe, G. Wingefeld "Zur Kenntnis der Hexafluorocuprate(III)" Zeitschrift für anorganische und allgemeine Chemie 1984, Vol. 519, pages 195–203. {{doi|10.1002/zaac.19845191221}}</ref> The compound reacts with water easily, producing oxygen and copper(II) products.<ref name=H&W/> |
||
==See also== |
==See also== |
||
Latest revision as of 19:41, 27 October 2022
Potassium hexafluorocuprate(III) is an inorganic compound with the chemical formula K3CuF6. It is a green paramagnetic solid, a relatively rare example of a copper(III) compound.[1]
Synthesis and structure
[edit]The compound is prepared by oxidizing the mixture of potassium chloride and cuprous chloride with fluorine:[2]
- 3 KCl + CuCl + 3 F2 → K3CuF6 + 2 Cl2
A variety of analogues are known.[3] The compound reacts with water easily, producing oxygen and copper(II) products.[1]
See also
[edit]References
[edit]- ^ a b Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.), Inorganic Chemistry, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, ISBN 0-12-352651-5
- ^ Popova, T. V.; Aksenova, N. V. (November 1, 2003). "Complexes of Copper in Unstable Oxidation States". Russian Journal of Coordination Chemistry. 29 (11): 743–765. doi:10.1023/B:RUCO.0000003432.39025.cc. S2CID 93464243.
- ^ R. Hoppe, G. Wingefeld "Zur Kenntnis der Hexafluorocuprate(III)" Zeitschrift für anorganische und allgemeine Chemie 1984, Vol. 519, pages 195–203. doi:10.1002/zaac.19845191221
 | This inorganic compound–related article is a stub. You can help Wikipedia by expanding it. |