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'''Charcoal''' is the blackish residue consisting of impure [[carbon]] obtained by |
'''Charcoal''' is the blackish residue consisting of impure [[carbon]] obtained by |
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removing water and other volatile constituents of animal and vegetable substances. |
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It is usually produced by heating [[wood]] in the absence of [[oxygen]] (see [[char]]), but sugar |
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charcoal, [[bone char|bone charcoal]] (which contains a great amount of [[calcium]] [[phosphate]]), |
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and others can be produced as well. |
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The light, black, porous material is 85% to 98% carbon, and resembles [[coal]]. |
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The first part of the word is of obscure origin. |
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The independent use of "char", meaning to scorch, to reduce to carbon, is |
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comparatively recent and must be a [[back-formation]] from the earlier charcoal. |
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It may be a use of the word ''charren'', meaning to turn, i.e., wood changed or |
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turned to coal; or it may be from the French ''charbon''. A person who manufactured charcoal was formerly known as a [[collier]], though the term was used later for those who dealt in [[coal]]. |
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===Production=== |
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Production of wood charcoal in districts where there is an abundance of wood dates |
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back to a very remote period, and generally consists of piling billets of wood on |
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their ends so as to form a conical pile, openings being left at the bottom to admit air, |
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with a central shaft to serve as a flue. |
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The whole pile is covered with turf of moistened soil. |
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The firing is begun at the bottom of the flue, and gradually spreads outwards |
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and upwards. The success of the operation depends upon the rate of the combustion. |
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Under average conditions, 100 parts of wood yield about 60 parts by volume, |
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or 25 parts by weight, of charcoal. |
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The modern process of carbonizing wood either in small pieces or as sawdust |
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in [[cast iron]] retorts is extensively practiced where wood is scarce, and also |
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by reason of the recovery of valuable byproducts ([[wood spirit]], [[pyroligneous acid]], |
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[[wood tar]]), which the process permits. |
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The question of the temperature of the carbonization is important; according to |
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J. Percy, wood becomes brown at 220°C., a deep brown-black after some time at 280°, |
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and an easily powdered mass at 310°. |
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Charcoal made at 300° is brown, soft and friable, and readily inflames at 380°; |
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made at higher temperatures it is hard and brittle, and does not fire until heated |
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to about 700°. |
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===Use=== |
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One of the most important applications of wood charcoal is as a constituent of [[gunpowder]]. |
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It is also used in metallurgical operations as a reducing agent, but its application has been |
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diminished by the introduction of [[coke (coal)|coke]], [[anthracite]] smalls, etc. |
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A limited quantity is made up into the form of drawing [[crayon]]s; but the greatest |
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amount is used as a [[fuel]], which burns hotter and cleaner than wood. |
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Charcoal is often used by [[blacksmith]]s, for cooking, and for other industrial applications. |
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The porosity of wood charcoal explains why it floats on the surface of water, |
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although it is actually denser. |
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This also accounts for its ability to readily absorb gases and liquids; |
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charcoal is often used to filter water or absorb odors. |
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Its pharmacological action depends on the same property; it absorbs the |
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gases of the [[stomach]] and [[intestine]]s, and also liquids and solids (hence its |
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use in the treatment of certain poisonings). Charcoal filters are used in some types of [[gas mask]] to remove poisonous gases from inhaled air. |
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Wood charcoal has also the power of removing coloring matters from solutions, |
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but this property is possessed in a much higher degree by animal charcoal. |
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Animal charcoal or bone black is the carbonaceous residue obtained by the dry |
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distillation of bones; it contains only about 10% carbon, the remainder being calcium |
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and [[magnesium]] phosphates (80%) and other inorganic material originally present |
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in the bones. |
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It is generally manufactured from the residues obtained in the [[glue]] |
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and [[gelatin]] industries. |
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Its decolorizing power was applied in [[1812]] by Derosne to the clarification of |
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the [[syrup]]s obtained in [[sugar]] refining; but its use in this direction has now greatly |
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diminished, owing to the introduction of more active and easily managed reagents. |
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It is still used to some extent in laboratory practice. |
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The decolorizing power is not permanent, becoming lost after using for some time; |
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it may be revived, however, by washing and reheating. |
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Charcoal is used in art for drawing, making rough sketches in painting, and is one of the possible media for making a [[Surrealist_techniques#Parsemage|parsemage]].  Bamboo charcoal is the principal tool in Japanese [[Sumi-e]] (炭絵 lit: charcoal drawing) art. |
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==See also== |
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*[[Activated carbon]] |
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[[da:Trækul]] |
[[da:Trækul]] |
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[[de:Holzkohle]] |
[[de:Holzkohle]] |
Revision as of 21:58, 12 April 2005
Charcoal is the blackish residue consisting of impure carbon obtained by