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'''Charcoal''' is the blackish residue consisting of impure [[carbon]] obtained by
'''Charcoal''' is the blackish residue consisting of impure [[carbon]] obtained by
removing water and other volatile constituents of animal and vegetable substances.
It is usually produced by heating [[wood]] in the absence of [[oxygen]] (see [[char]]), but sugar
charcoal, [[bone char|bone charcoal]] (which contains a great amount of [[calcium]] [[phosphate]]),
and others can be produced as well.
The light, black, porous material is 85% to 98% carbon, and resembles [[coal]].

The first part of the word is of obscure origin.
The independent use of "char", meaning to scorch, to reduce to carbon, is
comparatively recent and must be a [[back-formation]] from the earlier charcoal.
It may be a use of the word ''charren'', meaning to turn, i.e., wood changed or
turned to coal; or it may be from the French ''charbon''. A person who manufactured charcoal was formerly known as a [[collier]], though the term was used later for those who dealt in [[coal]].

===Production===

Production of wood charcoal in districts where there is an abundance of wood dates
back to a very remote period, and generally consists of piling billets of wood on
their ends so as to form a conical pile, openings being left at the bottom to admit air,
with a central shaft to serve as a flue.
The whole pile is covered with turf of moistened soil.
The firing is begun at the bottom of the flue, and gradually spreads outwards
and upwards. The success of the operation depends upon the rate of the combustion.
Under average conditions, 100 parts of wood yield about 60 parts by volume,
or 25 parts by weight, of charcoal.

The modern process of carbonizing wood either in small pieces or as sawdust
in [[cast iron]] retorts is extensively practiced where wood is scarce, and also
by reason of the recovery of valuable byproducts ([[wood spirit]], [[pyroligneous acid]],
[[wood tar]]), which the process permits.
The question of the temperature of the carbonization is important; according to
J. Percy, wood becomes brown at 220°C., a deep brown-black after some time at 280°,
and an easily powdered mass at 310°.
Charcoal made at 300° is brown, soft and friable, and readily inflames at 380°;
made at higher temperatures it is hard and brittle, and does not fire until heated
to about 700°.

===Use===

One of the most important applications of wood charcoal is as a constituent of [[gunpowder]].
It is also used in metallurgical operations as a reducing agent, but its application has been
diminished by the introduction of [[coke (coal)|coke]], [[anthracite]] smalls, etc.
A limited quantity is made up into the form of drawing [[crayon]]s; but the greatest
amount is used as a [[fuel]], which burns hotter and cleaner than wood.
Charcoal is often used by [[blacksmith]]s, for cooking, and for other industrial applications.

The porosity of wood charcoal explains why it floats on the surface of water,
although it is actually denser.
This also accounts for its ability to readily absorb gases and liquids;
charcoal is often used to filter water or absorb odors.
Its pharmacological action depends on the same property; it absorbs the
gases of the [[stomach]] and [[intestine]]s, and also liquids and solids (hence its
use in the treatment of certain poisonings). Charcoal filters are used in some types of [[gas mask]] to remove poisonous gases from inhaled air.
Wood charcoal has also the power of removing coloring matters from solutions,
but this property is possessed in a much higher degree by animal charcoal.

Animal charcoal or bone black is the carbonaceous residue obtained by the dry
distillation of bones; it contains only about 10% carbon, the remainder being calcium
and [[magnesium]] phosphates (80%) and other inorganic material originally present
in the bones.
It is generally manufactured from the residues obtained in the [[glue]]
and [[gelatin]] industries.
Its decolorizing power was applied in [[1812]] by Derosne to the clarification of
the [[syrup]]s obtained in [[sugar]] refining; but its use in this direction has now greatly
diminished, owing to the introduction of more active and easily managed reagents.
It is still used to some extent in laboratory practice.
The decolorizing power is not permanent, becoming lost after using for some time;
it may be revived, however, by washing and reheating.

Charcoal is used in art for drawing, making rough sketches in painting, and is one of the possible media for making a [[Surrealist_techniques#Parsemage|parsemage]].  Bamboo charcoal is the principal tool in Japanese [[Sumi-e]] (炭絵 lit: charcoal drawing) art.

==See also==
*[[Activated carbon]]

[[da:Trækul]]
[[da:Trækul]]
[[de:Holzkohle]]
[[de:Holzkohle]]

Revision as of 21:58, 12 April 2005

Charcoal is the blackish residue consisting of impure carbon obtained by