Carbon trioxide: Difference between revisions
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| author = [[John Pople|Pople J. A. ]] , Seeger U., Seeger R., [[Paul von Rague Schleyer|Schleyer P. v. R.]] |
| author = [[John Pople|Pople J. A. ]] , Seeger U., Seeger R., [[Paul von Rague Schleyer|Schleyer P. v. R.]] |
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| title = The structure of |
| title = The structure of carbonate |
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| title = Carbonate: Its Production, Infrared Spectrum, and Structure Studied in a Matrix of Solid CO<sub>2</sub> |
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| journal =The Journal of Chemical Physics |
| journal =The Journal of Chemical Physics |
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| year =1966 |
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Revision as of 22:44, 18 January 2008
Carbon trioxide (CO3) is an unstable product of reactions between carbon dioxide (CO2) and atomic oxygen (O).[1] It is different from the carbonate ion (CO32-). It has also been detected in reactions between carbon monoxide, CO, and molecular oxygen, O2. Among other places it has been shown to be created in the drift zone of a negative corona discharge.[2] This pathway arises from reactions between carbon dioxide and atomic oxygen ions, created from molecular oxygen by free electrons in the plasma. Carbon trioxide is a liquid.
Three possible isomers of carbon trioxide exist, denoted Cs, D3h, and C2v. The C2v state has been shown by various studies to be the ground state of the molecule.[3]
References
- Electronic structure and spectroscopy of carbon trioxide
- Sabin J. R., Kim H. (1971). "A theoretical study of the structure and properties of carbon trioxide". Chemical Physics Letters. 11 (5): 593–597. doi:10.1016/0009-2614(71)87010-0.
- Sobek V., Skalný J. D. (1993). Czechoslovak Journal of Physics. 43 (8) http://www.springerlink.com/(3xbvg4fk245a5l45su5fwm55)/app/home/contribution.asp?referrer=parent&backto=issue,5,9;journal,147,588;linkingpublicationresults,1:106035,1.
{{cite journal}}: Cite has empty unknown parameter:|coauthors=(help); Missing or empty|title=(help) - Pople J. A. , Seeger U., Seeger R., Schleyer P. v. R. (2004). "The structure of carbonate". Journal of Computational Chemistry. 1 (2): 199–203. doi:10.1002/jcc.540010215.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - Moll N. G., Clutter D. R., Thompson W. E. (1966). "Carbonate: Its Production, Infrared Spectrum, and Structure Studied in a Matrix of Solid CO2". The Journal of Chemical Physics. 45 (12): 4469–4481. doi:10.1063/1.1727526.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - Gimarc B. M., Chou T. S. (1968). "Geometry and Electronic Structure of Carbon Trioxide". The Journal of Chemical Physics. 49 (9): 4043–4047. doi:10.1063/1.1670715.
- DeMore W. B., Jacobsen C. W. (1969). "Formation of carbon trioxide in the photolysis of ozone in liquid carbon dioxide". Journal of Physical Chemistry. 73 (9): 2935–2938. doi:10.1021/j100843a026.
- DeMore W. B., Dede C. (1970). "Pressure dependence of carbon trioxide formation in the gas-phase reaction of O(1D) with carbon dioxide". Journal of Physical Chemistry. 74 (13): 2621–2625. doi:10.1021/j100707a006.
- Francisco J. S., Williams I. H. (1985). "A theoretical study of the force field for carbon trioxide". Chemical Physics. 95 (3). doi:10.1016/0301-0104(85)80160-9.
{{cite journal}}: Text "pages 373-383" ignored (help)