Ruby

Ruby
A naturally occurring ruby crystal
General
Category	Mineral variety
Formula (repeating unit)	aluminium oxide with chromium, Al2O3:Cr
Crystal system	Trigonal (Hexagonal Scalenohedral) Symbol (-3 2/m) Space Group: R-3c
Identification
Color	Red, may be brownish, purplish or pinkish
Crystal habit	Varies with locality. Terminated tabular hexagonal prisms.
Cleavage	No true cleavage
Fracture	Uneven or conchoidal
Mohs scale hardness	9.0
Luster	Vitreous
Streak	white
Diaphaneity	transparent
Specific gravity	4.0
Refractive index	nω=1.768 - 1.772 nε=1.760 - 1.763, Birefringence 0.008
Pleochroism	Orangey red, purplish red
Ultraviolet fluorescence	red under longwave
Melting point	2044 °C
Solubility	none
Major varieties
Sapphire	Any color except red
Corundum	various colors
Emery	Granular

Crystal structure of ruby

A ruby is a pink to blood-red gemstone, a variety of the mineral corundum (aluminium oxide). The red color is caused mainly by the presence of the element chromium. Its name comes from ruber, Latin for red. Other varieties of gem-quality corundum are called sapphires. The ruby is considered one of the four precious stones, together with the sapphire, the emerald, and the diamond.

Prices of rubies are primarily determined by color. The brightest and most valuable "red" called pigeon blood-red, commands a huge premium over other rubies of similar quality. After color follows clarity: similar to diamonds, a clear stone will command a premium, but a ruby without any needle-like rutile inclusions may indicate that the stone has been treated. Cut and carat (size) also determine the price.

Physical properties

Rubies have a hardness of 9.0 on the Mohs scale of mineral hardness. Among the natural gems only moissanite and diamond are harder, with diamond having a Mohs hardness of 10.0 and moissonite falling somewhere in between corundum (ruby) and diamond in hardness. Ruby is α-alumina (the most stable form of Al₂O₃) in which a small fraction of the aluminum³⁺ ions are replaced by chromium³⁺ ions. Each Cr³⁺ is surrounded octahedrally by six O^2- ions. This crystallographic arrangement strongly affects each Cr³⁺, resulting in light absorption in the yellow-green region of the spectrum and thus in the red color of the gem. When yellow-green light is absorbed by Cr³⁺, it is re-emitted as red luminescence. This red emission adds to the red colour perceived by the subtraction of green and violet light from white light, and adds luster to the gem's appearance. When the optical arrangement is such that the emission is stimulated by 694-nanometer photons reflecting back and forth between two mirrors, the emission grows strongly in intensity. This effect was used by Theodore Maiman in 1960 to make the first successful laser, based on ruby.

All natural rubies have imperfections in them, including color impurities and inclusions of rutile needles known as "silk". Gemologists use these needle inclusions found in natural rubies to distinguish them from synthetics, simulants, or substitutes. Usually the rough stone is heated before cutting. Almost all rubies today are treated in some form, with heat treatment being the most common practice. However, rubies that are completely untreated but still of excellent quality command a large premium.

Some rubies show a 3-point or 6-point asterism or "star". These rubies are cut into cabochons to display the effect properly. Asterisms are best visible with a single-light source, and move across the stone as the light moves or the stone is rotated. Such effects occur when light is reflected off the "silk" (the structurally oriented rutile needle inclusions) in a certain way. This is one example where inclusions increase the value of a gemstone. Furthermore, rubies can show color changes — though this occurs very rarely —; as well as chatoyancy or the "cat's eye" effect.

Natural occurrence

Rubies have historically been mined in Thailand, the Pailin and Samlot provinces of Cambodia, and Afghanistan. Rubies were rarely found in Sri Lanka where pink sapphires are more common.

After the Second World War new ruby deposits were found in Tanzania, Kenya, Madagascar, Vietnam, Nepal, Tajikistan, and Pakistan. They have also been sometimes found in the U.S. states of Montana, North Carolina, and South Carolina. More recently, large ruby deposits have been found under the receding ice shelf of Greenland. The Mogok Valley in Upper Myanmar was for centuries the world main source for rubies. It has produced some of the finest rubies ever mined, but in recent years very few good rubies have been found there. The very best color in Myanmar (Burmese) rubies is sometimes described as "pigeon's blood". In central Myanmar the area of Mong Hsu also started to produce rubies during the 1990s and rapidly became the world's main ruby mining area. The latest ruby deposit to be found in Myanmar is situated in Namya (Namyazeik) located in the northern Kachin state. In 2002 rubies were found in the Waseges River area of Kenya. Spinel, another red gemstone, is sometimes found associated with rubies from the same gem gravel or marble. Red spinel may be mistaken with ruby by people lacking experience with gems. However, fine red spinels may approach the average ruby in value.

A cut ruby.

Factors affecting value

Diamonds are graded using criteria that have become known as the four Cs, namely color, cut, clarity and carat weight. Similarly natural rubies can be evaluated using the four Cs together with their size and geographic origin.

Color: In the evaluation of colored gemstones, color is the single most important factor. Color divides into three components; hue, saturation and tone. Hue refers to "color" as we normally use the term. Transparent gemstones occur in the following hues: red, orange, yellow, green, blue, violet, purple and pink are the spectral hues. The first six are known as spectral hues; the last two are modified spectral hues. Purple is a hue that falls halfway between red and blue and pink is a paler shade of red. In nature there are rarely pure hues so when speaking of the hue of a gemstone we speak of primary and secondary and sometimes tertiary hues. In ruby the primary hue must be red. All other hues of the gem species corundum are called sapphire. Ruby may exhibit a range of secondary hues. Orange, purple, violet and pink are possible.

• 
  Natural Ruby with inclusions
• 
  Rubies set in jewellery

The finest ruby is best described as being a vivid medium-dark toned red. Secondary hues add an additional complication. Pink, orange, and purple are the normal secondary hues in ruby. Of the three, purple is preferred because, firstly, the purple reinforces the red making it appear richer. Secondly, purple occupies a position on the color wheel halfway between red and blue. In Burma where the term pigeon blood originated, rubies are set in pure gold. Pure gold is, itself a highly saturated yellow. Set a purplish-red ruby in yellow and the yellow neutralizes its compliment blue leaving the stone appearing to be pure red in the setting.

Treatments and enhancements

Improving the quality of gemstones by treating them is common practice. Some treatments are used in almost all cases and are therefore considered acceptable. During the late 1990s, a large supply of low-cost materials caused a sudden surge in supply of heat-treated rubies, leading to a downward pressure on ruby prices.

Improvements used include color alteration, improving transparency by dissolving rutile inclusions, healing of fractures (cracks) or even completely filling them.

The most common treatment is the application of heat. Most, if not all, rubies at the lower end of the market are heat treated on the rough stones to improve color, remove purple tinge, blue patches and silk. These heat treatments typically occur around temperatures of 1800 °C (3300 °F). Some rubies undergo a process of low tube heat, when the stone is heated over charcoal of a temperature of about 1300 °C (2400 °F) for 20 to 30 minutes. The silk is only partially broken as the color is improved.

A less acceptable treatment, which has gained notoriety in recent years, is lead glass filling. Filling the fractures inside the ruby with lead glass dramatically improves the transparency of the stone, making previously unsuitable rubies fit for applications in jewelry. The process is done in four steps:

1. The rough stones are pre-polished to eradicate all surface impurities that may affect the process
2. The rough is cleaned with hydrogen fluoride
3. The first heating process during which no fillers are added. The heating process eradicates impurities inside the fractures. Although this can be done at temperatures up to 1400 °C (2500 °F) it most likely occurs at a temperature of around 900 °C (1600 °F) since the rutile silk is still intact
4. The second heating process in an electrical oven with different chemical additives. Different solutions and mixes have shown to be successful, however mostly lead-containing glass-powder is used at present. The ruby is dipped into oils, then covered with powder, embedded on a tile and placed in the oven where it is heated at around 900 °C (1600 °F) for one hour in an oxidizing atmosphere. The orange colored powder transforms upon heating into a transparent to yellow-colored paste, which fills all fractures. After cooling the color of the paste is fully transparent and dramatically improves the overall transparency of the ruby.

If a color needs to be added, the glass powder can be "enhanced" with copper or other metal oxides as well as elements such as sodium, calcium, potassium etc.

The second heating process can be repeated three to four times, even applying different mixtures. When jewelry containing rubies is heated (for repairs) it should not be coated with boracic acid or any other substance, as this can etch the surface; it does not have to be "protected" like a diamond.

Synthetic and imitation rubies

In 1837 Gaudin made the first synthetic rubies by fusing aluminium at a high temperature with a little chromium as a pigment. In 1847 Ebelmen made white sapphire by fusing alumina in boric acid. In 1877 Frenic and Freil made crystal corundum from which small stones could be cut. Frimy and Auguste Verneuil manufactured artificial ruby by fusing BaF₂ and Al₂O₃ with a little Chromium at red heat. In 1903 Verneuil announced he could produce synthetic rubies on a commercial scale using this flame fusion process.

Other processes in which synthetic rubies can be produced are through the Pulling process, flux process, and the hydrothermal process. Most synthetic rubies originate from flame fusion, due to the low costs involved. Synthetic rubies may have no imperfections visible to the naked eye but magnification may reveal curves striae and gas bubbles. The fewer the number and the less obvious the imperfections, the more valuable the ruby is; unless there are no imperfections (i.e., a "perfect" ruby), in which case it will be suspected of being artificial. Dopants are added to some manufactured rubies so they can be identified as synthetic, but most need gemmological testing to determine their origin.

Synthetic rubies have technological uses as well as gemological ones. Rods of synthetic ruby are used to make ruby lasers and masers. The first working laser was made by Theodore H. Maiman in 1960 at Hughes Research Laboratories in Malibu, California, beating several research teams including those of Charles H. Townes at Columbia University, Arthur Schawlow at Bell Labs, and Gould at a company called TRG (Technical Research Group). Maiman used a solid-state light-pumped synthetic ruby to produce red laser light at a wavelength of 694 nanometers (nm). Ruby lasers are still in use.

Imitation rubies are also marketed. Red spinels, red garnets, and colored glass have been falsely claimed to be rubies. Imitations go back to Roman times and already in the 17th century techniques were developed to color foil red—by burning scarlet wool in the bottom part of the furnace—which was then placed under the imitation stone. Trade terms such as balas ruby for red spinel and rubellite for red tourmaline can mislead unsuspecting buyers. Such terms are therefore discouraged from use by many gemological associations such as the Laboratory Manual Harmonisation Committee (LMHC).

Records

Rubies at the National Museum of Natural History, Washington DC, USA

The Smithsonian's National Museum of Natural History in Washington DC, has received one of the world's largest and finest ruby gemstones. The 23.1 carats (4.62 g) Burmese ruby, set in a platinum ring with diamonds, was donated by businessman and philanthropist Peter Buck in memory of his wife Carmen Lúcia. This gemstone displays a richly saturated red color combined with an exceptional transparency. The finely proportioned cut provides vivid red reflections. The stone was mined from the famous Mogok region of Burma (now Myanmar) in the 1930s.

Historical and cultural references

• An early recorded note of the transport and trading of rubies arises in the literature on the North Silk Road of China, where in about 200 BC rubies were carried along this ancient trackway moving westward from China.
• Rubies have always been held in high esteem in Asian countries. They were used to ornament armor, scabbards, and harnesses of noblemen in India and China. Rubies were laid beneath the foundation of buildings to secure good fortune to the structure.

See also

• List of minerals
• Sapphire
• Ruby laser
• Corundum
• Aluminium oxide
• Verneuil process

External links

• International Colored Stone Association's ruby overview page
• Webmineral crystallographic and mineral info
• Farlang's Historical references on rubies: mining, famous rubies etc.
• Mindat Ruby localities