Potassium ferrocyanide: Difference between revisions
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[[Image:800px-Kaliumhexacyanoferrat II.jpg|200px|thumb|Small yellow crystals]] |
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'''Potassium ferrocyanide''' (K<sub>4</sub>Fe(CN)<sub>6</sub>·3H<sub>2</sub>O), also known as yellow prussiate of potash or potassium hexacyanoferrate(II), is a [[complex (chemistry)|coordination compound]] forming lemon-yellow [[monoclinic]] [[crystal]]s at [[room temperature]] and decomposing at its boiling point. It is insoluble in [[alcohol]] but a litre of water can dissolve just under three hundred [[gram]]s of the crystals, and the solution can be reduced with acid to release [[cyanide]] gas. The resulting [[hydrogen cyanide]] (HCN) boils at 26 °[[Celsius|C]] and, being slightly [[lighter than air]], quickly [[evaporation|evaporates]] clear of the release point. |
'''Potassium ferrocyanide''' (K<sub>4</sub>Fe(CN)<sub>6</sub>·3H<sub>2</sub>O), also known as yellow prussiate of potash or potassium hexacyanoferrate(II), is a [[complex (chemistry)|coordination compound]] forming lemon-yellow [[monoclinic]] [[crystal]]s at [[room temperature]] and decomposing at its boiling point. It is insoluble in [[alcohol]] but a litre of water can dissolve just under three hundred [[gram]]s of the crystals, and the solution can be reduced with acid to release [[cyanide]] gas. The resulting [[hydrogen cyanide]] (HCN) boils at 26 °[[Celsius|C]] and, being slightly [[lighter than air]], quickly [[evaporation|evaporates]] clear of the release point. |
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Revision as of 14:22, 20 December 2005
Potassium ferrocyanide (K4Fe(CN)6·3H2O), also known as yellow prussiate of potash or potassium hexacyanoferrate(II), is a coordination compound forming lemon-yellow monoclinic crystals at room temperature and decomposing at its boiling point. It is insoluble in alcohol but a litre of water can dissolve just under three hundred grams of the crystals, and the solution can be reduced with acid to release cyanide gas. The resulting hydrogen cyanide (HCN) boils at 26 °C and, being slightly lighter than air, quickly evaporates clear of the release point.
Potassium ferrocyanide is also one of two chemicals present in ferroxyl indicator solution (along with phenolphthalein) which turns blue in the presence of Fe2+ ions, and which can therefore be used to detect rust. It is possible to calculate the number of moles of Fe2+ ions by using a colorimeter.
On February 20, 2002 four Moroccans were arrested while in possession of detailed maps of the United States embassy in Rome, the Rome water supply network, and four kilograms of potassium ferrocyanide.
See also
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