Molybdenum disilicide: Difference between revisions
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[[File:CM Furnaces 1700C Box Furnace.jpg|thumb|Example of a laboratory furnace with molybdenum disilicide heating elements installed]] |
[[File:CM Furnaces 1700C Box Furnace.jpg|thumb|Example of a laboratory furnace with molybdenum disilicide heating elements installed]] |
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'''Molybdenum disilicide''' ('''{{Molybdenum}}{{Silicon}}<sub>2</sub>''', '''molybdenum silicide''', or '''MOSI2'''), an [[intermetallic compound]], a [[silicide]] of [[molybdenum]], is a [[refractory material|refractory]] ceramic with primary use in [[heating element]]s. It has moderate [[density]], melting point 2030 °C, and is [[electrically conductive]]. At high temperatures it forms a [[passivation layer]] of [[silicon dioxide]], protecting it from further oxidation. Its [[CAS number]] is {{CASREF|CAS=12136-78-6}}. It is a gray metallic-looking material with [[tetragonal]] [[crystal structure]] (alpha-modification); its beta-modification is [[hexagonal (crystal system)|hexagonal]] and unstable. It is insoluble in most acids but soluble in [[nitric acid]] and [[hydrofluoric acid]]. |
'''Molybdenum disilicide''' ('''{{Molybdenum}}{{Silicon}}<sub>2</sub>''', '''molybdenum silicide''', or '''MOSI2'''), an [[intermetallic compound]], a [[silicide]] of [[molybdenum]], is a [[refractory material|refractory]] [[ceramic]] with primary use in [[heating element]]s. It has moderate [[density]], melting point 2030 °C, and is [[electrically conductive]]. At high temperatures it forms a [[passivation layer]] of [[silicon dioxide]], protecting it from further oxidation. Its [[CAS number]] is {{CASREF|CAS=12136-78-6}}. It is a gray metallic-looking material with [[tetragonal]] [[crystal structure]] (alpha-modification); its beta-modification is [[hexagonal (crystal system)|hexagonal]] and unstable. It is insoluble in most acids but soluble in [[nitric acid]] and [[hydrofluoric acid]]. |
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<!-- Deleted image removed: [[Image:Kanthal-super.jpg|thumb|left|Heating elements of MoSi<sub>2</sub>]] --> |
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While MoSi<sub>2</sub> has excellent resistance to oxidation and high [[Young's modulus]] at temperatures above 1000 °C, it is [[brittle]] in lower temperatures. Also, at above 1200 °C it loses [[creep (deformation)|creep]] resistance. These properties limits its use as a [[structural material]], but may be offset by using it together with another material as a composite material. |
While MoSi<sub>2</sub> has excellent resistance to oxidation and high [[Young's modulus]] at temperatures above 1000 °C, it is [[brittle]] in lower temperatures. Also, at above 1200 °C it loses [[creep (deformation)|creep]] resistance. These properties limits its use as a [[structural material]], but may be offset by using it together with another material as a [[composite material]]. |
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Molybdenum disilicide and MoSi<sub>2</sub>-based materials are usually made by [[sintering]]. [[Plasma spraying]] can be used for producing its dense monolithic and composite forms; material produced this way may contain a proportion of β-MoSi<sub>2</sub> due to its rapid cooling. |
Molybdenum disilicide and MoSi<sub>2</sub>-based materials are usually made by [[sintering]]. [[Plasma spraying]] can be used for producing its dense monolithic and composite forms; material produced this way may contain a proportion of β-MoSi<sub>2</sub> due to its rapid cooling. |
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Revision as of 01:49, 2 May 2011
| Names | |
|---|---|
| IUPAC name
Molybdenum disilicide
| |
| Identifiers | |
| ECHA InfoCard | 100.032.016 |
CompTox Dashboard (EPA)
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| Properties | |
| MoSi2 | |
| Molar mass | 152.11 g/mol |
| Appearance | grey metallic solid |
| Melting point | 2030 °C |
| Hazards | |
| Flash point | Non-flammable |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Molybdenum disilicide (Template:MolybdenumTemplate:Silicon2, molybdenum silicide, or MOSI2), an intermetallic compound, a silicide of molybdenum, is a refractory ceramic with primary use in heating elements. It has moderate density, melting point 2030 °C, and is electrically conductive. At high temperatures it forms a passivation layer of silicon dioxide, protecting it from further oxidation. Its CAS number is . It is a gray metallic-looking material with tetragonal crystal structure (alpha-modification); its beta-modification is hexagonal and unstable. It is insoluble in most acids but soluble in nitric acid and hydrofluoric acid.
While MoSi2 has excellent resistance to oxidation and high Young's modulus at temperatures above 1000 °C, it is brittle in lower temperatures. Also, at above 1200 °C it loses creep resistance. These properties limits its use as a structural material, but may be offset by using it together with another material as a composite material.
Molybdenum disilicide and MoSi2-based materials are usually made by sintering. Plasma spraying can be used for producing its dense monolithic and composite forms; material produced this way may contain a proportion of β-MoSi2 due to its rapid cooling.
Molybdenum disilicide heating elements can be used for temperatures up to 1800 °C, in electric furnaces used in laboratory and production environment in production of glass, steel, electronics, ceramics, and in heat treatment of materials. While the elements are brittle, they can operate at high power without aging, and their electrical resistivity does not increase with operation time. Their maximum operating temperature has to be lowered in atmospheres with low oxygen content due to breakdown of the passivation layer.
Other ceramic materials used for heating elements are eg. silicon carbide, barium titanate, and lead titanate composite materials.
Molybdenum disilicide is used in microelectronics as a contact material. It is often used as a shunt over polysilicon lines to increase their conductivity and increase signal speed.