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Triarylmethane dye: Difference between revisions

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Families: Malachite greens
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===Methyl violet dyes===
===Methyl violet dyes===
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Image:Methyl Violet 2B.png|Methyl violet 2B
Image:Methyl Violet 2B.png|[[Methyl violet]] 2B
Image:Methyl Violet 6B.png|Methyl violet 6B
Image:Methyl Violet 6B.png|[[Methyl violet]] 6B
Image:Methyl Violet 10B.png|Methyl violet 10B
Image:Methyl Violet 10B.png|[[Crystal violet|Methyl violet 10B]]
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===Malachite green dyes===
===Malachite green dyes===
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Image:Malachite green structure.svg |Malachite green
Image:Malachite green structure.svg |[[Malachite green]]
Image:brilliantgruen.png|Brilliant green
Image:brilliantgruen.png|[[Brilliant green (dye)]]
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Revision as of 13:34, 14 June 2011

Triarylmethane dyes are synthetic organic compounds containing triphenylmethane backbones. As dyes, these compounds are intensely colored. Many of these dyes undergo reactions in response to acid and base, and thus serve as pH indicators.[1]

Bromocresol green reacts with acids and bases to give differently colored compounds

As a consequence of their structure, the Friedel-Crafts alkylation reaction is a popular method to prepare many of these compounds:

Friedel-Crafts synthesis of thymolphthalein

Families

Some triarylmethane dyes can be grouped into families of dyes with very similar structures. In some cases, the anions associated with the cationic dyes (say crystal violet) vary even though the name of the dye does not.

Methyl violet dyes

Fuchsine dyes

Fuchsine dyes have amine functional groups at the p-positions of each phenyl group.

Phenol dyes

Phenol dyes have hydroxyl groups at the p positions of each phenyl group.

Malachite green dyes

Bridged arenes

Where two of the aryl groups are bridged by a heteroatom, these triarylmethane compounds may be further categorized into acridines (nitrogen-bridged), xanthenes (oxygen-bridged), and thioxanthenes (sulfur-bridged).

References

  1. ^ Gessner, Thomas; Mayer, Udo (2000). "Triarylmethane and Diarylmethane Dyes". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a27_179. ISBN 978-3527306732.