Triphenylcarbethoxymethylenephosphorane: Difference between revisions
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'''Triphenylcarbethoxymethylenephosphorane''' is an [[organophosphorus compound]] with the [[chemical formula]] Ph<sub>3</sub>PCHCO<sub>2</sub>Et (Ph = [[phenyl]], Et = [[Ethyl group|ethyl]]). It is a white solid that is soluble in organic solvents. |
'''Triphenylcarbethoxymethylenephosphorane''' is an [[organophosphorus compound]] with the [[chemical formula]] Ph<sub>3</sub>PCHCO<sub>2</sub>Et (Ph = [[phenyl]], Et = [[Ethyl group|ethyl]]). It is a white solid that is soluble in organic solvents. |
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The compound is a [[Wittig reagent]]. It is used to replace oxygen centres in ketones and aldehydes with CHCO<sub>2</sub>Et.<ref>{{ OrgSynth | author = Lang, R. W.; Hansen, H.-J. | year = 2009 | title = Allenic Esters From α-Phosphoranylidene Esters and Acid Chlorides: Ethyl 2,3-Pentadienoate | collvol = 7 | collvolpages = 232 | prep = CV7P0232 }}</ref> |
The compound is a [[Wittig reagent]]. It is used to replace oxygen centres in ketones and aldehydes with CHCO<sub>2</sub>Et.<ref>{{ OrgSynth | author = Lang, R. W.; Hansen, H.-J. | year = 2009 | title = α-Allenic Esters From α-Phosphoranylidene Esters and Acid Chlorides: Ethyl 2,3-Pentadienoate | collvol = 7 | collvolpages = 232 | prep = CV7P0232 }}</ref> |
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==References== |
==References== |
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Revision as of 04:21, 20 May 2012
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| Names | |
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| Other names
(2-Ethoxy-2-oxoethylidene)triphenylphosphorane
(Carbethoxymethylene)triphenylphosphorane | |
| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.012.865 |
PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| C22H21O2P | |
| Molar mass | 348.382 g·mol−1 |
| Melting point | 124-129 °C |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Triphenylcarbethoxymethylenephosphorane is an organophosphorus compound with the chemical formula Ph3PCHCO2Et (Ph = phenyl, Et = ethyl). It is a white solid that is soluble in organic solvents.
The compound is a Wittig reagent. It is used to replace oxygen centres in ketones and aldehydes with CHCO2Et.[1]
References
- ^ Lang, R. W.; Hansen, H.-J. (2009). "α-Allenic Esters From α-Phosphoranylidene Esters and Acid Chlorides: Ethyl 2,3-Pentadienoate". Organic Syntheses
{{cite journal}}: CS1 maint: multiple names: authors list (link); Collected Volumes, vol. 7, p. 232.