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{{Antimony compounds}}
{{Antimony compounds}}
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{{Acetates}}


[[Category:Antimony compounds]]
[[Category:Antimony compounds]]

Revision as of 10:17, 20 July 2015

Antimony(III) acetate
Antimony(III) acetate
Names
IUPAC name
Antimony(III) acetate
Other names
Antimony triacetate
Acetic acid, antimony(3+) salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.027.312 Edit this at Wikidata
RTECS number
  • AF4200000
  • InChI=1S/3C2H4O2.Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3 checkY
    Key: JVLRYPRBKSMEBF-UHFFFAOYSA-K checkY
  • InChI=1/3C2H4O2.Sb.3H/c3*1-2(3)4;;;;/h3*1H3,(H,3,4);;;;/q;;;+3;;;/p-3/r3C2H4O2.H3Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);1H3/q;;;+3/p-3
    Key: NSMVVPJZMRQLMR-ZHOQVWKLAW
  • InChI=1/3C2H4O2.Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
    Key: JVLRYPRBKSMEBF-DFZHHIFOAU
  • CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[SbH3+3]
  • CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Sb+3]
Properties
C6H9O6Sb
Molar mass 298.892 g·mol−1
Appearance White powder
Density 1.22 g/cm³ (20 °C)
Melting point 128.5 °C (263.3 °F; 401.6 K) (decomposes to Sb2O3)
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Lethal dose or concentration (LD, LC):
4480 mg/kg (rat)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Antimony(III) acetate is the antimony salt of acetic acid with the chemical formula of Sb(CH3COO)3. It has the appearance of a white powder, is moderately water soluble, and is used as a catalyst in the production of synthetic fibers.

Preparation

It can be prepared by the reaction of antimony(III) oxide with acetic acid:

Sb2O3 + 6 HC2H3O2 → 2 Sb(C2H3O2)3 + 3H2O

Crystal Structure

The crystal structure of antimony(III) acetate has been determined by X-ray crystallography. It consists of discrete Sb(OAc)3 monomers with monodentate acetate ligands. The monomers are linked together into chains by weaker C=O···Sb intermolecular interactions.[1]

References

  1. ^ Hall, M.; Sowerby, D. B. (1980). "Antimony(III) acetate and thioacetate: spectra and crystal structures". J. Chem. Soc., Dalton Trans. (8): 1292–1296. doi:10.1039/DT9800001292.
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