Isopentane: Difference between revisions

Isopentane
Names
	IUPAC name 2-Methylbutane
Identifiers
CAS Number	78-78-4 ;
3D model (JSmol)	Interactive image;
Beilstein Reference	1730723
ChEBI	CHEBI:30362 ;
ChemSpider	6308 ;
ECHA InfoCard	100.001.039
EC Number	201-142-8;
Gmelin Reference	49318
MeSH	isopentane
PubChem CID	6556;
RTECS number	EK4430000;
UNII	ZH67814I0O ;
UN number	1265
CompTox Dashboard (EPA)	DTXSID901335409, DTXSID201032357 DTXSID8025468, DTXSID901335409, DTXSID201032357 ;
	InChI InChI=1S/C5H12/c1-4-5(2)3/h5H,4H2,1-3H3 Key: QWTDNUCVQCZILF-UHFFFAOYSA-N ;
	SMILES CCC(C)C;
Properties
Chemical formula	C5H12
Molar mass	72.151 g·mol−1
Appearance	Colorless liquid
Odor	Odorless
Density	616 mg mL−1
Melting point	−161 to −159 °C; −258 to −254 °F; 112 to 114 K
Boiling point	27.8 to 28.2 °C; 81.9 to 82.7 °F; 300.9 to 301.3 K
Vapor pressure	76.992 kPa (at 20 °C)
Henry's law; constant (kH)	7.2 nmol Pa−1 kg−1
UV-vis (λmax)	192 nm
Refractive index (nD)	1.354
Thermochemistry
Heat capacity (C)	164.85 J K−1 mol−1
Std molar; entropy (S⦵298)	260.41 J K−1 mol−1
Std enthalpy of; formation (ΔfH⦵298)	−179.1–−177.3 kJ mol−1
Std enthalpy of; combustion (ΔcH⦵298)	−3.5052–−3.5036 MJ mol−1
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H224, H304, H336, H411
Precautionary statements	P210, P261, P273, P301+P310, P331
NFPA 704 (fire diamond)	1 4 0
Flash point	−51 °C (−60 °F; 222 K)
Autoignition; temperature	420 °C (788 °F; 693 K)
Explosive limits	1.4–8.3%
Related compounds
Related alkanes	Isobutane; 2-Methylpentane; 3-Methylpentane; 3-Ethylpentane;
Related compounds	2-Ethyl-1-butanol
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

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Revision as of 05:15, 18 October 2015

Isopentane, C₅ H₁₂, also called methylbutane or 2-methylbutane, is a branched-chain alkane with five carbon atoms . Isopentane is an extremely volatile and extremely flammable liquid at room temperature and pressure. The normal boiling point is just a few degrees above room temperature and isopentane will readily boil and evaporate away on a warm day. Isopentane is commonly used in conjunction with liquid nitrogen to achieve a liquid bath temperature of −160 °C. It is 1% or less of natural gas.^[3]

Nomenclature

Isopentane is the name recommended by the International Union of Pure and Applied Chemistry (IUPAC).^[4] An isopentyl group is a subset of the generic pentyl group. It has the chemical structure -CH₂CH₂CH(CH₃)₂.

Isomers

Isopentane is one of three structural isomers with the molecular formula C₅H₁₂, the others being pentane (n-pentane) and neopentane (dimethyl propane).

Uses

Isopentane is used in a closed loop in geothermal power production to drive turbines.^[5]

Isopentane is used, in conjunction with dry ice or liquid nitrogen, to freeze tissues for cryosectioning in histology^[6].

References

^ "isopentane - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification and Related Records. Retrieved 5 March 2012.
^ James Wei (1999), Molecular Symmetry, Rotational Entropy, and Elevated Melting Points. Ind. Eng. Chem. Res., volume 38 issue 12, pp. 5019–5027 doi:10.1021/ie990588m
^ Georg Hammer, Torsten Lübcke, Roland Kettner, Mark R. Pillarella, Herta Recknagel, Axel Commichau, Hans-Joachim Neumann and Barbara Paczynska-Lahme "Natural Gas" in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. doi:10.1002/14356007.a17_073.pub2
^ Panico, R.; & Powell, W. H. (Eds.) (1994). A Guide to IUPAC Nomenclature of Organic Compounds 1993. Oxford: Blackwell Science. ISBN 0-632-03488-2.{{cite book}}: CS1 maint: multiple names: authors list (link)
^ Byproduct Isopentane also used in some of the LPG plant to run the boiler and generate the power. HS Orka HF Energy Plant IV
^ Freezing Tissues for Cryosectioning [1]

External links

International Chemical Safety Card 1153
IUPAC Nomenclature of Organic Chemistry (online version of the "Blue Book")

[1] "isopentane - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification and Related Records. Retrieved 5 March 2012.

[Wei-2] James Wei (1999), Molecular Symmetry, Rotational Entropy, and Elevated Melting Points. Ind. Eng. Chem. Res., volume 38 issue 12, pp. 5019–5027 doi:10.1021/ie990588m

[3] Georg Hammer, Torsten Lübcke, Roland Kettner, Mark R. Pillarella, Herta Recknagel, Axel Commichau, Hans-Joachim Neumann and Barbara Paczynska-Lahme "Natural Gas" in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. doi:10.1002/14356007.a17_073.pub2

[4] Panico, R.; & Powell, W. H. (Eds.) (1994). A Guide to IUPAC Nomenclature of Organic Compounds 1993. Oxford: Blackwell Science. ISBN 0-632-03488-2.{{cite book}}: CS1 maint: multiple names: authors list (link)

[5] Byproduct Isopentane also used in some of the LPG plant to run the boiler and generate the power. HS Orka HF Energy Plant IV

[6] Freezing Tissues for Cryosectioning [1]

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@@ Line 90: / Line 90: @@
 Isopentane is used in a closed loop in geothermal power production to drive turbines.<ref>
 Byproduct Isopentane also used in some of the LPG plant to run the boiler and generate the power.
 [http://hsorka.is/english/HSProduction/Svartsengi/OrkuverIV.aspx HS Orka HF Energy Plant IV]</ref>
+Isopentane is used, in conjunction with [[dry ice]] or [[liquid nitrogen]], to freeze tissues for [[cryosection|cryosectioning]] in [[histology]]<ref>Freezing Tissues for Cryosectioning [http://www.uab.edu/research/administration/offices/ARP/ComparativePathology/Pathology/Histopathology/TissueSubmission/Pages/Freezing-Tissues-for-Cryosectioning.aspx]</ref>.
 ==References==