Coking: Difference between revisions
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{{related|[[Coke (fuel)]], a carbon-rich solid obtained by coal |
{{related|[[Coke (fuel)]], a carbon-rich solid obtained by coal pyrolysis}} |
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'''Coking''' is the deposition of carbon-rich solids. In [[heterogeneous catalysis]], the process is undesirable because the [[Clinker (waste)|clinker]] blocks the catalytic sites. Coking is characteristic of high temperature reactions involving hydrocarbons feedstocks. Typically coking is reversed by combustion, provided that the catalyst will tolerate such.<ref>{{cite journal|title=“Coking” of zeolites during methanol conversion: Basic reactions of the MTO-, MTP- and MTG processes|journal=Catalysis Today|volume=154|pages=183-194|doi=10.1016/j.cattod.2010.05.012|author=H. Schultz}}</ref> |
'''Coking''' is the deposition of carbon-rich solids. In [[heterogeneous catalysis]], the process is undesirable because the [[Clinker (waste)|clinker]] blocks the catalytic sites. Coking is characteristic of high temperature reactions involving hydrocarbons feedstocks. Typically coking is reversed by combustion, provided that the catalyst will tolerate such.<ref>{{cite journal|title=“Coking” of zeolites during methanol conversion: Basic reactions of the MTO-, MTP- and MTG processes|journal=Catalysis Today|volume=154|pages=183-194|doi=10.1016/j.cattod.2010.05.012|author=H. Schultz}}</ref> |
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Coking is one of several mechanisms for the deactivation of a [[heterogeneous catalyst]]. Other mechanisms include [[sintering]], [[catalyst poisoning|poisoning]], and [[Phase transition|solid-state transformation]] of the catalyst.<ref>{{cite journal|title=Catalyst Deactivation|authors=Forzatti, P.; Lietti, L.|journal=Catalysis Today|year=1999|volume=52|pages=165-181|doi=10.1016/S0920-5861(99)00074-7}}</ref><ref>{{cite journal|last1=Bartholomew|first1=Calvin H|title=Mechanisms of Catalyst Deactivation|journal=Applied Catalysis A: General|volume=212|issue=1–2|pages=17–60|doi=10.1016/S0926-860X(00)00843-7|year=2001}}</ref> |
Coking is one of several mechanisms for the deactivation of a [[heterogeneous catalyst]]. Other mechanisms include [[sintering]], [[catalyst poisoning|poisoning]], and [[Phase transition|solid-state transformation]] of the catalyst.<ref>{{cite journal|title=Catalyst Deactivation|authors=Forzatti, P.; Lietti, L.|journal=Catalysis Today|year=1999|volume=52|pages=165-181|doi=10.1016/S0920-5861(99)00074-7}}</ref><ref>{{cite journal|last1=Bartholomew|first1=Calvin H|title=Mechanisms of Catalyst Deactivation|journal=Applied Catalysis A: General|volume=212|issue=1–2|pages=17–60|doi=10.1016/S0926-860X(00)00843-7|year=2001}}</ref> |
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Cooking tendency increases with in reading molecular weight |
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==References== |
==References== |
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Revision as of 17:11, 26 June 2019
Coking is the deposition of carbon-rich solids. In heterogeneous catalysis, the process is undesirable because the clinker blocks the catalytic sites. Coking is characteristic of high temperature reactions involving hydrocarbons feedstocks. Typically coking is reversed by combustion, provided that the catalyst will tolerate such.[1]
A simplified equation for coking is shown in the case of ethylene:
- 3 C2H4 → 2 C ("coke") + 2 C2H6
A more realistic but complex view involves the alkylation of an aromatic ring of a coke nucleus. Acidic catalysts are thus especially prone to coking because they are effective at generating carbocations (i.e., alkylating agents).
Coking is one of several mechanisms for the deactivation of a heterogeneous catalyst. Other mechanisms include sintering, poisoning, and solid-state transformation of the catalyst.[2][3]
References
- ^ H. Schultz. ""Coking" of zeolites during methanol conversion: Basic reactions of the MTO-, MTP- and MTG processes". Catalysis Today. 154: 183–194. doi:10.1016/j.cattod.2010.05.012.
- ^ "Catalyst Deactivation". Catalysis Today. 52: 165–181. 1999. doi:10.1016/S0920-5861(99)00074-7.
{{cite journal}}: Unknown parameter|authors=ignored (help) - ^ Bartholomew, Calvin H (2001). "Mechanisms of Catalyst Deactivation". Applied Catalysis A: General. 212 (1–2): 17–60. doi:10.1016/S0926-860X(00)00843-7.