Perfluorobutanesulfonic acid: Difference between revisions

Perfluorobutanesulfonic acid
Names
	Preferred IUPAC name Perfluorobutanesulfonic acid
	Systematic IUPAC name 1,1,2,2,3,3,4,4,4-Nonafluorobutane-1-sulfonic acid
	Other names FC-98; Nonaflate; Nonafluorobutanesulphonic acid; Perfluorobutane sulfonate; PFBS
Identifiers
CAS Number	375-73-5 ; 59933-66-3 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:132446 ;
ChemSpider	61132 ;
ECHA InfoCard	100.006.176
EC Number	206-793-1;
PubChem CID	67815;
RTECS number	EK5930000;
UN number	3094, 3265
CompTox Dashboard (EPA)	DTXSID5030030 ;
	InChI InChI=1S/C4HF9O3S/c5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h(H,14,15,16) Key: JGTNAGYHADQMCM-UHFFFAOYSA-N ; InChI=1S/C4HF9O3S/c5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h(H,14,15,16) Key: JGTNAGYHADQMCM-UHFFFAOYSA-N;
	SMILES OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F;
Properties
Chemical formula	C4HF9O3S
Molar mass	300.10 g/mol
Melting point	76 to 84 °C (169 to 183 °F; 349 to 357 K)
Boiling point	211 °C (412 °F; 484 K)
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H302, H314
Precautionary statements	P280, P305+P351+P338, P310
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

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Revision as of 22:26, 22 November 2019

Perfluorobutanesulfonic acid (PFBS) is a chemical compound with a four carbon fluorocarbon chain and a sulfonic acid functional group. As an anion it functions as a stable fluorosurfactant because of the strength of carbon–fluorine bonds.

Since June 2003, 3M has used PFBS as a replacement for the persistent, toxic, and bioaccumulative perfluorooctanesulfonic acid (PFOS) in its Scotchgard stain repellents.^[4]3M markets surfactant with PFBS in two fluorosurfactants.^[5]

PFBS has a half-life of a little over one month in people, much shorter than PFOS with 5.4 years.^[6] PFBS is persistent in the environment. Studies have not yet been specifically conducted to determine safety in humans.

References

^ "Nonafluorobutanesulphonic acid – 59933-66-3 Catalog of Chemical Suppliers". Retrieved 16 January 2009.
^ Template:ChemID
^ ^a ^b Sigma-Aldrich Co., Nonafluorobutane-1-sulfonic acid. Retrieved on 15 January 2018.
^ Ullah, Aziz (October 2006). "The Fluorochemical Dilemma: What the PFOS/PFOA fuss is all about" (PDF). Cleaning & Restoration. Retrieved 16 January 2009.
^ Renner R (January 2006). "The long and the short of perfluorinated replacements". Environ. Sci. Technol. 40 (1): 12–3. doi:10.1021/es062612a. PMID 16433328.
^ Betts KS (May 2007). "Perfluoroalkyl acids: what is the evidence telling us?". Environ. Health Perspect. 115 (5): A250–6. doi:10.1289/ehp.115-a250. PMC 1867999. PMID 17520044.

[1] "Nonafluorobutanesulphonic acid – 59933-66-3 Catalog of Chemical Suppliers". Retrieved 16 January 2009.

[ChemID-2] Template:ChemID

[Sigma-Aldrich-3] Sigma-Aldrich Co., Nonafluorobutane-1-sulfonic acid. Retrieved on 15 January 2018.

[4] Ullah, Aziz (October 2006). "The Fluorochemical Dilemma: What the PFOS/PFOA fuss is all about" (PDF). Cleaning & Restoration. Retrieved 16 January 2009.

[long-5] Renner R (January 2006). "The long and the short of perfluorinated replacements". Environ. Sci. Technol. 40 (1): 12–3. doi:10.1021/es062612a. PMID 16433328.

[Betts2007-6] Betts KS (May 2007). "Perfluoroalkyl acids: what is the evidence telling us?". Environ. Health Perspect. 115 (5): A250–6. doi:10.1289/ehp.115-a250. PMC 1867999. PMID 17520044.

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@@ Line 60: / Line 60: @@
 * [[PFNA]]
 * [[FBSA]]
+*[[Perfluorinated alkylated substances]] (PFAS)
+*[[Timeline of events related to per- and polyfluoroalkyl substances (PFAS)]]
 ==References==

Revision as of 22:26, 22 November 2019

See also

References