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== Structure ==
== Structure ==
The titanium group elements form layered hexagonal crystals that can be [[Intercalation (chemistry)|exfoliated]] to [[monolayer]]s. These contain [[ditelluride]] Te<sub>2</sub><sup>2-</sup> units.<ref name=":2">{{Cite journal|last=Chen|first=K-W|last2=Das|first2=S|last3=Rhodes|first3=D|last4=Memaran|first4=S|last5=Besara|first5=T|last6=Siegrist|first6=T|last7=Manousakis|first7=E|last8=Balicas|first8=L|last9=Baumbach|first9=R E|date=2016-04-13|title=Uncovering the behavior of Hf 2 Te 2 P and the candidate Dirac metal Zr 2 Te 2 P|url=https://iopscience.iop.org/article/10.1088/0953-8984/28/14/14LT01|journal=Journal of Physics: Condensed Matter|volume=28|issue=14|pages=14LT01|doi=10.1088/0953-8984/28/14/14LT01|issn=0953-8984|arxiv=1602.03252}}</ref> These layered compounds can be [[Intercalation (chemistry)|intercalated]] to form [[non-stoichiometric compound]]s with [[zinc]], [[copper]] or [[cadmium]] by heating with the metals.<ref>{{Cite journal|last=Yajima|first=Takeshi|last2=Koshiko|first2=Masaki|last3=Zhang|first3=Yaoqing|last4=Oguchi|first4=Tamio|last5=Yu|first5=Wen|last6=Kato|first6=Daichi|last7=Kobayashi|first7=Yoji|last8=Orikasa|first8=Yuki|last9=Yamamoto|first9=Takafumi|last10=Uchimoto|first10=Yoshiharu|last11=Green|first11=Mark A.|date=December 2016|title=Selective and low temperature transition metal intercalation in layered tellurides|url=http://www.nature.com/articles/ncomms13809|journal=Nature Communications|language=en|volume=7|issue=1|pages=13809|doi=10.1038/ncomms13809|issn=2041-1723|pmc=5171714|pmid=27966540|via=}}</ref> Actinide telluride phosphides contain diphosphide anions P<sub>2</sub>.<ref>{{Cite journal|last=Stolze|first=Karoline|last2=Isaeva|first2=Anna|last3=Schwarz|first3=Ulrich|last4=Doert|first4=Thomas|date=February 2015|title=UPTe, ThPTe and U 2 PTe 2 O: Actinide Pnictide Chalcogenides with Diphosphide Anions: Actinide Pnictide Chalcogenides with Diphosphide Anions|url=http://doi.wiley.com/10.1002/ejic.201402951|journal=European Journal of Inorganic Chemistry|language=en|volume=2015|issue=5|pages=778–785|doi=10.1002/ejic.201402951|via=}}</ref>
The titanium group elements form layered hexagonal crystals that can be [[Intercalation (chemistry)|exfoliated]] to [[monolayer]]s. These contain [[ditelluride]] Te<sub>2</sub><sup>2-</sup> units.<ref name=":2">{{Cite journal|last1=Chen|first1=K-W|last2=Das|first2=S|last3=Rhodes|first3=D|last4=Memaran|first4=S|last5=Besara|first5=T|last6=Siegrist|first6=T|last7=Manousakis|first7=E|last8=Balicas|first8=L|last9=Baumbach|first9=R E|date=2016-04-13|title=Uncovering the behavior of Hf 2 Te 2 P and the candidate Dirac metal Zr 2 Te 2 P|journal=Journal of Physics: Condensed Matter|volume=28|issue=14|pages=14LT01|doi=10.1088/0953-8984/28/14/14LT01|pmid=26953683|issn=0953-8984|arxiv=1602.03252|bibcode=2016JPCM...28nLT01C|s2cid=40508370}}</ref> These layered compounds can be [[Intercalation (chemistry)|intercalated]] to form [[non-stoichiometric compound]]s with [[zinc]], [[copper]] or [[cadmium]] by heating with the metals.<ref>{{Cite journal|last1=Yajima|first1=Takeshi|last2=Koshiko|first2=Masaki|last3=Zhang|first3=Yaoqing|last4=Oguchi|first4=Tamio|last5=Yu|first5=Wen|last6=Kato|first6=Daichi|last7=Kobayashi|first7=Yoji|last8=Orikasa|first8=Yuki|last9=Yamamoto|first9=Takafumi|last10=Uchimoto|first10=Yoshiharu|last11=Green|first11=Mark A.|date=December 2016|title=Selective and low temperature transition metal intercalation in layered tellurides|journal=Nature Communications|language=en|volume=7|issue=1|pages=13809|doi=10.1038/ncomms13809|issn=2041-1723|pmc=5171714|pmid=27966540|bibcode=2016NatCo...713809Y}}</ref> Actinide telluride phosphides contain diphosphide anions P<sub>2</sub>.<ref>{{Cite journal|last1=Stolze|first1=Karoline|last2=Isaeva|first2=Anna|last3=Schwarz|first3=Ulrich|last4=Doert|first4=Thomas|date=February 2015|title=UPTe, ThPTe and U 2 PTe 2 O: Actinide Pnictide Chalcogenides with Diphosphide Anions: Actinide Pnictide Chalcogenides with Diphosphide Anions|journal=European Journal of Inorganic Chemistry|language=en|volume=2015|issue=5|pages=778–785|doi=10.1002/ejic.201402951}}</ref>


==List==
==List==
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|<ref name=":1">{{Cite web|title=Prinzipien der Syntheseplanung in der anorganischen Festkörperchemie: Analyse der Phasenbildung in Systemen M/P/Te, M = Ti, Ce, Si|url=https://tud.qucosa.de/enwiki/api/qucosa%3A23662/attachment/ATT-0/|last=Philipp|first=Frauke|date=16 October 2008|website=Qucosa|url-status=live|archive-url=|archive-date=|access-date=}}</ref><ref name=":3">{{Cite journal|last=Baldus|first=Hans Peter|last2=Blachnik|first2=Roger|date=1990-12-01|title=Neue A4B3-Moleküle: P3SbS3, P4S2Te und P4STe2 / New A4B3 Molecules: P3SbS3, P4S2Te and P4STe2|url=https://www.degruyter.com/view/journals/znb/45/12/article-p1605.xml|journal=Zeitschrift für Naturforschung B|volume=45|issue=12|pages=1605–1609|doi=10.1515/znb-1990-1201|issn=1865-7117}}</ref>
|<ref name=":1">{{Cite web|title=Prinzipien der Syntheseplanung in der anorganischen Festkörperchemie: Analyse der Phasenbildung in Systemen M/P/Te, M = Ti, Ce, Si|url=https://tud.qucosa.de/enwiki/api/qucosa%3A23662/attachment/ATT-0/|last=Philipp|first=Frauke|date=16 October 2008|website=Qucosa|url-status=live|archive-url=|archive-date=|access-date=}}</ref><ref name=":3">{{Cite journal|last1=Baldus|first1=Hans Peter|last2=Blachnik|first2=Roger|date=1990-12-01|title=Neue A4B3-Moleküle: P3SbS3, P4S2Te und P4STe2 / New A4B3 Molecules: P3SbS3, P4S2Te and P4STe2|url=https://www.degruyter.com/view/journals/znb/45/12/article-p1605.xml|journal=Zeitschrift für Naturforschung B|volume=45|issue=12|pages=1605–1609|doi=10.1515/znb-1990-1201|s2cid=97778193|issn=1865-7117}}</ref>
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|also monolayer
|also monolayer
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|<ref>{{Cite journal|last=Tschulik|first=Kristina|last2=Ruck|first2=Michael|last3=Binnewies|first3=Michael|last4=Milke|first4=Edgar|last5=Hoffmann|first5=Stefan|last6=Schnelle|first6=Walter|last7=Fokwa|first7=Boniface P. T.|last8=Gilleßen|first8=Michael|last9=Schmidt|first9=Peer|date=July 2009|title=Chemistry and Physical Properties of the Phosphide Telluride Zr 2 PTe 2|url=http://doi.wiley.com/10.1002/ejic.200900346|journal=European Journal of Inorganic Chemistry|language=en|volume=2009|issue=21|pages=3102–3110|doi=10.1002/ejic.200900346|via=}}</ref>
|<ref>{{Cite journal|last1=Tschulik|first1=Kristina|last2=Ruck|first2=Michael|last3=Binnewies|first3=Michael|last4=Milke|first4=Edgar|last5=Hoffmann|first5=Stefan|last6=Schnelle|first6=Walter|last7=Fokwa|first7=Boniface P. T.|last8=Gilleßen|first8=Michael|last9=Schmidt|first9=Peer|date=July 2009|title=Chemistry and Physical Properties of the Phosphide Telluride Zr 2 PTe 2|journal=European Journal of Inorganic Chemistry|language=en|volume=2009|issue=21|pages=3102–3110|doi=10.1002/ejic.200900346}}</ref>
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|<ref>{{Cite journal|last=Zintl|first=E.|date=1939-01-07|title=Intermetallische Verbindungen|url=http://doi.wiley.com/10.1002/ange.19390520102|journal=Angewandte Chemie|language=de|volume=52|issue=1|pages=1–6|doi=10.1002/ange.19390520102}}</ref>
|<ref>{{Cite journal|last=Zintl|first=E.|date=1939-01-07|title=Intermetallische Verbindungen|journal=Angewandte Chemie|language=de|volume=52|issue=1|pages=1–6|doi=10.1002/ange.19390520102}}</ref>
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|<ref name=":1" /><ref>{{Cite journal|last=Jörgens|first=Stefan|last2=Johrendt|first2=Dirk|last3=Mewis|first3=Albrecht|date=2003-06-06|title=BaP4Te2—A Ternary Telluride with P-Te Bonds and a Structural Fragment of Black Phosphorus|url=http://doi.wiley.com/10.1002/chem.200304858|journal=Chemistry - A European Journal|volume=9|issue=11|pages=2405–2410|doi=10.1002/chem.200304858|via=}}</ref>
|<ref name=":1" /><ref>{{Cite journal|last1=Jörgens|first1=Stefan|last2=Johrendt|first2=Dirk|last3=Mewis|first3=Albrecht|date=2003-06-06|title=BaP4Te2—A Ternary Telluride with P-Te Bonds and a Structural Fragment of Black Phosphorus|journal=Chemistry - A European Journal|volume=9|issue=11|pages=2405–2410|doi=10.1002/chem.200304858|pmid=12794885}}</ref>
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|<ref>{{Cite journal|last=Kliche|first=Gerhard|date=1986-01-01|title=NOTIZEN: Iridiumphosphidtellurid, IrPTe / Iridium Phosphide Telluride, IrPTe|url=https://www.degruyter.com/view/journals/znb/41/1/article-p130.xml|journal=Zeitschrift für Naturforschung B|volume=41|issue=1|pages=130–131|doi=10.1515/znb-1986-0126|issn=1865-7117}}</ref>
|<ref>{{Cite journal|last=Kliche|first=Gerhard|date=1986-01-01|title=NOTIZEN: Iridiumphosphidtellurid, IrPTe / Iridium Phosphide Telluride, IrPTe|url=https://www.degruyter.com/view/journals/znb/41/1/article-p130.xml|journal=Zeitschrift für Naturforschung B|volume=41|issue=1|pages=130–131|doi=10.1515/znb-1986-0126|s2cid=98059160|issn=1865-7117}}</ref>
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|<ref>{{Cite journal|last=Lutz|first=H. D.|last2=Schmidt|first2=Th.|last3=Wäschenbach|first3=G.|date=1988|title=Phasendiagramme von Chalkogeniden und Pnictiden des Rutheniums und Osmiums mit Pyrit-, Markasit-, Löllingit‐ und Arsenopyritstruktur|url=http://doi.wiley.com/10.1002/zaac.19885620102|journal=Zeitschrift für anorganische und allgemeine Chemie|language=de|volume=562|issue=1|pages=7–16|doi=10.1002/zaac.19885620102|issn=0044-2313|via=}}</ref>
|<ref>{{Cite journal|last1=Lutz|first1=H. D.|last2=Schmidt|first2=Th.|last3=Wäschenbach|first3=G.|date=1988|title=Phasendiagramme von Chalkogeniden und Pnictiden des Rutheniums und Osmiums mit Pyrit-, Markasit-, Löllingit‐ und Arsenopyritstruktur|journal=Zeitschrift für anorganische und allgemeine Chemie|language=de|volume=562|issue=1|pages=7–16|doi=10.1002/zaac.19885620102|issn=0044-2313}}</ref>
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Revision as of 11:56, 26 August 2020

The telluride phosphides are a class of mixed anion compounds containing both telluride and phosphide ions (Te2− P3−). The phosphidotelluride or telluridophosphide compounds have a [TeP]3− group in which the tellurium atom has a bond to the phosphorus atom. A formal charge of −2 is on the phosphorus and −1 on the tellurium. There is no binary compound of tellurium and phosphorus. Not many telluride phosphides are known, but they have been discovered for noble metals, actinides, and group 4 elements.

Structure

The titanium group elements form layered hexagonal crystals that can be exfoliated to monolayers. These contain ditelluride Te22- units.[1] These layered compounds can be intercalated to form non-stoichiometric compounds with zinc, copper or cadmium by heating with the metals.[2] Actinide telluride phosphides contain diphosphide anions P2.[3]

List

Artificial

name formula MW ratio

Te:P

system space group unit cell

Å

volume density optical band gap CAS references
P4S2Te molecular [4][5]
P4STe2 molecular [4][5]
Ti2PTe2 hexagonal R3m a=3.6387 c=28.486 metallic on c axis also monolayer [4]
Zr2PTe2 rhombohedral R3m a=3.8117 c=29.189 Z=3 367.27 6.356 black also monolayer [6]
RuTeP [7]
BaP4Te orthorhombic Pnma with a =16.486 b =6.484 c =7.076 Z =4 [4][8]
CeP0.4Te1.6 [4]
CeP1.1Te0.9 [4]
cerium phosphide telluride Ce3Te3P 3:1 [9]
Hf2Te2P R3m a=3.7946 c=29.14 also monolayer [1]
IrTeP orthorhombic a=6.030 b=6.131 c=12.132 [10]
OsTeP 1:1 arsenopyrite structure P21/c a = 6.2291 b = 6.1604 c = 6.2449 β = 112.01° 222.2 10.43 [11]
ThPTe 1:1 tetragonal a = 4.2505 and c = 17.268
UPTe tetragonal a=4.100 c=17.026 [12]
U2PTe2O pseudo tetragonal a = 40.37c = 32.07
NpPTe tetragonal P4/nmm a=4.265 c=9.067 [12]
PuPTe tetragonal P4/nmm a=4.289 c=9.098 [12]
AmPTe tetragonal P4/nmm a=4.269 c=9.050 [12]

References

  1. ^ a b Chen, K-W; Das, S; Rhodes, D; Memaran, S; Besara, T; Siegrist, T; Manousakis, E; Balicas, L; Baumbach, R E (2016-04-13). "Uncovering the behavior of Hf 2 Te 2 P and the candidate Dirac metal Zr 2 Te 2 P". Journal of Physics: Condensed Matter. 28 (14): 14LT01. arXiv:1602.03252. Bibcode:2016JPCM...28nLT01C. doi:10.1088/0953-8984/28/14/14LT01. ISSN 0953-8984. PMID 26953683. S2CID 40508370.
  2. ^ Yajima, Takeshi; Koshiko, Masaki; Zhang, Yaoqing; Oguchi, Tamio; Yu, Wen; Kato, Daichi; Kobayashi, Yoji; Orikasa, Yuki; Yamamoto, Takafumi; Uchimoto, Yoshiharu; Green, Mark A. (December 2016). "Selective and low temperature transition metal intercalation in layered tellurides". Nature Communications. 7 (1): 13809. Bibcode:2016NatCo...713809Y. doi:10.1038/ncomms13809. ISSN 2041-1723. PMC 5171714. PMID 27966540.
  3. ^ Stolze, Karoline; Isaeva, Anna; Schwarz, Ulrich; Doert, Thomas (February 2015). "UPTe, ThPTe and U 2 PTe 2 O: Actinide Pnictide Chalcogenides with Diphosphide Anions: Actinide Pnictide Chalcogenides with Diphosphide Anions". European Journal of Inorganic Chemistry. 2015 (5): 778–785. doi:10.1002/ejic.201402951.
  4. ^ a b c d e f Philipp, Frauke (16 October 2008). "Prinzipien der Syntheseplanung in der anorganischen Festkörperchemie: Analyse der Phasenbildung in Systemen M/P/Te, M = Ti, Ce, Si". Qucosa.{{cite web}}: CS1 maint: url-status (link)
  5. ^ a b Baldus, Hans Peter; Blachnik, Roger (1990-12-01). "Neue A4B3-Moleküle: P3SbS3, P4S2Te und P4STe2 / New A4B3 Molecules: P3SbS3, P4S2Te and P4STe2". Zeitschrift für Naturforschung B. 45 (12): 1605–1609. doi:10.1515/znb-1990-1201. ISSN 1865-7117. S2CID 97778193.
  6. ^ Tschulik, Kristina; Ruck, Michael; Binnewies, Michael; Milke, Edgar; Hoffmann, Stefan; Schnelle, Walter; Fokwa, Boniface P. T.; Gilleßen, Michael; Schmidt, Peer (July 2009). "Chemistry and Physical Properties of the Phosphide Telluride Zr 2 PTe 2". European Journal of Inorganic Chemistry. 2009 (21): 3102–3110. doi:10.1002/ejic.200900346.
  7. ^ Zintl, E. (1939-01-07). "Intermetallische Verbindungen". Angewandte Chemie (in German). 52 (1): 1–6. doi:10.1002/ange.19390520102.
  8. ^ Jörgens, Stefan; Johrendt, Dirk; Mewis, Albrecht (2003-06-06). "BaP4Te2—A Ternary Telluride with P-Te Bonds and a Structural Fragment of Black Phosphorus". Chemistry - A European Journal. 9 (11): 2405–2410. doi:10.1002/chem.200304858. PMID 12794885.
  9. ^ Schmidt, Peer; Dallmann, Hannelore; Kadner, Gudrun; Krug, Jutta; Philipp, Frauke; Teske, Klaus (October 2009). "The thermochemical behaviour of Te8O10(PO4)4 and its use for phosphide telluride synthesis". Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie. 635 (13–14): 2153. doi:10.1002/zaac.200900350.
  10. ^ Kliche, Gerhard (1986-01-01). "NOTIZEN: Iridiumphosphidtellurid, IrPTe / Iridium Phosphide Telluride, IrPTe". Zeitschrift für Naturforschung B. 41 (1): 130–131. doi:10.1515/znb-1986-0126. ISSN 1865-7117. S2CID 98059160.
  11. ^ Lutz, H. D.; Schmidt, Th.; Wäschenbach, G. (1988). "Phasendiagramme von Chalkogeniden und Pnictiden des Rutheniums und Osmiums mit Pyrit-, Markasit-, Löllingit‐ und Arsenopyritstruktur". Zeitschrift für anorganische und allgemeine Chemie (in German). 562 (1): 7–16. doi:10.1002/zaac.19885620102. ISSN 0044-2313.
  12. ^ a b c d . pp. 153–154. ISBN 9783540456841. {{cite book}}: Missing or empty |title= (help)
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