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Fossil fuel power station

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A working coal plant in Rochester, Minnesota
The St. Clair Power Plant, a large coal fired generating station in Michigan.
Sources of electricity in the U.S. in 2009.[1]

A fossil-fuel power station is a power station that burns fossil fuels such as coal, natural gas or petroleum (oil) to produce electricity. Central station fossil-fuel power plants are designed on a large scale for continuous operation. In many countries, such plants provide most of the electrical energy used.

Fossil fuel power stations (except for MHD generators) have some kind of rotating machinery to convert the heat energy of combustion into mechanical energy, which then operate an electrical generator. The prime mover may be a steam turbine, a gas turbine or, in small isolated plants, a reciprocating internal combustion engine. All plants use the drop between the high pressure and temperature of the steam or combusting fuel and the lower pressure of the atmosphere or condensing vapour in the steam turbine.

Byproducts of power thermal plant operation need to be considered in both the design and operation. Waste heat due to the finite efficiency of the power cycle must be released to the atmosphere, using a cooling tower, or river or lake water as a cooling medium. The flue gas from combustion of the fossil fuels is discharged to the air; this contains carbon dioxide and water vapour, as well as other substances such as nitrogen, nitrogen oxides, sulfur oxides, and (in the case of coal-fired plants) fly ash, mercury and traces of other metals. Solid waste ash from coal-fired boilers must also be removed. Some coal ash can be recycled for building materials.

Fossil fueled power stations are major emitters of CO2, the most important greenhouse gas (GHG) which according to the consensus of scientific organisations is a major contributor to the global warming observed over the last 100 years. Brown coal emits 3 times as much CO2 as natural gas, black coal emits twice as much CO2 per unit of electric energy. Carbon capture and storage of emissions are not expected to be available on a commercial economically viable basis until 2025.

Basic concepts

In a fossil fuel power plant the chemical energy stored in fossil fuels (such as coal, fuel oil, natural gas or oil shale) and oxygen of the air is converted successively into thermal energy, mechanical energy and, finally, electrical energy for continuous use and distribution across a wide geographic area. Each fossil fuel power plant is a highly complex, custom-designed system. Construction costs, as of 2004, run to US$1,300 per kilowatt, or $650 million for a 500 MWe unit[citation needed]. Multiple generating units may be built at a single site for more efficient use of land, natural resources and labour. Most thermal power stations in the world use fossil fuel, outnumbering nuclear, geothermal, biomass, or solar thermal plants.

Heat into mechanical energy

The second law of thermodynamics states that any closed-loop cycle can only convert a fraction of the heat produced during combustion into mechanical work. The rest of the heat, called waste heat, must be released into a cooler environment during the return portion of the cycle. The fraction of heat released into a cooler medium must be equal or larger than the ratio of absolute temperatures of the cooling system (environment) and the heat source (combustion furnace). Raising the furnace temperature improves the efficiency but also increases the steam pressure, complicates the design and makes the furnace more expensive. The waste heat cannot be converted into mechanical energy without an even cooler cooling system. However, it may be used in cogeneration plants to heat buildings, produce hot water, or to heat materials on an industrial scale, such as in some oil refineries, plants, and chemical synthesis plants.

Typical thermal efficiency for electrical generators in the industry is around 33% for coal and oil-fired plants, and up to 50% for combined-cycle gas-fired plants. Plants designed to achieve peak effiency while operating at capacity will be less efficient when operating off-design (i.e. temperatures too low.)[2]

The Carnot cycle is the theoretically most efficient closed thermodynamic cycle for conversion of heat energy into useful work, and practical fossil-fuel stations cannot exceed this limit. In principle, fuel cells do not have the same thermodynamic limits as they are not heat engines.

Fuel transport and delivery

Big Bend Coal Power Station in Apollo Beach, Florida in the United States.
Coal fired power plants provide about 50% of consumed electricity in the United States. This is the Castle Gate Plant near Helper, Utah.

Coal is delivered by highway truck, rail, barge, collier ship or coal slurry pipeline. Some plants are even built near coal mines and coal is delivered by conveyors. A large coal train called a "unit train" may be two kilometers (over a mile) long, containing 100 cars with 100 short tons of coal in each one, for a total load of 10,000 tons. A large plant under full load requires at least one coal delivery this size every day. Plants may get as many as three to five trains a day, especially in "peak season" during the hottest Summer and/or coldest Winter months (depending on local climate) when power consumption is high. A large thermal power plant such as the one in Nanticoke, Ontario stores several million metric tons of coal for winter use when the lakes are frozen.

Modern unloaders use rotary dump devices, which eliminate problems with coal freezing in bottom dump cars. The unloader includes a train positioner arm that pulls the entire train to position each car over a coal hopper. The dumper clamps an individual car against a platform that swivels the car upside down to dump the coal. Swiveling couplers enable the entire operation to occur while the cars are still coupled together. Unloading a unit train takes about three hours.

Shorter trains may use railcars with an "air-dump", which relies on air pressure from the engine plus a "hot shoe" on each car. This "hot shoe" when it comes into contact with a "hot rail" at the unloading trestle, shoots an electric charge through the air dump apparatus and causes the doors on the bottom of the car to open, dumping the coal through the opening in the trestle. Unloading one of these trains takes anywhere from an hour to an hour and a half. Older unloaders may still use manually operated bottom-dump rail cars and a "shaker" attached to dump the coal. Generating stations adjacent to a mine may receive coal by conveyor belt or massive diesel-electric-drive trucks.

A collier (cargo ship carrying coal) may hold 40,000 long tons of coal and takes several days to unload. Some colliers carry their own conveying equipment to unload their own bunkers; others depend on equipment at the plant. Colliers are large, seaworthy, self-powered ships. For transporting coal in calmer waters, such as rivers and lakes, flat-bottomed vessels called barges are often used. Barges are usually unpowered and must be moved by tugboats or towboats.

For start up or auxiliary purposes, the plant may use fuel oil as well. Fuel oil can be delivered to plants by pipeline, tanker, tank car or truck. Oil is stored in vertical cylindrical steel tanks with capacities as high as 90,000 barrels (14,000 m3)' worth. The heavier no. 5 "bunker" and no. 6 fuels are typically steam-heated before pumping in cold climates.

Plants fueled by natural gas are usually built adjacent to gas transport pipelines or have dedicated gas pipelines extended to them.

Fuel processing

Coal is prepared for use by crushing the rough coal to pieces less than 2 inches (5 cm) in size. The coal is then transported from the storage yard to in-plant storage silos by rubberized conveyor belts at rates up to 4,000 short tons per hour.

In plants that burn pulverized coal, silos feed coal pulverizers (coal mills) that take the larger 2-inch (51 mm) pieces, grind them to the consistency of face powder, sort them, and mix them with primary combustion air which transports the coal to the furnace and preheats the coal to drive off excess moisture content. A 500 MWe plant may have six such pulverizers, five of which can supply coal to the furnace at 250 tons per hour under full load.

In plants that do not burn pulverized coal, the larger 2-inch (51 mm) pieces may be directly fed into the silos which then feed either mechanical distributors that drop the coal on a traveling grate or the cyclone burners, a specific kind of combustor that can efficiently burn larger pieces of fuel.

Steam-electric

Most electric power made from fossil fuel is produced by thermal power stations. Reciprocating steam engines fell out of use rapidly after the first steam turbines were introduced around 1906.

Gas turbine plants

480 megawatt GE H series power generation gas turbine
Currant Creek Power Plant near Mona, Utah is a natural gas fired electrical plant.

One type of fossil fuel power plant uses a gas turbine in conjunction with a heat recovery steam generator (HRSG). It is referred to as a combined cycle power plant because it combines the Brayton cycle of the gas turbine with the Rankine cycle of the HRSG. The thermal efficiency of these plants has reached a record heat rate of 5690 Btu/(kW·h), or just under 60%, at a facility in Baglan Bay, Wales.[3]

The turbines are fueled either with natural gas, syngas or fuel oil. While more efficient and faster to construct (a 1,000 MW plant may be completed in as little as 18 months from start of construction), the economics of such plants is heavily influenced by the volatile cost of fuel, normally natural gas. The combined cycle plants are designed in a variety of configurations composed of the number of gas turbines followed by the steam turbine. For example, a 3-1 combined cycle facility has three gas turbines tied to one steam turbine. The configurations range from (1-1), (2-1), (3-1), (4-1), (5-1), to (6-1)

Simple-cycle or open cycle gas turbine plants, without a steam cycle, are sometimes installed as emergency or peaking capacity; their thermal efficiency is much lower. The high running cost per hour is offset by the low capital cost and the intention to run such units only a few hundred hours per year. Other gas turbine plants are installed in stages, with an open cycle gas turbine the first stage and additional turbines or conversion to a closed cycle part of future project plans.

Reciprocating engines

Diesel engine generator sets are often used for prime power in communities not connected to a widespread power grid. Emergency (standby) power systems may use reciprocating internal combustion engines operated by fuel oil or natural gas. Standby generators may serve as emergency power for a factory or data center, or may also be operated in parallel with the local utility system to reduce peak power demand charge from the utility. Diesel engines can produce strong torque at relatively low rotational speeds, which is generally desirable when driving an alternator, but diesel fuel in long-term storage can be subject to problems resulting from water accumulation and chemical decomposition. Rarely-used generator sets may correspondingly be installed as natural gas or LPG to minimize the fuel system maintenance requirements.

Spark-ignition internal combustion engines operating on gasoline (petrol), propane, or LPG are commonly used as portable temporary power sources for construction work, emergency power, or recreational uses.

Reciprocating external combustion engines such as the Stirling engine can be run on a variety of fossil fuels, as well as renewable fuels or industrial waste heat. Installations of Stirling engines for power production are relatively uncommon.

Environmental impacts

The Mohave Power Station, a 1,580 MW coal power station near Laughlin, Nevada, out of service since 2005 due to environmental restrictions[4]

The world's power demands are expected to rise 60% by 2030.[5] With the worldwide total of active coal plants over 50,000 and rising,[6] the International Energy Agency (IEA) estimates that fossil fuels will account for 85% of the energy market by 2030.[5]

World organizations and international agencies, like the IEA, are concerned about the environmental impact of burning fossil fuels, and coal in particular. The combustion of coal contributes the most to acid rain and air pollution, and has been connected with global warming. Due to the chemical composition of coal there are difficulties in removing impurities from the solid fuel prior to its combustion. Modern day coal power plants pollute very little due to new technologies in "scrubber" designs that filter the exhaust air in smoke stacks. Nowadays, the only pollution caused from coal-fired power plants comes from the emission of gases—carbon dioxide, nitrogen oxides, and sulfur dioxide into the air. Acid rain is caused by the emission of nitrogen oxides and sulfur dioxide into the air. These themselves may be only mildly acidic, yet when they react with the atmosphere, they create acidic compounds (such as sulfurous acid, nitric acid and sulfuric acid) that fall as rain, hence the term acid rain. In Europe and the U.S.A., stricter emission laws and decline in heavy industries have reduced the environmental hazards associated with this problem, leading to lower emissions after their peak in 1960s.

European Environment Agency (EEA) gives fuel-dependent emission factors based on actual emissions from power plants in EU.[7]

Pollutant Hard coal Brown coal Fuel oil Other oil Gas
CO2 (g/GJ) 94600 101000 77400 74100 56100
SO2 (g/GJ) 765 1361 1350 228 0.68
NOx (g/GJ) 292 183 195 129 93.3
CO (g/GJ) 89.1 89.1 15.7 15.7 14.5
Non methane organic compounds (g/GJ) 4.92 7.78 3.70 3.24 1.58
Particulate matter (g/GJ) 1203 3254 16 1.91 0.1
Flue gas volume total (m3/GJ) 360 444 279 276 272

Carbon dioxide

Electricity generation using carbon based fuels is responsible for a large fraction of carbon dioxide (CO2) emissions worldwide and for 41% of U.S. man-made carbon dioxide emissions.[8] Of fossil fuels, coal combustion in thermal power stations result in greater amounts of carbon dioxide emissions per unit of electricity generated (2249 lbs/MWh[9]) while oil produces less (1672 lb/(MW·h)[10] or 211 kg/GJ) and natural gas produces the least 1135 lb/(MW·h) (143 kg/GJ).[11])

The Intergovernmental Panel on Climate Change (see IPCC) states that carbon dioxide is a greenhouse gas and that increased quantities within the atmosphere will "very likely" lead to higher average temperatures on a global scale (global warming); concerns regarding the potential for such warming to change the global climate prompted IPCC recommendations calling for large cuts to CO2 emissions worldwide.[12]

Emissions may be reduced through more efficient and higher combustion temperature and through more efficient production of electricity within the cycle. Carbon capture and storage (CCS) of emissions from coal fired power stations is another alternative but the technology is still being developed and will increase the cost of fossil fuel-based production of electricity. CCS may not be economically viable, unless the price of emitting CO2 to the atmosphere rises.

Particulate matter

Another problem related to coal combustion is the emission of particulates that have a serious impact on public health. Power plants remove particulate from the flue gas with the use of a bag house or electrostatic precipitator. Several newer plants that burn coal use a different process, Integrated Gasification Combined Cycle in which synthesis gas is made out of a reaction between coal and water. The synthesis gas is processed to remove most pollutants and then used initially to power gas turbines. Then the hot exhaust gases from the gas turbines are used to generate steam to power a steam turbine. The pollution levels of such plants are drastically lower than those of "classic" coal power plants.[13]

Particulate matter from coal-fired plants can be harmful and have negative health impacts. Studies have shown that exposure to particulate matter is related to an increase of respiratory and cardiac mortality.[14] Particulate matter can irritate small airways in the lungs, which can lead to increased problems with asthma, chronic bronchitis, airway obstruction, and gas exchange.[14]

There are different types of particulate matter, depending on the chemical composition and size. The dominant form of particulate matter from coal-fired plants is coal fly ash, but secondary sulfate and nitrate also comprise a major portion of the particulate matter from coal-fired plants.[15] Coal fly ash is what remains after the coal has been combusted, so it consists of the incombustible materials that are found in the coal.[16]

The size and chemical composition of these particles affects the impacts on human health.[14][15] Currently coarse (diameter greater than 2.5 μm) and fine (diameter between 0.1 μm and 2.5 μm) particles are regulated, but ultrafine particles (diameter less than 0.1 μm) are currently unregulated, yet they pose many dangers.[14] Unfortunately much is still unknown as to which kinds of particulate matter pose the most harm, which makes it difficult to come up with adequate legislation for regulating particulate matter.[15]

There are several methods of helping to reduce the particulate matter emissions from coal-fired plants. Roughly 80% of the ash falls into an ash hopper, but the rest of the ash then gets carried into the atmosphere to become coal-fly ash.[16] Methods of reducing these emissions of particulate matter include:

  1. a baghouse
  2. an electrostatic precipitator (ESP)
  3. cyclone collector

The baghouse has a fine filter that collects the ash particles, electrostatic precipitators use an electric field to trap ash particles on high-voltage plates, and cyclone collectors use centrifugal force to trap particles to the walls.[16]

Radioactive trace elements

As most ores in the Earth's crust, coal also contains low levels of uranium, thorium, and other naturally occurring radioactive isotopes whose release into the environment leads to radioactive contamination. While these substances are present as very small trace impurities, enough coal is burned that significant amounts of these substances are released. A 1,000 MW coal-burning power plant could have an uncontrolled release of as much as 5.2 metric tons per year of uranium (containing 74 pounds (34 kg) of uranium-235) and 12.8 metric tons per year of thorium.[17] In comparison, a 1,000 MW nuclear plant will generate about 500 pounds of plutonium and 30 short tons of high-level radioactive controlled waste.[18] Just one accident like Chernobyl can release 35 times as much radiation in 10 days as the total radioactive emissions from coal power plants on the entire planet Earth over the course of a century. The Chernobyl accident is estimated to have released 25–50 million curies (2,5–5 exabecquerels) (IAEA estimations), whereas the collective radioactivity resulting from all coal burning worldwide between 1937 and 2040 is estimated to be 2,700,000 curies or 0.101 EBq).[17] However, it is estimated that during 1982, US coal burning released 155 times as much uncontrolled radioactivity into the atmosphere as the Three Mile Island incident.[19] It should also be noted that during normal operation, the effective dose equivalent from coal plants is 100 times that from nuclear plants.[17]

Water and air contamination by coal ash

A study released in August 2010 that examined state pollution data in the United States by the organizations Environmental Integrity Project, the Sierra Club and Earthjustice found that coal ash produced by coal-fired power plants dumped at sites across 21 U.S. states has contaminated ground water with toxic elements. The contaminants including the poisons arsenic and lead. [20]

Arsenic has been shown to cause skin cancer, bladder cancer and lung cancer, and lead damages the nervous system.[21] Coal ash contaminants are also linked to respiratory diseases and other health and developmental problems, and have disrupted local aquatic life.[20] Additional contaminants emitted include boron, which attacks the testes, kidney and brain, and the heavy metal mercury, a neurotoxicant particularly harmful to a child's development, causing nerve damage and impairment of a child's ability to write, read and learn. Coal ash also releases a variety of toxic contaminants into nearby air, posing a health threat to those who breath in fugitive coal dust.[22]

Currently, the EPA does not regulate the disposal of coal ash; regulation is up to the states and the electric power industry has been lobbying to maintain this status quo. Most states require no monitoring of drinking water near coal ash dump sites. The study found an additional 39 contaminated U.S. sites and concluded that the problem of coal ash-caused water contamination is even more extensive in the United States than has been estimated. The study brought to 137 the number of ground water sites across the United States that are contaminated by power plant-produced coal ash.[20]

Range of mercury contamination in fish

U.S. government scientists tested fish in 291 streams around the country for mercury contamination. They found mercury in every fish tested, according to the study by the U.S. Department of the Interior. They found mercury even in fish of isolated rural waterways. Twenty five percent of the fish tested had mercury levels above the safety levels determined by the U.S. Environmental Protection Agency for people who eat the fish regularly. The largest source of mercury contamination in the United States is coal-fueled power plant emissions.[23]

Greening of fossil fuel power plants

At present, several methods exist to improve the efficiency of fossil fuel power plants. A frequently used and cost-efficient method is to convert a plant to run on a different fuel. This includes conversions as biomass and waste.[24][25][26] Conversions to waste-fired power plants have the benefit that they can be used to eliminate existing landfills. In addition, waste fired power plants can be equipped with material recovery, allowing again additional environmental gain.

Regardless of the conversion, in order to become a truly green fossil fuel power plant, carbon capture and storage may be implemented. CCS means that the exhaust CO2 is captured. This method allows any fossil fuel power plants to be converted to a emissionless power plant. Examples of a CCS fossil fuel power plant includes the Elsam power station near Esbjerg, Denmark.[27]

Clean coal

"Clean coal" is the name attributed to a process whereby coal is chemically washed of minerals and impurities, sometimes gasified, burned and the resulting flue gases treated with steam, with the purpose of removing sulfur dioxide, and reburned so as to make the carbon dioxide in the flue gas economically recoverable. The coal industry uses the term "clean coal" to describe technologies designed to enhance both the efficiency and the environmental acceptability of coal extraction, preparation and use,[28] but has provided no specific quantitative limits on any emissions, particularly carbon dioxide. Whereas contaminates like sulfur or mercury can be removed from coal, carbon cannot be effectively removed while still leaving a usable fuel, and clean coal plants without carbon sequestration and storage do not significantly reduce carbon dioxide emissions. James Hansen in an open letter to U.S. President Barack Obama has advocated a "moratorium and phase-out of coal plants that do not capture and store CO2".[29] In his book Storms of My Grandchildren, similarly, Hansen discusses his Declaration of Stewardship the first principle of which requires "a moratorium on coal-fired power plants that do not capture and sequester carbon dioxide".[30]

Combined heat and power

Combined heat and power (CHP), also known as cogeneration, is the use of a power station to provide both electric power and process heat or district heating. While rejecting heat at a higher than normal temperature to enable building heating lowers overall plant electric power efficiency, the extra fuel burnt is more than offset by the reduction in fossil fuel that would otherwise be used for heating buildings. This technology is widely practiced in for example Denmark, other Scandinavian countries and parts of Germany. Calculations show that CHPDH is the cheapest method of carbon emissions reductions.[31]

Alternatives to fossil fuel power plants

Alternatives to fossil fuel power plants include nuclear power, solar power, geothermal power, wind power, tidal power, hydroelectric power (hydroelectricity) and other renewable energies (see non-carbon economy). Some of these are proven technologies on an industrial scale (i.e. nuclear, wind, tidal and hydroelectric power) others are still in prototype form.

Generally, the cost of electrical energy produced by non fossil fuel burning power plants is greater than that produced by burning fossil fuels. This statement however only includes the cost to produce the electrical energy and does not take into account indirect costs associated with the many pollutants created by burning fossil fuels (e.g. increased hospital admissions due respiratory diseases caused by fine smoke particles).

Relative cost by generation source

See also Relative cost of electricity generated by different sources

When comparing power plant costs, it is customary to start by calculating the cost of power at the generator terminals by considering several main factors. External costs such as connections costs, the effect of each plant on the distribution grid are considered separately as an additional cost to the calculated power cost at the terminals.

Initial factors considered are:

  • Capital costs (including waste disposal and decommissioning costs for nuclear energy)
  • Operating and maintenance costs
  • Fuel costs (for fossil fuel and biomass sources, and which may be negative for wastes)
  • Likely annual hours per year run or load factor (may be 30% for wind energy, but 90% for nuclear energy)
  • Offset sales of heat (for example in combined heat and power district heating (CHP/DH)).

These costs occur over the 30–50 year life of the fossil fuel power plants, using discounted cash flows. In general large fossil plants are attractive due to their low initial capital costs—typically around £750–£1000 per kilowatt electrical compared to perhaps £1500 per kilowatt for onshore wind.[citation needed]

See also

References

  1. ^ EIA.doe.gov
  2. ^ [Electrical Generation Efficiency—Working Document of the NPC Global Oil & Gas Study, 18 July 2007]
  3. ^ GE Power’s H Series Turbine
  4. ^ SEC Mohave Generation Station Retrieved 24-07-2008
  5. ^ a b World Outlook 2004 (PDF), Paris: IEA, 2004-10-26, p. 31, ISBN 92-64-1081-73, retrieved 2006-06-13
  6. ^ "Carbon Dioxide Emissions From Power Plants Rated Worldwide". Science News. 2007-11-15. Retrieved 2008-01-29.
  7. ^ Air pollution from electricity-generating large combustion plants, Copenhagen: EEA, 2008, ISBN 978-92-9167-355-1
  8. ^ Human-Related Sources and Sinks of Carbon Dioxide 2005 figures
  9. ^ US EPA Clean Energy—Coal
  10. ^ US EPA Clean Energy—Oil
  11. ^ US EPA Clean Energy—Gas
  12. ^ Solomon, S.; et al. (2007). "Summary for policymakers" (PDF). A report of Working Group I of the Intergovernmental Panel on Climate Change. IPCC. Retrieved 24 March 2010. {{cite web}}: Cite has empty unknown parameter: |coauthors= (help); Explicit use of et al. in: |last= (help)
  13. ^ Committee on Benefits of DOE R&D on Energy Efficiency and Fossil Energy, US NRC (2001), Energy research at DOE: was it worth it? Energy efficiency and fossil energy research 1978 to 2000, National Academies Press, p. 174, ISBN 0-3090-7448-7
  14. ^ a b c d Nel, A. (2005, May 6). Air Pollution-Related Illness: Effects of Particles. Science, 308(5723), 804-806.
  15. ^ a b c Grahame, T., & Schlesinger, R. (2007, April 15). Health Effects of Airborne Particulate Matter: Do We Know Enough to Consider Regulating Specific Particle Types or Sources?. Inhalation Toxicology, 19(6–7), 457–481.
  16. ^ a b c Schobert, H. H. (2002). Energy and Society. New York: Taylor & Francis, 241–255.
  17. ^ a b c Coal Combustion: Nuclear Resource or Danger? by Alex Gabbard, ORNL Review, Summer/Fall 1993, Vol. 26, Nos. 3 and 4.
  18. ^ International Atomic Energy Agency—Managing Radioactive Waste
  19. ^ Physics.ohio-state.edu
  20. ^ a b c McClatchy Newspaper, "Study of Coal Ash Sites Finds Extensive Water Contamination," Mcclatchydc.com ; article also archived at: commondreams.org Cite error: The named reference "mcclatchydc.com" was defined multiple times with different content (see the help page).
  21. ^ EarthJustice news release, 2010 Sept. 16, "New Report—Coal Ash Linked To Cancer and Other Maladies; Coal's Waste Is Poisoning Communities in 34 States," unearthed.earthjustice.org citing detailed study by Earthjustice and Physicians for Social Responsibility, "Coal Ash: The Toxic Threat to Our Communities and Our Environment," 2010 September 16, earthjustice.org
  22. ^ EarthJustice news release, 2010 September 16, "New Report—Coal Ash Linked To Cancer and Other Maladies; Coal's Waste Is Poisoning Communities in 34 States," unearthed.earthjustice.org citing detailed study by Earthjustice and Physicians for Social Responsibility, "Coal Ash: The Toxic Threat to Our Communities and Our Environment," 2010 September 16, earthjustice.org
  23. ^ New York Times, 2009 Aug. 19, "Mercury Found in Every Fish Tested, Scientists Say," nytimes.com
  24. ^ Coal to biomass power plant conversion
  25. ^ Coal to biomass conversion by Georgia Power
  26. ^ Conversion of coal to waste-fired power plant
  27. ^ CCS Fossil fuel power plant
  28. ^ AustralianCoal.com.au—Clean Coal Overview
  29. ^ James Hansen. Letter to Obama, columbia.edu, accessed 10 December 2009.
  30. ^ Hansen, James (2009). Storms of My Grandchildren. London: Bloomsbury Publishing. p. 242. ISBN 1408807459.
  31. ^ Claverton-energy.com

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