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Thiogermanate

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Thiogermanates are chemical compounds containing anions with sulfur atoms bound to germanium. They are in the class of chalcogenidotetrelates. Related compounds include thiosilicates, thiostannates, selenidogermanates, telluridogermanates and selenidostannates.

formula name system space group cell Å volume density comments ref
H4Ge4S10 thiogermanic acid triclinic P1_ a = 8.621, b = 9.899, c = 10.009, α = 85.963°, β = 64.714°, γ = 89.501°, Z = 2 [1][2]
H2Ge4S9 thiogermanic acid [1]
[CH3NH3]4Ge2S6 tetrakis(methylammonium) bis(μ-sulfido)-tetrakis(sulfido)-di-germanium triclinic P1_ a 7.3336 b 7.3760 c 10.0007, α 108.598° β 111.332° γ 90.297° [3]
[CH3CH2NH3]4Ge2S6•CH3CH2NH2 tetrakis(ethylammonium) bis(μ-sulfido)-tetrakis(sulfido)-di-germanium ethylamine orthorhombic Pnma a 7.8501 b 18.3444 c 17.4386 [3]
[CH3CH2NH3]3[CH3NH3]Ge4S10 tris(diethylammonium) methylammonium hexakis(μ-sulfido)-tris(sulfido)-tetra-germanium P a 3 a 17.9402 c 17.9402 [3]
(NH4)2[NH2(CH3)2]2Ge2S6 a = 6.9647(14) Å, b = 15.719(3) Å, c = 7.2042(14) Å, β = 92.76(3)° monoclinic P21/c a = 6.965, b = 15.7195, c = 7.2045, β = 92.765° band gap 3.50 eV [4]
(NH3NH2)2[(RNGe)2(μ-S)2S2] [5]
[(R1Ge)4(μ-S)6] R1 = CMe2CH2COMe [5][6]
Na4Ge2S6 · 14H2O triclinic P1_ a = 9.978, b = 7.202, c = 9.601, α = 108.41 β = 92.39, γ = 91.69° Z = 1 [7]
Na6Ge2S7 [8]
Na(AlS2)(GeS2)4 monoclinic P21/n a = 6.803, b = 38.207, c = 6.947, β = 119.17° [9]
K6Ge2S7 [8]
[VO(dien)]2GeS4 orthorhombic Pna21 a =19.831, b = 8.0814, c = 12.0889, Z = 4 1937.4 [10]
{[V(en)2]2O}Ge2S6 en = ethylenediamine monoclinic P21/n a=8.352 b=12.682 c=11.339  β=94.75 Z=2 1196.9 1.931 black [11]
[VO(dap)2]2Ge2S6·dap dap = 1,2-diaminopropane hexagonal R2_c a=38.284 c=11.170 Z=18 14178 1.619 purple; hexagonal nanotubes [11]
{[Mn(2,2′-bipy)2(H2O)]2Ge4S10}·3H2O bipy = bipyridine triclinic P1_ a=10.6511 b=13.0443 c=22.995, α=79.539 β=77.653° γ=79.737° Z=2 3036.6 1.570 [12]
{Mn(tepa)}2(μ-Ge2Se6) tetragonal I41/a [13]
Mn2(en)4Ge2S6 en=ethylenediamine [14]
Mn2(dap)4Ge2S6 dap = 1,2-diaminopropane [14]
H2dienMnGeS4 dien = diethylenetriamine [14]
[(dien)2Mn]Ge2S4 dien=diethylenetriamine orthorhombic P212121 a=9.113, b=12.475, c=17.077, Z=4 1941 1D [Ge2S4]2− chains [15]
[Fe(2,2′-bipy)3]2[Ge4S10]·10H2O monoclinic P21/c a=23.8411 b=13.6462 c=22.9029 β=93.400° Z=4 7438.1 1.643 [12]
{Fe(tepa)}2(μ-Ge2Se6) tetragonal I41/a [13]
[{Co(tepa)}2(μ-Ge2S6)] tepa= tetraethylenepentaamine tetragonal I41/a [13]
[dienH2][Co(dien)2][Ge2S6] dien = diethylenetriamine triclinic P1_ Z=4 2741.5 1.715 yellow [16]
[dienH2][Co(dien)2][Ge2S6] triclinic P1_ Z=1 679.62 1.730 yellow [16]
[dienH2][Co(dien)2][Ge2S6] orthorhombic Pbca a=15.2110 b=16.7025 c=21.8821 Z=8 5559.4 1.692 yellow [16]
[dienH2][Co(dien)2][Ge2S6] orthorhombic Pca21 a=a=14.7043 b=9.0099 c=21.4540 Z=4 2842.3 1.655 yellow [16]
[Ni(cyclam)]3[Ni(cyclam)(H2O)2][Ge4S10]2·21H2O cyclam = 1,4,8,11-tetraazacyclotetradecane monoclinic Cc a=35.915 b=10.047 c=30.607 β =115.32 Z=4 9983 1.778 [12]
[(CH3CH2)4N]3CuGe4S10 catena-[hexakis(tetraethylammonium) hexadecakis(μ-sulfido)-tetrakis(sulfido)-octa-germanium-di-copper] monoclinic P 21/n a 15.0956 b 14.2127 c 19.5889, β 91.131° [3]
[H4teta]5[Cu40Ge15S60]·2.5(teta) [17]
Cu(AlS2)(GeS2)4 monoclinic P21/n a 6.7960(14)Å b 37.628(8)Å c 6.8797(14)Å, α 90° β 119.52(3)° [9]
Y3LiGeS7 [18]
[{RNGe(μ-S)3}4Pd6]·MeOH RN = CMe2CH2CMeNNH2 [5]
[(CH3CH2)4N]3AgGe4S10 catena-[hexakis(tetraethylammonium) hexadecakis(μ-sulfido)-tetrakis(sulfido)-di-silver-octa-germanium] monoclinic P 21/n a 15.1898 b 14.3043 c 19.5059, β 91.056° [3]
Ag(AlS2)(GeS2)4 monoclinic P21/n a 6.799 b 38.4169 c 6.813 β 119.65° [9]
Y3Cd0.5GeS7 [18]
Na9Sb(Ge2S6)2 monoclinic C2/m a=7.5857 b=11.574 c=6.817 β=106.587 Z=1 573.7 2.905 yellow [19]
[(Me)2NH2]6[Ge2Sb2S7][Ge4S10] microporous, can exchange dimethyl ammonium for alkalis [16][20]
[dabcoH]2[Ge2Sb3S10] dabco = 1,4-diazabicyclo[2.2.2]octane [16]
[AEPH2][GeSb2S6]·CH3OH AEP = N-(2-aminoethyl)piperazine [16]
[Mn(en)3][GeSb2S6] dien = diethylenetriamine orthorhombic Pbca a=13.374 b=17.607 c=18.562 Z=8 4370.8 2.26 yellow [16][21]
[Co(dien)2]2[GeSb4S10] dien = diethylenetriamine orthorhombic Pbca a=14.684 b=17.133 c=33.478 Z=8 8422 2.205 yellow [16][21]
[Ni(dien)2]3[Ge3Sb8S21]·0.5H2O [16]
[Pr(dien)3]2[Ge2S6]Cl2 dien = diethylenetriamine monoclinic P21/n a=11.637 b=14.143 c=15.120 β=98.149° Z=4 2463 1.765 green [22]
[Sm(dien)3]2[Ge2S6]Cl2 dien = diethylenetriamine monoclinic P21/n 11.532 b=14.423 c=14.573 β=97.105° Z=4 2405 1.834 light yellow [22]
Sm3Zn0.5GeS7 [18]
Gd3Cd0.5GeS7 [18]
[Gd(dien)3]2[Ge2S6]Cl2 dien = diethylenetriamine monoclinic P21/n 11.548 b=14.677 c=14.427 β=96.332° Z=4 2430.4 1.834 colourless [22]
[Dy(dien)3]2[Ge2S6]Cl2 dien = diethylenetriamine monoclinic P21/n a=11.503 b=14.645 c=14.340 β=96.178° Z=4 2401.8 1.870 light yellow [22]
[Ho(trien)(en)GeS3(SH)] trien = triethylenetetramine [22]
Er2(tepa)2(μ-OH)2(μ-Ge2S6)]n·nH2O tepa = tetraethylenepentamine [23]
[Er2(dien)4(μ-OH)2][Ge2S6] dien = diethylenetriamine monoclinic P21/n 11.710 b=11.318 c=13.548 β=97.635° Z=4 1779.6 2.088 red [22]
Tm2(tepa)2(μ-OH)2(μ-Ge2S6)]n·nH2O tepa = tetraethylenepentamine [23]

References

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  2. ^ Poling, Steven A.; Nelson, Carly R.; Sutherland, Jacob T.; Martin, Steve W. (2003-11-01). "Crystal Structure of Thiogermanic Acid H 4 Ge 4 S 10". Inorganic Chemistry. 42 (23): 7372–7374. doi:10.1021/ic034659s. ISSN 0020-1669.
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