Talk:Colloid

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Untitled

In Netscape Communicator 4.79, this table overlaps the frames in the standard skin, rendering the whole an unreadable mess. -- April 12:06 Aug 6, 2002 (PDT)

So I'm reading about asphalt when I see a link to a page on colloids, and as I click it I wonder out loud, "What's a colloid?" The first words that load are in the caption for the picture : "milk is a colloid." Problem solved! I didn't even have to wait for the rest of the page to load! Love it how things sometimes work out. --Ye Olde Luke (talk) 05:08, 18 April 2008 (UTC)

Revise Definition

The first sentence defines a colloid as the colloidal particle, but the rest of the entry discusses colloid as the mixture, not the substance that is dispersed. Although some dictionary definitions identify the colloid as the substance, colloid is not synonymous with substance.

First sentence: "A colloid is a substance microscopically dispersed evenly throughout another substance." This is inconsistent with the way the word colloid is used in the rest of the entry.

Example: "Many familiar substances are colloids, as shown in the chart below." This definition would imply that whipped cream, fog, milk, etc. are the substances dispersed in another.

Again: "because colloids have the appearance of solutions"--in this context, the colloid is the mixture, not the substance.

Colloid should be defined as a mixture in which...

-also it should be mentioned in the definition that only a dispersion of a certain degree (what degree is dependent on the source, usually around 1nm - 1μm) is a colloid. 178.221.31.19 (talk) 15:34, 15 October 2013 (UTC)

---

http://www.xamplified.com/colloidal-solution-true-solution-and-suspension/ The above link has more information on colloids, and in the first part of the article, it says that colloids are 2-500 nanometers in diameter. This website claims otherwise... —Preceding unsigned comment added by Nujman (talk • contribs) 15:35, 19 May 2011 (UTC)

Merging with colloidal suspension

Should we perhaps merge this article with colloidal suspension?

Typo Correction

Made a typo correction (changed 'is' to 'are') --fixman88 01:36, Jun 12, 2005 (UTC)

Question

how can colloids be made to settle?what is the procedure that must be done?and why it cant passes the membranes but can pas to filter paper? —Preceding unsigned comment added by 77.64.14.25 (talk) 23:22, 23 November 2009 (UTC)

I will refer to colloidal gold, the colloid is produced from a solution of gold dissolved by acids (aqua regia, HCl/ sodium hypochlorite, or HCl/concentrated H2O2,and so on). The gold being dissolved by loss of electrons of the gold atom, making an ionic salt of gold in solution (halide, in this example the chloride ionic solution of AuCl3. the colloid is produced with a reducing agent like SnCl2 (Purple of Cassius, a test for gold in solution). In the case of colloidal gold, the reducing agent gives back electrons to the gold atom, these atoms combine to form clumps of atoms, but with colloids, these clumps of atoms only grow to a certain size and become charged(positive or negative depending on how the colloids were formed, Like charges repel, so the clumps of metallic gold atoms begin to repel each other, pushing each other away (constantly moving in solution), because the cannot come into contact the clumps of atoms cannot grow to a large enough size to precipitate, and are constantly pushing each other around they will not settle. the size of the clumps of metallic gold atoms reflected light giving the solution a color to our eyes, we see the reflected light, the size of the clumps of atoms of colloidal gold gives certain colors in relation to their size, different methods of making colloidal gold with give specific colors of reflected light or size of clumps of atoms before the become charged. stannous chloride gives us the violet color of colloidal gold.

The charged of these clumps of gold atoms is also why the colloid will react with the diaphragm of paper (cellulose), in the manner it does. There are many documents on the research of colloids, reading these are the best way to answer questions like these, with a search you can find tons of information on this particular niche of science. With gold in colloidal solution we can bring it to high heat in a solution of acid (I prefer H2SO4)for about an hour, or we can use electrolysis to "break the colloid" or break the charge of the clumps so the gold atoms will collide and join to make large enough clumps of gold atoms to overcome gravity and precipitate from solution.

Richard Butcher — Preceding unsigned comment added by 208.74.128.1 (talk) 00:17, 18 August 2016 (UTC)

Shoe polish a colloid?

Most shoe polishes consists of a wax base with pigment particles. The viscoelasticity (i.e. "semisolidness") of shoe polish is a result of the behavior of the hydrocarbon chains that form the wax, which entangle to form a solid at rest, but can disentangle with applied shear, resulting in "liquid-like" behavior (for example, wiping the polish on a cloth). Therefore, while there may be some small particles present in the shoe polish that contain the pigment, the viscoelatic behavior of shoe polish is not due to colloidal interactions.

That being said, cream shoe polish is an emulsion, and therefore would be considered a colloidal suspension. The viscoelastic properties of cream shoe polish (or hand cream for that matter) ARE due to colloidal interactions betwen emulsion droplets.

Nature claims 6 errors

Nature disputes the accuracy of this article; see http://www.nature.com/news/2005/051212/multimedia/438900a_m1.html and Wikipedia:External_peer_review#Nature. We're hoping they will provide a list of the alleged errors soon. —Steven G. Johnson 01:54, 15 December 2005 (UTC)

Errors ID'd by Nature, to correct

The results of what exactly Nature suggested should be corrected is out... italicize each bullet point once you make the correction. -- user:zanimum

• 'In general, a colloid or colloidal dispersion is a two-phase system of matter'; No, a uniform dispersion of particles in a liquid is a one-phase system of two or more components, no matter how large the particles are. A two-phase system requires there to be two distinct phases separated by an interface. If all the colloidal particles coalesced into one large particle, only then would it be a two-phase system, and the original colloid would be considered to have been in a meta-stable state
• In a phase colloid, small droplets or particles of one substance, are dispersed in another substance, the continuous phase. In a molecular colloid, macromolecules are dispersed in a continuous phase (or dispersion medium). I’ve never heard of this division of colloids into phase colloids and molecular colloids.
• Colloids can be classified as follows: ß Inconsistency: What follows is a very different classification than given in the opening two paragraphs. à

	Dispersed phase material	   
	Gas 	Liquid droplets	Solid particles	   

	Gas	None: all gases are mutually soluble	Liquid aerosol,

Examples: fog, mist Solid aerosol, Examples: Smoke, dust

	Liquid	Foam,

Examples: Whipped cream Emulsion, Examples: Micelles, milk, mayonnaise, hand cream, vesicles, blood Sol, Examples: Paint, pigmented ink

	Solid	Solid foam,

Examples: Aerogel, Styrofoam, Pumice Gel, Examples: Gelatin, jelly, cheese, Opal Solid sol, Examples: Cranberry glass, Ruby glass

• Misconception: van der Waals forces: These are due to dipole-dipole interactions (permanent and/or induced). Even if the particles don't have a permanent dipole there could be are always quantum mechanical fluctuations of the electron gas giving rise to an instantaneous a temporary dipole. So these types of forces are always present.
• Omission in 'interactions' section: * Steric forces between polymer-covered surfaces or in solutions containing non-adsorbing polymer can modulate interparticle forces, producing an additional repulsive steric stabilization force or attractive depletion force between them.
• The charge on the dispersed particles can be observed by applying an electric field: all particles migrate to the same electrode ß Only if the sign of their charge (positive or negative) is the same and therefore must all have the same charge. ß The same sign, not necessarily the same charge. The logic of this sentence is backwards.

---

I believe I've fixed the errors now (at least, I've done what I would do if that was the referee report on my own paper) and have removed the naturedispute tag. Sdedeo (tips) 23:51, 5 January 2006 (UTC)

Nature Review: possible misunderstandings

the article should probably state "all gases are soluble" in the classification table instead of "all gases are soluble", as suggested, because "all gases are soluble" does not imply they are mutually soluble, which is the relevant property in this context. In addition, I would recommend to replace the word "medium" in the column head by "material", as suggested, because "medium" usually refers to the solvent in which the other substance is solved, "medium" impies that the material is of greater quantity than the other.

--- This is WRONG. The medium is the continuous phase, by definition and is therefore perfectly appropriate here. Some other of the Nature objections also seem to be wrong. For instance, the claim that a colloidal suspension is a single phase is only true if tests can not measure differences in physical properties between the two (or more) materials. In general, we can measure differences so that - arguably - a colloidal suspension is a multiple phase system.71.31.147.72 (talk) 00:07, 2 February 2012 (UTC)

Identifying Colloids

How would I go about identifying a colloid? Say a textbook gives you a series of substances which you have to identify as colloid, suspension, or solution, how would you do it? (other than the Tyndall effect - you can't pull that off everywhere) Are people just supposed to memorize what are colloids?

Welll, off the top of my head, a suspension will settle out whereas a colloid will stay suspended. That's a start, anyway. Gzuckier 18:31, 3 October 2006 (UTC)

One method is the Tyndall effect-- shine a light through it. Richard Butcher — Preceding unsigned comment added by 208.74.128.1 (talk) 00:19, 18 August 2016 (UTC)

Isn't milk more properly a sol and not an emulsion?

I believe milk is an emulsion when stored about 32 degrees celsius, but I hope for your health that you are storing it at a temperature below that. So, I'm editting the page to classify milk as a sol rather than as a emulsion. - 63.107.91.99 17:01, 27 August 2007 (UTC)

Regardless of storage temperature, milk comes out of the teat at a somewhat higher temperature than normal storage. It is perfectly healthy to drink at this point. How, then, do you classify it? Water could be classified as a solid, because, when stored below 0 Celsius, it is a solid, if we go by storage temperatures Fiddle Faddle 17:02, 4 October 2007 (UTC)

How about we just go with how people actually encounter milk the vast majority of the time? No question milk is an emulsion coming out of the teat, but at 4 celsius it's a sol. - 63.107.91.99 17:41, 6 November 2007 (UTC)

Okay, someone modified milk back to being an emulsion rather than a sol, without commenting here. Butter was left listed as a gel, rather than an emulsion, though, which is inconsistant in an unexplained way. - 63.107.91.99 (talk) 19:32, 24 March 2008 (UTC)

User:Epastore had a discussion on his talk page, but not here, about the reasoning behind his change. In any case, I just removed milk and butter from the table; if the purpose of the table is to inform people of examples of various colloids, there's no need to include confusing edge cases like butter and milk. - 63.107.91.99 (talk) 19:39, 24 March 2008 (UTC)

Second paragraph of lead section

The second paragraph lists 7 books on the subject of colloids. The referencing format is distracting and should be replaced. I suggest creating a separate section at the end of the article for "further reading", and listing the books there. Shalom (Hello • Peace) 00:58, 30 October 2007 (UTC)

Colloid: State of matter?

On the bottom of the page there is a list of phases of matter; in the list is a colloid. Does this, as it suggests make a colloid a phase?

Smoke and whipped cream are suspensions, not colloids.

If you are using this Wikipedia page for a project for Chemistry class you should find your informaition elsewhere- most of the information here is in-correct. Colloids are heterogeneous. Smoke and whipped cream are suspensions, not colloids. Whipped cream if left over time gets watery, smoke once dispersed leaves ash behind, these are signs of suspensions, not colloids. (this editorial comment by User:142.227.15.1 moved to talk page from article) -- Paleorthid (talk) 16:29, 14 December 2007 (UTC)

Following this logic, then surely blood is a suspension rather than a colloid - draw a blood sample and let it sit - the erythrocytes will settle to the bottom, with the leukocytes and platelets forming a thin film between the erythrocytes and plasma. Dlegros (talk) 11:20, 7 April 2011 (UTC)

Blood is simultaneously a colloid and a suspension, it has dispersed particles of different sizes in it. 178.221.31.19 (talk) 16:20, 15 October 2013 (UTC)

My understanding is that the distinction between is a colloid and a suspension is that a colloid is stable over time whereas a suspension will settle out. This introduces a gray area since if something settles after a year is it a colloid or a suspension? The larger particles will settle faster so with the smoke example the smoke might clear quickly as the larger ash particles fall but the very fine ash can stay suspended for a very long time, in which case fine ash smoke would be a colloid. I don't think a strict definition works because of this ambiguity.Malaquey Wiki (talk) 12:48, 29 April 2020 (UTC)

Homogeneous?

The article says that, "In some cases, a colloid can be considered as a homogeneous (not heterogeneous) mixture."

I don't see how this can be correct. A homogeneous mixture is a solution, not a colloid, right? If you look at the solution article, it defines a solution as "a homogeneous mixture composed of two or more substances". Deepfryer99 (talk) 15:23, 9 April 2008 (UTC)

Chemistry of the introduction is completely wrong

NaCl+H2O does not make any reaction, does not form NaOH. NaOH is a strong base that would rip apart any organic matter, so salt water would be deadly and life would not exist. I am not correcting this because it obviously needs to be sourced and I can't figure out how to do that either.

Also, why would a covalent solution require hydrogen bonding?

These problems cause the whole introduction to be false and require a serious rewriting. I might be able to work more on this, once I figure out the wikipedia editing (again). Renduy (talk) 06:34, 18 December 2009 (UTC)

Plasmas?

The article talks about solids, liquids and gases, but leaves out plasmas. Is it possible to form a colloid using a plasma? As a possible example, how about a gas-plasma colloid where a plasma is right at its critical ionization velocity? Or how about a dusty plasma (may better be called a suspension instead)? -Justin Ormont (talk) 04:10, 6 February 2010 (UTC)

Another Error?

"A colloid is a type of chemical mixture..." - isn't this wrong?

A colloid is not a chemical mixture, colloids are particles in the size range of a couple of nanometers. To speak of chemical mixtures here is very confusing (even wrong). RonaldRonn (talk) 17:35, 13 February 2010 (UTC)

Thanks. Removed "chemical". Materialscientist (talk) 00:08, 14 February 2010 (UTC)

Missing: Polymers and Thermodynamics

There is not sharp dividing line between solutions and colloids. This is especially clear when you consider macromolecules. At the opposite end, the same thing can be (should be) argued: that colloidal suspensions and less stable suspensions (with larger dispersed phase particles) form a continuum. The thermodynamics is not (for me) clear. This article speaks about stability of a colloid as if it is an inherent property. Yet, while there are forces at work keeping particles separate, there are also processes at work changing the inherent stability of the colloid. Surface energy, thermodynamic stability, kinetic stability, should in my opinion be discussed here. There should be MUCH more to say about biocolloids. These must be the largest class of colloids and gets almost no print here. Is a strand of DNA in solution, a colloid or in suspension?71.31.147.72 (talk) 00:20, 2 February 2012 (UTC)

Excellent job!

What a wonderfully understandable, well-written article! I confess that I have technical degrees, but I still consider this a proper encyclopaedic article aimed at a lay audience. I had no trouble understanding it. You can ditch this comment; I just wanted to say: Good job, boys!  :^) — Preceding unsigned comment added by CousinJohn (talk • contribs) 18:18, 3 March 2012 (UTC)

Modified closely related page on Particle aggregation

and here added reference to it under "see also". One could eventually shorten/move some of the information on "Stabilization of a colloidal dispersion (peptization)" and "Destabilizing a colloidal dispersion (flocculation)", refer to that article, and eventually adapt it a bit. The subsection on "Technique monitoring colloidal stability" is bit too specialized. There are several other techniques (like light scattering, single particle counting) to do the same job, and they are not discussed. One could discuss that topic in the particle aggregation page or create separate page for it. Otherwise, I find the colloid page pretty good. Williams12357 (talk) 09:25, 10 April 2012 (UTC)

Modified edit on High-shear mixer

The fact that a High-shear mixer can be used to make colloidal dispersion is fine, but has nothing to do with the definition of colloids. While probably added for promotional purposes, it is nevertheless a valid technique for making powders and colloids. What is true, however, that the section on the preparation of colloids is too brief, so I tried to expand slightly, and putting the reference to the High-shear mixer there. But the way its stand it remains quite incomplete, and would require a major edit. Williams12357 (talk) 11:07, 17 May 2012 (UTC)

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UwU — Preceding unsigned comment added by 100.4.70.62 (talk) 19:27, 5 November 2020 (UTC)

Undefined refs

@Yasrena: several times now you've added a ref tag with the name ":0", but you've not provided any reference with that name. Please fill those in with the source(s) of your information and I'd suggest in future using the Preview button to see if any new errors pop up as a result of your edits. Thanks for your contributions. -- Fyrael (talk) 19:27, 20 April 2021 (UTC)

Chemistry

principle of solubility colloid 43.242.176.30 (talk) 09:08, 18 March 2023 (UTC)