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Oxalate chloride

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An oxalate chloride is a mixed anion compound contains both oxalate and chloride anions.

List

name formula crystal space group cell volume density comment ref
Novgorodovaite Ca2(C2O4)Cl2•2H2O monoclinic I2/m a= 6.936 b= 7.382 c= 7.443 β= 94.3° loses water over 205°C; refract: α=1.500 β=1.545 γ=1.568 2V=71° (−) [1][2]
Ca2(C2O4)Cl2•7H2O monoclinc monoclinic looses water at 25°C to 2H2O; refract: α=1.571 β=1.648 γ=1.718 2V=87° (−) [1]
Ca4(C2O4)3Cl2•8H2O dubious [1]
C(NH2)3Cd(C2O4)Cl(H2O)·H2O triclinic P1 a =6.8136 b =7.4890 c =10.0515 α =84.082° β =77.806° γ =88.813° band gap 3.76 eV [3]
BaCd(C2O4)1.5Cl(H2O)2 monoclinic C2/c a=23.101 b=8.253 c=10.040 β 99.14° band gap 4.53 eV [3]

References

  1. ^ a b c Jones, Francis T.; White, Lawrence M. (1946-07). "The Composition, Optical and Crystallographic Properties of Two Calcium Oxalate-Chloride Double Salts". Journal of the American Chemical Society. 68 (7): 1339–1342. doi:10.1021/ja01211a075. ISSN 0002-7863. {{cite journal}}: Check date values in: |date= (help)
  2. ^ Baran, Enrique J. (2014-12-17). "Review: Natural oxalates and their analogous synthetic complexes". Journal of Coordination Chemistry. 67 (23–24): 3734–3768. doi:10.1080/00958972.2014.937340. ISSN 0095-8972.
  3. ^ a b Xu, Wei; Ma, Liang; Lv, Yi-Lei; Ma, Si-Yu; Liu, Wenlong; Guo, Sheng-Ping; Tang, Ru-Ling (2023-12-19). "C(NH 2 ) 3 Cd(C 2 O 4 )Cl(H 2 O)·H 2 O and BaCd(C 2 O 4 ) 1.5 Cl(H 2 O) 2 : Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties". Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c04154. ISSN 0020-1669.
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