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Oxalate chloride

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An oxalate chloride is a mixed anion compound contains both oxalate and chloride anions.


Related compounds include oxalate fluorides[1] and oxalate bromides.[2]

List

name formula crystal space group cell volume density comment ref
Novgorodovaite Ca2(C2O4)Cl2•2H2O monoclinic I2/m a= 6.936 b= 7.382 c= 7.443 β= 94.3° loses water over 205°C; refract: α=1.500 β=1.545 γ=1.568 2V=71° (−) [3][4][5]
Ca2(C2O4)Cl2•7H2O triclinic P1 a = 7.3928 b = 8.9925 c = 10.484 α = 84.070 β = 70.95 γ = 88.545° 655.3 looses water at 25°C to 2H2O; refract: α=1.571 β=1.648 γ=1.718 2V=87° (−) [3][6]
Ca4(C2O4)3Cl2•8H2O dubious [3]
octakis(ethyl(dimethyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese [NH(CH3)2(C2H5)]8[Mn4Cl4Cr4(C2O4)12] monoclinic P21 a=13.8321 b=17.1042 c=20.4209 β=91.874° [7]
octakis(diethyl(methyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese [NH(CH3)(C2H5)2]8[Mn4Cl4Cr4(C2O4)12] monoclinic P21 a=14.1863 b=17.3479 c=20.4140 β=91.937° [7]
tetrakis(methylammonium) tetrakis(μ-oxalato)-octachloro-tetra-iron(iii) pentahydrate (MeNH3)2[Fe2(ox)2Cl4]·2.5H2O monoclinic P21/c a 10.7832 b 13.913 c 13.0578 β 104.060° [8]
methylammonium (μ-hydroxo)-bis(μ-oxalato)-dichloro-di-iron(iii) trihydrate MeNH3[Fe2(OH)(ox)2Cl2]·2H2O monoclinic Cc a=8.945 b=14.936 c=12.408 β=108.531° [8]
methylammonium oxonium bis(μ-oxalato)-(μ-oxo)-dichloro-di-iron(iii) dihydrate (H3O)(MeNH3)[Fe2O(ox)2Cl2]·3H2O orthorhombic Fdd2 a=14.914 b=23.507 c=9.261 [8]
(dimim)2[Fe2Cl4(μ-ox)] ionic liquid [9]
L2=1,4-bis(imidazol-1-ylmethyl)benzene

bis(1,1'-(1,4-Phenylenebis(methylene))bis-1H-imidazol-3-ium) (μ2-oxalato)-tetrachloro-bis(oxalato)-di-iron(iii)

(H2-L2)2{Fe2(C2O4)3Cl4} triclinic P1 a 10.6758 b 10.7457 c 10.8774 α 113.219° β 109.138° γ 99.294° Z=1 1020.8 1.624 emerald [10]
tetramelaminium trioxalatoferrate(III) chloride dihydrate (C3H7N6)4{Fe(C2O4)3}Cl·2H2O monoclinic P21/c a=11.597 b=22.299 c=13.655 β=94.344° Z=4 3521 1.698 green [11]
methylammonium (μ-aqua)-tris(μ-chloro)-(μ-oxalato)-iron(iii)-potassium K(MeNH3)[Fe(ox)Cl3(H2O) monoclinic P21/m a=8.725 b=7.508 c=9.026 β=112.421° [8]
diethylmethylammonium [NH(CH3)(C2H5)2][FeCl2(C2O4)] P21/c a=8.5125 b=10.775 c=14.9703 β=104.798° Z=4 1327.6 1.516 yellow; proton conductor [12]
C(NH2)3Cd(C2O4)Cl(H2O)·H2O triclinic P1 a =6.8136 b =7.4890 c =10.0515 α =84.082° β =77.806° γ =88.813° band gap 3.76 eV [13]
BaCd(C2O4)1.5Cl(H2O)2 monoclinic C2/c a=23.101 b=8.253 c=10.040 β 99.14° band gap 4.53 eV [13]
La(C2O4)Cl [14]
La(C2O4)Cl·3H2O [15]
Ce(C2O4)Cl [1]
Ce(C2O4)Cl·3H2O [15]
Pr(C2O4)Cl·3H2O stable to 163°C [15][1]
Nd(C2O4)Cl·3H2O stable to 167°C; dec 510° to NdOCl [15][1][16]
Sm(C2O4)Cl·3H2O stable to 174°C; dec at 347° to EuC2O4 [15][1]
Eu(C2O4)Cl·3H2O stable to 178°C [15][1]
Gd(C2O4)Cl·3H2O [15]

References

  1. ^ a b c d e f Mulokozi, A.M.; Weigel, F. (1973-05). "Differential thermal analysis studies of some rare earth metal oxalato halide-hydrates". Journal of Inorganic and Nuclear Chemistry. 35 (5): 1487–1492. doi:10.1016/0022-1902(73)80236-2. {{cite journal}}: Check date values in: |date= (help)
  2. ^ Lugwisha, E. H. J.; Mulokozi, A. M.; Masabo, M. K. J. (1991-11). "Activation energy of thermal decomposition of LaC2O4Br". Journal of Thermal Analysis. 37 (11–12): 2567–2572. doi:10.1007/BF01912801. ISSN 0368-4466. {{cite journal}}: Check date values in: |date= (help)
  3. ^ a b c Jones, Francis T.; White, Lawrence M. (1946-07). "The Composition, Optical and Crystallographic Properties of Two Calcium Oxalate-Chloride Double Salts". Journal of the American Chemical Society. 68 (7): 1339–1342. doi:10.1021/ja01211a075. ISSN 0002-7863. {{cite journal}}: Check date values in: |date= (help)
  4. ^ Baran, Enrique J. (2014-12-17). "Review: Natural oxalates and their analogous synthetic complexes". Journal of Coordination Chemistry. 67 (23–24): 3734–3768. doi:10.1080/00958972.2014.937340. ISSN 0095-8972.
  5. ^ Rastsvetaeva, R. K.; Chukanov, N. V.; Nekrasov, Yu. V. (2001). "[No title found]". Doklady Chemistry. 381 (1/3): 329–331. doi:10.1023/A:1012984825792.
  6. ^ Piro, Oscar E.; Echeverría, Gustavo A.; González-Baró, Ana C.; Baran, Enrique J. (2018-02). "Crystal structure and spectroscopic behavior of synthetic novgorodovaite Ca2(C2O4)Cl2·2H2O and its twinned triclinic heptahydrate analog". Physics and Chemistry of Minerals. 45 (2): 185–195. doi:10.1007/s00269-017-0907-0. ISSN 0342-1791. {{cite journal}}: Check date values in: |date= (help)
  7. ^ a b Lozančić, Ana; Renka, Sanja; Barišić, Dario; Burazer, Sanja; Molčanov, Krešimir; Pajić, Damir; Jurić, Marijana (2023-06-19). "High Proton Conductivity of Magnetically Ordered 2D Oxalate-Bridged [Mn II Cr III ] Coordination Polymers with Irregular Topology". Inorganic Chemistry. 62 (24): 9418–9428. doi:10.1021/acs.inorgchem.3c00443. ISSN 0020-1669.
  8. ^ a b c d Mastropietro, Teresa F.; Marino, Nadia; Munno, Giovanni De; Lloret, Francesc; Julve, Miguel; Pardo, Emilio; Armentano, Donatella (2016-11-07). "Selective Guest Inclusion in Oxalate-Based Iron(III) Magnetic Coordination Polymers". Inorganic Chemistry. 55 (21): 11160–11169. doi:10.1021/acs.inorgchem.6b01769. ISSN 0020-1669.
  9. ^ Cot, Sergi; Leu, Meike K.; Kalamiotis, Alexis; Dimitrakis, Georgios; Sans, Victor; de Pedro, Imanol; Cano, Israel (2019-07). "An Oxalate‐Bridged Binuclear Iron(III) Ionic Liquid for the Highly Efficient Glycolysis of Polyethylene Terephthalate under Microwave Irradiation". ChemPlusChem. 84 (7): 786–793. doi:10.1002/cplu.201900075. ISSN 2192-6506. {{cite journal}}: Check date values in: |date= (help)
  10. ^ Wang, Lei; Wang, Wenqiang; Guo, Dong; Zhang, Ao; Song, Yaoguang; Zhang, Yiheng; Huang, Keke (2014). "Design and syntheses of hybrid supramolecular architectures: based on [Fe(C 2 O 4 ) 3 ] 3− metallotectons and diverse organic cations". CrystEngComm. 16 (24): 5437–5449. doi:10.1039/C4CE00357H. ISSN 1466-8033.
  11. ^ Wang, Lei; Wang, Wenqiang; Guo, Dong; Zhang, Ao; Song, Yaoguang; Zhang, Yiheng; Huang, Keke (2014). "Design and syntheses of hybrid supramolecular architectures: based on [Fe(C 2 O 4 ) 3 ] 3− metallotectons and diverse organic cations". CrystEngComm. 16 (24): 5437–5449. doi:10.1039/C4CE00357H. ISSN 1466-8033.
  12. ^ Burazer, Sanja; Molčanov, Krešimir; Šantić, Ana; Klaser, Teodoro; Wenger, Emmanuel; Pajić, Damir; Jagličić, Zvonko; Popović, Jasminka; Jurić, Marijana (2021-09-24). "Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility". Materials. 14 (19): 5543. doi:10.3390/ma14195543. ISSN 1996-1944.{{cite journal}}: CS1 maint: unflagged free DOI (link)
  13. ^ a b Xu, Wei; Ma, Liang; Lv, Yi-Lei; Ma, Si-Yu; Liu, Wenlong; Guo, Sheng-Ping; Tang, Ru-Ling (2023-12-19). "C(NH 2 ) 3 Cd(C 2 O 4 )Cl(H 2 O)·H 2 O and BaCd(C 2 O 4 ) 1.5 Cl(H 2 O) 2 : Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties". Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c04154. ISSN 0020-1669.
  14. ^ Hölsä, Jorma; Koriseva, Eija (1991-08). "Thermal decomposition of LaC2O4Cl·3H2O : Eu3+: a high-resolution luminescence spectroscopy study". Thermochimica Acta. 185 (1): 25–33. doi:10.1016/0040-6031(91)80114-X. {{cite journal}}: Check date values in: |date= (help)
  15. ^ a b c d e f g Möbius, R.; Matthes, F. (1964-06). "Über die Verhältnisse beim Austausch von Oxalationen gegen Chloridionen bei Oxalathydraten der Seltenen Erden und des Yttriums". Zeitschrift für Chemie. 4 (6): 234–235. doi:10.1002/zfch.19640040618. ISSN 0044-2402. {{cite journal}}: Check date values in: |date= (help)
  16. ^ Mulokozi, A. M.; Zuru, A. A. (1989-11). "Activation energy of thermal decomposition of fully dehydrated NdC2O4Cl·3H2O to NdOCl". Journal of Thermal Analysis. 35 (7): 2359–2366. doi:10.1007/BF01911900. ISSN 0368-4466. {{cite journal}}: Check date values in: |date= (help)
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