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Oxalate chloride

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An oxalate chloride or oxalato chloride is a mixed anion compound contains both oxalate and chloride anions.

Related compounds include oxalate fluorides[1] and oxalate bromides.[2]

Production

Oxalate chlorides may be produced by treating an oxalate salt with concentrated hydrochloric acid, or with a metal oxide dissolved in oxalic acid and hydrochloric acid solutions that are evaporated.[3]

List

name formula crystal space group cell volume density comment ref
Novgorodovaite Ca2(C2O4)Cl2•2H2O monoclinic I2/m a=6.936 b=7.382 c=7.443 β=94.3° loses water over 205°C; refract: α=1.500 β=1.545 γ=1.568 2V=71° (−) [4][5][6]
Ca2(C2O4)Cl2•7H2O triclinic P1 a = 7.3928 b = 8.9925 c = 10.484 α = 84.070 β = 70.95 γ = 88.545° 655.3 looses water at 25°C to 2H2O; refract: α=1.571 β=1.648 γ=1.718 2V=87° (−) [4][7]
Ca4(C2O4)3Cl2•8H2O dubious [4]
octakis(ethyl(dimethyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese [NH(CH3)2(C2H5)]8[Mn4Cl4Cr4(C2O4)12] monoclinic P21 a=13.8321 b=17.1042 c=20.4209 β=91.874° [8]
octakis(diethyl(methyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese [NH(CH3)(C2H5)2]8[Mn4Cl4Cr4(C2O4)12] monoclinic P21 a=14.1863 b=17.3479 c=20.4140 β=91.937° [8]
tetrakis(methylammonium) tetrakis(μ-oxalato)-octachloro-tetra-iron(iii) pentahydrate (MeNH3)2[Fe2(ox)2Cl4]·2.5H2O monoclinic P21/c a 10.7832 b 13.913 c 13.0578 β 104.060° [9]
methylammonium (μ-hydroxo)-bis(μ-oxalato)-dichloro-di-iron(iii) trihydrate MeNH3[Fe2(OH)(ox)2Cl2]·2H2O monoclinic Cc a=8.945 b=14.936 c=12.408 β=108.531° [9]
methylammonium oxonium bis(μ-oxalato)-(μ-oxo)-dichloro-di-iron(iii) dihydrate (H3O)(MeNH3)[Fe2O(ox)2Cl2]·3H2O orthorhombic Fdd2 a=14.914 b=23.507 c=9.261 [9]
DMF = dimethylformamide Fe2(C2O4)Cl4(DMF)4 triclinic P1 a=8.3919 b=8.7834 c=11.2881 α=70.248° β=71.993° γ=64.423° [10]
(dimim)2[Fe2Cl4(μ-ox)] ionic liquid [11]
L2=1,4-bis(imidazol-1-ylmethyl)benzene

bis(1,1'-(1,4-Phenylenebis(methylene))bis-1H-imidazol-3-ium) (μ2-oxalato)-tetrachloro-bis(oxalato)-di-iron(iii)

(H2-L2)2{Fe2(C2O4)3Cl4} triclinic P1 a=10.6758 b=10.7457 c=10.8774 α=113.219° β=109.138° γ=99.294° Z=1 1020.8 1.624 emerald [12]
tetramelaminium trioxalatoferrate(III) chloride dihydrate (C3H7N6)4{Fe(C2O4)3}Cl·2H2O monoclinic P21/c a=11.597 b=22.299 c=13.655 β=94.344° Z=4 3521 1.698 green [13]
methylammonium (μ-aqua)-tris(μ-chloro)-(μ-oxalato)-iron(iii)-potassium K(MeNH3)[Fe(ox)Cl3(H2O) monoclinic P21/m a=8.725 b=7.508 c=9.026 β=112.421° [9]
diethylmethylammonium [NH(CH3)(C2H5)2][FeCl2(C2O4)] monoclinic P21/c a=8.5125 b=10.775 c=14.9703 β=104.798° Z=4 1327.6 1.516 yellow; proton conductor [14]
BETS = Bis(ethylenedithio)tetraselenafulvalene κ-BETS2[FeIII(C2O4)Cl2] black; metallic; [15]
bis(2-(5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-1-ium) bis(μ-oxalato)-tetrachloro-di-iron(iii) [BEDT-TTF][Fe(C2O4)Cl2] triclinic P1 a=8.896 b=11.401 c=11.427 α=112.062° β=103.775° γ=100.328° [16]
BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)[Fe(C2O4)Cl2](CH2Cl2) monoclinic P21/c a=8.858 b=11.012 c=14.932 β=103.39° [17]
tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate [Co(en)3]Cl(C2O4)·3H2O monoclinic C2/c a = 19.932 b = 9.3344 c = 19.088 β = 96.846° Z = 8 [18]
C(NH2)3Cd(C2O4)Cl(H2O)·H2O triclinic P1 a=6.8136 b=7.4890 c=10.0515 α=84.082° β=77.806° γ=88.813° band gap 3.76 eV [19]
(NH4)2Sb(C2O4)Cl3 orthorhombic P212121 a=8.6961 b=8.7844 c=13.5956 Z=4 1038.57 2.253 [20]
K2Sb(C2O4)Cl3 orthorhombic P212121 a=8.3966 b=8.6023 c=13,6342 Z=4 984.80 2.660 [20]
Rb2Sb(C2O4)Cl3 orthorhombic P212121 a=8.6769 b=8.8485 c=13.8014 Z=4 1059.64 3.053 birefringence 0.22@546 nm;NLO 2.1 × KH2PO4 [20]
BaCd(C2O4)1.5Cl(H2O)2 monoclinic C2/c a=23.101 b=8.253 c=10.040 β 99.14° band gap 4.53 eV [19]
La(C2O4)Cl monoclinic P21/n a=8.489 b=16.19 c=5.880 β=104.14° [21][22]
La(C2O4)Cl·3H2O [23]
Ce(C2O4)Cl [1]
Ce(C2O4)Cl·3H2O [23]
Pr(C2O4)Cl·3H2O stable to 163°C [23][1]
Nd(C2O4)Cl·3H2O stable to 167°C; dec 510° to NdOCl [23][1][24]
Sm(C2O4)Cl·3H2O stable to 174°C; dec at 347° to EuC2O4 [23][1]
Eu(C2O4)Cl·3H2O stable to 178°C [23][1]
Gd(C2O4)Cl·3H2O [23][25]
[Pt(HC2O4)Cl3]2− [26]
[Pt(HC2O4)(C2O4)Cl]2− [26]
K2[Pt(C2O4)Cl2]·H2O triclinic P1 a=7.136 b=7.308 c=10.130 α=86.75° β=74.58° γ=54.28° Z=2 457.7 3.27 [27][26]
[Pt(NH3)5Cl][Cr(C2O4)3] · 4H2O orthorhombic Pccn a=38.901 b=13.7267 c=14.9141 [28]
[Pt(NH3)5Cl][Fe(C2O4)3] · 4H2O orthorhombic Pccn a=39.0123 b=13.7232 c=14.8990 [28]
[Pt(NH3)5Cl][Co(C2O4)3] · 2H2O monoclinic P21 a=8.5158 b=12.6409 c=8.5726 β=105.000° [28]
lead chloride oxalate Pb2Cl2(C2O4) monoclinic C2/m a=5.9411 b=5.8714 c=9.4212 β=95.232° Z=2 327.26 5.82 dec 350°C to Pb, Pb5O2Cl6 and Pb3O2Cl2 [29]
Th4Cl4(C2O4)6•20H2O
Plutonium(III) oxalato chloride ?Pu(C2O4)Cl·3H2O blue; biaxial (−) [30]
Am(C2O4)Cl·3H2O monoclinic P21/n a=5.852 b=15.823 c=8.351 β=104.243° [31]

References

  1. ^ a b c d e f Mulokozi, A.M.; Weigel, F. (May 1973). "Differential thermal analysis studies of some rare earth metal oxalato halide-hydrates". Journal of Inorganic and Nuclear Chemistry. 35 (5): 1487–1492. doi:10.1016/0022-1902(73)80236-2.
  2. ^ Lugwisha, E. H. J.; Mulokozi, A. M.; Masabo, M. K. J. (November 1991). "Activation energy of thermal decomposition of LaC2O4Br". Journal of Thermal Analysis. 37 (11–12): 2567–2572. doi:10.1007/BF01912801 (inactive 2024-02-07). ISSN 0368-4466. S2CID 95356620.{{cite journal}}: CS1 maint: DOI inactive as of February 2024 (link)
  3. ^ Mulokozi, A.M. (June 1972). "The nature of products obtained from the reaction of hydrogen halides with some rare-earth metal oxalate hydrates". Journal of the Less Common Metals. 27 (3): 419–422. doi:10.1016/0022-5088(72)90075-6.
  4. ^ a b c Jones, Francis T.; White, Lawrence M. (July 1946). "The Composition, Optical and Crystallographic Properties of Two Calcium Oxalate-Chloride Double Salts". Journal of the American Chemical Society. 68 (7): 1339–1342. doi:10.1021/ja01211a075. ISSN 0002-7863. PMID 20991004.
  5. ^ Baran, Enrique J. (2014-12-17). "Review: Natural oxalates and their analogous synthetic complexes". Journal of Coordination Chemistry. 67 (23–24): 3734–3768. doi:10.1080/00958972.2014.937340. ISSN 0095-8972. S2CID 96163581.
  6. ^ Rastsvetaeva, R. K.; Chukanov, N. V.; Nekrasov, Yu. V. (2001). "[No title found]". Doklady Chemistry. 381 (1/3): 329–331. doi:10.1023/A:1012984825792 (inactive 2024-02-07). S2CID 91571345.{{cite journal}}: CS1 maint: DOI inactive as of February 2024 (link)
  7. ^ Piro, Oscar E.; Echeverría, Gustavo A.; González-Baró, Ana C.; Baran, Enrique J. (February 2018). "Crystal structure and spectroscopic behavior of synthetic novgorodovaite Ca2(C2O4)Cl2·2H2O and its twinned triclinic heptahydrate analog". Physics and Chemistry of Minerals. 45 (2): 185–195. doi:10.1007/s00269-017-0907-0 (inactive 2024-02-07). ISSN 0342-1791. S2CID 103745968.{{cite journal}}: CS1 maint: DOI inactive as of February 2024 (link)
  8. ^ a b Lozančić, Ana; Renka, Sanja; Barišić, Dario; Burazer, Sanja; Molčanov, Krešimir; Pajić, Damir; Jurić, Marijana (2023-06-19). "High Proton Conductivity of Magnetically Ordered 2D Oxalate-Bridged [Mn II Cr III ] Coordination Polymers with Irregular Topology". Inorganic Chemistry. 62 (24): 9418–9428. doi:10.1021/acs.inorgchem.3c00443. ISSN 0020-1669. PMID 37290133. S2CID 259118281.
  9. ^ a b c d Mastropietro, Teresa F.; Marino, Nadia; Munno, Giovanni De; Lloret, Francesc; Julve, Miguel; Pardo, Emilio; Armentano, Donatella (2016-11-07). "Selective Guest Inclusion in Oxalate-Based Iron(III) Magnetic Coordination Polymers". Inorganic Chemistry. 55 (21): 11160–11169. doi:10.1021/acs.inorgchem.6b01769. ISSN 0020-1669. PMID 27749048.
  10. ^ Zhang, Bin; Zhang, Yan; Kurmoo, Mohamedally (May 2007). "Preparation, crystal structure and magnetic property of a binuclear oxalate-bridged iron(III) compound: Fe2(C2O4)Cl4(DMF)4 (DMF=dimethylformamide)". Inorganica Chimica Acta. 360 (7): 2513–2517. doi:10.1016/j.ica.2006.10.028.
  11. ^ Cot, Sergi; Leu, Meike K.; Kalamiotis, Alexis; Dimitrakis, Georgios; Sans, Victor; de Pedro, Imanol; Cano, Israel (July 2019). "An Oxalate-Bridged Binuclear Iron(III) Ionic Liquid for the Highly Efficient Glycolysis of Polyethylene Terephthalate under Microwave Irradiation". ChemPlusChem. 84 (7): 786–793. doi:10.1002/cplu.201900075. hdl:10234/185443. ISSN 2192-6506. PMID 31943995. S2CID 196896383.
  12. ^ Wang, Lei; Wang, Wenqiang; Guo, Dong; Zhang, Ao; Song, Yaoguang; Zhang, Yiheng; Huang, Keke (2014). "Design and syntheses of hybrid supramolecular architectures: based on [Fe(C 2 O 4 ) 3 ] 3− metallotectons and diverse organic cations". CrystEngComm. 16 (24): 5437–5449. doi:10.1039/C4CE00357H. ISSN 1466-8033.
  13. ^ Wang, Lei; Wang, Wenqiang; Guo, Dong; Zhang, Ao; Song, Yaoguang; Zhang, Yiheng; Huang, Keke (2014). "Design and syntheses of hybrid supramolecular architectures: based on [Fe(C 2 O 4 ) 3 ] 3− metallotectons and diverse organic cations". CrystEngComm. 16 (24): 5437–5449. doi:10.1039/C4CE00357H. ISSN 1466-8033.
  14. ^ Burazer, Sanja; Molčanov, Krešimir; Šantić, Ana; Klaser, Teodoro; Wenger, Emmanuel; Pajić, Damir; Jagličić, Zvonko; Popović, Jasminka; Jurić, Marijana (2021-09-24). "Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility". Materials. 14 (19): 5543. Bibcode:2021Mate...14.5543B. doi:10.3390/ma14195543. ISSN 1996-1944. PMC 8509436. PMID 34639934.
  15. ^ Zhang, Bin; Wang, Zheming; Zhang, Yan; Takahashi, Kazuyuki; Okano, Yoshinori; Cui, Hengbo; Kobayashi, Hayao; Inoue, Katsuya; Kurmoo, Mohamedally; Pratt, Francis L.; Zhu, Daoben (2006-04-17). "Hybrid Organic−Inorganic Conductor with a Magnetic Chain Anion: κ-BETS 2 [Fe III (C 2 O 4 )Cl 2 ] [BETS = Bis(ethylenedithio)tetraselenafulvalene]". Inorganic Chemistry. 45 (8): 3275–3280. doi:10.1021/ic051870q. ISSN 0020-1669. PMID 16602784.
  16. ^ Zhang, B.; Zhang, Y.; Wang, Z.; Yang, D.; Gao, Z.; Wang, D.; Guo, Y.; Zhu, D.; Mori, T. (2016). "[BEDT-TTF][Fe(C 2 O 4 )Cl 2 ]: an organic–inorganic hybrid semiconductive antiferromagnet". Dalton Transactions. 45 (42): 16561–16565. doi:10.1039/C6DT01845A. ISSN 1477-9226.
  17. ^ Zhang, Bin; Zhang, Yan; Gao, Zengqiang; Chang, Guangcai; Su, Shaokui; Wang, Dongwei; Guo, Yanjun; Zhu, Daoben (2014-08). "Synthesis, Crystal Structure, and Characterization of the Charge‐Transfer Salt (BEDT‐TTF)[Fe(C 2 O 4 )Cl 2 ](CH 2 Cl 2 ), {BEDT‐TTF = Bis(ethylenedithio)tetrathiafulvalene}". European Journal of Inorganic Chemistry. 2014 (24): 4028–4032. doi:10.1002/ejic.201402112. ISSN 1434-1948. {{cite journal}}: Check date values in: |date= (help)
  18. ^ Jone Kirubavathy, S.; Velmurugan, R.; Parameswari, K.; Chitra, S. (November 2019). "Synthesis, characterization, single crystal XRD, in vitro antimicrobial and cytotoxicity study of tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate". Arabian Journal of Chemistry. 12 (7): 1581–1586. doi:10.1016/j.arabjc.2014.10.013.
  19. ^ a b Xu, Wei; Ma, Liang; Lv, Yi-Lei; Ma, Si-Yu; Liu, Wenlong; Guo, Sheng-Ping; Tang, Ru-Ling (2023-12-19). "C(NH 2 ) 3 Cd(C 2 O 4 )Cl(H 2 O)·H 2 O and BaCd(C 2 O 4 ) 1.5 Cl(H 2 O) 2 : Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties". Inorganic Chemistry. 63 (1): 67–72. doi:10.1021/acs.inorgchem.3c04154. ISSN 0020-1669. PMID 38112437. S2CID 266373131.
  20. ^ a b c Zhang, Die; Wang, Qiang; Luo, Han; Cao, Liling; Dong, Xuehua; Huang, Ling; Gao, Daojiang; Zou, Guohong (March 2023). "Deep Eutectic Solvents Synthesis of A 2 Sb(C 2 O 4 )Cl 3 (A = NH 4 , K, Rb) with Superior Optical Performance". Advanced Optical Materials. 11 (6). doi:10.1002/adom.202202874. ISSN 2195-1071.
  21. ^ Hölsä, Jorma; Koriseva, Eija (August 1991). "Thermal decomposition of LaC2O4Cl·3H2O : Eu3+: a high-resolution luminescence spectroscopy study". Thermochimica Acta. 185 (1): 25–33. doi:10.1016/0040-6031(91)80114-X.
  22. ^ Baker, P.; Smith, A. J. (1990-06-15). "Structure of lanthanum chloride oxalate trihydrate". Acta Crystallographica Section C Crystal Structure Communications. 46 (6): 984–985. Bibcode:1990AcCrC..46..984B. doi:10.1107/S0108270189009248. S2CID 98752634.
  23. ^ a b c d e f g Möbius, R.; Matthes, F. (June 1964). "Über die Verhältnisse beim Austausch von Oxalationen gegen Chloridionen bei Oxalathydraten der Seltenen Erden und des Yttriums". Zeitschrift für Chemie. 4 (6): 234–235. doi:10.1002/zfch.19640040618. ISSN 0044-2402.
  24. ^ Mulokozi, A. M.; Zuru, A. A. (November 1989). "Activation energy of thermal decomposition of fully dehydrated NdC2O4Cl·3H2O to NdOCl". Journal of Thermal Analysis. 35 (7): 2359–2366. doi:10.1007/BF01911900 (inactive 2024-02-07). ISSN 0368-4466. S2CID 95014944.{{cite journal}}: CS1 maint: DOI inactive as of February 2024 (link)
  25. ^ Mulokozi, A. M.; Weigel, F. (April 1975). "Characeriztion of Rare-Earth Metal Oxalato Halide-Hydrates by thermal analytical methods". Zeitschrift für anorganische und allgemeine Chemie. 414 (1): 62–68. doi:10.1002/zaac.19754140108. ISSN 0044-2313.
  26. ^ a b c Dunham, S. O.; Larsen, R. D.; Abbott, E. H. (1991-11). "Nuclear magnetic resonance investigation of the formation of oxalato, malonato, and 2-methylmalonato complexes of platinum(II). Crystal and molecular structures of potassium anti-bis(2-methylmalonato)platinate(II) dihydrate and potassium dichloro(oxalato)platinate(II) hydrate". Inorganic Chemistry. 30 (23): 4328–4335. doi:10.1021/ic00023a009. ISSN 0020-1669. {{cite journal}}: Check date values in: |date= (help)
  27. ^ "K2[Pt(C2O4)Cl2]·H2O (K2Pt[C2O4]Cl2[H2O]) Crystal Structure - SpringerMaterials". materials.springer.com. Retrieved 2024-02-08.
  28. ^ a b c Yusenko, K. V.; Vasil’chenko, D. B.; Zadesenets, A. V.; Baidina, I. A.; Shubin, Yu. V.; Korenev, S. V. (2007-10). "Double complex salts [Pt(NH3)5Cl][M(C2O4)3] · nH2O (M = Fe, Co, Cr): Synthesis and study". Russian Journal of Inorganic Chemistry. 52 (10): 1487–1491. doi:10.1134/S0036023607100014. ISSN 0036-0236. {{cite journal}}: Check date values in: |date= (help)
  29. ^ Boudaren, Chaouki; Auffrédic, Jean-Paul; Louër, Michèle; Louër, Daniel (September 2003). "A powder X-ray diffraction study of lead chloride oxalate Pb 2 Cl 2 (C 2 O 4 ): ab initio structure determination and thermal behavior". Powder Diffraction. 18 (3): 205–213. doi:10.1154/1.1590352. ISSN 0885-7156. S2CID 98700786.
  30. ^ Staritzky, Eugene (28 August 1949). Optical and Morphological Crystallography of Plutonium Compounds (PDF). US Atomic Energy Commission. p. 34.
  31. ^ Arteaga, Ana; Nicholas, Aaron D.; Ducati, Lucas C.; Autschbach, Jochen; Surbella, Robert G. (2023-03-27). "Americium Oxalate: An Experimental and Computational Investigation of Metal–Ligand Bonding". Inorganic Chemistry. 62 (12): 4814–4822. doi:10.1021/acs.inorgchem.2c03976. ISSN 0020-1669. PMID 36920249. S2CID 257534787.
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