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Saul Winstein

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Saul Winstein
Born(1912-10-08)October 8, 1912
DiedNovember 23, 1969(1969-11-23) (aged 57)
NationalityAmerican
Known forWinstein reaction
Grunwald-Winstein equation
Non-classical cation
Anchimeric assistance
Scientific career
FieldsPhysical Organic Chemistry
InstitutionsUCLA

Saul Winstein (October 8 1912November 23 1969) was the American chemist who discovered the Winstein reaction, in which he argued a non-classical cation was needed to explain the stability of the norbornyl cation. This fueled a debate with Herbert C. Brown over the existence of delocalized cations such as this.[1] Co-author of the Grunwald-Winstein equation concerning solvolysis rates.[2]

References

  1. ^ [http://nobelprize.org/nobel_prizes/chemistry/laureates/1994/illpres/problem.html Nobel Foundation description of the non-classical ion and its importance, and the debate over their existence.
  2. ^ W. G. Young, D. J. Cram (1951). "The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions Into Mechanistic Categories". Journal of the American Chemical Society. 73 (6): 2700–2707. doi:10.1021/ja01150a078.

Sources

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