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Carnallite

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Carnallite
General
CategoryHalide mineral
Formula
(repeating unit)
KMgCl3·6(H2O)
Crystal systemOrthorhombic, (2/m 2/m 2/m), space group: Pcna
Identification
Formula mass277.85
ColorBlue, colorless, yellow, white, red
Crystal habitFibrous
FractureConchoidal
Mohs scale hardness2.5
LusterGreasy
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity1.6
Optical propertiesBiaxial (+)
Refractive indexnα = 1.467
nβ = 1.476
nγ = 1.494
Birefringence0.0270
2V angle70
Other characteristicsNon-fluorescent
References[1][2][3]

Carnallite is an evaporite mineral, a hydrated potassium magnesium chloride with formula: KMgCl3·6(H2O). It is variably colored yellow to white, reddish, and sometimes colorless or blue. It is usually massive to fibrous with rare pseudohexagonal orthorhombic crystals. The mineral is deliquescent (absorbs moisture from the surrounding air) and specimens must be stored in an airtight container.

Carnallite occurs with a sequence of potassium and magnesium evaporite minerals sylvite, kainite, picromerite, polyhalite and kieserite. Carnallite is a somewhat rare double chloride mineral which only forms under a specific environmental conditions in an evaporating sea or sedimentary basin. It is mined for both potassium and magnesium and occurs in the evaporite deposits of Carlsbad, New Mexico; the Paradox Basin in Colorado and Utah; Stassfurt, Germany; the Perm Basin, Russia; and the Williston Basin in Saskatchewan, Canada. These deposits date from the Devonian through the Permian Periods. In contrast, both Israel and Jordan produce potash from the Dead Sea by using evaporation pans to further concentrate the brine until carnallite precipitates, dredging the carnallite from the pans, and processing to remove the magnesium chloride from the potassium chloride.[3]

Carnallite was first described in 1856 from its type location of Stassfurt Deposit, Saxony-Anhalt, Germany. It was named for the Prussian mining engineer, Rudolf von Carnall (1804–1874).[3]

Carnallite from Russia

See also

References