Trinitramide
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IUPAC name
N,N-Dinitronitramide
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Other names
Trinitroamine
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
CompTox Dashboard (EPA)
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Properties | |
N4O6 | |
Molar mass | 152.022 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Trinitramide is a compound of nitrogen and oxygen with the molecular formula N(NO2)3. The compound was detected and described in 2010 by researchers at the Royal Institute of Technology (KTH) in Sweden.[1]
Earlier, there had been speculation[by whom?] whether trinitramide could exist.[need quotation to verify] Theoretical calculations by Montgomery and Michels in 1993 showed that the compound was likely to be stable.[2]
Trinitramide has a potential use as one of the most efficient and least polluting of rocket propellant oxidizers, as it is chlorine-free.[3] This is potentially an important development, because the Tsiolkovsky rocket equation implies that even small improvements in rocket delta-v can make large improvements in the size of practical rocket launch payloads. The density impulse (impulse per volume) of a trinitramide based propellant could be 20 to 30 per cent better than most existing formulations [4], however the specific impulse (impulse per mass) of formulations with liquid oxygen is higher [5].
References
- ^ Angewandte Chemie International Edition, Early View, Dec. 23, 2010
- ^ J. A. Montgomery Jr. and H. H. Michels (July 1993). "Structure and stability of trinitramide". Journal of Physical Chemistry. 97 (26): 6774–6775. doi:10.1021/j100128a005.
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(help) - ^ Discovery of New Molecule Could Lead to More Efficient Rocket Fuel, Science Daily, 2010-12-22, accessed 2011-01-03.
- ^ http://www.rsc.org/chemistryworld/News/2011/January/07011103.asp
- ^ http://onlinelibrary.wiley.com/store/10.1002/anie.201007047/asset/supinfo/anie_201007047_sm_miscellaneous_information.pdf?v=1&s=2b7789919ea7a0858400749fd4a8859942236a1e