Potassium bromate
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| Names | |
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| IUPAC name
Potassium bromate
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| Other names
Potassium bromate(V); Bromic acid, potassium salt
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| Identifiers | |
| ECHA InfoCard | 100.028.936 |
| EC Number |
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PubChem CID
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| RTECS number |
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| UN number | 1484 |
CompTox Dashboard (EPA)
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| Properties | |
| KBrO3 | |
| Molar mass | 167.00 g/mol |
| Appearance | white crystalline powder |
| Density | 3.27 g/cm3 |
| Melting point | 350 °C (662 °F; 623 K) |
| Boiling point | 370 °C (decomposes) |
| 6.91 g/100 mL (20 °C) 13.3 g/100 mL (40 °C) | |
| Solubility | slightly soluble in alcohol insoluble in acetone |
| Hazards | |
| NFPA 704 (fire diamond) | |
| Flash point | Non-flammable |
| Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
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321 mg/kg |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Potassium bromate (KBrO3), is a bromate of potassium and takes the form of white crystals or powder.
It is typically used as a flour improver (E number E924), strengthening the dough and allowing higher rising. It is an oxidizing agent, and under the right conditions, will be completely used up in the baking bread. However, if too much is added, or if the bread is not baked long enough or not at a high enough temperature, then a residual amount will remain, which may be harmful if consumed. Potassium bromate might also be used in the production of malt barley where the U.S. Food and Drug Administration (FDA) has prescribed certain conditions where it may be used safely, which includes labeling standards for the finished malt barley product.[1] It is a very powerful oxidizer (E° = 1.5 volts comparable to potassium permanganate). Bromate is considered a category 2B (possibly carcinogenic to humans) carcinogen by the International Agency for Research on Cancer (IARC).[2]
Bans
Potassium bromate has been banned from use in food products in Europe, as well as the United Kingdom in 1990, and Canada in 1994, and most other countries. It was banned in Sri Lanka in 2001[3] and China in 2005. It is also banned in Nigeria, Brazil[citation needed] and Peru.
In the United States, it has not been banned. The FDA sanctioned the use of bromate before the Delaney clause of the Food, Drug, and Cosmetic Act went into effect in 1958—which bans carcinogenic substances—so that it is more difficult for it to now be banned. Instead, since 1991 the FDA has urged bakers to voluntarily stop using it. In California a warning label is required when bromated flour is used.
Japanese baked goods manufacturers stopped using potassium bromate voluntarily in 1980; however, Yamazaki Baking resumed its use in 2005, claiming they had new production methods to reduce the amount of the chemical which remained in the final product.[4]
Reference In Popular Culture
In the television show Fringe, one character; Walter Bishop causes an uproar in a supermarket over the use of potassium bromate in a strawberry flavoured pudding. He refers to the ingredient as 'delicious, strawberry flavoured death'.[5]
References
- ^ Section 172.730 Potassium Bromate, Food Additives Permitted for Direct Addition to Food for Human Consumption, US Code of Federal Regulations, US Food and Drug Administration
- ^ IARC--Summaries & Evaluations: Potassium Bromate (Group 2B), International Agency for Research on Cancer
- ^ Bridges Across Borders, Environmental Law Alliance Worldwide
- ^ AsiaPulse News: Japan's Yamazaki Baking to use potassium bromate in bread
- ^ YouTube: Walter Bishop - Delicious, strawberry flavoured death (Fringe)