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Copper(II) arsenate

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Copper(II) arsenate
File:Copper (II) Arsenate.gif
Names
IUPAC name
Copper(II) arsenate
Other names
Copper arsenate
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/2AsH3O4.3Cu/c2*2-1(3,4)5;;;/h2*(H3,2,3,4,5);;;/q;;3*+2/p-6 checkY
    Key: RKYSWCFUYJGIQA-UHFFFAOYSA-H checkY
  • InChI=1/2AsH3O4.3Cu/c2*2-1(3,4)5;;;/h2*(H3,2,3,4,5);;;/q;;3*+2/p-6
    Key: RKYSWCFUYJGIQA-CYFPFDDLAM
  • [Cu+2].[Cu+2].[Cu+2].[O-][As]([O-])(=O)[O-].[O-][As]([O-])([O-])=O
Properties
Cu3(AsO4)2
Molar mass 468.48 g/mol
Appearance blue or bluish green powder
Density 5.2 g/cm3
Melting point 1100 °C
insoluble
Solubility soluble in ammonia, dilute acids
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Copper arsenate (Cu3(AsO4)2.4H2O, or Cu5H2(AsO4)4.2H2O), also called copper orthoarsenate or tricopper arsenate or tricopper orthoarsenate, is an insecticide used in agriculture. It is also used as a herbicide, fungicide, and a rodenticide. It is a blue or bluish-green powder insoluble in water and alcohol and soluble in aqueous ammonium and dilute acids. Its CAS number is 7778-41-8 or 10103-61-4. It also occurs naturally as the mineral rollandite.[1]

Copper arsenate hydroxide or basic copper arsenate (Cu(OH)AsO4) is a basic variant with CAS number 16102-92-4. It is found naturally as the mineral olivenite. It is used as an insecticide, fungicide, and miticide. Its use is banned in Thailand since 2001.[1]

Copper arsenate is also used as a poison in slug baits.

Copper arsenate can also be a misnomer for copper arsenite, especially when meant as a pigment.

See also

References

  1. ^ Sarp, H.; Cerny, R. (2000). European Journal of Mineralogy. 12: 1045–1050. {{cite journal}}: Missing or empty |title= (help)