Arsenate mineral
Appearance
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3- anion group and, more rarely, other arsenates with anions like AsO3(OH)2- (also written HAsO42-) (example: pharmacolite Ca(AsO3OH).2H2O) or (very rarely) [AsO2(OH)2]- (example: andyrobertsite). Arsenite minerals are much less common.[1] Both the Dana[2] and the Strunz[3] mineral classifications place the arsenates in with the phosphate minerals.
Example arsenate minerals include:
- Annabergite Ni3(AsO4)2·8H2O
- Austinite CaZn(AsO4)(OH)
- Clinoclase Cu3(AsO4)(OH)3
- Conichalcite CaCu(AsO4)(OH)
- Cornubite Cu5(AsO4)2(OH)4
- Cornwallite Cu2+5(AsO4)2(OH)2
- Erythrite Co3(AsO4)2·8H2O
- Mimetite Pb6(AsO4)3Cl
- Olivenite Cu2(AsO4)OH
Nickel-Strunz Classification -08- Phosphates
IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel-Strunz (10 ed, pending publication).
- Abbreviations:
- "*" - Mineral not IMA Approved.
- "?" - IMA Discredited Mineral Name.
- "REE" - Rare-earth element (Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)
- "PGE" - Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt)
- 03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V[5,6] Vanadates), 09 Silicates:
- Neso: insular (from Greek νησος nēsos, island)
- Soro: grouping (from Greek σωροῦ sōros, heap, mound (especially of corn))
- Cyclo: ring
- Ino: chain (from Greek ις [genitive: ινος inos], fibre)
- Phyllo: sheet (from Greek φύλλον phyllon, leaf)
- Tekto: three-dimensional framework
- Nickel-Strunz code scheme: NN.XY.##x
- NN: Nickel-Strunz mineral class number
- X: Nickel-Strunz mineral division letter
- Y: Nickel-Strunz mineral family letter
- ##x: Nickel-Strunz mineral/group number, x add-on letter
Class: arsenates
- 08.A Arsenates without additional anions, without H2O
- 08.AA With small cations (some also with larger ones): 05 Alarsite
- 08.AB With medium-sized cations: 25 Xanthiosite, 30 Lammerite, 35 Stranskiite
- 08.AC With medium-sized and large cations: 10 Arseniopleite, 10 Caryinite, 10 Yazganite, 10 Johillerite, 10 Odanielite, 10 Nickenichite, 10 Bradaczekite; 25 Berzeliite, 25 Manganberzeliite, 85 Filatovite
- 08.AD With only large cations: 10 Svenekite, 10 Weilite; 30 Schultenite, 35 Chernovite-(Y); 50 Gasparite-(Ce), 50 Rooseveltite; 55 Tetrarooseveltite, 60 Chursinite
- 08.B Arsenates with Additional Anions, without H2O
- 08.C Arsenates without Additional Anions, with H2O
- 08.CA With small and large/medium cations: 35 Warikahnite, 50 Keyite, 55 Pushcharovskite, 60 Prosperite
- 08.CB With only medium-sized cations, RO4:H2O = 1:1: 10 IMA2008-066, 10 IMA2008-047, 10 Sainfeldite, 10 Villyaellenite; 15 Krautite, 15 Fluckite; 20 Cobaltkoritnigite, 20 Koritnigite; 25 Yvonite, 30 Geminite, 40 Radovanite, 55 Irhtemite, 60 Burgessite
- 08.CC With only medium-sized cations, RO4:H2O = 1:1.5: 10 Kaatialaite, 15 Leogangite
- 08.CD With only medium-sized cations, RO4:H2O = 1:2: 10 Mansfieldite, 10 Scorodite, 10 Yanomamite; 15 Parascorodite, 25 Sterlinghillite, 30 Rollandite
- 08.CE With only medium-sized cations, RO4:H2O £ 1:2.5: 05 Geigerite, 05 Chudobaite, 15 Brassite, 20 Rosslerite, 30 Veselovskyite, 30 IMA2008-010, 30 Lindackerite, 40 Ferrisymplesite, 40 Manganohornesite, 40 Annabergite, 40 Erythrite, 40 Hornesite, 40 Kottigite, 40 Parasymplesite, 45 Symplesite, 60 Kankite, 85 Metakottigite
- 08.CF With large and medium-sized cations, RO4:H2O > 1:1: 05 Grischunite
- 08.CG With large and medium-sized cations, RO4:H2O = 1:1: 05 Gaitite, 05 Parabrandtite, 05 Talmessite, 10 Roselite-beta, 10 Brandtite, 10 Roselite, 10 Zincroselite, 10 Wendwilsonite, 15 Ferrilotharmeyerite, 15 Cabalzarite, 15 Lotharmeyerite, 15 Cobaltlotharmeyerite, 15 Mawbyite, 15 Cobalttsumcorite, 15 Nickellotharmeyerite, 15 Schneebergite, 15 Nickelschneebergite, 15 Tsumcorite, 15 Thometzekite, 15 Manganlotharmeyerite; 20 Zincgartrellite, 20 Lukrahnite, 20 Gartrellite, 20 Helmutwinklerite, 20 Rappoldite; 35 Nickeltalmessite
- 08.CH With large and medium-sized cations, RO4:H2O < 1:1: 05 Walentaite, 15 Picropharmacolite; 55 Smolianinovite, 55 Fahleite; 60 Barahonaite-(Fe), 60 Barahonaite-(Al)
- 08.CJ With only large cations: 20 Haidingerite, 25 Vladimirite, 30 Ferrarisite, 35 Machatschkiite; 40 Phaunouxite, 40 Rauenthalite; 50 Pharmacolite, 55 Mcnearite, 75 Guerinite
- 08.D Arsenates
- 08.E Uranyl Arsenates
- 08.EA UO2:RO4 = 1:2: 05 Orthowalpurgite, 05 Walpurgite; 10 Hallimondite
- 08.EB UO2:RO4 = 1:1: 05 Metarauchite, 05 Heinrichite, 05 Kahlerite, 05 Novacekite, 05 Uranospinite, 05 Zeunerite; 10 Metazeunerite, 10 Metauranospinite, 10 Metaheinrichite, 10 Metakahlerite, 10 Metakirchheimerite, 10 Metalodevite, 10 Metanovacekite; 15 Uramarsite, 15 Trogerite, 15 Abernathyite, 15 Natrouranospinite; 20 Chistyakovaite, 25 Arsenuranospathite
- 08.EC UO2:RO4 = 3:2: 10 Arsenuranylite, 15 Hugelite, 20 Arsenovanmeersscheite, 45 Nielsbohrite
- 08.ED Unclassified: 10 Asselbornite
- 08.F Polyarsenates
- 08.FA Polyarsenates, without OH and H2O; dimers of corner-sharing RO4 tetrahedra: 25 Petewilliamsite
- 08.X Unclassified Strunz Arsenates
- 08.XX Unknown: 00 Kamarizaite, 00 Chernovite-(Ce)*, 00 Arsenobismite?, 00 Slavkovite, 00 Lapeyreite, 00 IMA2000-020, 00 IMA2008-063, 00 IMA2009-002, IMA2009-016
Class: vanadates
- 04.H V[5,6] Vanadates
- 04.HB Uranyl Sorovanadates: 05 Carnotite, 05 Margaritasite; 10 Sengierite; 15 Fritzscheite, 15 Curienite, 15 Francevillite; 20 Metavanuralite, 20 Vanuralite; 25 Metatyuyamunite, 25 Tyuyamunite; 30 Strelkinite, 35 Uvanite, 40 Rauvite
- 04.HC [6]-Sorovanadates: 05 Magnesiopascoite, 05 Lasalite, 05 Pascoite; 10 Hummerite, 15 Sherwoodite
- 04.HD Inovanadates: 05 Rossite, 10 Metarossite, 15 Munirite, 20 Metamunirite, 25 Dickthomssenite, 30 Ansermetite
- 04.HE Phyllovanadates: 05 Melanovanadite, 10 Shcherbinaite; 15 Hewettite, 15 Metahewettite; 20 Bokite, 20 Bariandite, 20 Corvusite, 20 Fernandinite, 20 Straczekite; 25 Haggite, 30 Doloresite, 35 Duttonite, 40 Cavoite
- 04.HF Tektovanadates: 05 Bannermanite
- 04.HG Unclassified V oxides: 05 Fervanite, 10 Huemulite, 15 Vanalite, 20 Simplotite, 25 Vanoxite, 30 Navajoite, 35 Delrioite, 40 Metadelrioite, 45 Barnesite, 50 Hendersonite, 55 Grantsite, 60 Lenoblite, 65 Satpaevite
- 08.A Vanadates without additional anions, without H2O
- 08.AB With medium-sized cations: 35 Mcbirneyite, 40 Lyonsite
- 08.AC With medium-sized and large cations: 05 Howardevansite; 25 Palenzonaite, 25 Schaferite; 75 Ronneburgite, 80 Tillmannsite
- 08.AD With only large cations: 35 Wakefieldite-(La), 35 Wakefieldite-(Nd), 35 Wakefieldite-(Ce), 35 Wakefieldite-(Y), 35 Dreyerite; 40 Pucherite, 65 Clinobisvanite
- 08.B Vanadates with Additional Anions, without H2O
- 08.BB With only medium-sized cations, (OH, etc.):RO4 £ 1:1: 50 Namibite, 70 Turanite, 75 Stoiberite, 80 Fingerite, 85 Averievite
- 08.BD With only medium-sized cations, (OH, etc.):RO4 = 2:1: 20 Reppiaite
- 08.BE With only medium-sized cations, (OH, etc.):RO4 > 2:1: 45 Turtmannite, 80 Coparsite
- 08.BF With medium-sized and large cations, (OH, etc.):RO4 < 0.5:1: 20 Nabiasite
- 08.BG With medium-sized and large cations, (OH, etc.):RO4 = 0.5:1: 05 Brackebuschite, 05 Gamagarite, 05 Tokyoite, 05 Bushmakinite, 05 Calderonite
- 08.BH With medium-sized and large cations, (OH,etc.):RO4 = 1:1: 35 Tangeite, 35 Gottlobite, 40 Descloizite, 40 Cechite, 40 Pyrobelonite, 40 Mottramite, 40 Duhamelite?, 45 Vesignieite, 65 Leningradite
- 08.BK With medium-sized and large cations, (OH, etc.): 20 Heyite
- 08.BL With medium-sized and large cations, (OH, etc.):RO4 = 3:1: 20 Cheremnykhite
- 08.BN With only large cations, (OH, etc.):RO4 = 0.33:1: 05 Vanadinite
- 08.BO With only large cations, (OH, etc.):RO4 1:1: 10 Schumacherite, 15 Hechtsbergite, 20 Kombatite
- 08.C Vanadates without Additional Anions, with H2O
- 08.CB With only medium-sized cations, RO4:H2O = 1:1: 35 Schubnelite, 45 Kazakhstanite, 50 Kolovratite
- 08.CE With only medium-sized cations, RO4:H2O £ 1:2.5: 65 Steigerite; 70 Metaschoderite, 70 Schoderite
- 08.CG With large and medium-sized cations, RO4:H2O = 1:1: 15 Mounanaite, 15 Krettnichite, 25 Pottsite
- 08.D Vanadates
- 08.DC With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1: 32 Tinticite; 60 Cloncurryite, 60 Nevadaite
- 08.DF With only medium-sized cations, (OH,etc.):RO4 > 3:1: 15 Rusakovite
- 08.DM With large and medium-sized cations, (OH, etc.):RO4 > 2:1: 20 Phosphovanadylite, 40 Santafeite
- 08.F [4]-Polyvanadates
- 08.FA [4]-Polyvanadates, without OH and H2O; dimers of corner-sharing RO4 tetrahedra: 05 Blossite, 10 Ziesite, 15 Chervetite
- 08.FC [4]-Polyvanadates, with H2O only: 05 Fianelite, 15 Pintadoite
- 08.FD [4]-Polyvanadates, with OH and H2O: 05 Martyite, 05 Volborthite
- 08.FE Ino-[4]-vanadates: 05 Ankinovichite, 05 Alvanite
- 08.X Unclassified Strunz Vanadates
- 08.XX Unknown: 00 Vanuranylite?
References
- Stuart J. Mills, Frédéric Hatert, Ernest H. Nickel, and Giovanni Ferraris (2009). "The standardisation of mineral group hierarchies: application to recent nomenclature proposals" (PDF). Eur. J. Mineral. 21: 1073–1080. doi:10.1127/0935-1221/2009/0021-1994.
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: CS1 maint: multiple names: authors list (link) - Ernest H. Nickel and Monte C. Nichols (2009). "IMA-CNMNC List of Mineral Names" (PDF). IMA-CNMNC.
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ignored (help) - Ferraiolo, Jim. "Nickel-Strunz (Version 10) Classification System". webmineral.com.