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Calcium citrate

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Calcium citrate
Calcium citrate
Chemical name Tricalcium citrate
Chemical formula Ca3(C6H5O7)2
Molecular mass 498.46 g/mol
CAS number [5785-44-4]
Density 1.63 g/cm3
Melting point unknown °C
Boiling point unknown °C
SMILES

C(C(=O)[O-])C(CC(=O)[O-])(C(=O)[O-])O.
C(C(=O)[O-])C(CC(=O)[O-])(C(=O)[O-])O.
[Ca+2].[Ca+2].[Ca+2]

Disclaimer and references

Calcium citrate is the calcium salt of citric acid. It is commonly used as a food additive (E333), usually as a preservative, but sometimes for flavor. In this sense, it is similar to sodium citrate. Calcium citrate is also used as a water softener.

Chemical properties

Like citric acid, calcium citrate has a sour taste. Like other salts, however, it also has a salty taste. For this reason, citrates such as sodium and calcium citrate are commonly known as sour salt.


Solubility in water 25C is 0.095 g/100 ml

Melt Point:120C (loses water)

Boiling Point: Decomposes

Biological role

Calcium citrate supplements may increase aluminium toxicity. Patients with renal disease are at an increased risk of toxicity.

Bioavailability is 2.5 times higher than calcium carbonate. For this reason, patients who have undergone the Roux-en-Y variety of weight-loss surgery (also known as gastric bypass) are usually instructed to take calcium citrate as a dietary supplement.

Organometallic importance

Calcium citrate is used as a water softener because the citrate chelates unwanted metal ions.