Hydrogeology

Hydrogeology (hydro- meaning water, and -geology meaning the study of rocks) is the part of hydrology that deals with the distribution and movement of groundwater in the soil and rocks of the Earth's crust (commonly in aquifers). The term geohydrology is often used interchangeably. Some make the minor distinction between a hydrologist or engineer applying themselves to geology (geohydrology), and a geologist applying themselves to hydrology (hydrogeology).

Introduction

Hydrogeology (like most earth sciences) is an interdisciplinary subject; it can be difficult to account fully for the chemical, physical, biological and even legal interactions between soil, water, nature and society. Although the basic principles of hydrogeology are very intuitive (e.g., water flows "downhill"), the study of their interaction can be quite complex. Taking into account the interplay of the different facets of a multi-component system often requires knowledge in several diverse fields at both the experimental and theoretical levels. This being said, the following is a more traditional (reductionist viewpoint) introduction to the methods and nomenclature of saturated subsurface hydrology, or simply hydrogeology.

Hydrogeology in relation to other fields

Hydrogeology, as stated above, is a branch of the earth sciences dealing with the flow of water through aquifers and other shallow porous media (typically less than 450 m or 1,500 ft below the land surface.) The very shallow flow of water in the subsurface (the upper 3 m or 10 ft) is pertinent to the fields of soil science, agriculture and civil engineering, as well as to hydrogeology. The general flow of fluids (water, hydrocarbons, geothermal fluids, etc.) in deeper formations is also a concern of geologists, geophysicists and petroleum geologists. Groundwater is a slow-moving, viscous fluid (with a Reynolds number less than unity); many of the empirically derived laws of groundwater flow can be alternately derived in fluid mechanics from the special case of Stokes flow (viscosity and pressure terms, but no inertial term).

The mathematical relationships used to describe the flow of water through porous media are the diffusion and Laplace equations, which have applications in many diverse fields. Steady groundwater flow (Laplace equation) has been simulated using electrical, elastic and heat conduction analogies. Transient groundwater flow is analogous to the diffusion of heat in a solid, therefore some solutions to hydrological problems have been adapted from heat transfer literature.

Traditionally, the movement of groundwater has been studied separately from surface water, climatology, and even the chemical and microbiological aspects of hydrogeology (the processes are uncoupled). As the field of hydrogeology matures, the strong interactions between groundwater, surface water, water chemistry, soil moisture and even climate are becoming more clear.

Definitions and material properties

Main article: Aquifer

In order to further characterize aquifers and aquitards some primary and derived physical properties are introduced below. Aquifers are broadly classified as being either confined or unconfined (water table aquifers), and either saturated or unsaturated; the type of aquifer affects what properties control the flow of water in that medium (e.g., the release of water from storage for confined aquifers is related to the storativity, while it is related to the specific yield for unconfined aquifers).

Hydraulic head

Main article: Hydraulic head

Changes in hydraulic head (h) are the driving force which causes water to move from one place to another. It is composed of pressure head (ψ) and elevation head (z). The head gradient is the change in hydraulic head per length of flowpath, and appears in Darcy's law as being proportional to the discharge.

Hydraulic head is a directly measurable property, which can take on any value (because of the arbitrary datum involved in the z term); ψ can be measured with a pressure transducer (this value can be negative, e.g., suction, but is positive in saturated aquifers), and z can be measured relative to a surveyed datum (typically the top of the well casing). Commonly, in wells tapping unconfined aquifers the water level in a well is used as a proxy for hydraulic head, assuming there is no vertical gradient of pressure. Often only changes in hydraulic head through time are needed, so the constant elevation head term can be left out (Δh = Δψ).

A record of hydraulic head through time at a well is a hydrograph or, the changes in hydraulic head recorded during the pumping of a well in a test are called drawdown.

Porosity

Main article: Porosity

Porosity (n) is a directly measurable aquifer property; it is a fraction between 0 and 1 indicating the amount of pore space between unconsolidated soil particles or within a fractured rock. Typically, the majority of groundwater (and anything dissolved in it) moves through the porosity available to flow (sometimes called effective porosity).

Porosity does not directly affect the distribution of hydraulic head in an aquifer, but it very strongly effects the migration of dissolved contaminants, since it affects groundwater flow velocities through an inversely proportional relationship.

Water content

Main page: water content

Water content (θ) is also a directly measurable property; it is the fraction of the total rock which is filled with liquid water. This is also a fraction between 0 and 1, but it must also be less than or equal to the total porosity.

The water content is very important in vadose zone hydrology, where the hydraulic conductivity is a strongly nonlinear function of water content; this complicates the solution of the unsaturated groundwater flow equation.

Hydraulic conductivity

Main article: Hydraulic conductivity

Hydraulic conductivity (K) and transmissivity (T) are indirect aquifer properties (they cannot be measured directly). T is the K integrated over the vertical thickness (b) of the aquifer (T=Kb when K is constant over the entire thickness). These properties are measures of an aquifer's ability to transmit water. Intrinsic permeability (κ) is a secondary medium property which does not depend on the viscosity and density of the fluid (K and T are specific to water); it is used more in the petroleum industry.

Specific storage and specific yield

Main article: Specific storage

Specific storage (S_s) and its depth-integrated equivalent, storativity (S=S_sb), are indirect aquifer properties (they cannot be measured directly); they indicate the amount of groundwater released from storage due to a unit depressurization of a confined aquifer. They are fractions between 0 and 1.

Specific yield (S_y) is also a ratio between 0 and 1 (S_y ≤ porosity) which indicates the amount of water released due to drainage, from lowering the water table in an unconfined aquifer. Typically S_y is orders of magnitude larger than S_s. Often the porosity or effective porosity is used as an upper bound to the specific yield.

Governing equations

Darcy's Law

Main Article: Darcy's law

Darcy's law is a Constitutive equation (empirically derived by Henri Darcy, in 1856) which states the amount of groundwater discharging through a given portion of aquifer is proportional to the cross-sectional area to flow, the hydraulic head gradient and the hydraulic conductivity.

Groundwater flow equation

Main Article: Groundwater flow equation

The groundwater flow equation, in its most general form, describes the movement of groundwater in a porous medium (aquifers and aquitards). It is known in mathematics as the diffusion equation, and has many analogs in other fields. Many solutions for groundwater flow problems were borrowed or adapted from existing heat transfer solutions.

It is often derived from a physical basis using Darcy's law and a conservation of mass for a small control volume. The equation is often used to predict flow to wells, which have radial symmetry, so the flow equation is commonly solved in polar or cylindrical coordinates.

The Theis equation is one of the most commonly used and fundamental solutions to the groundwater flow equation; it can be used to predict the transient evolution of head, due to the effects of pumping one or a number of pumping wells.

The Thiem equation is a solution to the steady state groundwater flow equation (Laplace's Equation). Unless there are large sources of water nearby (a river or lake), true steady-state is rarely achieved in reality.

Calculation of groundwater flow

To use the groundwater flow equation to estimate the distribution of hydraulic heads, or the direction and rate of groundwater flow, this partial differential equation (PDE) must be solved. The most common means of analytically solving the diffusion equation in the hydrogeology literature are:

Laplace and Fourier transforms (to reduce the number of dimensions of the PDE),
similarity transform (also called the Boltzmann transform) is commonly how the Theis solution is derived,
separation of variables, which is more useful for non-Cartesian coordinates, and
Green's functions, which is another common method for deriving the Theis solution — from the fundamental solution to the diffusion equation in free space.

No matter which method we use to solve the groundwater flow equation, we need both initial conditions (heads at time (t) = 0) and boundary conditions (representing either the physical boundaries of the domain, or an approximation of the domain beyond that point). Often the initial conditions are supplied to a transient simulation, by a corresponding steady-state simulation (where the time derivative in the groundwater flow equation is set equal to 0).

There are two broad categories of how the (PDE) would be solved; either analytical methods, numerical methods, or something possibly in between. Typically, analytic methods solve the groundwater flow equation under a simplified set of conditions exactly, while numerical methods solve it under more general conditions to an approximation.

Analytic methods

Analytic methods typically use the structure of mathematics to arrive at a simple, elegant solution, but the required derivation for all but the simplest domain geometries can be quite complex (involving non-standard coordinates, conformal mapping, etc.). Analytic solutions typically are also simply an equation, which can give a quick answer based on a few basic parameters. The Theis equation is a very simple (yet still very useful) analytic solution to the groundwater flow equation, typically used to analyze the results of an aquifer test or slug test.

Numerical methods

The topic of numerical methods is quite large, obviously being of use to most fields of engineering and science in general. Numerical methods have been around much longer than computers have (In the 1920s Richardson developed some of the finite difference schemes still in use today, but they were calculated by hand, using paper and pencil, by human "calculators"), but they have become very important through the availability of fast and cheap personal computers. A quick survey of the main numerical methods used in hydrogeology, and some of the most basic principles is below.

There are two broad categories of numerical methods: gridded or discretized methods and non-gridded or mesh-free methods. In the common finite difference method and finite element method (FEM) the domain is completely gridded ("cut" into a grid or mesh of small elements). The analytic element method (AEM) and the boundary integral equation method (BIEM — sometimes also called BEM, or Boundary Element Method) are only discretized at boundaries or along flow elements (line sinks, area sources, etc.), the majority of the domain is mesh-free.

General properties of gridded methods

Gridded Methods like finite difference and finite element methods solve the groundwater flow equation by breaking the problem area (domain) into many small elements (squares, rectangles, triangles, blocks, tetrahedra, etc.) and solving the flow equation for each element (all material properties are assumed constant or possibly linearly variable within an element), then linking together all the elements using conservation of mass across the boundaries between the elements (similar to the divergence theorem). This results in a system which overall approximates the groundwater flow equation, but exactly matches the boundary conditions (the head or flux is specified in the elements which intersect the boundaries).

Finite differences are a way of representing continuous differential operators using discrete intervals (Δx and Δt), and the finite difference methods are based on these (they are derived from a Taylor series). For example the first-order time derivative is often approximated using the following forward finite difference, where the subscripts indicate a discrete time location,

{\frac {\partial h}{\partial t}}=h'(t_{i})\approx {\frac {h_{i}-h_{i-1}}{\Delta t}}.

The forward finite difference approximation is unconditionally stable, but leads to an implicit set of equations (that must be solved using matrix methods, e.g. LU or Cholesky decomposition). The similar backwards difference is only conditionally stable, but it is explicit and can be used to "march" forward in the time direction, solving one grid node at a time (or possibly in parallel, since one node depends only on its immediate neighbors). Rather than the finite difference method, sometimes the Galerkin FEM approximation is used in space (this is different from the type of FEM often used in structural engineering) with finite differences still used in time.

Application of finite difference models

MODFLOW is a well-known example of a general finite difference groundwater flow model. It is developed by the US Geological Survey as a modular and extensible simulation tool for modeling groundwater flow. It is free software developed, documented and distributed by the USGS. Many commercial products have grown up around it, providing graphical user interfaces to its input file based interface, and typically incorporating pre- and post-processing of user data. Many other models have been developed to work with MODFLOW input and output, making linked models which simulate several hydrologic processes possible (flow and transport models, surface water and groundwater models and chemical reaction models), because of the simple, well documented nature of MODFLOW.

Application of finite element models

Finite Element programs are more flexible in design (triangular elements vs. the block elements most finite difference models use) and there are some programs available (SUTRA, a 2D or 3D density-dependent flow model by the USGS; Hydrus, a commercial unsaturated flow model; FEFLOW, a commercial modeling environment for subsurface flow, solute and heat transport processes; and COMSOL Multiphysics (FEMLAB) a commercial general modeling environment), but unless they are gaining in importance they are still not as popular in with practicing hydrogeologists as MODFLOW is. Finite element models are more popular in university and laboratory environments, where specialized models solve non-standard forms of the flow equation (unsaturated flow, density dependent flow, coupled heat and groundwater flow, etc.)

Other methods

These include mesh-free methods like the Analytic Element Method (AEM) and the Boundary Integral Equation Method (BIEM), which are closer to analytic solutions, but they do approximate the groundwater flow equation in some way. The BIEM and AEM exactly solve the groundwater flow equation (perfect mass balance), while approximating the boundary conditions. These methods are more exact and can be much more elegant solutions (like analytic methods are), but have not seen as widespread use outside academic and research groups.

External links and sources

EPA drinking water standards
US Geological Survey water resources homepage — a good place to find free data (for both surface water and groundwater) and free groundwater modeling software like MODFLOW.
US Geological Survery TWRI index — a series of instructional manuals covering common procedures in hydrogeology. They are freely available online as PDF files.
International Ground Water Modeling Center (IGWMC) — an educational repository of groundwater modeling software which offers support for most software, some of which is free.
Decision tree to choose an uncertainty method for hydrogeological and modelling, Choosing an uncertainty analysis for modelling.
GoldSim - Water Resources and Hydrological Modeling