Titanyl

In inorganic chemistry, titanyl refers to the functional group Ti=O, where the oxo ligand is not bridging but terminal. The term is used more loosely to describe many titanium(IV) oxide complexes. For example titanyl sulfate with the formula TiOSO₄, although it does not contain a terminal oxo ligand.

References

^ "{Mono- and Dinuclear Titanium(III)/Titanium(IV) Complexes with 1,4,7-Trimethyl-1,4,7-triazacyclononane (L). Crystal Structures of a Compositionally Disordered Green and a Blue Form of [LTiCl₃]. Structures of [LTi(O)(NCS)₂], [LTi(OCH₃)Br₂](ClO₄), and [L₂Ti₂(O)₂F₂(mu-F)](PF₆)". Inorganic Chemistry. 31: 3737–3748. 1992. doi:10.1021/ic00044a015. {{cite journal}}: Unknown parameter |authors= ignored (help)

[1] "{Mono- and Dinuclear Titanium(III)/Titanium(IV) Complexes with 1,4,7-Trimethyl-1,4,7-triazacyclononane (L). Crystal Structures of a Compositionally Disordered Green and a Blue Form of [LTiCl₃]. Structures of [LTi(O)(NCS)₂], [LTi(OCH₃)Br₂](ClO₄), and [L₂Ti₂(O)₂F₂(mu-F)](PF₆)". Inorganic Chemistry. 31: 3737–3748. 1992. doi:10.1021/ic00044a015. {{cite journal}}: Unknown parameter |authors= ignored (help)

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