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Radiative cooling

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This is an old revision of this page, as edited by Jyot1.5hompad0k (talk | contribs) at 22:35, 23 February 2019 (→Architecture: I have added important architectural designs for passive radiative cooling of buildings. Especially, I mentioned cool roof paints, which are the most common radiative coolers used in buildings but was not mentioned in this article. I also added some notable scientific advances for radiative cooling designs reported since the 1970s, such as photonic structures, paintable porous polymers, polymer and dielectric films on silver mirrors. Appropriate citations have been included.). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Earth's longwave thermal radiation intensity, from clouds, atmosphere and surface.

Radiative cooling is the process by which a body loses heat by thermal radiation.

Terrestrial radiative cooling

Earth's energy budget

Further information: Earth's energy budget

In the case of the Earth-atmosphere system radiative cooling is the process by which long-wave (infrared) radiation is emitted to balance the absorption of short-wave (visible light) energy from the sun.

The exact process by which Earth loses heat is rather more complex than often portrayed. In particular, convective transport of heat, and evaporative transport of latent heat are both important in removing heat from the surface and redistributing it in the atmosphere. Pure radiative transport is more important higher up in the atmosphere. Diurnal and geographical variation further complicate the picture.

The large-scale circulation of the Earth's atmosphere is driven by the difference in absorbed solar radiation per square meter, as the sun heats the Earth more in the Tropics, mostly because of geometrical factors. The atmospheric and oceanic circulation redistributes some of this energy as sensible heat and latent heat partly via the mean flow and partly via eddies, known as cyclones in the atmosphere. Thus the tropics radiate less to space than they would if there were no circulation, and the poles radiate more; however in absolute terms the tropics radiate more energy to space.

Nocturnal surface cooling

Radiative cooling is commonly experienced on cloudless nights, when heat is radiated into space from the surface of the Earth, or from the skin of a human observer. The effect is well-known among amateur astronomers, and can personally be felt on the skin of an observer on a cloudless night. To feel the effect, one compares the difference between looking straight up into a cloudless night sky for several seconds, to that of placing a sheet of paper between one's face and the sky. Since outer space radiates at about a temperature of 3 kelvins (-270 degrees Celsius or -450 degrees Fahrenheit), and the sheet of paper radiates at about 300 kelvins (room temperature), the sheet of paper radiates more heat to one's face than does the darkened cosmos. The effect is blunted by Earth's surrounding atmosphere, and particularly the water vapor it contains, so the apparent temperature of the sky is far warmer than outer space. Note that it is not correct to say that the sheet "blocks the cold" of the night sky; instead, the sheet is radiating heat to your face, just like a camp fire warms your face; the only difference is that a campfire is several hundred degrees warmer than a sheet of paper, just like a sheet of paper (at approximately air temperature) is warmer than the night sky.

The same radiative cooling mechanism can sometimes cause frost or black ice to form on surfaces exposed to the clear night sky, even when the ambient temperature does not fall below freezing.

Kelvin's estimate of the Earth's age

Further information: Age of the Earth

The term radiative cooling is generally used for local processes, though the same principles apply to cooling over geological time, which was first used by Kelvin to estimate the age of the Earth (although his estimate ignored the substantial heat released by radioisotope decay, not known at the time).

Astronomy

Radiative cooling is one of the few ways an object in space can give off energy. In particular, white dwarf stars are no longer generating energy by fusion or gravitational contraction, and have no solar wind. So the only way their temperature changes is by radiative cooling. This makes their temperature as a function of age very predictable, so by observing the temperature, astronomers can deduce the age of the star.[1][2]

Applications

Architecture

Cool roofs combine high solar reflectance with high infrared emittance, thereby simultaneously reducing heat gain from the sun and increasing heat removal through radiation. Radiative cooling thus offers immense potential for supplementary passive cooling to residential and commercial buildings.[3] Traditional building surfaces, such as paint coatings, brick and concrete have high emittances of up to 0.96.[4] Consequently, they radiate heat into the sky to passively cool buildings at night. If made sufficiently reflective to sunlight, these materials can also achieve radiative cooling during the day.

The most common radiative coolers found on buildings are white cool-roof paint coatings, which have solar reflectances of up to 0.94, and a thermal emittances of up to 0.96.[5] The solar reflectance of the paints arises from optical scattering by the dielectric pigments embedded in the polymer paint resin, while the thermal emittance arises from the polymer resin itself. However, because typical white pigments like titanium dioxide and zinc oxide absorb ultraviolet radiation, the solar reflectances of paints based on such pigments do not exceed 0.95. Recently, researchers have developed paintable porous polymer coatings, whose pores scatter sunlight to give solar reflectance of 0.99 and thermal emittance of 0.97.[6] In experiments under direct sunlight, the coatings achieve 6°C sub-ambient temperatures and a cooling power of 96 W/m2.

Other notable radiative cooling strategies include dielectric films on metal mirrors,[7] and polymer or polymer composites on silver or aluminum films.[8] In 2014, researchers developed a multi-layer thermal photonic structure which selectively emits long wavelength infrared radiation into space, and can achieve 5°C sub-ambient cooling under direct sunlight.[9] Silvered polymer films with solar reflectances of 0.97 and thermal emittance of 0.96, which remain 11°C cooler than commercial white paints under the mid-summer sun, have been also been reported.[10] More recently, researchers engineered a metamaterial with resonant polar silica microspheres randomly embedded in a polymeric matrix.[11] The material is transparent to sunlight and has infrared emissivity greater than 0.93. When backed with silver coating, the material achieved a midday radiative cooling power of 93 W/m2 under direct sunshine along with high-throughput, economical roll-to-roll manufacturing

Nocturnal ice making

In India before the invention of artificial refrigeration technology, ice making by nocturnal cooling was common. The apparatus consisted of a shallow ceramic tray with a thin layer of water, placed outdoors with a clear exposure to the night sky. The bottom and sides were insulated with a thick layer of hay. On a clear night the water would lose heat by radiation upwards. Provided the air was calm and not too far above freezing, heat gain from the surrounding air by convection was low enough to allow the water to freeze.[12]

See also

References

  1. ^ Mestel, L. (1952). "On the theory of white dwarf stars. I. The energy sources of white dwarfs". Monthly Notices of the Royal Astronomical Society. 112 (6): 583–597. Bibcode:1952MNRAS.112..583M. doi:10.1093/mnras/112.6.583.{{cite journal}}: CS1 maint: unflagged free DOI (link)
  2. ^ "Cooling white dwarfs" (PDF).
  3. ^ Hossain, Md Muntasir; Gu, Min (2016-02-04). "Radiative cooling: Principles, progress and potentials". Advanced Science. 3 (7): 1500360. doi:10.1002/advs.201500360. ISSN 2198-3844. PMID 27812478.
  4. ^ "Emissivity Coefficients Materials". www.engineeringtoolbox.com. Retrieved 2019-02-23.
  5. ^ "Find rated products - Cool Roof Rating Council". coolroofs.org. Retrieved 2019-02-23.
  6. ^ Mandal, Jyotirmoy; Fu, Yanke; Overvig, Adam; Jia, Mingxin; Sun, Kerui; Shi, Norman Nan; Yu, Nanfang; Yang, Yuan (19 October 2018). "Hierarchically porous polymer coatings for highly efficient passive daytime radiative cooling". Science. 362: 315–319. doi:10.1126/science.aat9513.
  7. ^ Granqvist, C. G.; Hjortsberg, A. (1981-6). "Radiative cooling to low temperatures: General considerations and application to selectively emitting SiO films". Journal of Applied Physics. 52 (6): 4205–4220. doi:10.1063/1.329270. ISSN 0021-8979. {{cite journal}}: Check date values in: |date= (help)
  8. ^ Grenier, Ph. (January 1979). "Réfrigération radiative. Effet de serre inverse". Revue de Physique Appliqee. 14(1): 87–90. doi:10.1051/rphysap:0197900140108700.
  9. ^ Raman, Aaswath P.; Anoma, Marc Abou; Zhu, Linxiao; Rephaeli, Eden; Fan, Shanhui (2014-11). "Passive radiative cooling below ambient air temperature under direct sunlight". Nature. 515 (7528): 540–544. doi:10.1038/nature13883. ISSN 0028-0836. {{cite journal}}: Check date values in: |date= (help)
  10. ^ Gentle, Angus R.; Smith, Geoff B. (2015-9). "A Subambient Open Roof Surface under the Mid-Summer Sun". Advanced Science. 2 (9): 1500119. doi:10.1002/advs.201500119. PMC 5115392. PMID 27980975. {{cite journal}}: Check date values in: |date= (help)CS1 maint: PMC format (link)
  11. ^ Zhai, Yao; Ma, Yaoguang; David, Sabrina N.; Zhao, Dongliang; Lou, Runnan; Tan, Gang; Yang, Ronggui; Yin, Xiaobo (2017-03-10). "Scalable-manufactured randomized glass-polymer hybrid metamaterial for daytime radiative cooling". Science. 355 (6329): 1062–1066. Bibcode:2017Sci...355.1062Z. doi:10.1126/science.aai7899. ISSN 0036-8075. PMID 28183998.
  12. ^ "Lesson 1: History Of Refrigeration, Version 1 ME" (PDF). Indian Institute of Technology Kharagpur. Archived from the original (PDF) on 2011-11-06. {{cite web}}: Unknown parameter |deadurl= ignored (|url-status= suggested) (help)
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