Telluride phosphide

The telluride phosphides are a class of mixed anion compounds containing both telluride and phosphide ions (Te²⁻ P³⁻). The phosphidotelluride or telluridophosphide compounds have a [TeP]³⁻ group in which the tellurium atom has a bond to the phosphorus atom. A formal charge of −2 is on the phosphorus and −1 on the tellurium. There is no binary compound of tellurium and phosphorus.

The titanium group elements form layered hexagonal crystals that can be exfoliated to Monolayers.^[1]

List

Artificial

name	formula	ratio Te:P	system	space group	unit cell Å	volume	density	optical	band gap		references
	PTe		gas phase								^[2]
	P₄S₂Te		molecular								^[2]
	P₄STe₂		molecular								^[2]
	Ti₂PTe₂		hexagonal	R3_m	a=3.6387 c=28.486			metallic	on c axis	also monolayer	^[2]
	Zr₂PTe₂		rhombohedral	R3_m	a=3.8117 c=29.189 Z=3	367.27	6.356	black		also monolayer	^[3]
	RuTeP										^[4]
	BaP₄Te		orthorhombic	Pnma with	a =16.486 b =6.484 c =7.076 Z =4						^[2]^[5]
	CeP_0.4Te_1.6										^[2]
	CeP_1.1Te_0.9										^[2]
cerium phosphide telluride	Ce₃Te₃P	3:1									^[6]
	Hf₂Te₂P			R3_m	a=3.7946 c=29.14					also monolayer	^[1]
	IrTeP		orthorhombic		a=6.030 b=6.131 c=12.132						^[7]
	OsTeP		arsenopyrite structure	P2₁/c	a = 6.2291 b = 6.1604 c = 6.2449 β = 112.01°	222.2	10.43				^[8]
	UPTe		tetragonal		a=4.100 c=17.026						^[9]
	NpPTe		tetragonal	P4/nmm	a=4.265 c=9.067						^[9]
	PuPTe		tetragonal	P4/nmm	a=4.289 c=9.098						^[9]
	AmPTe		tetragonal	P4/nmm	a=4.269 c=9.050						^[9]

References

^ ^a ^b Chen, K-W; Das, S; Rhodes, D; Memaran, S; Besara, T; Siegrist, T; Manousakis, E; Balicas, L; Baumbach, R E (2016-04-13). "Uncovering the behavior of Hf 2 Te 2 P and the candidate Dirac metal Zr 2 Te 2 P". Journal of Physics: Condensed Matter. 28 (14): 14LT01. doi:10.1088/0953-8984/28/14/14LT01. ISSN 0953-8984.
^ ^a ^b ^c ^d ^e ^f ^g Philipp, Frauke (16 October 2008). "Prinzipien der Syntheseplanung in der anorganischen Festkörperchemie: Analyse der Phasenbildung in Systemen M/P/Te, M = Ti, Ce, Si". Qucosa.{{cite web}}: CS1 maint: url-status (link)
^ Tschulik, Kristina; Ruck, Michael; Binnewies, Michael; Milke, Edgar; Hoffmann, Stefan; Schnelle, Walter; Fokwa, Boniface P. T.; Gilleßen, Michael; Schmidt, Peer (July 2009). "Chemistry and Physical Properties of the Phosphide Telluride Zr 2 PTe 2". European Journal of Inorganic Chemistry. 2009 (21): 3102–3110. doi:10.1002/ejic.200900346.
^ Zintl, E. (1939-01-07). "Intermetallische Verbindungen". Angewandte Chemie (in German). 52 (1): 1–6. doi:10.1002/ange.19390520102.
^ Jörgens, Stefan; Johrendt, Dirk; Mewis, Albrecht (2003-06-06). "BaP4Te2—A Ternary Telluride with P-Te Bonds and a Structural Fragment of Black Phosphorus". Chemistry - A European Journal. 9 (11): 2405–2410. doi:10.1002/chem.200304858.
^ Schmidt, Peer; Dallmann, Hannelore; Kadner, Gudrun; Krug, Jutta; Philipp, Frauke; Teske, Klaus (October 2009). "The thermochemical behaviour of Te8O10(PO4)4 and its use for phosphide telluride synthesis". Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie. 635 (13–14): 2153. doi:10.1002/zaac.200900350.
^ Kliche, Gerhard (1986-01-01). "NOTIZEN: Iridiumphosphidtellurid, IrPTe / Iridium Phosphide Telluride, IrPTe". Zeitschrift für Naturforschung B. 41 (1): 130–131. doi:10.1515/znb-1986-0126. ISSN 1865-7117.
^ Lutz, H. D.; Schmidt, Th.; Wäschenbach, G. (1988). "Phasendiagramme von Chalkogeniden und Pnictiden des Rutheniums und Osmiums mit Pyrit-, Markasit-, Löllingit‐ und Arsenopyritstruktur". Zeitschrift für anorganische und allgemeine Chemie (in German). 562 (1): 7–16. doi:10.1002/zaac.19885620102. ISSN 0044-2313.
^ ^a ^b ^c ^d . pp. 153–154. ISBN 9783540456841. {{cite book}}: Missing or empty |title= (help)

[:2-1] Chen, K-W; Das, S; Rhodes, D; Memaran, S; Besara, T; Siegrist, T; Manousakis, E; Balicas, L; Baumbach, R E (2016-04-13). "Uncovering the behavior of Hf 2 Te 2 P and the candidate Dirac metal Zr 2 Te 2 P". Journal of Physics: Condensed Matter. 28 (14): 14LT01. doi:10.1088/0953-8984/28/14/14LT01. ISSN 0953-8984.

[:1-2] ^ ^a ^b ^c ^d ^e ^f ^g Philipp, Frauke (16 October 2008). "Prinzipien der Syntheseplanung in der anorganischen Festkörperchemie: Analyse der Phasenbildung in Systemen M/P/Te, M = Ti, Ce, Si". Qucosa.{{cite web}}: CS1 maint: url-status (link)

[3] Tschulik, Kristina; Ruck, Michael; Binnewies, Michael; Milke, Edgar; Hoffmann, Stefan; Schnelle, Walter; Fokwa, Boniface P. T.; Gilleßen, Michael; Schmidt, Peer (July 2009). "Chemistry and Physical Properties of the Phosphide Telluride Zr 2 PTe 2". European Journal of Inorganic Chemistry. 2009 (21): 3102–3110. doi:10.1002/ejic.200900346.

[4] Zintl, E. (1939-01-07). "Intermetallische Verbindungen". Angewandte Chemie (in German). 52 (1): 1–6. doi:10.1002/ange.19390520102.

[5] Jörgens, Stefan; Johrendt, Dirk; Mewis, Albrecht (2003-06-06). "BaP4Te2—A Ternary Telluride with P-Te Bonds and a Structural Fragment of Black Phosphorus". Chemistry - A European Journal. 9 (11): 2405–2410. doi:10.1002/chem.200304858.

[6] Schmidt, Peer; Dallmann, Hannelore; Kadner, Gudrun; Krug, Jutta; Philipp, Frauke; Teske, Klaus (October 2009). "The thermochemical behaviour of Te8O10(PO4)4 and its use for phosphide telluride synthesis". Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie. 635 (13–14): 2153. doi:10.1002/zaac.200900350.

[7] Kliche, Gerhard (1986-01-01). "NOTIZEN: Iridiumphosphidtellurid, IrPTe / Iridium Phosphide Telluride, IrPTe". Zeitschrift für Naturforschung B. 41 (1): 130–131. doi:10.1515/znb-1986-0126. ISSN 1865-7117.

[8] Lutz, H. D.; Schmidt, Th.; Wäschenbach, G. (1988). "Phasendiagramme von Chalkogeniden und Pnictiden des Rutheniums und Osmiums mit Pyrit-, Markasit-, Löllingit‐ und Arsenopyritstruktur". Zeitschrift für anorganische und allgemeine Chemie (in German). 562 (1): 7–16. doi:10.1002/zaac.19885620102. ISSN 0044-2313.

[:0-9] . pp. 153–154. ISBN 9783540456841. {{cite book}}: Missing or empty |title= (help)

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