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Bowen's reaction series

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Discontinuous
Series
Continuous
Series
High
OlivinePlagioclase
(Calcium rich)
Pyroxene
Amphibole
Biotite
(Black Mica)
Plagioclase
(Sodium rich)
Relative
Crystallization
Temperature
Orthoclase
Muscovite
(White Mica)
Quartz
Low

Within the field of geology, Bowen's reaction series is the work of the petrologist Norman L. Bowen,[1] who summarized, based on experiments and observations of natural rocks, the sequence of crystallization of common silicate minerals from typical basaltic magma undergoing fractional crystallization (i.e. crystallization wherein early-formed crystals are removed from the magma by crystal settling, leaving behind a liquid of slightly different composition).[2] Bowen's reaction series is able to explain why certain types of minerals tend to be found together while others are almost never associated with one another. He experimented in the early 1900s with powdered rock material that was heated until it melted and then allowed to cool to a target temperature whereupon he observed the types of minerals that formed in the rocks produced. He repeated this process with progressively cooler temperatures and the results he obtained led him to formulate his reaction series which is still accepted today as the idealized progression of minerals produced by cooling basaltic magma that undergoes fractional crystallization. Based upon Bowen's work, one can infer from the minerals present in a rock the relative conditions under which the material had formed.[3]

Description

Olivine weathering to iddingsite within a mantle xenolith, demonstrating the principles of the Goldich dissolution series
Bowen's Reaction Series

The series is broken into two branches, the continuous and the discontinuous. The branch on the right is the continuous. The minerals at the top of the illustration (given aside) are first to crystallize and so the temperature gradient can be read to be from high to low with the high temperature minerals being on the top and the low temperature ones on the bottom. Minerals such as olivine will crystallize at a higher temperature, as magma cools. Since the surface of the Earth is a low temperature environment compared to the zones of rock formation, the chart also easily shows the stability of minerals with the ones at bottom being most stable and the ones at top being quickest to weather, known as the Goldich dissolution series. This is because minerals are most stable in the conditions closest to those under which they had formed. On the other hand, the low temperature minerals are much more stable because the conditions at the surface are much more similar to the conditions under which they formed.

References

  1. ^ Tilley, C. E. (1957). "Norman Levi Bowen 1887-1956". Biographical Memoirs of Fellows of the Royal Society. 3: 6–26. doi:10.1098/rsbm.1957.0002. JSTOR 769349.
  2. ^ Bowen, N.L. (1956). The Evolution of the Igneous Rocks. Canada: Dover. pp. 60–62.
  3. ^ Klein, Cornelis and Cornelius S. Hurlbut, Jr., Manual of Mineralogy, Wiley, 20th ed. 1985, p. 476 ISBN 0-471-80580-7