Detergent enzymes
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Laundry enzymes refer to the enzymes that are frequently used in the laundry industry.[1] They usually exist as little blue particles or flecks in both liquid and powder detergents. On contact with water they dissolve rapidly, boosting the rate of the reaction between stains and the aqueous solution by acting as a catalyst.[2] Therefore, laundry enzymes are good at stain removal. The addition of laundry enzymes in detergent products improves laundry efficiency and also makes the process more environmentally friendly, and thus detergent manufacturers are willing to update the products with laundry enzyme formula added.[1]
Laundry enzyme is still the largest industrial enzyme application[3] and thus plays a significant role in helping both household laundry and the relative industrial business.[1] With the consumers' high interest in new bio-technique gradually growing, laundry enzyme detergents are becoming more and more popular in the globe, which reveals the success of laundry enzyme's application in the industry. However, there are still several concerns from consumers brought by laundry enzymes such as the potential allergies and cloth damages, but current experimental shows the concerns are unnecessary.[4]
History
Otto Röhm introduced the use of enzymes in detergent, to which he added trypsin extracted from the tissues of slaughtered animals. Röhm's formula, though successful compared to the traditional cleaning methods employed in German households, was considered unstable when dealing with alkali and bleach.[clarification needed] In 1959 yields were improved by microbial synthesis of proteases.[5]
Properties
Laundry enzymes must be able to function normally in a wide array of adverse conditions: water temperatures as high as 60°C. or as low as 0℃.; alkaline and acidic environments; solutions with high ionic strength; and the presence of surfactants or oxidizing agents.[6][3]
Types
 | This section is missing information about more information on the enzymes: what kind of enzymes? Subtilisin-like proteases (PMID 25579194)? What organisms produce these hardy enzymes? Is site-directed mutation used?. |
The five classes of enzymes found in laundry detergent include proteases, amylases, lipases, cellulases, and mannanases. They break down proteins (e.g. in blood and egg stain), starch, fats, cellulose (e.g. in vegetable puree), and mannans (e.g. in bean gum stain) respectively.[3]
Merits
Household energy saving
Conventionally, the household laundering machine would heat up the tap water to provide a better laundry condition for the dirty stain on the cloth to dissolve.[7] This is because most stubborn stain have better solubility in the hot solvent. However, the energy used in this process is not negligible and thus it is a cost-worthy way to do traditional household laundering. After laundry enzymes were introduced into the market, the situation has been improved significantly. For energy saving, there are no longer extra usage of high temperature in household or dishwashers because the temperature used has been lessened recently.[3] It is mentioned that laundry enzymes are still in highest performance even in cold tap water, and thus for most of the household laundry, there is no need to heat up for a household washing machine to heat up the tap water. From this perspective, laundry enzymes are considered indispensable in helping save household bills[7]
A wider variety of clothes at one time
As a consequential benefit, consumers can freely choose a larger range of clothes with diverse materials. Lower temperature laundry condition allows more delicate materials like wool and silk that are easily affected when placed into a high-temperature environment. Moreover, lower temperature also avoids fading jeans and denim which are usually dyed with dark colors. Thus there will be less color transfer.[7]
Better laundry process for leather manufacture
There is another evidence that emphasizes the merits of using laundry enzyme in the leather industry. The traditional procedure was complex. First, animal hides with a mixture of urine and lime were soaked altogether to get rid of unwanted hairs, flesh, and fat.[8] Then, the skins were softened by kneading them in dogs or pigeons' feces, which was usually done with bare feet.[8] What really made the leather industry infamous was the discharges and refuse disposal. They caused severe hazards and problem both on human health and environmental eco-system because of the enormous amount of effluents with highly concentrated sulfide and chromium.[9] Therefore, leather making was considered a noxious and redundant trade without any doubt.[8] After laundry enzymes were introduced into the leather pre-treating procedure, the leather industry discarded the foul method[8] to pre-process the leather and also the situation has changed apparently better.[7] The use of sodium sulfide, a hazardous iconic compound to remove hair from animal hides, is lessened by 60%,[8] water usage for soaking and hair cut is lowered by 25%,[8] the most remarkable one is toxic pollution and emission has been greatly reduced by 30%.[8] These laundry enzymes have never completely substituted the industrial chemical compounds, nevertheless the working conditions, wastewater and the processing time have been greatly improved.
Phosphate and synthetic surfactants' replacement
With the more completed legislative files and contexts coming towards the laundry industry. The environmentally unfriendly synthetic surfactants and phosphate salts are no longer allowed to use without any usage limit. Consequently, synthetic surfactants are then used with lower concentration in combination with enzymes.[10] Currently, laundry industry manufacturers have recognized the importance of producing environmentally friendly detergents, and to fulfill the achievement, laundry enzymes have been added to reformulate the detergent and replace the previous chemical surfactants and phosphate.[10] Laundry enzymes are biological active factors such as bacteria, yeast or even mushrooms[11] that are biologically sourced, and hence there will be less chemical pollution from the enzymes and they decompose some toxicants[10]
Public concerns
Damage to jeans
Indeed, it is found that the laundry enzyme has a side effect on the cloth made from delicate materials. According to the test, untreated knit and woolen fabrics were soaked in a solution with household laundry enzyme formulation.[12] Other variables, time and temperature up to 10 days and 40℃ respectively, were kept constant.[12] As a result, it was found that the loss in strength was proportional to both soaking time and the laundry enzyme concentration[12] and these materials were weakened also to some extent.[12] The loss was also accompanying with reduced mass and the relationship between the loss and soaking time was linearly logarithmic, suggesting laundry enzymes would damage the fragile textile if soaked for a long time.[12]
Skin allergy and testing
After laundry enzymes have been popular for a few decades, consumers’ response also varies personally. It is reported that some Philippine consumers who are used to laundering by hand slightly suffered from powder detergents and the noticeable granular components were found to be mainly with laundry enzyme formulation. As a result, it was thought that laundry enzymes have the potential to increase the likelihood of getting occupational type 1 allergic responses. [4] However, a large-scale skin prick test (SPT) containing 15,765 volunteers with 8 different types of laundry enzymes finds that the allergy reaction is extremely rare among the public, with only 0.23% showing an reaction.[13] The issue in Filipino consumers are said to be the mighty and rush way of rubbing laundry with hands.[4] After various tests with abundant volunteers worldwide, it is found that exposure to laundry enzymes leads to neither skin allergy (Type I sensitization) nor skin erosion.[4][13]
See also
References
- ^ a b c Berg, Jeremy M. (Jeremy Mark), 1958- (2002). Biochemistry. Tymoczko, John L., 1948-, Stryer, Lubert., Stryer, Lubert. (5th ed.). New York: W.H. Freeman. ISBN 0716730510. OCLC 48055706.
{{cite book}}: CS1 maint: multiple names: authors list (link) CS1 maint: numeric names: authors list (link) - ^ "Cosmetics & Toiletries & Household Products Marketing News in Japan". Pacific Research Consulting, Inc. February 25, 2009.
- ^ a b c d Kirk, Ole; Borchert, Torben; Fuglsang, Claus (1 August 2002). "Industrial enzyme applications". Current Opinion in Biotechnology. 13 (4): 345–351. doi:10.1016/s0958-1669(02)00328-2. PMID 12323357.
- ^ a b c d SARLO, K; CORMIER, E; MACKENZIE, D; SCOTT, L (January 1996). "749 Lack of type I sensitization to laundry enzymes among consumers in the Philippines". Journal of Allergy and Clinical Immunology. 97 (1): 370. doi:10.1016/s0091-6749(96)80967-5. ISSN 0091-6749.
- ^ Leisola, Matti; Jokela, Jouni; Pastinen, Ossi; Turunen, Ossi; Schoemaker, Hans. "INDUSTRIAL USE OF ENZYMES" (PDF). Physiology and Maintenance. II: 2–3.
- ^ Yim, Joung Han; Lee, Jun Hyuck; Koo, Bon-Hun; Kim, Jung Eun; Han, Se Jong; Do, Hackwon; Kim, Dockyu; Lee, Chang Woo; Park, Ha Ju (2018-02-21). "Crystal structure of a cold-active protease (Pro21717) from the psychrophilic bacterium, Pseudoalteromonas arctica PAMC 21717, at 1.4 Å resolution: Structural adaptations to cold and functional analysis of a laundry detergent enzyme". PLOS ONE. 13 (2): e0191740. Bibcode:2018PLoSO..1391740P. doi:10.1371/journal.pone.0191740. ISSN 1932-6203. PMC 5821440. PMID 29466378.
{{cite journal}}: CS1 maint: unflagged free DOI (link) - ^ a b c d "Enzymes in Biological Detergents – The Facts About Laundry Detergents and How They Work". Persil UK. Retrieved 2019-05-19.
- ^ a b c d e f g says, Novozymes. "From excrement to enzyme: How biotech helped clean up leather production – Rethink Tomorrow". Retrieved 2019-05-19.
- ^ Choudhary, R; Jana, A; Jha, M (September 2004). "Enzyme technology applications in leather processing" (PDF). Indian Journal of Chemical Technology. 11: 659–671.
- ^ a b c Gaubert, Alexandra; Jeudy, Jérémy; Rougemont, Blandine; Bordes, Claire; Lemoine, Jérôme; Casabianca, Hervé; Salvador, Arnaud (2016-07-01). "Identification and absolute quantification of enzymes in laundry detergents by liquid chromatography tandem mass spectrometry". Analytical and Bioanalytical Chemistry. 408 (17): 4669–4681. doi:10.1007/s00216-016-9550-8. ISSN 1618-2650. PMID 27098933. S2CID 39950551.
- ^ Waldhoff, Heinrich; Spilker, Rudiger, eds. (2016-04-19). Handbook Of Detergents, Part C. doi:10.1201/9781420030334. ISBN 9780429132605.
- ^ a b c d e Friedman, Mendel (April 1971). "Effect of Enzymes and Enzyme-Containing Detergent On Strength of Untreated Woolen Fabrics". Textile Research Journal. 41 (4): 315–318. doi:10.1177/004051757104100405. ISSN 0040-5175. S2CID 137326402.
- ^ a b Sarlo, Katherine; Kirchner, Donald B.; Troyano, Esperanza; Smith, Larry A.; Carr, Gregory J.; Rodriguez, Carlos (May 2010). "Assessing the risk of type 1 allergy to enzymes present in laundry and cleaning products: Evidence from the clinical data". Toxicology. 271 (3): 87–93. doi:10.1016/j.tox.2010.03.007. ISSN 0300-483X. PMID 20223268.